DE183139C - - Google Patents
Info
- Publication number
- DE183139C DE183139C DENDAT183139D DE183139DA DE183139C DE 183139 C DE183139 C DE 183139C DE NDAT183139 D DENDAT183139 D DE NDAT183139D DE 183139D A DE183139D A DE 183139DA DE 183139 C DE183139 C DE 183139C
- Authority
- DE
- Germany
- Prior art keywords
- parts
- gas
- alcohol
- distillation
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- 238000004821 distillation Methods 0.000 claims description 3
- 239000002023 wood Substances 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 2
- 238000005406 washing Methods 0.000 claims description 2
- 239000003398 denaturant Substances 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- CSCPPACGZOOCGX-UHFFFAOYSA-N acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 4
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- XXROGKLTLUQVRX-UHFFFAOYSA-N Allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 description 2
- 238000004925 denaturation Methods 0.000 description 2
- 230000036425 denaturation Effects 0.000 description 2
- 238000004508 fractional distillation Methods 0.000 description 2
- 150000002576 ketones Chemical class 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- 238000000197 pyrolysis Methods 0.000 description 2
- RWGFKTVRMDUZSP-UHFFFAOYSA-N Cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 description 1
- HFPZCAJZSCWRBC-UHFFFAOYSA-N P-Cymene Chemical compound CC(C)C1=CC=C(C)C=C1 HFPZCAJZSCWRBC-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 239000003034 coal gas Substances 0.000 description 1
- 229930007927 cymenes Natural products 0.000 description 1
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 1
- 150000002240 furans Chemical class 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 150000003222 pyridines Chemical class 0.000 description 1
- 238000004153 renaturation Methods 0.000 description 1
- -1 saturated benzene hydrocarbons Chemical class 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003505 terpenes Chemical class 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12F—RECOVERY OF BY-PRODUCTS OF FERMENTED SOLUTIONS; DENATURED ALCOHOL; PREPARATION THEREOF
- C12F5/00—Preparation of denatured alcohol
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Bioinformatics & Cheminformatics (AREA)
- General Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Genetics & Genomics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Medicines Containing Plant Substances (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
Description
besesp
&i>Ci cjjcvi 3a I'c 11 tar 1η Ib.
iiHicjfc, iit otii 11/1 it It mg &i> Ci cjjcvi 3a I'c 11 tar 1η Ib.
iiHicjfc, iit otii 11/1 it It mg
KAISERLICHESIMPERIAL
PATENTAMT.PATENT OFFICE.
PATENTSCHRIFTPATENT LETTERING
- M 183139 -. KLASSE 6ö. GRUPPE- M 183139 -. CLASS 6ö. GROUP
PAUL LJUBIMOFF und FRIEDRICH ENGEL in MOSKAU.PAUL LJUBIMOFF and FRIEDRICH ENGEL in MOSCOW.
Unser Mittel zur Denaturierung von Spiritus besteht aus zwei Flüssigkeiten, die wir im folgenden als Nr. I und II bezeichnen wollen, welche aus den Rückständen der trockenen Destillation des Holzes behufs . Gewinnung von Leuchtgas gewonnen werden.Our means of denaturing alcohol consists of two liquids that we use in the want to designate the following as No. I and II, which from the residues of the dry Distillation of the wood for the purpose. Obtaining coal gas can be obtained.
Flüssigkeit Nr. I ist das Ergebnis der nochmaligen Destillation des Gaswaschwassers, welches durch fraktionierte Destillation zwisehen 38 und 90 ° C. aufgefangen wird. Diese Fraktion ist von hellgrüner Farbe, vollständig klar und enthält in 100 Teilen: Kohlenwasserstoffe der zweiten Azetylenreihe 24, Methylalkohol 11, Allylalkohol 4,5, Acetone und Ketone 14, Aldehyde 11,5, Hydrosine 6, Pyridinbasen 0,9, Furanverbindungen 3,6, Äther 7,5, Wasser 14, im ganzen 97,5 Teile. Spezifisches Gewicht etwa 0,875; Stärkegrad nach Tralles 68 bis 70 °. In Wasser leicht löslich.Liquid No. I is the result of the repeated distillation of the gas washing water, which is collected by fractional distillation between 38 and 90 ° C. These Fraction is light green in color, completely clear and contains in 100 parts: hydrocarbons of the second acetylene series 24, methyl alcohol 11, allyl alcohol 4,5, acetone and Ketones 14, aldehydes 11.5, hydrosines 6, pyridine bases 0.9, furan compounds 3.6, ether 7.5, water 14, a total of 97.5 parts. Specific Weight about 0.875; Degree of strength according to Tralles 68 to 70 °. Easily soluble in water.
Flüssigkeit Nr. II wird gleichfalls aus den Rückständen der trockenen Destillation des Holzes gewonnen, und zwar aus den dunkelrotbraunen teerigen Stoffen, welche sich während des Überganges des Gases in den Gasometer in den Röhren und Behältern ansammeln. Diese dunkelrotbraunen Rückstände werden einer fraktionierten Destillation unterzogen; die Fraktion von 68 bis 125° C. wird zuerst aufgefangen, alsdann die Fraktion von 125 bis 185 ° C., welch letzterer auch noch der obere Teil der öligen Abscheidungen der Fraktion 68 bis 125 ° C. hinzugefügt werden kann. Diese vereinigten Destillate werden 35 Liquid No. II is also obtained from the residues of the dry distillation of the wood, namely from the dark red-brown tarry substances which accumulate in the tubes and containers during the passage of the gas into the gasometer. These dark red-brown residues are subjected to a fractional distillation; the fraction from 68 to 125 ° C. is collected first, then the fraction from 125 to 185 ° C., to which the upper part of the oily deposits of fraction 68 to 125 ° C. can be added. These combined distillates turn 35
4040
behufs Reinigung von harzigen Bestandteilen mittels wiederholter Destillation gereinigt. Das Resultat ist von gelbgrünlicher Farbe, durchsichtig klar, hat ein spezifisches Gewicht von etwa 0,905 und eine Stärke von 63 bis 65 ° Tralles, ist in Wasser unlöslich und enthält in 100 Teilen: Methylalkohol 3,6, Allylalkohol 7,6, Acetone und Ketone 10, gesättigte Benzolkohlenwasserstoffe 10,5, Kohlenwasserstoffe der Reihe CqH12 (Cumole) 7,3, Pyridine und Collidine 16,2, Kohlenwasserstoffe der Reihe C10 .H14 (Cymole) 9,8, Terpene 9,6, Hydronaphtaline 3,8, Äther 4,2, Wasser 9,3, harzige Rückstände 5,8 Teile.Purified for the purification of resinous components by means of repeated distillation. The result is yellow-greenish in color, transparent, has a specific gravity of about 0.905 and a strength of 63 to 65 ° Tralles, is insoluble in water and contains in 100 parts: methyl alcohol 3.6, allyl alcohol 7.6, acetones and ketones 10, saturated benzene hydrocarbons 10.5, hydrocarbons of the series CqH 12 (cumene) 7.3, pyridines and collidines 16.2, hydrocarbons of the series C 10, H 14 (cymene) 9.8, terpenes 9.6, hydronaphthalins 3, 8, ether 4.2, water 9.3, resinous residue 5.8 parts.
Die vorstehend beschriebenen Flüssigkeiten Nr. I und II werden behufs Denaturierung zu gleichen Teilen, je 1,5 bis 2,5 Prozent, dem Spiritus beigefügt, also im ganzen 3 bis 5 Teile beider Flüssigkeiten auf 100 Teile Spiritus. Bereits eine Beimengung von 3 Prozent schließt eine lohnende Renaturierung aus, während eine verstärkte Beimengung, bis etwa 5 Prozent, dieselbe unmöglich macht. " Der nach unserem Verfahren denaturierte Spiritus ist als Genußmittel seines stark adstringierenden, brenzligen, Widerwillen erregenden Geschmackes wegen nicht verwendbar. Mit Wasser verdünnt, opalisiert er.The liquids Nos. I and II described above are used for denaturation in equal parts, 1.5 to 2.5 percent each, added to the spirit, i.e. a total of 3 to 5 parts of both liquids to 100 parts of alcohol. Already an admixture of 3 percent excludes a worthwhile renaturation, while an increased admixture, up to about 5 percent, makes the same impossible. "The one denatured by our process As a stimulant, alcohol is its strongly astringent, burdensome, reluctant Cannot be used due to taste. When diluted with water, it becomes opalescent.
Durch nach unserem Verfahren erwirkte Denaturierung wird der Spiritus in seinem Charakter in keiner Weise nachteilig beeinflußt, verliert fast nichts an Stärke und verbrennt ohne Rückstand, genügt daher inDue to the denaturation achieved by our method, the alcohol becomes in his Character does not adversely affect in any way, loses almost nothing of strength and burns with no residue, so in
weitestem Sinne alien technischen Anforderungen. in the broadest sense, all technical requirements.
Claims (1)
Rückständen der Destillation von Holz
zwecks Leuchtgasgewinnung, dadurch geProcess for the manufacture and use of denaturants
Residues from the distillation of wood
for the purpose of illuminating gas, thereby ge
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE183139C true DE183139C (en) |
Family
ID=447172
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT183139D Active DE183139C (en) |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE183139C (en) |
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0
- DE DENDAT183139D patent/DE183139C/de active Active
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