DE1792657A1 - Process for the production of consumable products - Google Patents

Description

Dlpi.-Pnyt. C. OetZler FmlHgrethetr ^ · «PoMtach 1«

Dlpl.-Ing. W. Herrmann-Trentepohl Fen ^ redwrH.rn.eoeaounde ««

Telex: 08229865 PATENTANWÄLTE «" ^ n ^.

Γ Π MM MMMn Ο, der / ⁷ ' ^bt ^ «68

Elaanachw Strata 17 Telephonist: 388011, 3βββ12, 3β »13

Telex: 06Mi "

01 1 16 B / il AWmNf. II
In answer

for the production of consumable products »

Jie Uriindang "concerns a procedure for the production of fully verraucrioaren products by the addition of the boiu" smoking entotelienden hint of aromatic substances 3U aiii AuQ _ü ancs :: aat3rial, like tobacco, in particular ^ ülltabalr, 2ab? J: folieii, ΓatztabaJcen, ^ ab .: τΙοι-αη auai smoking, for example in Sißarettencler Siearrenfor ^ üOei ^ -ieten materials.

oc

.. "- af _S a-) e dar Jrf.inclunc is eo, Auscan ^ Siaaterialien, vii 'feba;:, in particular Plältabalc, uabakfolien, ^ rsatata r.ber also Tabal.-oroatz and other possibly completely loose ujac: - nneutral, -liLDn capable substances ^ u aromatize, '\ r £ -Ho Crrundnoto des Auggaiitiamat ^ riale so far changed - / id / zorbessort that a ucrtvolloa:' aba]: prouu :: ten {>leio''ii;uset; .

In the event that they are to be added to the initial material, the

109846/1503

A touch, aronatisisrenden substances can be produced from as far as possible militia materials and thus, if necessary, a fully-fledged good that does not die from dear labakpflanse. contains end product s verrauchbares uit full ^r Dabakg3sahmack ersielt be *

In particular, however, the invention is also intended to ensure that the sabak's own basic smoking area is / is independent of the location of the cultivation areas of the Bx ^ ÄUgungsjahrgai-ge or 'labaktypisierungen. amplified &&& xt produces v / ground, whereby the tobacco smoke of the starting material treated according to the invention leads to a greater taste-content, even in cases of such tabaJ-ce as starting material, which in itself are aromatic or "such" Gliiiinable neutral substances that have no aroma at all. This ira Price naturgeiaä-i to be estimated low 'tobaccos or Ausgan ^ SJaateriallen vrerde.n by the ancestors gemä3 the invention arOi.oactarkeii and therefore Legelfall also expensive tobaccos _i ^GCSC:;: approximated cklich vreitgehendst Uc?.

It is already known IDagasttabatefaaern geselnaac.viich to improve by the fact that a given ' a 3xtr? jction treatment- under Extraction of the water-soluble non-aromatic substances - is undergone. Baftmrek

ΛΐΌ'.1 ", GtOfTe des 2abalrs won., Which in 3? Orn of a Jroc.": E: .e :: tra ": ts a carrier substance made of cellulose or Letr ^ -l ^ ellulossei-iaterial mixed in, whereupon di ;? 1IiCc] IiUiJ zn ₁ vo fibers: ii "cross-section of the natural, 3IR; .- 32nd? Z : *. ^ R.re11em; iisc.'rang based on the 1st T a.Tjal: faöern V3r ^ _po: i: i3 ^ v; ird.

The ? J \; eo!.: This procedure is aussc! Ilie.11ic ^: i the establishment of an Eunstta "bal: s, which is free from the detrimental woody good ;. Sollulose "consisted of tobacco. The starting material ■ for the extraction of the aroma substances is a given one [iaoalai: *. Seining.

Iis is further known to use sabak or tabalaniscliungen Dxtralcten of labal: or certain fractions of ■ 2a.ba .-: e :: treat tracts au to avoid quality fluctuations to balance within given tobacco blends or to improve flavored tobacco. Because of this However, it is not possible to use a given procedure 2a.balnniscb.ung in their taste properties differently than by using the unextracted TabaJrs within the tobacco blend to be supplemented would also be possible. According to this method, only the ""! Wake is tracked within a tobacco

109848/1663

1732657

/1 _
'τ -

mixture a favorable distribution dor Aros & stoffe now Strive to compensate for quality fluctuations, or the flavoring substances within the roughly the sigarettenfLilliirig

ΥΟΓ: '.

forming 2abakctrangs no c; i3uordnon, ca.C they hatchetrom and are not guided to the smoker, ojine that a large part of them remains within the cellular structure and is decomposed by the forward-leading G-lutaone GD '/ fait and pjTolvtiscli. Here, too, the starting material for the extracts used to treat the ^ ab ^ cs ο (".or of the 2abaiaa mixtures is again a 'labalc.

The same purpose pursues a different process, according to which Tabalcextralcte freeze-dried and ds more concentrated Powdered flavor carrier on terrible Inferior tobacco can be applied. In this process, too, the "tobacco tracts from Sabakon" are obtained.

! According to other known processes, certain chemical compounds are added to the! tobacco smoke of the so treated! Tobacco are supposed to imprint certain flavors! However, "Jine such treatment of tobacco leads to liegelfäll unilateral G-esclunacksverschiebungen within the Raucligeschmackbouquets. Article from soTdlhen 'fabaken be dalier rejected by consumers as tabakentfremdet. Examples of such chemical compounds

109848/1563 bad original

are mentioned:

4- (2-butenylidene) -3 , 5 > 5-trine thyl-S-cyclolieren-i -bn., Which gives the 2abak a whistle!

4i 4 ", 3 * ^ ™ 2etrahydro-4> 4 _} 7-triinet! Iyl-2- (3E) -naphthalenone, 4 ~ (4-0-0-2, S, 3-triaiet} iyl-2" c3rcloliexeii -1 -Vl) -I, 3-dutadiene.

2-AcGtyl ~ 5-I-ethylpyrrole snr determination of a!

ÜacL. ci: ae: vi other known yerfalire: iv / earth dea! tobacco OC, /^-``c.ii^-3 saturated ^ -lactones rai ^ e ^ eOeii., whose pliysiolo- (juGche unuedenlcliGliIzeit is unselected, .and - whose 7ervjendun ^ sick alone forbids solion for this reason »

Loie Lüf ^ abe, improve tobaccos in their G-rundarona six without them tabakfrerade to give G-esclTiii-acIrslcomponenteii, .l: durcli axm the methods listed above provided they do not end orrcrahierte labakgesamtinhaltsstoffe verv /, or only unsatisfactory be solved . The use of OiabsJiinhaltsstoffe ^ which were previously extracted from Sabak, is no longer justifiable today for economic reasons, even if the extraction material consists of, for example, waste from the cigarette industry. 3olehe waste is in the

Tobacco processing industry processed into iabak foils according to known methods, in which they alc τοίΐ-vjertiges scorn material again your processing proso. ⁰ are available.

The lirfindung solves the problem of a ι optionally completely gescliinacksnsutralen, gliimnf aiii gen Ausi7a \ £; cnryb3s: tos give z \ i, characterized in that any of: i the properties ei.-.es vol rerti ^ ^ en jjaßal: produl in essential oils and alkaloids η preferably as poor as possible?., ni'3.? aifiliclies leaf material containing chlorophyll! after air drying by prolonged Urv / ärrating at -Qsnperaturen below 110 ⁰ O, and the absence of air f'3me: .itiert v / ith fermented and from the sheet material em entste in Perraentation ^ ndenen Aroaastoffe extracted and the resulting Ausgangsniaterial the 8.1S when smoked A touch of flavor & added substances. / Earth.

is the hrfinduns about> these

Sufficient air drying of the ffliarnolysis see below Subject to the vrass he steam volatile healing products one lthere: itra.L'tion su miterxrerfen and die freed from the solvent ibrfcrak'fce the starting materials to add.

BATH ORIGINAL

* "7

10984Ö / 1563

IDas ynGctr ^ i of IZrrfcra ^ te ku d.3R. Starting material Ιΐα · - .: ι now through example; The starting material is immersed in I: ösunr; e: ^ ibr 'Jstralitlonsprodulrto in suitable, ^ ut volatile' solvents, such as iithane oil, or by toi * sprülieii soldier solutions in suitable Eonner-itratio? ^. r.ui cs.s starting triatsDrial. Since ¹ OeX 2: o, rui this toi '^ orir, an; any! I; s Ticc it is particularly "advantageous to use the supply to the siiateri-al gate aur Si ^ arettenmasdiine with a 0.3 to 7. ^ -igen aetiianolical solution of the. G-escIrascIz des Cell phones influencing the drctralitionprodiLvte zn oesprlüien.

. In a3.1s3 "'I'3:' nen characterized it, the su be stranded with the 13xtralrten JLusgaiigsiiiaterialien the Sxtral: tionsprodul: te in a slope 'from 0.0001 to 2.0; S (CrockensubstanH) besogen & m ~ Z The Iroctengev / idit of the starting material siiGusetsen.Me feed quantity depends on the type of starting material, the taste quality of the starting material to be treated, the drying conditions of the thermolysis and 3: ttralrtion subject to the plant, laundering material, the possible in-house processing of the tobacco industry, the thermolytic conditions of the industry common and additionally used aromatizing

- 8 BATH

109848./1S63

food, etc.

The invention is not limited to the use of an extraction product from the leaf material, each according to a unique plant species or genus. On the contrary, it has proven to be specific, chlorophyll-containing, the ri'lansem material, capable of assimilation, from one of the different types of plums, in the form of empirically determined ratios outside and in common, those for the extraction of the aromas sprodiito necessary treatment he step · .- su subject, vu: the reaction mixture from the different!?. AuscangGr-ujstanaen to be applied to the Cls-s starting material together without ■ prior separation.

In a further development of the invention, plant material of different origins can also be subjected to different sheriolysis conditions separately from one another. Then subject them together to the ^T .vanserdaiipfdestillation and Üifcher extraction au.

Here, too, the Realctionp "bed: \ ngungcn and Mixing proportions of the Sinaelaußgaugosiibfstansen Determine the lower parts of each other through preliminary experiments.

Furthermore, it has proven itself as zweetanä.Qig ervr.icfioi.1,

109848 / 1S63

-BAD ORIGINAL

Bchieden-like plant materials separated: process from one another below and first dissolve the reaction products in suitable dissolution proportions in the amount of solvent required for application to the starting material and the starting material after this application
to undergo an iiaclifernientation.

The uptake of the traction products by the starting material can be increased by evacuating the dry waste material in a suitable vessel
and is acted upon with the corresponding Eirtraktionaprsodulctlösiing with sudden pressure equalization.

Another possibility for carrying out the process according to the invention consists in producing greater knowledge of extrusion products, initially exhaustively with the starting plant material, then with ethanol and chlorinated. EohlenwasEjerstof f & xi. au extract, narrow the ^ ztraJc'u ^ ixml as such or on an in ~
diff © reiten ajlingex *, such as z, B * cellulose, burnt 2) o: iigranulai | en, kieselguhr oW der (Ehennoljse zuvrer-
Isolate the reaction products from the embossing materials by steam distillation.

23er Yorteil this modified embodiment of the
According to the invention / method is that both

- ίο - ■. /

the action sequence "can be better controlled than ..- also the possibility "ordered this seal-rbion flow ■ by using suitable catalysts, such as ζ.Ώ, ■ acidic aluminum silicates and aluminum oxides in desired; To steer tracks. Naturally, this is only possible if the reaction products are derived from vegetable structures have been isolated.

ladder is the addition of synthetically produced, occurring in the green tobacco leaf imd schmacirsbe.stin-. mende! DhernolysepiOdulcte resulting substances sttsi Sheraoljoo-, - "" Output files are just as possible as the routing of the

Reaction by Sinsata of ensya-forming JSaJcteria or andosn. microorganisms or the ' Enzymes themselves *; ■ ■ -.- ■

. ■ ■■;

v; "■ '; The einsßhlageB.de lieg is based on the

. _v gangsjnaterial, the iUabaJendprodukt; and its desired -> influencing requirements.

In the following, the invention is intended to be based on the examples to be explained in more detail,

example 1
.1000 g air-dried chestnut leaves v / ordcn for a time of 2 vocheii at 80 ^! .Ί relative Lui'tfeuchtiglce.it

f 0 9 8 4 8 / 1S 6 3 bad original

11 -

lind a Te: ipere.tur of 50 ° 0 stored and thereafter llomaldruck a ^ fesserdaapfdestillation under-'iorfe: i. The llondensate (3.700 ml, ρΞ 5,?) Me de after saturation nil; Kochsais exhaustively extracted and the jltlier langseu. blown off. The remaining, i: tral: t of 0.1 = 1-0 g vmrde dissolved in ethanol and on a: A IPulltabaii, ie e ::; \ o: i Uabah, which is practically free from sticking out substances, in particular of atiiar ^ iseiien oil, in an ilege aufoprillit, that? · the nacii Terempfen the solvent on dam Saba :; The remaining amount of tract was 0.001;

This treated 3? Ülltabali: vmrde naoli a storage time Λ-οΐ- 72 hours at 21 ° C uiid 67 ^ relative air- "f3-uchtig.lEeit Gescnmaelilicli checked by a 2 :: pertengreniuiii and in its ubiquitous base note tasted a v. ^R ertvollesi Tergl calibrates from al: equals.

Example 1a, - -

The TergleichstabaÜE was established by Tfssserestr & tetion of his Aronaträgsrn bsw. the pyrolytic starting products his ?: Flavor carrier freed ^ so that he in gustatory point of view judged as completely empty. 2iii: <i i Part of the Sabalr material prepared in this way vmrde with 0.05 / 5 of his Ge-Kriclite in excess of extract dissolved in ethanol

109848 / 1S 6 3

sprayed according to Example 1 and after a Lagers2it you 72 hours at 21 ⁰ C and 6? , '■> relative humidity organoleptieej with the "hangangstabal: by a! J :: ~ expert committee :: .. Ιυχβ beliandelte sample proved öic / i c - ?, T <ei geceniilDGr der unoe act en eis £ osomo, cl : licl. taoal: good olme exs ^ eprägte liruancierun ^; des G-eccluuaci: r. ■ liinnicirblicl). a ooot: '. ri;.: tej.i ProTeniena «I) .Ig TaD"": - ^ round note vfjirde alo a: inül: <ornd v; iede r' -. ev ^ estellt iDesc'-iieoen.

l 2

2 ^ 00 (j air-dry zastanioribl'ittor vrardcn riit ./asser, then nit iit "; anol ₅ Dic'ilorriet'ian and" 3ο? Ιγ; ο1 "Ό:;'Γ · ο -'v'piC ^ T'.da:; tra. ^ iert and öio nacn .J? vl; fernun £; der or; "n:, .. '. nc}' o: i I:? 5ri: n ^ e 'nittel united Urtra": te in v / enicj v / aßoer ait; fi; e ^J ße''xläLiiiit and applied to glass fiber fleece. JJacIi! Trdc'jnuug im u'-i mirde ds, s "impacted YIiοR 4", iOcnen at 30, '

relative humidity and a tenporature: from ^r rj ~ (J stored in closed! containers and then * tiutor jor :: ial pressure of a './asscrdsxipf de st illation i: ntorT', Orfen. The Eondeiisat (4200 nl, pH 5 .., 7) vrnr.de iuit chef air · saturated and tracted with Ilther eröchöpfend e "'' oc: \ / Zublasendes ether on a water remained a 'livestock was von.0, ^ 2.0 g of ethanol in ai! ; xgcnoilucn and po also of- any artificial or nctvrliohen 'lA ^ iteo-i

BATH ORIGINAL

109848/1563 "' ^: "

■ ■ - 1 τ -

free 2abal: was sprayed that "dor treated ΐ from air 0.002 ;; ' of his Sroelreiigewichues. Untralctioiisprouhten contained. It has a storage time of 72 hours boi 20 G and 65, '■ relative; Iaiftf3VLchuigi: eit was .-' tl:. '3 89r lienandelte [Dabal ·: ait ^ leicuoii, .ber unbelianclelten 2aba? ^ Organoleptisoli ver ^ lic'ion "xi.C .vou IJ-cpGrtengreniiun als ^ escliiiaolülicli "ab £; erxLnd3" bor: .iit Terctär ^ tor G-riindno "ü <3 üe ^ enliber der ¥ er ^; ls: .chsprou3 judged.

example 3

IPriscli geemteter ^IEabaI:; \ rarde η?, ο! ι the usual 2roclaumg er.sprayed according to example 2 and then ferijier.tiert as usual. This! 3? Aba! -R proves to be genuinely pre-strengthened against something that has been treated but otherwise the same, so that he vossi bourteileyiden. "

Example 4

100 g air-dry cheeses aiii en leaves are subjected to thermolysis for 21 days at 85 ° C. over saturated, aqueous potassium chloride solution. 308 g of this material with a moisture content of 1.0 fi Mormalctruck were distilled as in Example 1 with water vapor and the. Condensate (J.000 ml, pH 3.3) as processed there, ilit dom "JztralttionGproduljt

109848 / 1S63 - 1-1- - ■

le a iOabakiOlie! ".. lit 0.02, '■ their ^ roo": 3 _J ..j_:' ^- .riü-.tc: b ο sprays, according to c.eLi in the USE 5.29J.?7a uoEo-rioben process had been established. Lio riLiL ^ r .rüxfl ^ l'L '~ Yergleioliaprobe turned out to be in geac / uiiac'ilichor "lL; iü: \ c. Sc as - clearly flatter \ md s, usdruc :: sloner and:.; U Tsrgl ^. io ". sur behejidelter-i Proue 3cr.i.iii as full β ~ ^> Ull ::: at ':: rir · "'. suitable for cigarettes *

v, ^r ie the Tereointhalos, το: ι whom the Ho.?I:asta::.ie - · aesculus hippoIiastarraLi - as representatives of this order vn;. :: de, are also the aosiuiliGre ^ .clor. l ⁿ haste before the extraction ürticales aur. ^r /,v.:c ^ a '/ jal ·: - aronatisation suitable; ji: treJ :: tionDprod "aL" t -y ... r, \: jr Urs ie lung e ine s affiliated !!! a .baJrr a ^ achgrundga r: ■:;. '...: acl: .a

example 5

4-50 g air-dried stinging leaves - 7? Ol .. i-.rtico, dioica - vrarden 15 2 days at 50 ⁰ O and 75; '<relative humidity in a closed vessel under a nitrogen atmosphere and v; ie described in Example 1 of the Subjected to steam distillation (1-500 ml) and resulted in "0.130 g extraction product, which was already camouflaged in an amount of 0.00001 ■■ '. Bea.oGop

1098487 1 5S 3 ^BATH

tj luiTttro levels 3re] rie £ caI ': r. ⁱ ? ..- tG'7 - Urtier, C: ο ic a

> .id.- ·! in? 53ispiol 1 lieric ^ riooTi "j-;" · Τ.dolt, J3doc '\

^ r ^r .s'.ρ? .I :: -: of 5, ' ties GrG \;:. c ~ ::' cec r.:i lv.f * o "Gro'cJ: e: aG: .: i-im

"■; · '. 1ο:.".! 3; ^λ γο ill-. : ΐ υ et rue 0,210 ^ ^ ol oiii'r ^ e ^ onilwor ί.3 "-ρΐΌΊ.Λ ': Ί · --Ig :: 3.5ia, p ^ .olc 1. v.:v" · ". lsr ^ l ^ c / -. in Slme of Alj ^ r .-. rivi ^ esc- ¹ riac'csnote verirtär-rtn ". Ir 0: iat is ic ri'ä ^ .i.C '-. R

■ iro 'j: I "af" uje "u3: oebneten J3rG ^ .r.eaßGl": rcviii; 3n - · " ⁷ rtica dioicr: * - ^r -jG-on. \ R:'. N : Vi Example 6 beüianlelt -jedoeüi under 2usalic vo: .i;:. j doc G-evriclites an fernontierteraj getroc ^ netGia uiicl ^ Dp / .ilensiTO ..:? a ": rJ :. The luscious cn! Jxtra'rtionsprodulrt 'bet2: uj; 0.1

s ^ ej.iü.'ien application of the lü :: tra] -tioiinpro ~

3eis "p'i.el ':

-.tJ.o.:.; "!. ~) o?. :: ji ~ J. ' Lcco" rico3n ge.ianaolt, iedoc' a · '. "-.'!; ^ '·. 0/1 , ',' - ^ .: · ο "π: '.. ^IV ui'.C:' V: t :. ⁱ rJ ": ^ r ;, 'Ίοΐ ^1":.: ever tried g

1 09Ö48 / 1 5 6 3 - ι - bad

was made as follows:

50 Q of fresher tobacco leaves (German Burley) were finely chopped and homogenized in 125 ml of 0.05 m iCris-hydroxymethyl) -aminoiüethaji hydrochloric acid. With a coarse! Tilter, the plague was often separated and discarded. The green filtrate was centrifuged at 15,000 for 1 hour, a pale red-brown supernatant forming which was decanted off and freeze-dried. A .5% solution of the frozen product in 0.05 m Sris-Chjrdrosimetliyli-aininomethan-hydrochloric acid was used.

The yield of the extraction product was 0.245 g - with excellent labak base aronia properties, without penetrating the taste peaks of the tobacco treated with it. -

Example 9

4500 g fresh, coarsely chopped stinging nettle leaves 3Ό1. urtica clioica - vairden in a closed vessel with a solution of 1 1 of the ready-to-use Covered '"üabakextrakes according to Example S in 10 1 of water and evacuated to 100 torr. After that it was suddenly ventilated, with the solution in the plant material penetrated. The now appearing transparent

■ "" ^c: 109848/156 3 - i ^ * öoriginal

-; ■. ■ -17- ■

The material to be treated was air-dried as well as in Example 1 described further. "treated." The yield at. Extraction product / was "with an initial quantity of 400 g air-dried Plant material 0.240 g with very good! Ubacco base aroma properties. The Sabalers treated with this material showed compared to untreated comparison tobacco a strong, broadened gourmet base without Impairment or change in the flavor components specific to the variety or provenience.

Example 10 _:.

4000 g of fresh nettle leaves were finely chopped and homogenized in 0.15 in ice solution and ^{squeezed through a coarse I 1} UiBr. The liquid phase was then centrifuged for 15 minutes at 12500 g, the supernatant frozen and the precipitate with 2 % of its volume of tobacco extract added according to Example 8. Subsequent freeze-drying, the ffirockenprodukt was "blended ¹ " with the same volume of quartz sand washed and at 50.degree. $ 0 fo relative humidity subjected to £ hermolysis. Subsequent steam distillation was obtained from the condensate (3500 mlj pH 5> 4) after saturation with table salt and extraction with Ither 0.220 g of extraction product freed from Iib'smittel, which ate very good tobacco flavoring properties when eating according to the invention

1.0084-8 / 158 3 -18-

~ 18 -

Application to tobacco developed without varietal-specific ■ Covering or falsifying whipped cream components.

Highlight the lerebinthales, of those in the examples 1 - 4 for example ilesculushippocastanum and the

• Urticales, of denan in Examples 5-10 as representatives Urtica dioiea, the assimilative

.-, renden parts of the Ulotrichales with Enteromorpha spec, as representatives, the leptosporangiatae with Dryopteris' filix-mas as a representative as well as 'vonden Dialypetalae die' Eosales with Kubus frutiosus as a representative, the Legumino-sae with Vicia faba as a representative, the G-uttiferales with Camellia sinensis as representatives, the Oolumniferae with OJilia cordata and Sheobroma cacao as representatives and the Ümbelliflo £ a £ with Daueus carota as. Representative to the G-ev / guild of extraction products proved to be suitable.

(The assimilating! parts of the lägales with lagus silvatica var. purpureä as ^ representative, the Polygonales with Rumex dorne st icus and Iheum palmatum as a tertiary soie from the Sympetalae diö Personatae Solaaum tuberoBum and Solanum lycopersicum as representatives, the "RuMaIes with Ooffea arabica as representatives, the Gucurbitales with öucumis sätivus and the Synandrae with lussilago farfara as representatives. From the G-lumiflorae

109848/1563

are the G-ramineäe nut Iioliuri perenne and Sea Hays succesfully subjected to the mololysis and the 23: rtralrbionprodukte according to the invention on OJaToak with good "bit sohr good results applied.

As far as: the substances according to the invention as a component of saber: or 2ai3ak goods based on the regulation on Scbal; vuifi -2abci: products (iabakverOrdnung dated ΐf. 12.19? 9 (: 3Γτ?; 1 I Hr. 52 dated 22.12.1959 p. 730 esp. appendix '"-iff. 5) are currently not' permitted, they may only for such SabaJxe. or labainmren used vrer- ^ ώ; λ, which are intended for deliveries to outside the area of application of the food law.

'-tii.vbo literature

■ 1.1 ^ 1.

■ 1, 00-525

1.073.423 TfST- 5.17 ■ -: -.- 1-35 5,211,157

3,217,717 5,217,713 5,251,366

rctoiitaASpriicIie: -

0 9-848 / 1-5

Claims (1)

20 - Π 01 116 B / il Patent claims: 1. Process for the production of consumable products by adding the smoke flavoring substances produced when smoking to a starting material - such as sabak, especially 3? Ülltabak, üabakfolieii, iJrsatztabaken, Eabakartikel and other sum smoking, for example in cigarette "or Sigarrenforn appropriate I-iaterialien, dad acid hgek .e η n ■ records "that any, of essential oils and alkaloids preferably as low vegetable, Chlorophyll; ^T lllialtiges sheet material after air drying by prolonged heating at temperatures .Among 110 ° 0 and Fermented in the absence of air, the aroma substances produced during fermentation are extracted from this fermented leaf material and the Saudi aroma substances produced when smoking are added to the starting material ε, ΐε. 2. Ancestors according to claim 1, d a d u r c h g elce nnz e i c h net that chlorophyll-containing PfIansenmate mixed rial of different plant species and the pomentation sovrio jl ^ trrvktions treatment to be subjected BAD OBIGiNAt 109848/1563 3. The method according to claim 1, d a d u r c Ii g e I: e η n a e i c h η e t that plant material is more diverse Origin separated from each other iintersciiiedliclieii lermentationsbehandlimgen and then together which is subject to legal action. 4. Procedure naoli Insprucli- 1, d a d u r c Ii g e k e η ii draws that different types of plant matter, l fermented separately from one another and extracted and the JfetraJctionsprodulcte in the gev / ünsGriten Kisclmngsverl-i everything in the order to the ■ Starting material required amount of solvent be solved ..-. . ■ 5. ■ Method according to "e" .nen or redirecting the preceding Claims, - d ad ure Ii g e Ic en η s e i c h 11 e t, that this is the source material loaded with the sfebraLt solutions after the application of a post-fermentation will. 6. The method according oi. S] or more of the preceding Aiißprüclio, characterized geke η η ζ eic Ii net that aur increase Aufnalinie the Extraktionsprοdukte evacuated, the dry starting material in a vessel by daa Ausgarigsmaterial and sudden Druclcaus- 109848/156 3 ~ »ϊδ same with the corresponding -Sxt-ratbionsprodulrb-. solution "is applied. ; 7. Process for the creation of consumable products. Duroli addition of the "aroma-enhancing substances arising from smoking to an output" material such as 2! A "bak, in particular 3 ¹ UlIt abalr, lababfolien, Ursatstabalcen, 2abal: ersats and others on the smoked,, cam example in cigarette or cigar shape suitable materials, characterized gea eic Ii η et, dai3 any, of essential oils and JLlkaloiden preferably low as possible vegetable, Chloi ^ phvllhaltiges sheet material, first exhaustively with water, then with ethanol and chlorination -rten Icarbons are extracted, the Sxtralit is concentrated and this as such or on an indifferent carrier, such as _: cellulose, fired song granules, kieselguhr, glass fiber fleece or the like, is subjected to thermolysis and the reaction products from the " Support materials can be isolated by steam distillation. ■ ■. S. Yerfahren according to one or more of the preceding claims, since d- ureh Q e Jc e η η ζ calibrated, ... _a »AÜDRIGINÄt / 109848/1563 ■ tt- da.?· the plum, chlorophyll-containing leaves material before fermentation a few percent by weight on distant, dried mad-ground sabak "-. 2it (j3aetijt trarden. 9. The method according to one or more of the preceding claims, dadurc Ii ge 1: e η ii ζ eich η et, .la "de:" i vegetable, chloropayl-containing leaf material eir.ije .Gs ^ ichtsproEent a Üa "ba? Xe2ctral-rfces sugesetat 10. Termination of one or more of the preceding inconsistencies, α a marked by, the fresh vegetable, chlorophyllic leaf material nit liquid EalDalre ^ tralit soaked and then is fermented, before the li ^ traction he follows . 11. Yerialir2: i: · "ο"; e new or several :! the previous one , Ir-Sprücho, uad ü. reh ge Γ: 2nd r. : λ s cic "χ η et, da.3 the fermentation is hot y} ° never '30 ° G and" at ZO to 90 G-ev:.,' relative LtLftf.av.c-htigk-iit d \ irc? is carried out. 12. Method n-ac'x one or more of the preceding ■: ■ I 109848/1563 BAÖ OBlQlNAL Claims, characterized ge Ic e η η ζ eic Ii η e t in that the extractives in amounts zwischen.0,00001 and 2.0 percent are between 0.001 and 0.1 ffew ^ V based on the starting material dry weight applied preferably. ^. 13. Procedure according to one or more of the preceding Claims characterized by the Use of a tasteless, smolderable ifeterial as starting material. 14 · Method according to one or more of the preceding Claims characterized by the Use of a tobacco foil as the starting material. 109848/1563 SAD ORIGINAL