DE165149C - - Google Patents
Info
- Publication number
- DE165149C DE165149C DENDAT165149D DE165149DA DE165149C DE 165149 C DE165149 C DE 165149C DE NDAT165149 D DENDAT165149 D DE NDAT165149D DE 165149D A DE165149D A DE 165149DA DE 165149 C DE165149 C DE 165149C
- Authority
- DE
- Germany
- Prior art keywords
- chlorine
- indigo
- chlorinated
- iodine
- carbon tetrachloride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229910052801 chlorine Inorganic materials 0.000 claims description 7
- 239000000460 chlorine Substances 0.000 claims description 7
- ZAMOUSCENKQFHK-UHFFFAOYSA-N chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 7
- VZGDMQKNWNREIO-UHFFFAOYSA-N Carbon tetrachloride Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 claims description 6
- 229940097275 Indigo Drugs 0.000 claims description 4
- 241001062009 Indigofera Species 0.000 claims description 4
- 235000000177 Indigofera tinctoria Nutrition 0.000 claims description 4
- VIFKLIUAPGUEBV-UHFFFAOYSA-N 2-(3-hydroxy-1H-indol-2-yl)-1H-indol-3-ol Chemical compound N1C2=CC=CC=C2C(O)=C1C1=C(O)C2=CC=CC=C2N1 VIFKLIUAPGUEBV-UHFFFAOYSA-N 0.000 claims description 3
- 239000000969 carrier Substances 0.000 claims description 3
- 229910052740 iodine Inorganic materials 0.000 claims description 3
- 239000011630 iodine Substances 0.000 claims description 3
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 2
- 239000002904 solvent Substances 0.000 claims 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N HCl Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- NUJOXMJBOLGQSY-UHFFFAOYSA-N Manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 125000004429 atoms Chemical group 0.000 description 1
- -1 chlorine carbon Chemical compound 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 239000003701 inert diluent Substances 0.000 description 1
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B7/00—Indigoid dyes
- C09B7/02—Bis-indole indigos
- C09B7/04—Halogenation thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
KAISERLICHESIMPERIAL
PATENTAMT.PATENT OFFICE.
PATENTSCHRIFTPATENT LETTERING
M 165149 KLASSE 22 e. M 165149 CLASS 22 e.
FARBWERKE vorm. MEISTER LUCIUS & BRÜNING in HÖCHST a. M.FARBWERKE vorm. MASTER LUCIUS & BRÜNING in HÖCHST a. M.
Verfahren zur Herstellung von chlorierten Indigofarbstoffen.Process for the production of chlorinated indigo dyes.
Es wurde gefunden, daß man aus Indigweiß durch Einwirkung von Chlor unter Verwendung indifferenter Verdünnungsmittel und bei Gegenwart von Chlorüberträgern chlorierte Indigofarbstoffe in guter Ausbeute erhalten kann.It has been found that indigo white can be made from under the action of chlorine Use of inert diluents and in the presence of chlorine carriers chlorinated indigo dyes can be obtained in good yield.
Beispiel: In etwa 50 1 Tetrachlorkohlenstoff werden etwa 0,1 kg Jod gelöst. In diese Lösung werden 4 kg trockenes, reines Indigweiß gebracht und die Flüssigkeit mittels eines energisch wirkenden Rührers durchgerührt. Unter fortwährendem' raschen Rühren und unter Kühlung wird nun die berechnete, z. B. aus Braunstein und SaIzsäure entwickelte, zur Bildung von Dichlorindigo genügende Menge Chlor, z. B. 6 Atome, eingeleitet. Wenn alles Chlor verbraucht ist, wird der entstandene Chlorindigo abfiltriert, mit etwas Chlorkohlenstoff gewaschen und getrocknet.Example: Around 50 liters of carbon tetrachloride about 0.1 kg of iodine are dissolved. In this solution 4 kg dry, pure Brought indigo white and the liquid stirred by means of a vigorous stirrer. With continuous' rapid stirring and with cooling the calculated, e.g. B. developed from manganese dioxide and hydrochloric acid to form dichloroindigo sufficient amount of chlorine, e.g. B. 6 atoms initiated. When all the chlorine is used the resulting chlorine indigo is filtered off, washed with a little chlorine carbon and dried.
An Stelle von Jod können auch andere Überträger, wie z. B. Eisenoxydulsalze, ferner an Stelle von Tetrachlorkohlenstoff andere indifferente, wasserfreie Verdünnungsmittel verwendet werden.Instead of iodine, other carriers, such as. B. iron oxide salts, furthermore Instead of carbon tetrachloride, other inert, anhydrous diluents be used.
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE165149C true DE165149C (en) |
Family
ID=430678
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT165149D Active DE165149C (en) |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE165149C (en) |
-
0
- DE DENDAT165149D patent/DE165149C/de active Active
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