DE1608097C3 - Use of a tough, precipitation hardenable, rustproof, chrome, nickel and aluminum containing steel alloy - Google Patents
Use of a tough, precipitation hardenable, rustproof, chrome, nickel and aluminum containing steel alloyInfo
- Publication number
- DE1608097C3 DE1608097C3 DE1608097A DE1608097A DE1608097C3 DE 1608097 C3 DE1608097 C3 DE 1608097C3 DE 1608097 A DE1608097 A DE 1608097A DE 1608097 A DE1608097 A DE 1608097A DE 1608097 C3 DE1608097 C3 DE 1608097C3
- Authority
- DE
- Germany
- Prior art keywords
- steel alloy
- nickel
- tough
- rustproof
- aluminum
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 title claims description 16
- 229910000851 Alloy steel Inorganic materials 0.000 title claims description 10
- 229910052782 aluminium Inorganic materials 0.000 title claims description 9
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims description 9
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 title claims description 8
- 229910052759 nickel Inorganic materials 0.000 title claims description 8
- 238000001556 precipitation Methods 0.000 title description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
- 229910052758 niobium Inorganic materials 0.000 claims description 6
- 239000010955 niobium Substances 0.000 claims description 6
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 6
- 229910052804 chromium Inorganic materials 0.000 claims description 5
- 239000011651 chromium Substances 0.000 claims description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 4
- 229910052717 sulfur Inorganic materials 0.000 claims description 4
- 239000011593 sulfur Substances 0.000 claims description 4
- 239000010936 titanium Substances 0.000 claims description 4
- 229910052719 titanium Inorganic materials 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 229910052742 iron Inorganic materials 0.000 claims description 3
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 229910052750 molybdenum Inorganic materials 0.000 claims description 3
- 239000011733 molybdenum Substances 0.000 claims description 3
- 229910052710 silicon Inorganic materials 0.000 claims description 3
- 239000010703 silicon Substances 0.000 claims description 3
- 239000012535 impurity Substances 0.000 claims description 2
- 230000008018 melting Effects 0.000 claims description 2
- 238000002844 melting Methods 0.000 claims description 2
- 229910052757 nitrogen Inorganic materials 0.000 claims description 2
- 229910000831 Steel Inorganic materials 0.000 description 5
- 239000010959 steel Substances 0.000 description 5
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 229910000746 Structural steel Inorganic materials 0.000 description 1
- 238000005219 brazing Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
- 229910000859 α-Fe Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/44—Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/12—Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Heat Treatment Of Steel (AREA)
- Arc Welding In General (AREA)
- Heat Treatment Of Articles (AREA)
Description
Die Erfindung betrifft die Verwendung einer zähen, ausscheidungshärtbaren, rostfreien, chrom-, nickel- und aluminiumhaltigen Stahllegierung als Werkstoff für bestimmte Gegenstände, wie zusammengesetzte maschinenverarbeitete, geschweißte oder gelötete Teile von Druckkesseln oder Flugkörpern.The invention relates to the use of a tough, precipitation hardenable, stainless, chrome, nickel and aluminum-containing steel alloy as a material for certain items, such as composite machine-processed, welded or soldered parts of pressure vessels or missiles.
In der US-Patentschrift 31 31 055 ist eine Stahllegierung beschrieben, die aus 5 bis 16,5% Chrom, 10 bis 18,5% Nickel, 1 bis 6% Aluminium, bis zu 0,15% Kohlenstoff, bis zu 4% Mangan, bis zu 2% Silicium und zum Rest aus Eisen besteht, wobei das Aluminium teilweise durch Titan und/oder Molybdän ersetzt sein kann und der Aluminiumgehalt nicht unter 0,5% fällt. Dabei handelt es sich um einen ausscheidungshärtbaren rostfreien Stahl, der keinen freien cf-Ferrit enthält und eine leichte Strukturhärtung unter Erzielung einer guten Reproduzierbarkeit seiner mechanischen Eigenschaften erlaubt. Über die Zähigkeits- und Festigkeitseigenschaften dieses bekannten Stahls und über spezielle Anwendungsgebiete enthält diese Patentschrift keinerlei Angaben. Aus Küntscher-Kilger-Biegler, »Technische Baustähle«, 3. Auflage, Halle (Saale) 1958, Seiten 374/375 und 404, ist es ferner bekannt, daß rostfreien Stählen Niob zugesetzt werden kann. Daraus sind jedoch ebenfalls keine spezifischen Angaben in bezug auf Zähigkeits- und Festigkeitseigenschaften sowie spezielle Anwendungsgebiete der darin beschriebenen Stähle zu entnehmen.In US Pat. No. 31 31 055, a steel alloy is described, which consists of 5 to 16.5% chromium, 10 to 18.5% nickel, 1 to 6% aluminum, up to 0.15% carbon, up to 4% manganese, up to 2% silicon and the The remainder consists of iron, with the aluminum being partially replaced by titanium and / or molybdenum and the aluminum content does not fall below 0.5%. It is a precipitation hardenable stainless steel Steel that does not contain free cf ferrite and is a light one Structural hardening is allowed while achieving good reproducibility of its mechanical properties. About the toughness and strength properties of this well-known steel and about special areas of application this patent specification does not contain any information. From Küntscher-Kilger-Biegler, »Technical Structural Steel«, 3rd edition, Halle (Saale) 1958, pages 374/375 and 404 is it is also known that niobium can be added to stainless steels. However, none of these are either specific information regarding toughness and strength properties as well as special areas of application of the steels described therein.
In dem Patent 14 58 330 ist die Verwendung einer zähen, ausscheidungshärtbaren, rostfreien, chrom-, nikkel- und aluminiumhaltigen Stahllegierung, die aus 11,5 bis 13,5% Chrom, 7,0 bis 10,0% Nickel, 0,5 bis 1,5% Aluminium, 1,75 bis 2,50% Molybdän, bis zu 0,05% Kohlenstoff, bis zu 0,50% Mangan, bis zu 0,60% Silicium, bis zu 0,020% Schwefel, bis zu 0,05% Stickstoff, Rest Eisen einschließlich erschmelzungsbedingter Verunreinigungen besteht, als Werkstoff für Gegenstände, die bei Raumtemperatur in ausgehärtetem Zustand eine Mindestzugfestigkeit von 149,0 kg/mm2 in der Längs- und Querrichtung, eine Dehnung innerhalb 50,8 mm Meßlänge von mindestens 8% und eine Einschnürung von mindestens 29,3% aufweisen, wie zusammengesetzte maschinenverarbeitete, geschweißte oder gelötete Teile von Druckkesseln oder Flugkörpern, beschrieben.In the patent 14 58 330 is the use of a tough, precipitation hardenable, stainless, chromium, nickel and aluminum-containing steel alloy consisting of 11.5 to 13.5% chromium, 7.0 to 10.0% nickel, 0.5 up to 1.5% aluminum, 1.75 to 2.50% molybdenum, up to 0.05% carbon, up to 0.50% manganese, up to 0.60% silicon, up to 0.020% sulfur, up to 0 .05% nitrogen, the remainder iron, including impurities caused by the melting, as a material for objects that have a minimum tensile strength of 149.0 kg / mm 2 in the longitudinal and transverse direction at room temperature in the hardened state, an elongation within 50.8 mm measuring length of at least 8% and a necking of at least 29.3%, as described as assembled, machine-processed, welded or soldered parts of pressure vessels or missiles.
Die hier beschriebene Erfindung stellt nun eine weitere Ausgestaltung des Gegenstandes des oben genannten Patents dar und betrifft die Verwendung einer zähen, ausscheidungshärtbaren, rostfreien, chrom-, nickel- und aluminiumhaltigen Stahllegierung der vorstehend angegebenen Zusammensetzung für den in dem Patent genannten Zweck, die zusätzlich noch mehr als 0,10 und bis zu 0,50% Titan und/oder bis zu 0,75% Niob enthält.The invention described here represents a further embodiment of the subject matter of the above Patent and relates to the use of a tough, precipitation hardenable, rustproof, chrome, nickel and aluminous steel alloy of the above composition for the one in the patent mentioned purpose, which also contains more than 0.10 and up to 0.50% titanium and / or up to 0.75% niobium.
Beste Ergebnisse werden erzielt, wenn die Stahllegierung der vorstehend angegebenen Zusammensetzung 0,10 bis 0,50% Niob und weniger als 0,015% Schwefel enthält.Best results are obtained when the steel alloy has the composition given above Contains 0.10 to 0.50% niobium and less than 0.015% sulfur.
Die erfindungsgemäß verwendeten titanhaltigen und/ oder niobhaltigen Stähle sind frei von jeder interkristallinen oder intergranulären Korrosion im frisch geschweißten Zustand sowie im geschweißten und ausscheidungsgehärteten Zustand und sie sind im gehärteten Zustand nach dem Schweißen oder Hartlöten besonders korrosionsbeständig.The titanium-containing and / or niobium-containing steels used according to the invention are free of any intergranularity or intergranular corrosion in the freshly welded state as well as in the welded and precipitation hardened Condition and they are special in the hardened condition after welding or brazing corrosion resistant.
Die erfindungsgemäß verwendete Stahllegierung eignet sich insbesondere für die Herstellung von Teilen, bei denen Spannungen längs aller drei Hauptachsen auftreten. Der erfindungsgemäß zu verwendende Stahl weist eine ausgezeichnete Spannungsrißkorrosionsbeständigkeit auf selbst in einer stark salzhaltigen Atmosphäre.The steel alloy used according to the invention is particularly suitable for the manufacture of parts where stresses occur along all three main axes. The steel to be used according to the invention has excellent stress corrosion cracking resistance even in a highly saline atmosphere.
Claims (2)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US29948463A | 1963-08-02 | 1963-08-02 | |
| US37657064A | 1964-06-19 | 1964-06-19 | |
| US58529866A | 1966-10-10 | 1966-10-10 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE1608097A1 DE1608097A1 (en) | 1973-05-24 |
| DE1608097B2 DE1608097B2 (en) | 1977-06-02 |
| DE1608097C3 true DE1608097C3 (en) | 1985-04-25 |
Family
ID=27404660
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE1458330A Expired DE1458330C3 (en) | 1963-08-02 | 1964-08-03 | Use of a tough, precipitation hardenable, rustproof, chrome, nickel and aluminum containing steel alloy |
| DE1608097A Expired DE1608097C3 (en) | 1963-08-02 | 1967-07-21 | Use of a tough, precipitation hardenable, rustproof, chrome, nickel and aluminum containing steel alloy |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE1458330A Expired DE1458330C3 (en) | 1963-08-02 | 1964-08-03 | Use of a tough, precipitation hardenable, rustproof, chrome, nickel and aluminum containing steel alloy |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US3556776A (en) |
| BE (2) | BE651249A (en) |
| DE (2) | DE1458330C3 (en) |
| GB (2) | GB1077979A (en) |
| SE (1) | SE316023B (en) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE651249A (en) * | 1963-08-02 | 1964-11-16 | ||
| US3769003A (en) * | 1971-04-05 | 1973-10-30 | Int Nickel Co | Alloy steel particularly adaptable for use as a filler metal |
| US4125260A (en) * | 1976-05-17 | 1978-11-14 | True Temper Corporation | Tubular golf shaft of stainless steel |
| US4049430A (en) * | 1976-08-18 | 1977-09-20 | Carpenter Technology Corporation | Precipitation hardenable stainless steel |
| FR2419472A1 (en) * | 1978-03-08 | 1979-10-05 | Ciat Sa | Heating system for swimming pool - has air treated by heat pump with some flow by=passed around evaporator with total flow passing over condenser |
| US4754950A (en) * | 1984-10-30 | 1988-07-05 | Kabushiki Kaisha Toshiba | Valve |
| US5855844A (en) * | 1995-09-25 | 1999-01-05 | Crs Holdings, Inc. | High-strength, notch-ductile precipitation-hardening stainless steel alloy and method of making |
| US5681528A (en) * | 1995-09-25 | 1997-10-28 | Crs Holdings, Inc. | High-strength, notch-ductile precipitation-hardening stainless steel alloy |
| US5888449A (en) * | 1997-05-30 | 1999-03-30 | Teledyne Industries, Inc. | Stainless steel |
| US7901519B2 (en) * | 2003-12-10 | 2011-03-08 | Ati Properties, Inc. | High strength martensitic stainless steel alloys, methods of forming the same, and articles formed therefrom |
| FR2887558B1 (en) * | 2005-06-28 | 2007-08-17 | Aubert & Duval Soc Par Actions | MARTENSITIC STAINLESS STEEL COMPOSITION, PROCESS FOR MANUFACTURING A MECHANICAL PART THEREFROM, AND PIECE THUS OBTAINED |
| US7931758B2 (en) * | 2008-07-28 | 2011-04-26 | Ati Properties, Inc. | Thermal mechanical treatment of ferrous alloys, and related alloys and articles |
| JP5502575B2 (en) * | 2010-04-16 | 2014-05-28 | 株式会社日立製作所 | Precipitation hardening martensitic stainless steel and steam turbine blades |
| JP5528986B2 (en) * | 2010-11-09 | 2014-06-25 | 株式会社日立製作所 | Precipitation hardening type martensitic stainless steel and steam turbine member using the same |
| JP5764503B2 (en) * | 2012-01-19 | 2015-08-19 | 三菱日立パワーシステムズ株式会社 | Precipitation hardening type martensitic stainless steel, steam turbine long blade, turbine rotor and steam turbine using the same |
| JP6317542B2 (en) * | 2012-02-27 | 2018-04-25 | 三菱日立パワーシステムズ株式会社 | Steam turbine rotor |
| JP6259579B2 (en) * | 2012-03-29 | 2018-01-10 | 新日鐵住金ステンレス株式会社 | High-strength stainless steel wire, high-strength spring, and method of manufacturing the same |
| JP6113456B2 (en) * | 2012-10-17 | 2017-04-12 | 三菱日立パワーシステムズ株式会社 | Precipitation hardened martensitic stainless steel and steam turbine long blades using it |
| JP6128291B2 (en) * | 2015-04-21 | 2017-05-17 | Ｊｆｅスチール株式会社 | Martensitic stainless steel |
| US10988825B2 (en) * | 2016-04-12 | 2021-04-27 | Jfe Steel Corporation | Martensitic stainless steel sheet |
| SE539763C2 (en) * | 2016-06-16 | 2017-11-21 | Uddeholms Ab | Steel suitable for plastic moulding tools |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AT146720B (en) * | 1931-06-23 | 1936-08-10 | Krupp Ag | Manufacture of objects that must have special strength properties, in particular high vibration resistance and / or should have high resistance to becoming brittle due to intergranular corrosion. |
| FR743179A (en) * | 1933-03-25 | |||
| US2505763A (en) * | 1946-09-06 | 1950-05-02 | Armco Steel Corp | Stainless steel and method |
| US2505764A (en) * | 1946-09-06 | 1950-05-02 | Armco Steel Corp | Stainless steel and method |
| US2505762A (en) * | 1946-09-06 | 1950-05-02 | Armco Steel Corp | Stainless steel and method |
| US2799602A (en) * | 1956-10-04 | 1957-07-16 | Allegheny Ludlum Steel | Process for producing stainless steel |
| US2958618A (en) * | 1957-07-31 | 1960-11-01 | Armco Steel Corp | Method for hardening chromiumnickel stainless steel |
| US2958617A (en) * | 1957-07-31 | 1960-11-01 | Armco Steel Corp | Method for hardening chromiumnickel stainless steel |
| US3117860A (en) * | 1958-04-11 | 1964-01-14 | Ferrolegeringar Trollhetteverk | Methods of removing copper and related metals from sulfidic molybdenum ores and molybdenum-containing materials |
| US2999039A (en) * | 1959-09-14 | 1961-09-05 | Allegheny Ludlum Steel | Martensitic steel |
| US3131055A (en) * | 1960-03-11 | 1964-04-28 | Soc Metallurgique Imphy | Alloy based on iron, containing nickel, chromium and aluminium, and process for obtaining same |
| BE651249A (en) * | 1963-08-02 | 1964-11-16 |
-
1964
- 1964-07-31 BE BE651249D patent/BE651249A/xx unknown
- 1964-08-03 DE DE1458330A patent/DE1458330C3/en not_active Expired
- 1964-08-04 GB GB31438/64A patent/GB1077979A/en not_active Expired
-
1966
- 1966-10-10 US US585298A patent/US3556776A/en not_active Expired - Lifetime
-
1967
- 1967-04-24 BE BE697441D patent/BE697441A/xx unknown
- 1967-06-30 SE SE10016/67*A patent/SE316023B/xx unknown
- 1967-07-21 DE DE1608097A patent/DE1608097C3/en not_active Expired
- 1967-09-01 GB GB40115/67A patent/GB1138098A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| SE316023B (en) | 1969-10-13 |
| GB1077979A (en) | 1967-08-02 |
| DE1458330A1 (en) | 1972-03-23 |
| DE1458330C3 (en) | 1984-09-20 |
| US3556776A (en) | 1971-01-19 |
| BE651249A (en) | 1964-11-16 |
| BE697441A (en) | 1967-10-02 |
| DE1458330B2 (en) | 1977-02-24 |
| GB1138098A (en) | 1968-12-27 |
| DE1608097A1 (en) | 1973-05-24 |
| DE1608097B2 (en) | 1977-06-02 |
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