DE1594909A1 - Process for preparing and oiling fully synthetic and cellulose ester threads - Google Patents

Process for preparing and oiling fully synthetic and cellulose ester threads

Info

Publication number
DE1594909A1
DE1594909A1 DE19661594909 DE1594909A DE1594909A1 DE 1594909 A1 DE1594909 A1 DE 1594909A1 DE 19661594909 DE19661594909 DE 19661594909 DE 1594909 A DE1594909 A DE 1594909A DE 1594909 A1 DE1594909 A1 DE 1594909A1
Authority
DE
Germany
Prior art keywords
preparing
oiling
fully synthetic
cellulose ester
aliphatic hydrocarbon
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
DE19661594909
Other languages
German (de)
Inventor
Herbert Bruschek
Boehme Dr Peter
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dr Th Boehme KG Chemie Fabrik GmbH and Co
Original Assignee
Dr Th Boehme KG Chemie Fabrik GmbH and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dr Th Boehme KG Chemie Fabrik GmbH and Co filed Critical Dr Th Boehme KG Chemie Fabrik GmbH and Co
Publication of DE1594909A1 publication Critical patent/DE1594909A1/en
Pending legal-status Critical Current

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02GHOT GAS OR COMBUSTION-PRODUCT POSITIVE-DISPLACEMENT ENGINE PLANTS; USE OF WASTE HEAT OF COMBUSTION ENGINES; NOT OTHERWISE PROVIDED FOR
    • F02G1/00Hot gas positive-displacement engine plants
    • F02G1/04Hot gas positive-displacement engine plants of closed-cycle type
    • F02G1/043Hot gas positive-displacement engine plants of closed-cycle type the engine being operated by expansion and contraction of a mass of working gas which is heated and cooled in one of a plurality of constantly communicating expansible chambers, e.g. Stirling cycle type engines
    • F02G1/044Hot gas positive-displacement engine plants of closed-cycle type the engine being operated by expansion and contraction of a mass of working gas which is heated and cooled in one of a plurality of constantly communicating expansible chambers, e.g. Stirling cycle type engines having at least two working members, e.g. pistons, delivering power output
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53Polyethers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M7/00Treating fibres, threads, yarns, fabrics, or fibrous goods made of other substances with subsequent freeing of the treated goods from the treating medium, e.g. swelling, e.g. polyolefins
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/40Reduced friction resistance, lubricant properties; Sizing compositions

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Description

Verfahren zum Präparieren und Ölen von 1 ü α 4 J U <3 vollsynthetischen und Zellulose-Ester-FädenProcess for preparing and oiling 1 ü α 4 JU <3 fully synthetic and cellulose ester threads

In dem D.B.Po (Patentanmeldung Akts. B 87075 IVe/29b) wurda die Verwendung von Verbindungen der allgemeinen FormelIn the D.B.Po (patent application file B 87075 IVe / 29b) the use was made of compounds of the general formula

R1O - Y - OR2 R 1 O - Y - OR 2

worin R1 gradkettige oder verzweigtewherein R 1 is straight-chain or branched

geeättigte oder ungesättigte aliphatische Kohlenwasserstoffrestesaturated or unsaturated aliphatic hydrocarbon radicals

R2 kurzkettige aliphatische Kohlenwasserstoffreste mit 1-2 Kohlenstoffatomen im MolekülR 2 short-chain aliphatic hydrocarbon radicals with 1-2 carbon atoms in the molecule

und Y Polyglyoolreste mit 3-16 Alkylenoxydgruppenand Y polyglyool radicals with 3-16 alkylene oxide groups

bedeutenmean

als Mittel zum Ölen und Präparieren von gefärbten oder ungefärbten Zellulose-Ester- oder vollsynthetischen Fäden oder Garnen sowie deren Gemische mit nativen oder Regeneratfasern beschrieben.as a means for oiling and preparing colored or uncolored Cellulose ester or fully synthetic threads or yarns and their mixtures with native or regenerated fibers are described.

Weitere Untersuchungen ergaben, daß gleichwertige Effekte beim Ölen und Präparieren der genannten Fasern erzielt werden mit Verbindungen der allgemeinen FormelFurther investigations showed that equivalent effects when oiling and Preparing said fibers can be achieved with compounds of the general formula

R1 - COO - Y - OR2 R 1 - COO - Y - OR 2

worin R1 gradkettige oder verzweigtewherein R 1 is straight-chain or branched

gesättigte oder ungesättigte aliphatische Kohlenwasserstoffreste mit 5-17 Kohlenstoffatomen im Molekülsaturated or unsaturated aliphatic hydrocarbon radicals with 5-17 carbon atoms in the molecule

R-, wie in der Hauptanmeldung, kurzkettige aliphatische Kohlenwasserstoffreste mit 1-2 Kohlenstoffatomen im MolekülR-, as in the main application, short-chain aliphatic Hydrocarbon radicals with 1-2 carbon atoms in the molecule

und Y Polyglycolreste mit 3-10 Alkylenoxydgruppenand Y polyglycol residues with 3-10 alkylene oxide groups

bedeuten.mean.

Als Fettsäure bzw. Monocarbonsäure (S1 - COO) können Verwendung finden Fettsäuren, wie sie beispielsweise in der Paraffinoxydation anfallen oder solche, wie sie naoh Spaltung pflanzlicher, tierischer Öle und FetteThe fatty acids or monocarboxylic acids (S 1 - COO) that can be used are fatty acids such as those obtained, for example, in paraffin oxidation or those such as those obtained after the cleavage of vegetable and animal oils and fats

009845/182B0RiGIrJAL inspected009845 / 182B 0 RiGIrJAL inspected

erhalten werdene Die mit diesen Verbindungen erzielten Effekte entsprechen denen, welche mit den Verbindungen, wie sie in der Hauptanmeldung aufgeführt sind, erreicht werden.will receive e The effects achieved with these compounds correspond to those which can be achieved with the compounds, as listed in the parent application.

Beispiel 1example 1

Ein texturiertes Polyestergarn 135/17/2 rohweiß wurde geölt mit einem Methoxypolyglycol-Kokosfettsäureester, worin der Polyglycolrest etwa θ - 9 Äto-Gruppen enthält. Die Ölauflage betrug 2,6 %. Der Reibwert gegen Keramik verringerte sich im Vergleich zum unbehandelten Garn um 52 $. Die antistatische Wirksamkeit wurde mit einem Statikvoltmeter bei 20 C und 40 relativer Luftfeuchtigkeit gemessen. Während das unbehandelte Garn nach 420 Sekunden noch keine U!nt ladung des Kondensators zeigte, wurde beim geölten Garn nach 93 Sekunden eine völlige Entladung festgestellt. Ein Strickstück aus diesem Garn gefertigt, konnte unter HT-Bedingungen einwandfrei gefärbt werden.A textured polyester yarn 135/17/2 raw white was oiled with a methoxypolyglycol coconut fatty acid ester, in which the polyglycol residue contains about θ - 9 aeto groups. The oil coverage was 2.6%. The coefficient of friction against ceramics was reduced by $ 52 compared to the untreated yarn. The antistatic effectiveness was measured by a static voltmeter at 20 C and 40 i "relative humidity. While the untreated yarn showed no unloading of the capacitor after 420 seconds, a complete discharge was found in the oiled yarn after 93 seconds. A knitted piece made from this yarn could be dyed perfectly under HT conditions.

Beispiel 2Example 2

Ein texturiertes Triacetatgarn IOO/I wurde mit einem Isooctansäure-Äthoxypolyglycolester mit 12-14 Äto-Gruppen im Polyglycolrest geölt.A textured triacetate yarn 100/1 was made with an isooctanoic acid ethoxy polyglycol ester Oiled with 12-14 eto groups in the polyglycol residue.

Die Präparationsauflage betrug 3»2 i»\ Die Reibung gegen Metall im Vergleich zum unbehandelten Faden ging um 53 $ zurück.The preparation layer was 3 »2 » \ The friction against metal compared to the untreated thread was reduced by $ 53.

Beispiel 3Example 3

Ein Polyamidgarn 40/I wurde geölt mitA polyamide yarn 40/1 was oiled with

CH2 - CH - (CH2)8 - COO (CH2 - CH2O)10 CH3 CH 2 - CH - (CH 2 ) 8 - COO (CH 2 - CH 2 O) 10 CH 3

Die Ülauflage betrug 2,4 $· Es wurde eine Reibwertminderung im Vergleich zum unbehandelten Garn von 47 Ί· gemessen. Das Messgerät zeigte beim nicht präparierten Garn nach 420 Sekunden keine Entladung. Das präparierte Garn ergab nach 80 Sekunden eine vollständige Entladung des Kondensators.The overlay was $ 2.4 · A reduction in the coefficient of friction of 47 · was measured compared to the untreated yarn. With the unprepared yarn, the measuring device showed no discharge after 420 seconds. The prepared yarn resulted in a complete discharge of the capacitor after 80 seconds.

Ein Mischgarn aus 80 j£ Polyamidgarn und 20 Reyon zeigte mit dem vorerwähnten Produkt geölt, wesentlich günstigere Reibungswerte als mit einem herkömmlichen.A mixed yarn of 80 j £ polyamide and 20 i »rayon exhibited with the aforementioned product oiled, substantially more favorable values than with a conventional friction.

009845/1828009845/1828

Claims (1)

PATENTANSPRUCHPATENT CLAIM Verfahren zum Ölen und Präparieren von gefärbten oder ungefärbten Zelluloseester - oder vollsynthetischen Fäden oder Garnen sowie deren Gemische mit nativen oder Regeneratfasern, dadurch gekennzeichnet, daß zum Ölen und Präparieren der genannten Fasern Verbindungen der allgemeinen FormelProcess for oiling and preparing dyed or undyed cellulose esters - or fully synthetic threads or yarns as well as their Mixtures with native or regenerated fibers, characterized in that for oiling and preparing the fibers mentioned, compounds of the general formula E1 - COO - T - OR2 E 1 - COO - T - OR 2 worin R1 gradkettige oder verzweigte gesättigte oder ungesättigte aliphatische Kohlenwasserstoffreste mit 5-17 Kohlenstoffatomen im Molekülwherein R 1 straight-chain or branched, saturated or unsaturated aliphatic hydrocarbon radicals having 5-17 carbon atoms in the molecule Rp, wie in der Hauptanmeldung, kurzkettige aliphatische Kohlenwasserstoffreste mit 1-2 Kohlenstoffatomen im MolekülRp, as in the main application, short-chain aliphatic hydrocarbon radicals with 1-2 carbon atoms in the molecule und Y Polyglycolreste mit 3-10 Alkylenoxydgruppen bedeuten,and Y polyglycol residues with 3-10 alkylene oxide groups mean, verwendet werden»be used" 009845/1820009845/1820
DE19661594909 1966-05-11 1966-07-01 Process for preparing and oiling fully synthetic and cellulose ester threads Pending DE1594909A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DEB0087075 1966-05-11
DEB0087815 1966-07-01

Publications (1)

Publication Number Publication Date
DE1594909A1 true DE1594909A1 (en) 1970-11-05

Family

ID=25967883

Family Applications (2)

Application Number Title Priority Date Filing Date
DE19661594906 Pending DE1594906A1 (en) 1966-05-11 1966-05-11 Process for preparing and oiling fully synthetic and cellulose ester threads
DE19661594909 Pending DE1594909A1 (en) 1966-05-11 1966-07-01 Process for preparing and oiling fully synthetic and cellulose ester threads

Family Applications Before (1)

Application Number Title Priority Date Filing Date
DE19661594906 Pending DE1594906A1 (en) 1966-05-11 1966-05-11 Process for preparing and oiling fully synthetic and cellulose ester threads

Country Status (5)

Country Link
BE (1) BE698288A (en)
DE (2) DE1594906A1 (en)
FR (1) FR1522750A (en)
GB (1) GB1189581A (en)
NL (1) NL6706565A (en)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2812443C2 (en) * 1978-03-22 1982-12-02 Hoechst Ag, 6000 Frankfurt Polyglycol ether thermal formals and their use as fiber finishes
JPS60215873A (en) * 1984-04-06 1985-10-29 竹本油脂株式会社 Spinning oil composition of polyester or polyamide fiber yarn
DE3734931A1 (en) * 1987-10-15 1989-05-03 Henkel Kgaa AGENT FOR SMOOTHING TEXTILE FIBER MATERIALS
WO1997000351A2 (en) * 1995-06-19 1997-01-03 E.I. Du Pont De Nemours And Company Durable hydrophilic polymer coatings
US5767189A (en) * 1996-05-31 1998-06-16 E. I. Dupont De Nemours And Company Durable hydrophilic polymer coatings
US6068805A (en) * 1999-01-11 2000-05-30 3M Innovative Properties Company Method for making a fiber containing a fluorochemical polymer melt additive and having a low melting, high solids spin finish
US6207088B1 (en) 1999-01-11 2001-03-27 3M Innovative Properties Company Process of drawing fibers through the use of a spin finish composition having a hydrocarbon sufactant, a repellent fluorochemical, and a fluorochemical compatibilizer
US6117353A (en) 1999-01-11 2000-09-12 3M Innovative Properties Company High solids spin finish composition comprising a hydrocarbon surfactant and a fluorochemical emulsion
US6537662B1 (en) * 1999-01-11 2003-03-25 3M Innovative Properties Company Soil-resistant spin finish compositions
US6120695A (en) * 1999-01-11 2000-09-19 3M Innovative Properties Company High solids, shelf-stable spin finish composition
US6077468A (en) 1999-01-11 2000-06-20 3M Innovative Properties Company Process of drawing fibers

Also Published As

Publication number Publication date
GB1189581A (en) 1970-04-29
BE698288A (en) 1967-11-10
NL6706565A (en) 1967-11-13
DE1594906A1 (en) 1970-05-27
FR1522750A (en) 1968-04-26

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