DE1560672A1 - Process for the manufacture of non-woven fabrics - Google Patents
Process for the manufacture of non-woven fabricsInfo
- Publication number
- DE1560672A1 DE1560672A1 DE19651560672 DE1560672A DE1560672A1 DE 1560672 A1 DE1560672 A1 DE 1560672A1 DE 19651560672 DE19651560672 DE 19651560672 DE 1560672 A DE1560672 A DE 1560672A DE 1560672 A1 DE1560672 A1 DE 1560672A1
- Authority
- DE
- Germany
- Prior art keywords
- fibers
- thermoplastic film
- fiber structure
- layer
- textile fabric
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4326—Condensation or reaction polymers
- D04H1/4334—Polyamides
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4282—Addition polymers
- D04H1/4291—Olefin series
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4326—Condensation or reaction polymers
- D04H1/435—Polyesters
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/44—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling
- D04H1/46—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres
- D04H1/48—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres in combination with at least one other method of consolidation
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/44—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling
- D04H1/46—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres
- D04H1/48—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres in combination with at least one other method of consolidation
- D04H1/488—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres in combination with at least one other method of consolidation in combination with bonding agents
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/44—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling
- D04H1/46—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres
- D04H1/498—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres entanglement of layered webs
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
- D04H1/559—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving the fibres being within layered webs
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H11/00—Non-woven pile fabrics
- D04H11/08—Non-woven pile fabrics formed by creation of a pile on at least one surface of a non-woven fabric without addition of pile-forming material, e.g. by needling, by differential shrinking
Description
Beschreibung zur iratentanmeldung derdescription for the patent registration of
British. Nylon Spinners Ltd. Pontypool, IVioOnmouthshire, EnglandBritish. Nylon Spinners Ltd. Pontypool, IVioOnmouthshire, England
betreffend
"Verfahren zur Herstellung von nichtgewebten Textilstoffen"concerning
"Process for the manufacture of non-woven fabrics"
Es ist bekannt, Textilstoffe dadurch herzustellen, daß man einen Faseraufbau aus willkürlich abgelegten Fasern herstellt und dann die so erhaltene Faserbahn sticht, wodurch eine zusammenhaltende Struktur erhalten wird.It is known to produce textile fabrics by one Manufactures fiber structure from randomly deposited fibers and then punctures the resulting fiber web, creating a cohesive Structure is obtained.
Diese nichtgewebten Textilstoffe weisen jedoch verschiedene Nachr., teile auf, beispielsweise sind sie in ihren Abmessungen nicht stabil j außerdem sind sie nur schwierig mit der erforderlichen Oberflächengleichmäßigkeit herzustellen.However, these nonwoven fabrics have different messages, parts on, for example, they are not stable in their dimensions j in addition, they are difficult with the required Establish surface uniformity.
Zur Beseitigung dieser Nachteile wurde in der britischen Patentschrift. .... »».v. vorgeschlagen, eine thermoplastische folie in diese nichtgewebten Textilstoffe einzuarbeiten und sie durch eine geeignete Behandlung zu einer Verklebung mi't den Fasern au verblassen, " " "To overcome these drawbacks, the British patent. .... »» .v. proposed a thermoplastic film in incorporate these nonwoven fabrics and pass them through a suitable treatment for bonding with the fibers au fade, "" "
Se wurde nun gefunden, daß man Textilstoff θ .-mit .einer verbesserten -?olu»inoflität, Zusammendruokbarkelt und Porosität erhalten kann,It has now been found that textile fabric can be obtained with an improved oil inoflicity, compressibility and porosity,
1323 BAD ORIGINAL1323 BAD ORIGINAL
wenn man in nichtgewebte Textilstoffe, die eine Folie enthalten, durch die ein !"eil der Fasern des Textilstoffs hindurchgestochen ist, gekräuselte fasern einarbeitet.when looking at nonwoven fabrics that contain a film, through which a part of the fibers of the textile material is pierced, crimped fibers are incorporated.
So vvird gemäß der vorliegenden Erfindung ein Textilstoff vorgeschlagen, welcher dadurch gekennzeichnet ist, daß er aus einer Faserstruktur besteht, welche mindestens 20 $ gekräuselte Fasern und mindestens eine aus einer thermoplastischen Folie bestehenden Schicht, die mehr oder weniger parallel zu und zwischen den Oberflächen der Faserstruktur angeordnet ist, enthält, wobei ein Teil der Fasern in der Faserstruktur in Ebeneen parallel zu den Oberflächen derselben angeordnet sind und andere Fasern der Faserstruktur in Richtung des Querschnitts derselben angeordnet sind und die Schicht aus der thermoplastischen Folie durchqueren., Which is characterized in the present invention, proposed so vvird according to a textile material that comprising at least 20 $ curled fibers and at least one consisting of a thermoplastic film layer, the more or less parallel to and between the surfaces of the fiber structure, it consists of a fibrous structure, is arranged, contains, wherein a part of the fibers in the fiber structure are arranged in planes parallel to the surfaces thereof and other fibers of the fiber structure are arranged in the direction of the cross section thereof and traverse the layer of the thermoplastic film.
Vorzugsweise ist die thermoplastische Folie mit den Fasern verklebt.The thermoplastic film is preferably glued to the fibers.
Die thermoplastische i'Oxie kann auch einen aufgelösten Zustand aufweisen und sich über die gesamte Faserstruktur verteilen. Für verschiedene Zwecke sind jedoch riichtgewebts Textilstoffe, die eine thermoplastische Folie im aufgelösten Zustand enthalten, nicht geeignet, so daß es häufig bevorzugt wird, dpS die thermoplastische Polie ihre Folienform und ihre Lage durch die yerklebebehandlung nicht verloren hat.The thermoplastic i'Oxie can also have a dissolved state and spread over the entire fiber structure. For various purposes, however, directional woven fabrics are one thermoplastic film contained in the dissolved state, not suitable, so it is often preferred that dpS be the thermoplastic Polie its film shape and its position through the adhesive treatment has not lost.
Weiterhin wird gemäß der FJrfindung ein Verfahren zur Herstellung &ine3 nichtgewebten Textilstoffs vorgeschlagen, welches dadurch gekennzeichnet ist, dai3 man eine* ö c hi oh t struktur herstellt, welche einen Aufbau aus verhältnismäßig lose verbundenen Fasern, von denenFurthermore, according to the invention, a method for producing a nonwoven textile fabric is proposed, which is characterized in that a structure is produced which is made up of relatively loosely connected fibers, of which
009844/132 3 - - - *009844/132 3 - - - *
BAD OR)GfNAtBAD OR) GfNAt
mindestens 20 '/eine latente ICräuselung besitzen, und mindestens eine Schicht aus einer gesonderten thermoplastischen Folie enthält, daß man die Schichtstruktur sticht, so daß Fasern des Faseraufbaus durch die gesonderte thermoplastische Folie gezwungen werden, und daß man das gestochene Prodakt so- behandelt, daß die Kräuselung in den Fasern, die eine latente Kräuselung besitzen, entwickelt wird. ;■"■-'""■■.■ at least 20 '/ have a latent I-curling, and contains at least one layer of a separate thermoplastic film, that the layer structure is pierced so that fibers of the fiber structure are forced through the separate thermoplastic film, and that the pricked product is treated in such a way that the crimp is developed in the fibers having latent crimp . ; ■ "■ - '""■■. ■
Obwohl der so erhaltene Textilstoff eine zusammenhaltende Struktur ist, in welcher die Faserverschlingung, die durch das Stechen entstanden ist, durch die Entwicklung der Kräuselung verstärkt wurde, wird es bevorzugt, daß die thermoplastische Folie gleichzeitig mit der Kräuselungsbehandlung oder auch nachträglich zu einer Verklebung mit den Fasern veranlaßt wird.Although the fabric obtained in this way has a cohesive structure in which the fiber entanglement created by the stitching has been strengthened by the development of the crimp, it is preferred that the thermoplastic film be bonded at the same time as the curling treatment or also afterwards caused with the fibers.
Die Behandlung, durch welche die thermoplastische Folie klebrig gemacht wird, kann, je nachdem was für ein Produkt gewünscht wird, so durchgeführt werden, daß sie entweder ihre Form als gesonderte Folie beibehält oder sich auflöst und in der Faserstruktur verteilt.The treatment by which the thermoplastic film becomes sticky is made, depending on what is desired for a product, be carried out so that it either retains its shape as a separate film or dissolves and is distributed in the fiber structure.
Selbstverständlich kann man den bei der Stedioperation verwendeten 4ufbau aus mehreren Schichten zusammensetzen. Beispielsweise kann man die thermoplastische Folie auf beiden Seiten mit einer Faserbahn belegen und dann der Stechoperation zuführen. Es sind die verschiedensten Zusammenstellungen möglich»Of course you can use the one used in the stedi operation Assemble the structure from several layers. For example, can the thermoplastic film is covered with a fiber web on both sides and then fed to the piercing operation. They are various combinations possible »
Pasern die durch eine geeignete Behandlung zum Kräuseln veranlaßt '^•^op,,;. sind in der Technik allgemein bekannt, und sie bestehenPipes that cause curling by a suitable treatment '^ • ^ op ,,;. are well known in the art, and they persist
BAD ORJOtNAl. 0 0 9 8 4 4/1323BAD ORJOtNAl. 0 0 9 8 4 4/1323
meistens aus mindestens zwei verschiedenen sich über die Länge der Pasern getrennt erstreckenden künstlichen Polymerisaten. Durch eine chemische oder thermische Behandlung können die verschiedenen jrolymerisate zu einer unterschiedlichen Ausdehung oder Zusammenziehung oder anderweitigenVerformung veranlaßt werden, wodurch sich die Fasern kräuseln.mostly from at least two different synthetic polymers extending separately over the length of the fibers. By A chemical or thermal treatment can cause the various jolymerisate to expand or contract differently or otherwise deformation, whereby the fibers curl.
Die thermoplastische Siie kann aus den verschiedensten Materialien bestehen. Sie sollte jedoch bereits bei einer Temperatur klebrig werden, bei dir die fasern des nichtgewebten Textilstoffs nicht geschädigt werden. Es kommen beispielsweise in Präge: Polyäthylen und Polypropylen sowie andere Stoffe mit einem geeigneten Erweichungspunkt. The thermoplastic Siie can be made from a wide variety of materials exist. However, it should become tacky at a temperature that does not damage the fibers of the nonwoven fabric will. There are for example in embossing: polyethylene and Polypropylene and other materials with a suitable softening point.
Die erfindungsgemäßen Textilstoffe, bei welchen die thermoplastische Folie beim Verkleben ihren Charakter als Folie nicht verloren hat, sind insbesondere als Decken, brauchbar.The textile fabrics according to the invention, in which the thermoplastic Foil has not lost its character as a foil when glued, are particularly useful as blankets.
Die erfindungsgemäßen Textilstoffe, bei denen die thermoplastische Folie sich bei der Verklebung aufgelöst hat, sind etwas dichter und steifer und finden beispielsweise als Preßplatten für Koffer und für Innenauskleidungen für Automobile Verwendung.The textile fabrics according to the invention, in which the thermoplastic Foil has dissolved during gluing, are somewhat denser and stiffer and are used, for example, as press plates for suitcases and for interior linings for automobiles use.
Durch geeignete Auswahl der Stichdichte und der Stichtiefe können verschiedene nichtgewebte Textilstoffe mit einer ansprechenden Oberfläche erhalten werden.By suitable selection of the stitch density and the stitch depth, you can various non-woven fabrics with an attractive surface can be obtained.
0098U/13230098U / 1323
Das Elebrigwerden der thermoplastischen T?olie_ kann beispielsweise
durch eine i/ärmebehandlung oder durch eine Lösungsmittelbehandlung
veranlaßt werden. Die Entwicklung der Kräuselung kann durch die
selben Maßnahmen bewirkt werden. Aus diesem Grunde ist es mögliah
diese beiden Vorgänge gleichzeitig oder auch, falls selektiv,
wirkende ft aßncihmen ·angewendet werden, getrennt ablaufen zu lassen.The turning of the thermoplastic oil can be caused, for example, by a heat treatment or by a solvent treatment. The development of the ripple can be caused by the
the same measures are effected. For this reason it is possible to carry out these two processes simultaneously or, if selectively,
acting ft must be applied to drain separately.
BAD ORIGINALBATH ORIGINAL
Claims (6)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2205364A GB1063529A (en) | 1964-05-28 | 1964-05-28 | Non-woven products and a method for making the same |
Publications (1)
Publication Number | Publication Date |
---|---|
DE1560672A1 true DE1560672A1 (en) | 1970-10-29 |
Family
ID=10173137
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE19651560672 Pending DE1560672A1 (en) | 1964-05-28 | 1965-05-28 | Process for the manufacture of non-woven fabrics |
DE19651560673 Pending DE1560673A1 (en) | 1964-05-28 | 1965-05-28 | Nonwoven textile fabric and process for its manufacture |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE19651560673 Pending DE1560673A1 (en) | 1964-05-28 | 1965-05-28 | Nonwoven textile fabric and process for its manufacture |
Country Status (2)
Country | Link |
---|---|
DE (2) | DE1560672A1 (en) |
GB (1) | GB1063529A (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112411019B (en) * | 2020-12-04 | 2022-07-19 | 株洲千金药业股份有限公司 | Preparation method and application of composite non-woven fabric |
-
1964
- 1964-05-28 GB GB2205364A patent/GB1063529A/en not_active Expired
-
1965
- 1965-05-28 DE DE19651560672 patent/DE1560672A1/en active Pending
- 1965-05-28 DE DE19651560673 patent/DE1560673A1/en active Pending
Also Published As
Publication number | Publication date |
---|---|
GB1063529A (en) | 1967-03-30 |
DE1560673A1 (en) | 1970-12-10 |
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