DE1467699A1 - Detergent compositions and processes for their preparation - Google Patents

Description

Museum park. 1, Rotterdam / Holland

Detergent compositions, as well as methods too their manufacture

Priority: British patent application

IJr. $ 28 7C / 64 of July 10, 1964

The invention relates to detergents and in particular those which have a noticeable effect with good coarse washing capacity show pressurized foaming and a method of making these detergents.

Usual coarse detergents, which are no cause for complaint when used in paddle wheel washing machines cause difficulties when used in drum washing machines or such washing machines, which are similar to these in terms of strong movement. The foam that develops in excess tends not only to overflow, but also prevents the movement of the textiles in such a The extent that the agitation becomes insufficient for effective cleaning. (so-called "pillow effect")

Accordingly, as a result of the introduction of drum type washing machines there is an increasing demand for detergents which at least have good coarse washing capacity the usual detergents, but do not have the disadvantages of heavy foam development exhibit"

As it is a well known fact in the soap and detergent industry that soap, alone or

in a mixture with free fatty acids, the Schaumver-909825/1376

like a detergent of the sulfonate or sulfate type, Particularly in hard water, a solution to the problem should be to master the Foaming effect of such a detergent in the incorporation of a certain amount of soap in a strong foaming coarse detergent in order to arrive at a low foaming coarse detergent.

Various attempts have been made in this direction » However, if the addition of a soap or a soap / fatty acid mixture is too low, the The foam-reducing effect of the mixture is too low, on the other hand if too large a quantity of such a mixture is used, the same disadvantages arise, as they are experienced with soap powders, namely an incrustation of the substances, which leads to a yellow Discoloration of the washed items during storage leads to foaming, etc.

Attempts to overcome these difficulties are already known * from the literature for example, suggested a combination of soaps made from saturated fatty acids and nonionic To use detergents, which is not very attractive because it is an uneconomical effort of nonionics in such compositions.

It has now been found that it is a satisfactory, simple and economical / attractive process for regulating the foaming power of a detergent based on a synthetic anionic Detergent gives without the disadvantages of the presence of too much or too little Soap are given in the composition and without an uneconomical amount of expensive nonionics is used in the detergent formulation.

An important object of the invention is to provide a foam depressant mixture for incorporation into a detergent based on an anionic synthetic detergent with coarse washing ability to

to get such a rough detergent, which is especially 909825/1378 *

~ ³ ~ ORIGINAL BATHROOM

suitable for use in drum washing machines or similar washing machines with more powerful and faster Movement is because the foaming is reduced to such an extent that there is no risk of over-foaming in them Fasohmasohintypen is to be feared ·

A further aim of the invention is to provide such a low-foaming coarse detergent which has at least the good washing capacity of the usual detergents, but without having a foam capacity that would lead ^{to the "pillow effect 11.}

A further object of the invention is to reduce the stability of the sole formed so that none Risk of accumulation of foam that has already formed with newly formed foam as a result of the rotation of the cylindrical boiler of the drum washing machine, which lead to such an increase in Sohaumschioht that it would eventually cause foaming.

The invention is based on the observation that a mixture of essentially a hydrocarbon and a high molecular acyl-containing ingredient (a fatty acid or a mixture of fatty acids and / or their alkali soaps) has a pronounced inhibiting effect on the foaming power of an anionic synthetic detergent without this misalignment is disadvantageous for the coarse detergency of the detergent. It has been observed that the combination of one Hydrocarbons and a fatty acid or its alkali soap have a much more pronounced pressure on the skin Shows effect than using any of these compounds alone as an additive to detergent · Further Hosts the hydrocarbon - or the mixture of hydrocarbons - and the fatty acids and / or their Alkali soaps in a synergistic manner in terms of suppressing the foaming of synthetic anionic Detergents without adversely affecting their cleaning power.

According to the invention, a coarse detergent with a squeeze action essentially comprises a synthetic 909825/1376

- 4 - ^ßA D

Anionic sulphate or sulphonate detergent, an alkali polyphoid and a thick mixture which consists essentially of a hydrocarbon with a boiling point above 90 ⁰ O and a fatty acid with 12 to about 31 carbon atoms and / or their alkali salts.

Soap-squeezing added to the detergent mixture Mixture is to maintain an inventive Detergent approx. 0.6 - 20 grew.- £ of the total Wasohmittelansatzes, which also essentially about 5-30 percent by weight of a synthetic anionic Contains sulfate or sulfonate detergent and from 5-60 Grew.-ji of an alkali phosphate.

A preferred detergent approach according to the invention includes 10-20 Grew .- $ 6 of a synthetic anionic Sulphate or sulphonate detergent, 35-45% by weight of one Alkali polyphosphate and 2-14 wt .- ^ of a foaming agent Mixture·

Hydrocarbon suitable for use according to the present invention can be a straight-chain or branched alkane, an alkene, an alkylated benzene, a condensed aromatic compound, their alkylated derivatives, or an alioyolic hydrocarbon, for example paraffins with a boiling point above 10O ⁰ O, octene, decene , Undecene, dodecene, tetradeoene, hexadecene, octadeoene, n-propylbenzene, η-butylbenzene, t-butylbenzene, decylbenzene, t-indecylbenzene, n-dodecylbenzene, tetrapropylenebenzene, tetradecylbenzene, for example, tetra-decylbenzene and its derivatives, tetrahydronewe and its methyl derivatives, naphthalene and its hydrogenated derivatives. Anthracene and its methyl derivatives. Cyclohexane and cycloheptane may be mentioned as examples of an alicyclic compound, while menthane as monocyclic terpene and pinane, pinene, sibane and thuja as bicyclic terpene; Camphan is also suitable for this purpose

909825/1376

The fatty acids and / or their alkali soaps, which can be used together with a hydrocarbon as constituents of the foam-thickening mixture according to the invention, are generally commercially available fatty acids and / or soaps which are derived from preferably hydrogenated natural oils. Mixtures derived from preferably hydrogenated natural oils with a titer of at least 33 ^° C. are also suitable.

The mixture according to the invention preferably consists of fatty acids and / or their soaps, of which about 6C $ to 8 ($ a chain length of nxigKzxxlx 16-18 carbon atoms and about $ 20 to about $ 40 have a chain length of less than 16 carbon atoms

Mixtures of fatty acids which have such a distribution of the chain length of the acyl radical can by saponification of mixtures of vegetable and / or animal fats, which for example, tallow, palm kernel oil, palm oil and / or peanut oil. The mixes can also go through simple mixing of the individual fatty acids in a certain ratio can be obtained

For example, fatty acids and / or soaps, which have the above-mentioned distribution of acyl radicals, mixed with hydrocarbon material having a boiling point above 90 ⁰ C, such as Parafflnöl and / or paraffin wax, dodecylbenzene or turpentine oil, and this foam-suppressing mixture incorporated into a detergent, which is substantially contains a synthetic anionic sulfate or sulfonate detergent and an alkali polyphosphate, a detergent is obtained with little

cd foaming power

¹ ^ are preferably fatty acids and / or soaps ver - "* ·""addresses, which the subsequent distribution of Ket ~ c *> tenlänge the acyl radicals have" 15 - 30 i 'the cn acyl radicals have a chain length of less ale 18 Kohlenet of fat omen, 30 - 60 i> the aoyl radical

have a chain length of 18 carbon atoms, 15-30 $ of the acyl radicals have a chain length of more than 18 carbon atoms. In this case, the detergent finally obtained has an optimally low foaming power, especially at higher temperatures, even up to the boiling point of the washing solution. Mixtures of fatty acids containing the. have the last-mentioned distribution, are obtained by saponification of hydrogenated marine animal oils, for example herring oil, menhaden oil and whale oil or hydrogenated rapeseed oil

By incorporating a foam-suppressing agent consisting of a mixture of a hydrocarbon and the last-mentioned fatty acids and / or their soaps in a detergent formulation according to the invention, a detergent can be obtained which shows a pronounced reduction in the foam capacity, as in particular due to the height of the foam layer, which remains essentially constant over a wide temperature range is proven. This temperature range * is influenced by the choice of hydrocarbons or fatty acids and / or soaps. The wide range of temperatures, which temperatures of about 20 ⁰ C to above about 80 ⁰ C comprises, one of the most important properties of the detergent according to the invention, makes them particularly suitable for use in drum washing machines, which, depending on the laundry within this range specific to various Temperatures can be set.

The ratio between hydrocarbons and fatty acids and / or soap in the foam-suppressing misohung is preferably about 1: 1, but can vary between cd about 1: 2 and 3: 1, depending on the final product

J ₀ desired properties

NJ According to a particular embodiment of the invention

^ the foam-suppressing misohunt can also be a non-

^ J ionic synthetic detergent contain which ^ J can be defined in the broadest sense as a compound containing aue 'alkylene oxide groups and a hydrophobic organic part consists of Ale aiohUoni-

. * Surface Subatanzen example, can be used higher alcohols and alkyl phenols _t which with 8-50 Äthylenoxydgruppen condensed Bind, for example lauryl alcohol or tallow alcohol, which are condensed with about 10 moleη ethylene oxide per mole of alcohol, or compounds which bind duroh implementation tinea Polyoxydpropylena with ethylene oxide produced ·

The amount of the ternary squeeze-out mixture according to the invention (a hydrocarbon, a fatty acid and a Honionio) can be between 0.6 and 30 Gtow.fC dta total Wason average rate, this amount is preferably in the range of 6-20 otv.-ft based on the total product. The ratio of the amount of hydrocarbon to the total The amount of the component containing fatty acid radicals and non-ionic substances is preferably 1x1

Examples dtr synthetic anionic Sulfonatdetergentien that the inventions ^ »T« fcT be used dung according in the detergent, are branched or unbranched alkyl aryl sulfonates, especially those Alkylbenaolaulfonate, having an alkyl group of zumindeat 6 carbon atoms, such as Dodeoylbenzoliulfonat or Alkylglyoeryläthersulfonat.

Examples of synthetic anionic sulfate detergents are sulfates, which differ from higher fatty alcohols with at least 12 carbon atoms, such as lauryl alcohol, tallow alcohol, coconut oil alcohol, derive. The sulfates can also be obtained from alkylene oxide condensation products of these higher alcohols

<o or derive alkylphenols

° I

^ The detergent according to the invention can continue

w contain: build-up substances, fillers and normal "v» auxiliary substances, such as dirt-suspending agents, odoriferous substances or fluorescent dyes. Examples * " ⁴ separate components are silicates, sodium salts of ethylenediaminetetraacetic acid and nitrilotriacetic acid.

The aynergy-like effect that can be observed with solutions dtr inventive detergents,

which, in addition to a synthetic sulfate or sulfate detergent and an alkali polyphosphate, contain a foam-suppressing mixture of a hydrocarbon and a fatty acid and / or its soaps and preferably a nonionic, can be shown in the following way with regard to their foam-suppressing effect. A standard solution is prepared which contains an anionic synthetic detergent and a condensed polyphoaphate in constant ratio, and the peeling of this solution is obtained under standard conditions according to the internationally recognized method of Ross-Miles ("oil and Soap", te, 1941, p. 99 - 102), with this method the mixture consisting of the fatty acids hardened fish oil and paraffin oil was tested with or without polyoxypropylene ethylene oxide condensate, using a standard solution containing 1 g / l dodecylbenzenesulfonate and 2 g / l tripolyphosphate Results are given in Table I.

Foam height tests (Ross-Miles) at 20 ⁰ C, in hard water

1 1 1 1 1 CVJ 2 2 2 CVl 0.2 ^, 0.1

(g / l used in experiment no.)

1 _2 3 4 dodecylbenzenesulfonate
Tripolyphosphate

Sodium soap made from hydrogenated fish oil fatty acids

Polyoxypropylene ethylene oxide _ _{o n}

(Molecular weight about 2000) """ ^Ό * ^{ά Ul}

Paraffin oil - - - 0.2 -

Foam height (cm) a) eofort 20.5 12.5 16.5 15

b) after 5 min. 20.5 11 HU >

909825/1376 _ _Q "

7th 1467699 9 10 6th 1 8th 1 1 1 2 1 2 2 2 - 2 0.05 0.05 0.1 0.1 0.1 0.1 0.05 - 0.1 0.05 0.05 0.1 0.1 18th 0.05 10 12th 7th 16 6th 8.5 9.5 5 4.5

Dodecyl benzene sulfonate
Tripolyphosphate

Hardened sodium soap
Fish oil fatty acids

Polyoxypropylene ethylene oxide
(Molecular weight about 2000)

Paraffin oil

Foam height (cm) a) immediately

b) after 5 minutes

+) (DH - 1 ⁰ DH is 1 g CaO per 100 1 water)

The above values show that the foam-suppressing mixture, from the ingredients fatty acids and / or Soaps, a hydrocarbon and preferably nonionics, have a much more pronounced effect on those Has a reduction in the foaming power of the detergent, than either of these components alone. According to Table I, an optimal reduction in buccal strength becomes obtained when the ratio of soap in relation to the total amount of hydrocarbon and Nonionic is 1: 1 (see Experiment 8). This test also shows that the foam formed has poor persistence if a foam-suppressing mixing unit according to the invention is present in the detergent

In Table II the synergistic effect is shown, which is achieved when a foam suppressing Mixture according to Table I, in which, however, the paraffin is replaced by dodecylbenzene or turpentine oil was replaced, «Except for polyoxypropylene-ethylene oxide adduct the influence of Nonylphenol / 10 E.O. and lauryl alcohol / 10 E.O. on investigated the foaming power of the detergent.

909825/1376 - 10 -

ΐ ABe lie II , /

Foam height tests (Rosa Miles) at 8O ⁰ O in hard water (14 ° DH)

Concentration in g / l in the experiment ffr

1 2 3 4 5 6 7 8

Dodecylbenzenesulfonate 1 1 1 1 1 1 1 1 Tripolyphoshpat 2 2 2. 2 2 2 2 2 Hardened soap
Fish oil fatty acids - 0.2 0.1 0.1 0.1 0.1 0.1 0

Dodecylbenzene - - 0.1 - - - 0.05

Oil of turpentine - - - o, 1- - - -

Polyoxypropylene ethylene oxide _{n Λ n nt} -

Molecular weight about 2000) ~ "~" υ, ι - - υ, υρ

Ionylphenol / 10 E.O. _-.-__ 0.1 - -

Lauryl alcohol / 10 E.O. - - - - - - 0.1 -

Foot height (cm) immediately 20 18.5 10 15 13.5 16.5 16.4 4

after 5 min. 1.50 0 0 0 0 0 0

Time after which the _ ο Λ / ο Λ λ oVo oUo Va

Foam height is zero (min) d 1/2 1 1 ^ d 272 Y4

Foam height is zero (min)

9 10 11 12 13 14 15

Dodecylbenzenesulfonate 1111111

Tripolyphosphate 2 2 2 2 2 2 2

Soap of hardened _{ni n} ,,. ..

Fish oil fatty acids ⁰ ^ ° » ¹ ° ' ¹ °» ¹ ° » ¹ ~

Dodecyl benzene 0.05 0.05 - - - 0.2 co

ο turpentine oil - - 0.05 0.05 0.05 - 0.2 er>

Polyoxypropylene ethylene oxide _{Λ nt} -

5 lbs (molecular weight about 2000) "" "» ^ 5-

- »Nonylphenyl / 10 E.O. 0.05 - - 0.05 "-

^ ¹ lauryl alcohol / 10 EO - 0.05 - - 0.05 -

Foam height (cm) immediately 8 10 11 13 13 20 20

'after 5 min. 0 0 0 0 0 1 1

9 10 11 12 13 U

Time after which the foam height is zero (min)

According to Table II, the incorporation of turpentine oil alone into the dodecylbenzenesulfonate tripolyphosphate mixtures gives an instant foam height of 20 (Versuohi5) »which drops to 1 after 5 minutes, whereas the incorporation of soap alone under comparable conditions causes an immediate foam height of 18.5 (experiment 2), which drops to Hull after 5 minutes. Compared with these values, a pronounced synergistic effect observed when the combination of a special soap, the hydrocarbon and optionally a nonionio is incorporated into the mixtures containing dodeoylbenzenesulfonate and tripolyphosphate, namely in that in experiment 8 a maximum reduction in the height of the cavity, namely to 4, is determined. In addition, the above tests show that the durability of the foam is so greatly reduced by the use of the various foam-pressing mixes according to the invention that the foam height falls within 1 kinuie to Hull. This is an important property of the detergents according to the invention, since by using a washing bag, what a veriainaerte dohaumhöne ergiot, jeaooh A ucaoilen foam is exerted in an Irommeiwascnioaauhine or an annliunen Wascnmasohine with a starter and a similar movement - despite a reduced capacity in terms of space - foaming over we enter, as a result aes Aufscnionteus aes

co newly formed exi bcnauins aui αβη υβχ-eits

co foam when uiesex- noon mom. 2uaammeufteiaij.cn ιηι <·

ro detergents according to the present invention ί ^ generally prepared by mixing the ~ * synthetic anionic sulphate or Sulfonatde- ^ ³ tergens, the Alkalipolyphosphats, the hydrocarbon substances, the fatty acid (s) and / or one or more Soaps and the other additives with water in any order to a pulp, after which this

BATH

Slurry is homogenized to a high degree. This pulp becomes the final solid detergent through Heat drying methods such as spray drying or drum drying obtained. The hydrocarbon is, however, advantageously separately from the pulp of the other components of the Waedi means incorporated in such a way that a homogeneous dispersion is obtained. This can be achieved, for example by stirring the hydrocarbon particularly quickly into the slurry. With advantage the a is carried out by mixing the slurry containing the hydrocarbon in a homogenizing apparatus for example a colloid mill or similar device. The most preferable and simplest method of incorporating the hydrocarbon

in the pulp there is a pre-emulsification of the hydrocarbon with the synthetic anionic detergent ingredient, or a part thereof, and subsequent incorporation of this emulsion into the slurry with vigorous stirring.

Becomes a detergent in which a hydrocarbon is incorporated by the method described above is dissolved in water, a metastable emulsion is obtained which has a cloudy appearance. He follows incorporating the hydrocarbon in a different way does not result in a homogeneous dispersion of the hydrocarbon and accordingly no metastable emulsion, if the one made from this slurry Detergent is dissolved in water; in this case the hydrocarbon will be immediate separate from the aqueous solution as a separate layer, which is disadvantageous for the washing success is. Also, if a liquid hydrocarbon is not well distributed in the slurry is, the finally obtained dry powdery Sweat out the hydrocarbon product.

- 13 909825/1376

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The following examples serve to illustrate the invention

Example 1.

A hydrocarbon material made up of paraffin oil and paraffin wax in a ratio of 1: 1 (what if desired, can take place at a slightly elevated temperature) with a part or with the total amount dea dodeoylbenzenesulfonate, which should be contained in the finished detergent, emulsified die Emulsion was made with an aqueous slurry containing the others desired in the final product Ingredients, mixed. A comparison of the approaches is given in Table III. The thus obtained Slurry was then subjected to spray drying. The powder detergents produced in this way showed excellent back properties.

Table III

Wt .- $ in batch no.

Dodecyl benzene sulfonate 14th 40 13th 9 , 2 Sodium carboxymethyl cellulose 1.4 6th 1.2 1 Sodium tripolyphosphate 6th 40 40 Sodium ilicate 6th 6th 6th sodium 0.14 5 5 Sodium sulfate (anhydrous) 0.15 5 5 , 14 Fluorescent dye 15th 0.14 0 , 15 Fragrance 1 0.15 0 Sodium perborate - 15th 15th Sodium soaps of fatty acids
hydrogenated fish oil 1 1 Sodium soaps from coconut oil
acids - 4th Nonylphenol / 10 E. O. 3 3

- 14 -

Polyoxypropylene / ethylene- 111 oxide (Molgew, about 2000)

Paraffin wax 11 1

Paraffin oil 111

Humidity to 100 to 100 to 100

Foam height tests (Ross-Miles) at 20 ⁰ C in hard water (15 ⁰ DH)

(Concentration 5 g / l) approach ITr. 1 Mr. 2 No.

Foam height (cm) 10.0 10.5 6.5

Using a drum type washing machine, izx practical washing tests were carried out with water of 15 ° DH. The wash liquor contained 5.0 g detergent per liter. In the accompanying drawings A, FIGS. 1, 2 and 3, the graphs of foam height and temperature are shown. In these figures, the ordinate represents the foam height in cm, the abscissa the temperature of the foam in ⁰ O, while the items to be washed are added to the arrows. The curved line represents the level at which effervescence occurred · As seen from these representation is visible, keeps the foam-suppressing effect over a wide temperature range, namely at about 2O ⁰ C to about 80 ⁰ C.

Example 2 .

^ There were two series of practical washing experiments

with the following detergent approaches, which after

öd the method described in Example 1 prepared

cn had been carried out, with the washing liquor

_ »Contained 5.0 or 6.5 g detergent per liter. the to

<j results of these tests for containing 5 g per liter Detergent solutions are in curves 1-5 of the

- 15 -

Drawing B reproduced, with the tests for Waaohlauge, which contains 6.5 g per liter, in the Curves 2-6 of Drawing O are shown while Curve 1 not determined due to excessive foaming let. The meaning of the coordinate system, the curved line and the arrow are the same as in example 1 every curve number corresponds to the same approach number

Table IY

Waaohmittelan a uts used in the work experiment (Jew.-9t in batch no.

¹³ ' ^{2 13} ' ^{2 13} ' ^{2 13} » ^{2 13} ' ^{2 13} ' ^{2 13} ' ^{2 13} ' ²

Sodium Oarboxymethyloellulose

Tripolyphosphate 32.1 32.1 32.1 30.1 30.1 30.1 30.1 30.1 Polyphoephate 13.2 13.2 13.2 10.2 10.2 10.2 10.2 10.2 Sodium silioate 6.2 6.2 6.2 6.2 6.2 6.2 6.2 6.2 Sodium carbonate -. - - 5.0 5.0 5.0 5.0 5.0

Sodium sulfate 8.0 8.0 8.0 8aO 8.0 8.0 8.0 8.0 Sodium lump borate 12.0 12.0 12.0 12.0 12.0 12.0 12.0 12.0

Sodium from Fatty acids hardened - 42 4 2 2 1 0.5

killed fish oil

P oly oxy pr opy Ie n-

ethylene oxide (mol- ---- 2-1

weight about 2000)

Paraffin oil - - 1 1.4 1.4 0.7 0.7 0.35 Paraffin wax - - 1 1.4 1.4 0.7 0.7 0.35 Humidity to 100 to 100 -

909825/1376
- 16 -

Claims (12)

Claims 1. Detergent high Grobwasch- and reduced foaming capacity, characterized in that it comprises essentially a synthetic Toggle ionic sulphate or sulphonate detergent, an alkali metal polyphosphate and a foam-inhibiting mixture, the latter is a hydrocarbon having a boiling point above 90 ⁰ G and a fatty acid containing about 12 'to about 31 carbon atoms and / or their alkali elves. 2. Detergent according to claim 1, characterized that there is 5 to 30 wt .- $ of an anionic sulfate or sulfonate detergent, 5 to 60 wt .- ^ of an alkali polyphosphate and 0.6 to 20% by weight of a foam suppressing mixture. 3. detergent according to claim 2, characterized that the content of the synthetic anionic sulfate or sulfonate detergent between 10 and 20 $, the content of the alkali lipolyphosphate between $ 35 and $ 45 and the foam-inhibiting compound content between $ 2 and $ 14 is based on the total weight of the composition. 4. Detergent according to any one of claims 1-3, as through characterized in that the hydrocarbon component of the foam suppressing mixture is selected from the group consisting of straight chain or branched chain alkanes or alkenes, alkylated Benzene, naphthalene and anthracene and alkylated derivatives and alicyclic hydrocarbons is· 5. detergent according to claim 4, characterized in that that the hydrocarbon component consists of saturated straight-chain or branched-chain high molecular weight alkanes with a , Boiling point over 100 ⁰ C exists. - 17 909825/1376 6. Detergent according to claim 4, characterized in that the hydrocarbon component Dodecylbenzene is 7. Detergent according to claim 4 »characterized in that the hydrocarbon component Turpentine oil is 8. Detergent according to one of claims 1 to 7 »characterized in that the fatty acid component of the foam-suppressing mixture contains fatty acids and / or their alkali soaps, of which about 60 to about 80 fo acyl radicals with 16 to 18 carbon atoms and about 20 $ to about 40 ^a / o acyl radicals with fewer than 16 carbon atoms own" 9. Detergent according to one of claims 1 to 7> characterized in that the fatty acid component of the foam-suppressing mixture contains fatty acids and / or their alkali soaps, of which about 15 i ° to about 30 tfo acyl radicals with more than 18 carbon atoms, about 30 to about 60 ^a ß> acyl radicals with 18 carbon atoms and about 15 to about 30 ° ß> contain acyl radicals with fewer than 18 carbon atoms 10. Detergent according to one of claims 1-9 »characterized in that the ratio the amount of hydrocarbon to the amount of fatty acid or fatty acids and / or their soaps is about 1s1 in the foam-pressing mixture. 11. Detergent according to one of claims 1 to 9> characterized in that the foam suppressing mixture is also a nonionic synthetic Detergent contains ep 12. Detergent according to claim 11, characterized in that - ^ indicates that the content of the foam oppressive mixture between 0.6 and 30% by weight - ⁴ 'total detergent formulation is « ^ 13 «detergent according to claims 11 and ^, thereby marked that the , _o BAD OfUGjNAL - 18 - non-ionic synthetic detergent a polyoxyethylene condensation product of an ethylene oxide with higher alcohols or alkylphenols or with a propylene oxide / Propylene glycol condensation product is He detergent according to one of claims 11 bia ^, characterized characterized in that the ratio of the amount of hydrocarbon in relation to the total amounts of the component containing fatty acid radicals and the synthetic nonionic detergent is 1: 1 * 15 · A method for producing a detergent according to one or more of claims 1 to 14, characterized in that the synthetic nonionic sulphate or sulphonate detergent with an alkali polyphosphate, a hydrocarbon, fat- acid (s) and / or their alkali soaps and other additives and water to form a slurry or a Slurry mixed, then this slurry is homogenized and finally heat-dried. 16. The method according to claim 15, characterized in that that the hydrocarbon initially with part of the anionic sulfate or sulfonate detergent emulsified and then this emulsion was incorporated into the pulp BAD OniutNAL 9 0.9 825/1376