DE1444090A1 - Compositions and methods for treating textiles - Google Patents

Description

JJ * · IN THE MAAS »JW. G. PFEfFFER PATENT Attorneys

Monks 23

UNGERERSTR. 25. TEL 333036

62 897

Y.St.A.

=; = S s iss =;

Compositions and Methods for Treating

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Textiles.

The invention relates to compositions and methods fanren for treating textiles for cleaning and around to give them the desired Bigensciiaften de @ Griffi- ·.

Means "which for Beöandlusig of © ewcsfcfm are ₉ to vörfcessern uia their softness and their Sriff" eind known. in general these are wslcbmacheftisu Zummsmenmtζ \ ι · α & βη

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144408C

the ale Stoffwsiohmacnör bsgei paved and. star Bateadlung of substances wäbremcl the Wssölheras applied vj © rä®n ₉ Flüeelglceiten »which as the tohauptsäeblicli effective © component a © quaternär®

g included-. ■ <§ &. e5m "substituted ammonium = all 4 Waasex'stöffatome of the Ammoaiuaireetes through Keete «are substituted *

When turning aiua vias in the household, they become liquid ?! Sto££w@ichins.ehhabenr-Baufen wlte © nd fies Spüleng ias SpU-lvaaeer '' - sug @ s @ tst _s where generally about 3 -fels 5 minutes are g @ late. .The © © rforäörtj dal d © x Teribrauelie-r dsa tfasebvorganf "Eigans ■ Üherwac'ist or other YorsriebtsaisSamen meets» -demit

liquid © S "töf £ weiphffiäelier % vm r-icbtig ^ m Esltpunlst will ο Ia fall ψοη house frames nmk others

mui "der? @ rll3raueh © r e.ntweäer directly Tor äea Flush © the during d @ s Spilleag ira Eahaien- fiss Wasob ^ org see the V / aschmase.hin © surückkehrea ,, what kind of perssneti with Workload is an essential burden. Outside of that

. ¥ erbraueb @ r especially "dar-E" f -as ^ tetis, that he di © g @ 'MsBgt desiquid StöffK © lctoao & © re ia i @ r rinsing stage of the washing process y ^ ruetiu ^ t_ and a larger one

sleeps out to © im © 1 | ^ erd @@ iereig äi © _ ias V / asrcligut feMufig water-repellent Scann _£ with a continuous film on the fabric surface £ äitrü @ klbX © ii »t und i © a fabric« m eJr _s ; certain ⁵ v © rlieb. @ ni

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Ea datier in bohera measure desirable and advantageous _t to have a fabric softener * which can be used with the detergents with good effect »as they are usually used for washing stills» so that the fabric softener during the washing stage either on its own or can be equal to each other are added in Gsesisch with the cleaning agent "Iat the case of automatic washing" machine eliminates characterized _f the need for the consumer in the tfaschvorg & ng engages before he iat terminated and the laundry can be dried * Se _y is however generally recognized that the for Since available liquid fabric softeners cannot and should not be used in the washing process during the washing stage in the presence of detergents customary for this purpose, the deep fabric softeners cannot be combined in a single package with solid detergents, but what nooh is more essential, 1st the U It was necessary that the usual liquid plasticizers, even if they could be added on their own during the washing stage, do not fulfill the purpose intended with them and have little or no effect on the laundry. A possible explanation for this is that üb _s © r # 90 the usual detergent synthetic surface-active agents of the anionic type or nichtionlschen

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use. These detergents can, often 4p case is the more diverse amplifier, a * B, Alkall- "carbonate ₉ silicates _s phosphates, Hatriumsilieat and Satriiw"

j but elnA the synthetic superfiäehea means the main effective cleansings stoff® & $ r Ziägs & fimensetfsttngen. Bi? act as ingredients in the usual

Nature uafl.ee '% rird..aBgeaooaient -flafl ..die totidnissteea Stoff- * welohmaehef äurois your Utaeetsuiig ffli-t den In 4 · α

present 'p ^ e ^ fllsfeesiföletiven ISit-tslm inactivated

etcl2itafiB äLvA *. '-wend them in' der tfaeo & etnfe sussaatn.alt

dar .but suffered from se la tea

that the products aur tm ias? . .applied «mrdea shall« from which, .alflih mil® © liea,

. result the! bits of the "VerwenÄtsnig-dejp ■ & ®r Spttlietufe are connected *

mum g®fiaad © n ₉ - toi taatiniffie y

Present ^ oe Waschisittelsi during the W & eelia-tttf *

0 980 5/1034

a washing process for textile goods can be used and completely unexpected advantages are achieved. Further, it was found that the erfindungsgeaäßen Stoffwaictoaacbtr advantageous naf te rwei se can be combined with Waeohsiitteln containing as an active detergent sin synthetic, anionic © e or not s ionic surface active agent, and so resistant Hebreweckwaschmittel result _E in the Wasofastufe one on eineal tf & äeitvorgangs can be introduced, have a good washing effect and at the same time give the washed items the desired soft feel. 33er SasatE the erfindungsgeaäSen Zusapaensetsungen that • in prayer gene i $ r wash £ 5wecke and starry StaffwelehBaeher included, while the Waschstuf "of Wasehvorgangs has the advantage tHe consumers of the annoying üotwendigk» it is free, during the Spttlstufe in Sesa ^ process • intervene as was previously necessary «

Practicing I * Segenaats to previous views and Torsehriften diet erfindungsgenäSen Stoffweichaaaher a ausgcsciobne ^ · Virkung out when they are used by anionic and niohtionisoben detergents during Wasehstufe In (legeswmrt. Pie using the Stoffweiehmaoher In Wasohstufe * is nicbjfc only is insight the inconveniences are of great advantage for the consumer «but also has the remarkable and completely unexpected part of the goal

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14440S0

Items to be washed the desired whiteness and desired Sijgensebaften Sea Griffs fall in love very much will. These essential Srgebmise® are also received «© tee that & i @> @@ fabr insists that a tfeerdoeis the 3toffWeiebmacber on Sas WaBCbgut

Ui @ tltof fveiefemaeber can invent one of textiles in front of the washing machine

¥ asebVGrgang3 Tor o & er on the same side sit de? Betergens oS @ r wäbrenS of the Waso stage naoli Sugabe iat®

be sugesetst .. B @ ist | ®doo! s des ier Erfändwig «stable® _B feet® Mebrsweokwasel»

Fabric © & u eebgff @ n _@ die

Hluototof © - Si © @u wms @! Ä®nd @ n fabrics mm ^ i g®r®iiiigt al »

are known® Stoff ^ ₉ sm 'S @ nen gatas nitrogen-containing ¥ @ r "biM« nieti ₈ like

8 0 9805/1034

Amumium compounds and 4min® born * which contain at least one straight-chain organic bed with at least 8 carbon atoms, preferably with 12 to 18 carbon atoms.Examples of preferred cationic compounds are quaternary auraon preconditions with at least one straight-chain organic bed with 12 to 18 carbon atoms, primary, second »Dary and tertiary amine compounds with at least one straight-chain organic compound with 12 to 18 carbon atoms _and 1.3 ° propylenediamine compounds with a» straight-chain organic compound with 12 to 18 carbon atoms and laidazoline compounds with a straight-chain organic heat bit with 12 to 18 carbon atoms. Compounds * such as di (hydrogenated sebum) ° diaethy! Ammonium chloride, 2

Ui- (hydrogenated tallow) -diinethylammoniuffifflethylöulfa1 ;, primary tallow, primary hydrogenated lalgaiain, ialg-1, ^ profylen «diaijin, oleyl = 1,3-propylenediaain and Cooos« 1 ₉ 3 »propylen ~ diaein, Di ° {soya) -dimetbylammoniu »« ealorid and Bi «(cooo8.}« din »tbylaeaoniuncblorid.

Simple connections with at least one organic level Best with at least £ 8 oh1enstoffatOman, voraugewöiae 12 to 18 carbon atoms, ranging from liquids to see below semi-solid wacbsartiken cash registers can »can through Installation with urea in a manner known per se in free

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£ li® @ e »<t @ taitaasarfeig«

SCQ © Umpm? W% Mite atlt® --Sföc

tssio

ii £ ^ 9 *% £ &% U

OSS'J & Qlä.®feö% iC3ÖSsOS. ^ DG ¹ O

to Di®5

Di®5

Ε & θ & ϊ «

oä jl & c

efio

, no

SöS / 1034

■ 1444080

Me cationic, nitrogen-containing Κοκρόηβαλβ mvfot about 4 bid 40 weights «# _{e in} advance about 18 te®" 35 Sewie & ti of the Weietensaeseasitt® used according to the invention! " is uegeeetst gray "material _t« for it the kationisoben "stickstoffli & Xfige®. to form an adduct" steUt 4ea gr @ Ser 's bargain of Weiobaaeoersusasimensetsung is uni vixft in Heisge »ron about 50 eiageeetist to 90 öewichta- ^. B # r W & mmt & tt a set should be used which ¥ # »ig @ t @ m @ ύ $ τ for ii® with the Isationisolieii connection

required equal ± ®% ₉ and is votfsmgswelsis ifö over the amount used for the 3cationise! ie connection tHöoretlec ^ dear amount, n & EÜch in Keng @ m ⁷ / 3S. about 2 to 180 lfol Haraatoff / mol more cationic

Sin 'preferred β Yerfabren £ for Herstellmmg gierberen Stoffweicbmacfcermitteln the liier tetr & @ te & $$ & flookenfona in consists in the tftaset' ung RMI ISA matsff with a qv & terntttfen Aamoniuwverbinduiig "the v®Tmigm®tm at least one« ge ^ mdkettigen organic Esst with etoffatoaen? atbält, in countervalue an @ r that aicb -as sur training of a 'fixed % & stMk% e in for »necessary asked. The in the Be &% tl @ m ^ - @ iiig ^! I Uassenienge corresponds to about 2 to 1§ $ @ wl®Mü «» ^ about 3 to 5 weight -? * The ZusaosBense & isng · An® um leaktions »Seaiaob becomes a firm Reaction project won »the beer for common prerogatives» ss.B. a hal «esnfifitile *

BATH 809805/1034

₇ People sfteaS

I® ia iüiem ^ gÄ't

BAD ORIGINAt.

8OiSOS / 1 03 4

eB Alkjrlbenzoleulfouate _f Honoglycerideulfat®, oloate, sulfoethyl-N-niafbyl-oleliigäureaaiide% ai eelfen, e.B. HatriuiaBtearate. To the nioHfcioiiiseliea 3e * ax $ eatie & belong u. *. surfactants from iPolyalkylenoxydderivata toh pbenoliacbea

Dibutylwa4 Bianylpfeeaolea and »kresolsn usi Octyl ·, »onyl and deodorant / ipbaßolaa wa &

oxydderi-council «iron slipfcatiec & en, org & aiscfeaa

and AainoTerbiaduagea cd ©?

mn

Mol * kulÄrg «dedicates, like Ootylwaisi,

Dodecyl "" roaptan from

la d «a« ϊ * indung «

the "int satisfactory Weioijiiacbua ^ dt®

The Μβοί «» bÄagea in the mlmmtwm ml% ®1 & metM & t®hm®

rorb »ndeiii» Ä Heage de »

»Ittels * b. Ϊ »* i: i £« awifc »tt S2ÄM3bt die

'oüfje about the aue itoffwelobaaclier iimi -Hr & txge & s _t Mittele aue »Gariiigere Kengsa roa HilfseH @ ff # H ₉ wlt

8G980S / 1034 "

and dye, can next l © ifts »

the

to be leased to the inventions. In the following ,

Detergsas containing feed Irfimdnsg v / ied ^ rgegobea- wherein

as ß-ewietteila output

middle

15-40
20- ^ 50

70-90

10-30

40
32

SO-SiJ

10-50

BAD OFWG ¹ NAL

809805/1034

C. Anionic surfactant IatriuBtripolypboapbat

fetrft-

Uatriuapyropbospbat Hatriium partioate Hatrite sulfate

solid material weicbnacber (urea complex)

20 40 10 10 10

70-90

10-30

latriuMdodeeylbenesolsulfonat 40

Xatrliortripolypbospbat 32 Tetroimtrivuiipyrophoepbat 8

latrimnwtaeilioat 10

latrine sulfate 10 solid fabric weave (Harnetoffkoaplex)

70

30th

S. Vatriu dodecylbeneol sulfonate 10 Hatrioedodecyl sulfate 10 Batriu tripolypbosphate - 40 Iatrium pyro phosphate 10

latrivMtttfttllieat 10

latrluBa ^ ifat 20

solid ßoffveicbmacber (urea complex)

75

25th

609805/1034

J ?. H & tritmalkylarylsulfotiat

nonioniscfces ofeerfl & cheras & ti ^ es means

Vatriuntripolyplioeptiat Sodium sulfate

solid materialWeiebnaolier (HarEstofiioisplex)

20 5 1

20th 54

β. Hatri "mdo & ecylfee" soXsulfoaat

Oberflacbeaalctlvee means

Sodium metasilicate Hatrltuasölf ®t

solid fabric waictaacber 18th

50

22:

Ifetrlumtalgsulfst

Hatriiamtripoly p & o late

latriuiametssili cat

to

40

10 SUN

ORIGINAL BATHROOM

I. Amide densate from iauric acid and

Diethanolamine (non-ionic) 20

fetranatriuBpyropbosphat 45

Potassium carbonate 23

Bfttriuasulfat ig

solid plasticizer (urine toffkoa-plex) 10

The quantities of solid plasticizers given in the above examples represent the preferred proportions when the solid material contains about 1 % ± 1 cationic compound and 4 layers of urea. As stated, the active cationic constituents which form urea complexes can be modified to a limited extent. If, therefore, other quantities of active cationic oils are used, then the range of the solid plasticizer in the composition of the softener and detergent can be adjusted accordingly. .

As already mentioned, the fabric softeners are künnes geaäS before or during the training stage dee geaernten ¥ as90 <rorgangs separated from dea IJetorgena either Tor or nach the addition of the latter or dsinil at the same time; ziigeeetst how it is then when one realizes the invention Cushions of fabrics and detergents used. The StoffweiebssacfcareuGaaisensötiSURg is in watered in such quantities that iar desired © Iffekt on the case and the handle of the fabrics treated with it © rrcloht

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ig>

will. Pie preparations of the invention given above Means are constructed so that the amount of Stoffvelenmootr Bur available etebtg if you Wasobdetergentieii In the usual Quantities were poured in. "

For the Yeraneebau Shift of the forteile, the old d§r Y «rw # ndfcrag The invention is made up of materials that are made up of » the results TeraeMedener frUTatagen% fieder «« g »bea ·

example 1

At an early celebration, eiiä aan & elsü & lieBea (trade cleansing "Sld® ⁿ TroQtor Sasble 0®, 0inoiiiaAti ₉ ObIo) ₉ d & 8 apart from amplifiers an aai © aieoti * e OberflKelita" active medium was contained, in finer Heager a 3/4 f * e "e (cup) in a (teneral Sleotris automatiselssn Wasotaaeoain ", ▼ on filled above MiTa ₉ used. 20 g of a fset" n ₅ flocked fabric wafers with a "" Sebalt vom M

(an iarnetoffiadiuict

(24 ^)

quaternä ^ en Waaobatuf "

were fltioiiMitie «it of the Dettigeea in the ilt

. The "Mmatoff" addulct of the "at" raar "ft had been divided into noekeafo »barg te. '

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The filling of the washing machine consisted of 3! Perrytttob «bath towels and Brelltuoh ballast to achieve a filling weight a of about 2.7 kg. The machine filling was set to the 2.7 to 4.5 kg mark (78 * 4 liters of water). Tap water with a hardness of about 136 parts / Hillion, calculated as calcium corbonate, was used in all washing and rinsing stages.

The softness of the fabrics compared to controls used in the same way, but without the addition of the fabric white top were bandaged, was rated by 3 to 6 people experienced in this area. The result was as follows achieved »69 9 * preferred those with the invented smock banded samples as softer compared to the controls.

Various cationic, substance-white compounds with at least one straight-chain organic component with at least 8 carbon atoms as a complex compound with urea as the effective fabric softeners using practical

the same measures as described in Example 1 were used. These kationispben WSeiobnaober were prepared bit-urea as described in complex compounds transferred and used in a fixed cam form. The Ansahl of the people who participated in each evaluation is durob

8.09805 / 1034

■■■ -; ■■■■■ 1 ^ 44090

the number tainter is given after the slash. The number of People who have tested the test substances ale better or than in The grip is better than the controls indicated Number expressed before the slash. The results are shown in Table I.

Table I.

Wash with detergent * cationic Weieboeober compared to washing with detergent (control)

Salgamin hydrated tea / control 4/5 Tallow '?!, 3 "propylenedismine / control 5/5

5/5 5/5

Example 3

Practically the same working method as described in Example 1 and the same solid material is used, therefore, for carrying out a series of washing processes with different detergents. Detergent No. 1 is a hands-free, low-foaming, anionic laundry detergent (trade name "Dash ¹¹ Proctor 4 Gamble Oo., Oinointiatl, Ohio) and Detergent No. 2 is a commercially available, nonionic, limited-amount (Bandelsb @ 2eiohnung ^a All ^ffl £ $ ver Broühors, Inc), Ia cases a 3/4 cup of the setevgeiis 7 would be used, one

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"19".

in the case of Betergene No. 1 106 g and in the Pall dee

Detergent # 2 weighed 108 g. The reviews ron douptlt

ta washes carried out by the morning person / are in Table II

reproduced. '

Table II

Laundry with different detergents + solid softeners opposite Wash with the appropriate Detergents

solid plasticizer · § ■ Detergent No. I / Detergent No. 1 4/4

solid emollient + detergent # I / detergent # 1 3/3

solid W.ichoacher Hh detergent no * 2 / Det * rg # as no «2 4/4

solid softener + detergent # 2 / detergent # 2 3/3

Example 4 .

Three common types of fluid fabric weakening were used in the evaluation of the weakening prevention Vash level selected. In all cases the quantity of su the washing stage eugesetetest »effective» liquid soft aober so adjusted »that practically the same amount of works weiobMLcbeaden means »wit in dtm fixed Wficbaaober Torlag« The solid plasticizer was sugtettit the dry Wleobe » while the liquid plasticizers uotwtnaigtrwtlst according to Sugabe

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styles ESX

ΐΙΙ§§Ιι ©

tftiete ©, © ^ ® ^ Tm

g®? "t

E'a? » E ♦

its? s s © g @ gili fii® '

aa

© J?

8098Q5 / 1034

1444080

of anionic detergent, which was obtained after a leih® Y © a Koatroll® wash, was taken as the starting value for the calculations made. Ss were sway tesi $ eäer Wöacbe 60 g of a typical aniöniselhe "Detez ^ EIIS used, but were on average only 57 -;? g Bstergeme are recovered per washing process. MeU3an & 2ytis @ li <s determinations would give} that 20 g of solid kationiso ^ er ^% i @ lsmaetior ₉ that used in a usual washing step bandluog mi ^ dsa, 18.5 g of the anionic 'D & te - ^^. W equivalent vmraa "Tbeoretiaob should then be only 59.0 g of free anionic Batergena in the Vasohwaeeer etig @ g «ii after the growth rate has been changed. In virtually all cases had 33doeh the O _e balt of Waachwaasera of free anionieohen isetergens the Waschetufe nac! I the end of a value indicating tHe significant portion of the kationisohen not ait react the anionic Beter gene lmtt® _@ was deposited on the fabric.

In table IV are the results of the ch @ mis @ tai Isilyssa Waschwaeser> «, ri: before the end of the washing stage and ü®%> Frozentsats of deposited solid white, ah & r (Jt tfe ^ rsstoS over the theoretical value) on the fabric ia Tesfeftltais su the whole, given to the tfeschstufe singe & ®tmt @ n .

BATH

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23.9 Ms 24 »2 f>

material

.469 *.

80 9 805/10 34

a 2.7 kg wash with a setex dispenser and 2 ES spoons (about 20 g) of a solid white substance (urea complex).

In another laboratory I smoke imir Sxralttluog Aer the effect of strong overdosing leurd © öurebgef Ufert, .trotrei 2 _S 7 b $ 6 eels have been washed with a detergent and 20 g of solid fabric toioloNtir. 900 g of filling wurAea & fn 1, MaI gewasebs with the Beter genes with the addition of 40 g (tlb @ rio @ i ©) 's i @ Vteieiimaebers to the Vaeebstufe ". Dei ¹ ©! At the bottom of the droplet, no measurable brnieirigu ^ g & ®r absorption could be ascertained, ie-, εa © rt @ lgt @ tins instantaneous absorption.

Sun comparison were 1360 g Wiiacbo in the iflistef® old eiii »r Overdose (30 to 35 g) solid WfrlciiagLebosiO ail © ts, leliateäelt « The opposition to the abovementioned defamation is true Vigor with firm white mecisei · im pronounced decrease de?

the banded laundry is soaked - -ss lasts © 9 the Waasertx'opfön wheelchair absorMtrt wasp. It is nice that with certain 8toff & rten ' ₉ ' 8.B. BmfiirStsfesm ». such a vasöerdioBtmaöb ^ ada. Effect oier? # 2T2ust des Wassei absorptionTsraögöae ®i, which represents a disadvantage.

BATH

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i & t s »

Mam © Brille si "! ¥ @ 2Φ®41 gmi @ si® © m m ±%

O-

Ufo © @

; @s sit

809805/1034

Are ss should be noted DSS the erfindungsgesi & een substance "weiohnaoberisusamsienseteungim not only in 71oolmifomi and _y in powder or granular form used Sas main requirement beateat fact they Daae festet complex compounds with urea represent · ¥ i @ from those given in Example 4 results au can be seen "not in complex compounds with urea present liquid substance veiobnaolier rts ^ t eu satisfactory if they are used in the washing stage of the öeeamtwascbvorgasgs instead of in the rinsing stage * In general, the vascbe stage can be regarded as ended when the water containing the added Setergene, is drained from the washing tub, and the expressions "Wash ¹¹ " ^ Vasobstufe ¹ * and ^M Waschvorgsng ^H are to be understood in this way.

Of course, you can do the above Modify characteristics and apply equivalents of the same * without therefore get out of the scope of the invention »

BAD OFUGiNAU

809806/1034

Claims (1)

26 -. 14440: t β a t a β s p r ü c Ii e 1. In the presence of detergents used atoares * solid matter " maker, containing a complex & compound of "urea © lm®r k & tion-active organic Terlinausg with A good orsanisobic meal with “At least 8 2 "Stoffw @ ic! Iffia © ii8 ^ aaoh Ansprußb 1, thereby k" mweiebnet _v -'dftfioxganieehe S @ st 12 to 18 coals "toffatoa" released * 5. Stofi'usiolhisEicfegr according to claim 1 or S ₉ ladurob «Jai ti® organic © compound © I» ® g.uat@rnMre Äfflmoraium is a® anine compound. I- · Sto ££ W »£ oBflaotaer naeb Aasprucli t _f 2 or 3 $ dadi ^ red» seietaot »dog the amount of urea about 50 M® 90 and the amount® of cation-active compound about 4 to f © i £ tiiie & B containing ®1b dry ice Gisiseb ame B @ t®rg @ ns and ä © m
AneprSlebe -1 to 4, bath 8-09.8 Q 5/1034 ~ 27 ~ 6. Together η se teung according to claim 5, containing about 10 to 50 eewiebts-96 of the solid ? · Sending according to Anaprucb 5 or 6 _ff that the sea goose is an anionic or non-anionic one flttcbenaktivoe remedies bare. 8 * Zueaemensetcuag uach Aneprucb 5 _S δ or 7, imiurels gelcenn «seobnet · dsS the solid material content Ιτι is present · 9 · Zusanaeneeteung n & ob claim 5 »containing a Gettiacb from a Betergens and etvf.-a to bi @ SO. absorbed in the G ami sch, a firm WtotSm & iQhm & eimrti on the basis of a falgamin which is hydrated by unsetiung of urea with priaarea in Qeganv & xt a lot of water 10. Zueaaeeneeteung naob claim 9, daäurcb gek @ n% s @ $ ebii "t _v the substance MelislSBaabar In Flockenfors is present", BATH 809805/1034 11. Procedure for treatment of leggings sum-Improve your © ® handle, characterized by äaS uaa pre-washes these textiles with a batergent Stop washing solid matter. one of claims 1 to 4 12. '¥ erfatir @ ii after Amepruoh 11, tedurofe before * SEueabe ₉ ~ that * ate © s na @ fr Aaaj ^ uefe 11 _s dsÄü »©! 809 80 5/1034