DE1293377B - Process for producing hair-like growth on water-based soap - Google Patents
Process for producing hair-like growth on water-based soapInfo
- Publication number
- DE1293377B DE1293377B DED32858A DED0032858A DE1293377B DE 1293377 B DE1293377 B DE 1293377B DE D32858 A DED32858 A DE D32858A DE D0032858 A DED0032858 A DE D0032858A DE 1293377 B DE1293377 B DE 1293377B
- Authority
- DE
- Germany
- Prior art keywords
- soap
- gel
- growth
- water
- hair
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Cosmetics (AREA)
- Detergent Compositions (AREA)
- Paints Or Removers (AREA)
- Medicinal Preparation (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Description
Die Erfindung betrifft ein Verfahren zur Herstellung eines haarfönnigen Bewuchses auf wasserhaltiger Seife.The invention relates to a method of manufacture a hair-like growth on water-based soap.
Es ist bereits bekannt, daß Seife, die im Inneren einen Zusatz an Wasserglas enthält, je nach den Temperatur- und Feuchtigkeitsbedingungen ausblühen kann, wobei an der Oberfläche ein unregelmäßiger, mehr oder weniger starker Haarbewuchs entsteht.It is already known that soap that is inside contains an additive of water glass, depending on the temperature and humidity conditions can, whereby on the surface an irregular, more or less strong hair growth arises.
Das Hauptpatent 1265 905 betrifft ein Verfahren zur Herstellung eines haarfönnigen Bewuchses auf wasserhaltiger Seife, wobei die Suspension eines Gels, ein Sol oder die Lösung einer gelbildenden Substanz in geringer Schichtdicke auf die Oberfläche der Seife aufgebracht und getrocknet wird, wodurch ein gerichteter Bewuchs erzielt wird.The main patent 1265 905 relates to a method for producing a hair-like growth water-based soap, being the suspension of a gel, a sol or the solution of a gel-forming substance is applied in a thin layer to the surface of the soap and dried, creating a directed Vegetation is achieved.
Es wurde nun in weiterer Ausbildung des Gegenstandes des Hauptpatentes gefunden, daß ein haarförmiger Bewuchs auf wasserhaltiger Seife hergestellt werden kann, indem die Suspension eines Gels, ein so Sol oder die Lösung einer gelbildenden Substanz in die Masse der vorzugsweise natriumoleathaltigen Seife eingebracht und gegebenenfalls zur Freisetzung der Säure mit einem sauren Gas behandelt wird.It has now been found in a further development of the subject matter of the main patent that a hair-shaped Fouling on water-based soap can be produced by suspending a gel, such Sol or the solution of a gel-forming substance in the bulk of the preferably sodium oleate-containing Soap is introduced and, if necessary, treated with an acidic gas to release the acid.
Durch das Begasen mit einem sauren Gas, wie as z. B. CO2, blüht die Seife gleichmäßig und sehr rasch aus.By gassing with an acidic gas, such as z. B. CO 2 , the soap blooms evenly and very quickly.
Um auf den etwas lästigen Vorgang des Begasens der Seifenproben verzichten zu können, hat es sich als zweckmäßig erwiesen, der Seife nicht die erwähnten Vorprodukte, sondern unmittelbar die daraus entstehenden kolloidalen Stoffe einzuverleiben, wieIn order to be able to do without the somewhat annoying process of gassing the soap samples, it is a matter of course Proven to be expedient, the soap does not have the above-mentioned preliminary products, but the directly resulting products to incorporate colloidal substances, such as
frisch gefälltes SiO2-GeI,
frisch gefälltes Mg(OH)2-GeI, frisch gefälltes Al(OH)3-GeI,
frisch gefälltes Fe(OH)3-GeI,
frisch gefälltes Magnesiumsilikat, frisch gefälltes Zinksilikat,
frisch gefälltes Aluminiumsilikat, frisch gefälltes Eisen(III)-silikat,
frisch gefällte Alginsäure,
frisch gefällte Zelluloseglykolsäure.freshly precipitated SiO 2 gel,
freshly precipitated Mg (OH) 2 gel, freshly precipitated Al (OH) 3 gel, freshly precipitated Fe (OH) 3 gel, freshly precipitated magnesium silicate, freshly precipitated zinc silicate,
freshly precipitated aluminum silicate, freshly precipitated iron (III) silicate, freshly precipitated alginic acid,
freshly precipitated cellulose glycolic acid.
3535
4040
4545
Auch in diesem Fall ist an dem Ausblühen der Natriumoleat-Haarkristallite nur die in einer sehr dünnen Schicht an der Oberfläche enthaltene Gelmenge beteiligt, während das im Inneren der Seife enthaltene Gel für den Ausblühvorgang verloren ist. Da es sich aber bei den erwähnten kolloidalen Stoffen um billige Substanzen handelt, die die Qualität der Seife nicht nachteilig beeinflussen, ist dies belanglos, selbst wenn man berücksichtigt, daß man, wie Versuche zeigten, der Seife prozentual etwas mehr von der gelförmigen Substanz einverleiben muß als den wäßrigen Gelsuspensionen, gemäß der Hauptpatentanmeldung, die zum Zweck der Erzeugung eines Haarbewuchses auf die Oberfläche der Seife aufgetragen werden.In this case too, the sodium oleate whiskers are blooming only the amount of gel contained in a very thin layer on the surface is involved, while that contained inside the soap Gel for the blooming process is lost. But since the colloidal substances mentioned are cheap substances that do not adversely affect the quality of the soap are irrelevant, even if one takes into account that, as experiments have shown, the percentage of the soap is somewhat more than the gel-like Must incorporate substance than the aqueous gel suspensions, according to the main patent application, which are applied to the surface of the soap for the purpose of creating a hair growth will.
Bei Einverleibung in die Masse der Seife werden dieser z. B. beigemischt:When incorporated into the mass of the soap, this z. B. mixed in:
kolloidale Kieselsäure ,. 6 bis 10% (Festsubstanz)colloidal silica,. 6 to 10% (solids)
Metallhydroxyde 0,6 bis 3,0% (Festsubstanz)Metal hydroxides 0.6 to 3.0% (solids)
Metallsilikate 0,3 bis 1,5% (Festsubstanz)Metal silicates 0.3 to 1.5% (solids)
Der Vorteil der Einverleibung der Kolloide in die Masse der Seife liegt darin, daß die notwendige Handarbeit beim Bestreichen von z. B. Tierfiguren eingespart wird. Naturgemäß wachsen in diesem Fall die haarfönnigen Kristallite auf der gesamten Oberfläche der Seifenfigur. Sollen nun an einigen Stellen der Figur keine Haare wachsen, so werden diese Stellen mit wäßrigen Lösungen einer Konzentration von 2 bis 10% aus Polyvinylalkohol, Polyvinylpyrrolidon, Polymethacrylat, Gelatine u. a. bestrichen.The advantage of incorporating the colloids into the bulk of the soap is that it requires manual labor when painting z. B. animal figures is saved. Naturally, in this case the hairy crystallites on the entire surface of the soap figure. Shall now be in some places on the figure no hair grows, so these areas are treated with aqueous solutions of a concentration of 2 to 10% from polyvinyl alcohol, polyvinyl pyrrolidone, polymethacrylate, gelatin and others. coated.
Zu 92,5 Teilen einer Kernseife mit einem Fettsäuregehalt von 70% (Zusammensetzung des Fettansatzes: 90% Talg-, 10% Palrnkernöl-Fettsäure) werden 7,5 Teile frisch gefälltes Aluminiumhydroxyd nutschenfeucht (9,0% Trockenrückstand) beigemischt. Das Aluminiumhydroxyd wird durch Fällung mit Ammoniak, z. B. aus einer Aluminiumsulfatlösung bei 20° C hergestellt.To 92.5 parts of a curd soap with a fatty acid content of 70% (composition of the fat base: 90% tallow, 10% palm kernel oil fatty acid) are 7.5 parts of freshly precipitated aluminum hydroxide wet with suction (9.0% dry residue). The aluminum hydroxide is made by precipitation with ammonia, e.g. B. made from an aluminum sulfate solution at 20 ° C.
Die aus der homogenisierten Masse hergestellte, stranggepreßte Seife hat einen Fettgehalt von etwa 65% und einen Gehalt an Aluminiumhydroxydgel von 0,6%. Aus den erhaltenen Strängen werden z. B. Tierfiguren gepreßt. Läßt man diese 3 bis 4 Tage bei 20° C in einem Raum bei 70 bis 80% relativer Luftfeuchtigkeit stehen, so bildet sich ein gleichmäßiger Haarbewuchs, wobei die Haare eine Länge von etwa 5 mm besitzen.The extruded soap produced from the homogenized mass has a fat content of approximately 65% and an aluminum hydroxide gel content of 0.6%. From the strands obtained z. B. Pressed animal figures. If this is left for 3 to 4 days at 20 ° C in a room with 70 to 80% relative humidity stand, an even hair growth is formed, the hair being about a length 5 mm.
Sollen an einigen Stellen der Figuren gemäß Beispiel 1 keine Haare wachsen, so werden sie unmittelbar im Anschluß an die Formgebung durch Pressen an diesen Stellen mit einer 5%igen wäßrigen Lösung von Polyvinylalkohol gestrichen.If no hair is to grow in some places of the figures according to Example 1, they become immediately following the shaping by pressing at these points with a 5% aqueous solution deleted by polyvinyl alcohol.
Claims (3)
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DED32821A DE1265905B (en) | 1960-03-09 | 1960-03-09 | Process for the production of hair-like growth on solid curd soap |
DED32858A DE1293377B (en) | 1960-03-09 | 1960-03-14 | Process for producing hair-like growth on water-based soap |
FR855142A FR1297746A (en) | 1960-03-09 | 1961-03-09 | Process for obtaining an efflorescence in the form of hairs or hairs on soap containing water |
GB870761A GB916570A (en) | 1960-03-09 | 1961-03-09 | Improvements in or relating to soap |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DED32821A DE1265905B (en) | 1960-03-09 | 1960-03-09 | Process for the production of hair-like growth on solid curd soap |
DED32858A DE1293377B (en) | 1960-03-09 | 1960-03-14 | Process for producing hair-like growth on water-based soap |
Publications (1)
Publication Number | Publication Date |
---|---|
DE1293377B true DE1293377B (en) | 1969-04-24 |
Family
ID=25971060
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DED32821A Pending DE1265905B (en) | 1960-03-09 | 1960-03-09 | Process for the production of hair-like growth on solid curd soap |
DED32858A Pending DE1293377B (en) | 1960-03-09 | 1960-03-14 | Process for producing hair-like growth on water-based soap |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DED32821A Pending DE1265905B (en) | 1960-03-09 | 1960-03-09 | Process for the production of hair-like growth on solid curd soap |
Country Status (2)
Country | Link |
---|---|
DE (2) | DE1265905B (en) |
GB (1) | GB916570A (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3438894A (en) * | 1966-01-25 | 1969-04-15 | Kurt Ludwig Von Stoesser | Efflorescent composition |
WO2017202577A1 (en) * | 2016-05-27 | 2017-11-30 | Unilever N.V. | A shaped solid cleansing composition and process of manufacture thereof |
-
1960
- 1960-03-09 DE DED32821A patent/DE1265905B/en active Pending
- 1960-03-14 DE DED32858A patent/DE1293377B/en active Pending
-
1961
- 1961-03-09 GB GB870761A patent/GB916570A/en not_active Expired
Non-Patent Citations (1)
Title |
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None * |
Also Published As
Publication number | Publication date |
---|---|
DE1265905B (en) | 1968-04-11 |
GB916570A (en) | 1963-01-23 |
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