DE1204767B - Use of salts or mixtures of salts to lubricate when extruding steel - Google Patents

Use of salts or mixtures of salts to lubricate when extruding steel

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Publication number
DE1204767B
DE1204767B DEM60373A DEM0060373A DE1204767B DE 1204767 B DE1204767 B DE 1204767B DE M60373 A DEM60373 A DE M60373A DE M0060373 A DEM0060373 A DE M0060373A DE 1204767 B DE1204767 B DE 1204767B
Authority
DE
Germany
Prior art keywords
salts
mixtures
lubricate
extruding steel
lubricants
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
DEM60373A
Other languages
German (de)
Inventor
Dr-Ing Gerhard Naeser
Dipl-Ing Otto Wessel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Vodafone GmbH
Original Assignee
Mannesmann AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to DEM60373A priority Critical patent/DE1204767B/en
Application filed by Mannesmann AG filed Critical Mannesmann AG
Priority claimed from DEM60706A external-priority patent/DE1228016B/en
Priority to DE19651594495 priority patent/DE1594495A1/en
Priority to AT205565A priority patent/AT257794B/en
Priority to NL6503091A priority patent/NL6503091A/xx
Priority to ES0310730A priority patent/ES310730A1/en
Priority to SE03574/65A priority patent/SE325981B/xx
Priority to GB11798/65A priority patent/GB1107183A/en
Priority to FR10086A priority patent/FR1448029A/en
Priority to BE661471D priority patent/BE661471A/xx
Publication of DE1204767B publication Critical patent/DE1204767B/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21CMANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES OR PROFILES, OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
    • B21C23/00Extruding metal; Impact extrusion
    • B21C23/32Lubrication of metal being extruded or of dies, or the like, e.g. physical state of lubricant, location where lubricant is applied
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M7/00Solid or semi-solid compositions essentially based on lubricating components other than mineral lubricating oils or fatty oils and their use as lubricants; Use as lubricants of single solid or semi-solid substances
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/02Water
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06Metal compounds
    • C10M2201/062Oxides; Hydroxides; Carbonates or bicarbonates
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06Metal compounds
    • C10M2201/063Peroxides
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/08Inorganic acids or salts thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/08Inorganic acids or salts thereof
    • C10M2201/081Inorganic acids or salts thereof containing halogen
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/08Inorganic acids or salts thereof
    • C10M2201/082Inorganic acids or salts thereof containing nitrogen
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/08Inorganic acids or salts thereof
    • C10M2201/084Inorganic acids or salts thereof containing sulfur, selenium or tellurium
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/085Phosphorus oxides, acids or salts
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/086Chromium oxides, acids or salts
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00Metal present as such or in compounds
    • C10N2010/02Groups 1 or 11
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00Metal present as such or in compounds
    • C10N2010/04Groups 2 or 12
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/22Metal working with essential removal of material, e.g. cutting, grinding or drilling
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/24Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/241Manufacturing joint-less pipes
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/242Hot working
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/243Cold working
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/244Metal working of specific metals
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/244Metal working of specific metals
    • C10N2040/245Soft metals, e.g. aluminum
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/244Metal working of specific metals
    • C10N2040/246Iron or steel
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/244Metal working of specific metals
    • C10N2040/247Stainless steel
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00Form in which the lubricant is applied to the material being lubricated
    • C10N2050/015Dispersions of solid lubricants
    • C10N2050/02Dispersions of solid lubricants dissolved or suspended in a carrier which subsequently evaporates to leave a lubricant coating
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00Form in which the lubricant is applied to the material being lubricated
    • C10N2050/08Solids
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00Form in which the lubricant is applied to the material being lubricated
    • C10N2050/10Semi-solids; greasy
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2070/00Specific manufacturing methods for lubricant compositions

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Description

BUNDESREPUBLIK DEUTSCHLANDFEDERAL REPUBLIC OF GERMANY

DEUTSCHESGERMAN

PATENTAMTPATENT OFFICE

AUSLEGESCHRIFTEDITORIAL

Int. Cl.:Int. Cl .:

ClOmClOm

Deutsche KL: 23 c-1/04 German KL: 23 c -1/04

Nummer: 1 204 767Number: 1 204 767

Aktenzeichen: M 60373IV c/23 cFile number: M 60373IV c / 23 c

Anmeldetag: 20. März 1964Filing date: March 20, 1964

Auslegetag: 11. November 1965Opening day: November 11, 1965

Bekanntlich werden beim Warmverformen von Werkstoffen aus Eisen und Stahl, insbesondere beim Ziehen oder Strangpressen, die hierfür dienenden Werkzeuge mechanisch und thermisch sehr stark beansprucht. Sie unterliegen daher einem hohen Verschleiß, der auch zu einer schlechten Oberfläche des verformten Gegenstandes führt. Um den hohen Werkzeugverschleiß möglichst weitgehend auszuschalten, sind zahlreiche Vorschläge zur Verbesserung der Schmierung gemacht worden.It is known that when hot forming materials made of iron and steel, especially when Drawing or extrusion, the tools used for this are mechanically and thermally very strong claimed. They are therefore subject to high wear, which also leads to a poor surface of the deformed object leads. In order to eliminate the high level of tool wear as much as possible, numerous proposals have been made to improve lubrication.

Die bisher bekannten Schmierstoffe lassen sich in zwei Gruppen unterteilen. Die eine Gruppe umfaßt die homogenen Stoffe, von denen Gläser — in stükkiger oder pulveriger Form — und glasähnliche Stoffe, die keinen bestimmten Schmelzpunkt aufweisen und in einem gewissen Schmelzintervall unter dem Einfluß der Verformungstemperatur zähflüssig bleiben, eine große praktische Bedeutung erlangt haben, besonders beim Strangpressen von hochlegierten Stählen. Für die Verarbeitung von gewöhnlichen Massenstählen sind sie jedoch zu teuer. Nachteilig ist ferner, daß das erforderliche Entfernen der Glasreste von den verformten Werkstücken, das beispielsweise bei Stählen nur nach dem Abkühlen durch Abstrahlen oder Beizen möglich ist, beträchtliche Kosten verursacht. Bei stranggepreßten Rohren, die in der Preßhitze weiterverarbeitet werden müssen, um gegenüber den nach den modernen Schweißverfahren hergestellten Rohren wettbewerbsfähig bleiben zu können, wirken sich diese Kosten besonders belastend aus.The previously known lubricants can be divided into two groups. One group includes the homogeneous substances, of which glasses - in lumpy or powdery form - and glass-like ones Substances that do not have a specific melting point and are below in a certain melting range the influence of the deformation temperature remain viscous, has acquired great practical importance especially when extruding high-alloy steels. For processing ordinary However, they are too expensive for bulk steels. Another disadvantage is that the required removal the glass residues from the deformed workpieces, which, for example in the case of steels, only occurs after cooling by blasting or pickling is possible, causes considerable costs. In the case of extruded pipes, which have to be further processed in the press heat in order to be compared to the modern Welding manufactured pipes to remain competitive affect these costs particularly stressful.

Die zweite Gruppe der Schmiermittel umfaßt die inhomogenen Stoffe. Hierunter fallen die bekannten Mischungen von Öl mit Graphit, Pech, Kalk oder Borax. Da sich das öl bei den hohen Verformungstemperaturen, die meist über 10000C liegen, verflüchtigt oder zersetzt, werden die Zusatzstoffe leicht mechanisch entfernt, wodurch Werkstück und Werkzeug in metallische Berührung kommen und verschleißen. Weitere bekannte Mischungen bestehen aus feingemahlenen Substanzen, die Schichtgitter aufweisen wie Graphit, Molybdänsulfid oder Glimmer, mit anorganischen Salzen, z. B. Natrium- oder Kaliumhydroxyd, Natrium- oder Kaliumcyanid, Alkalibichromaten oder -Silikaten. Diese bei Verformungstemperatur dünnflüssigen Salze haben die Aufgabe, den Transport und die gleichmäßige Verteilung des festen Schmierstoffes zu gewährleisten. Diese Schmiermittel können jedoch nicht alle auf hohe Temperaturen erhitzt werden. Außerdem sind sie auch verhältnismäßig teuer.The second group of lubricants includes inhomogeneous substances. This includes the well-known mixtures of oil with graphite, pitch, lime or borax. Since the oil volatilizes or decomposes at the high deformation temperatures, which are usually above 1000 ° C., the additives are easily removed mechanically, whereby the workpiece and tool come into metallic contact and wear out. Other known mixtures consist of finely ground substances that have layer lattices such as graphite, molybdenum sulfide or mica, with inorganic salts, e.g. B. sodium or potassium hydroxide, sodium or potassium cyanide, alkali dichromates or silicates. These salts, which are thin at the deformation temperature, have the task of ensuring the transport and uniform distribution of the solid lubricant. However, not all of these lubricants can be heated to high temperatures. They are also relatively expensive.

Entgegen der bisherigen Ansicht, daß Salze wie Verwendung von Salzen oder Salzgemischen zum Schmieren beim Strangpressen von StahlContrary to the previous view that salts such as the use of salts or salt mixtures for Lubricating when extruding steel

Anmelder:Applicant:

Mannesmann Aktiengesellschaft,
Düsseldorf, Mannesmannufer 1 b
Mannesmann Aktiengesellschaft,
Düsseldorf, Mannesmannufer 1 b

Als Erfinder benannt:Named as inventor:

Dr.-Ing. Gerhard Naeser,
Dipl.-Ing. Otto Wessel, Duisburg
Dr.-Ing. Gerhard Naeser,
Dipl.-Ing. Otto Wessel, Duisburg

Natrium- und/oder Kaliumcarbonat wegen zu hoher Viskosität im flüssigen Zustand sich zur Verwendung beim Strangpressen nicht eignen, wurde nun überraschend gefunden, daß solche Salze oder auch Salzgemische, die einen Umwandlungspunkt aufweisen und die vor ihrem Gebrauch auf eine bei oder über dem Umwandlungspunkt liegende Temperatur erhitzt worden sind, zum Schmieren beim Strangpressen von Stahl verwendet werden können. Der Umwandlungspunkt liegt für Soda bei 356° C und für Pottasche bei 400° C.Sodium and / or potassium carbonate are suitable for use because of their viscosity in the liquid state not suitable for extrusion, it has now surprisingly been found that such salts or salt mixtures, which have a transition point and which, prior to their use, to an at or above the temperature lying at the transition point have been heated for lubrication during extrusion of steel can be used. The transformation point for soda is 356 ° C and for potash at 400 ° C.

Diese Schmiermittel sind bei der Verformungstemperatur sehr dünnflüssig und weisen eine Vis- kosität auf, die etwa derjenigen von Wasser bei Raumtemperatur entspricht. Sie benetzen den Werkstoff sehr schnell und erfüllen damit eine wichtige Voraussetzung für die Ausbildung eines geschlossenen Schmierfilmes. Die Verbesserung der Schmierwirkung dieser Salze durch die beschriebene Wärmebehandlung beruht wahrscheinlich darauf, daß die völlige Trocknung verhindert wird und daß nach der Wärmebehandlung infolge der langsamen Umwandlungsgeschwindigkeit die Hochtemperaturmodifikation erhalten bleibt. Diese ist aber leichter verformbar als das normale Salz; ein Zerbröckeln der zum Schmieren vielfach angewandten gesinterten Scheiben oder Ringe tritt deshalb beim Beginn des Preßvorganges nicht ein. Das Zerbröckeln verursacht erfahrungsgemäß Fehler in der Oberfläche und erhöht den Verschleiß der Matrizen.These lubricants are very thin at the deformation temperature and have a vis- viscosity, which corresponds approximately to that of water at room temperature. They wet the material very quickly and thus meet an important requirement for the training of a closed Lubricating film. The improvement of the lubricating effect of these salts through the heat treatment described is probably due to the fact that complete drying is prevented and that after the heat treatment due to the slow conversion rate, the high-temperature modification preserved. However, this is easier to deform than normal salt; a crumbling of the Sintered disks or rings, which are widely used for lubrication, therefore occur at the beginning of the Not pressing process. Experience has shown that crumbling causes defects in the surface and increases the wear and tear of the dies.

Die Viskosität der schmelzflüssigen Karbonate beträgt bei 1000° C nur 0,015 Poise und bei 1100° C nur noch 0,005 Poise, ist also etwa so groß wie Äther. Gegenüber den bisher bekannten Schmiermitteln sind die erfindungsgemäßen Schmiermittel erheblich billiger und die Weiterverarbeitung derThe viscosity of the molten carbonates is only 0.015 poise at 1000 ° C and at 1100 ° C only 0.005 poise, so it is about the size of ether. Compared to the previously known lubricants The lubricants according to the invention are considerably cheaper and the further processing of the

509 737/340509 737/340

verformten Werkstücke bereitet keinerlei Schwierigkeiten. Die Salzreste können durch einfaches Abwaschen mit Wasser oder gegebenenfalls durch hydraulisches Entzundern entfernt werden. Es empfiehlt sich, den Schmiersalzen geringe Mengen korrosionsverhütender Salze zuzusetzen, z. B. Phosphate oder Chromate, etwa in Mengen zwischen 0,1 bis 3 Gewichtsprozent, vorzugsweise 0,3 Gewichtsprozent, welche das Rosten der Werkstücke nach dem Abwaschen der Salzreste verhindert.deformed workpieces does not cause any problems. The salt residue can be removed by simply washing it off can be removed with water or, if necessary, by hydraulic descaling. It recommends add small amounts of anti-corrosion salts to the lubricating salts, e.g. B. Phosphates or chromates, for example in amounts between 0.1 to 3 percent by weight, preferably 0.3 percent by weight, which prevents the workpieces from rusting after washing off the residual salt.

Claims (2)

Patentansprüche:Patent claims: 1. Verwendung von Salzen oder Salzgemischen, die einen Umwandlungspunkt aufweisen und die vor ihrem Gebrauch auf eine bei oder über dem Umwandlungspunkt liegende Temperatur erhitzt worden sind, zum Schmieren beim Strangpressen von Stahl.1. Use of salts or mixtures of salts which have a point of transition and which heated to a temperature at or above the transition point before use have been used for lubricating steel extrusion. 2. Verwendung nach Anspruch 1, dadurch gekennzeichnet, daß Natrium- und/oder Kaliumkarbonat, gegebenenfalls mit geringen Mengen, z. B. zwischen 0,1 und 3 Gewichtsprozent, korrosionsverhütender Salze, z. B. Phosphate oder Chromate, verwendet wird.2. Use according to claim 1, characterized in that sodium and / or potassium carbonate, optionally with small amounts, e.g. B. between 0.1 and 3 percent by weight, anti-corrosive Salts, e.g. B. phosphates or chromates is used. In Betracht gezogene Druckschriften:
Britische Patentschrift Nr. 903 957;
USA.-Patentschrift Nr. 2751312.
Considered publications:
British Patent No. 903,957;
U.S. Patent No. 2751312.
509 737/340 11.65 © Bundesdruckerei Berlin509 737/340 11.65 © Bundesdruckerei Berlin
DEM60373A 1964-03-20 1964-03-20 Use of salts or mixtures of salts to lubricate when extruding steel Pending DE1204767B (en)

Priority Applications (9)

Application Number Priority Date Filing Date Title
DEM60373A DE1204767B (en) 1964-03-20 1964-03-20 Use of salts or mixtures of salts to lubricate when extruding steel
DE19651594495 DE1594495A1 (en) 1964-03-20 1965-01-26 Process for the manufacture of a lubricant for the extrusion of steel blocks
AT205565A AT257794B (en) 1964-03-20 1965-03-08 Process for lubricating during hot working of metals and for producing a lubricant
NL6503091A NL6503091A (en) 1964-03-20 1965-03-11
ES0310730A ES310730A1 (en) 1964-03-20 1965-03-18 A procedure for the lubrication in the hot deformation of metals, especially in the extrusion of steel. (Machine-translation by Google Translate, not legally binding)
SE03574/65A SE325981B (en) 1964-03-20 1965-03-19
GB11798/65A GB1107183A (en) 1964-03-20 1965-03-19 Lubrication method for the hot working of metals
FR10086A FR1448029A (en) 1964-03-20 1965-03-20 Lubrication process during heat forming of metals
BE661471D BE661471A (en) 1964-03-20 1965-03-22

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DEM60373A DE1204767B (en) 1964-03-20 1964-03-20 Use of salts or mixtures of salts to lubricate when extruding steel
DEM60706A DE1228016B (en) 1964-04-21 1964-04-21 Method of manufacturing lubricants for use in hot extrusion of steel blocks
DEM0063917 1965-01-26

Publications (1)

Publication Number Publication Date
DE1204767B true DE1204767B (en) 1965-11-11

Family

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Family Applications (2)

Application Number Title Priority Date Filing Date
DEM60373A Pending DE1204767B (en) 1964-03-20 1964-03-20 Use of salts or mixtures of salts to lubricate when extruding steel
DE19651594495 Pending DE1594495A1 (en) 1964-03-20 1965-01-26 Process for the manufacture of a lubricant for the extrusion of steel blocks

Family Applications After (1)

Application Number Title Priority Date Filing Date
DE19651594495 Pending DE1594495A1 (en) 1964-03-20 1965-01-26 Process for the manufacture of a lubricant for the extrusion of steel blocks

Country Status (8)

Country Link
AT (1) AT257794B (en)
BE (1) BE661471A (en)
DE (2) DE1204767B (en)
ES (1) ES310730A1 (en)
FR (1) FR1448029A (en)
GB (1) GB1107183A (en)
NL (1) NL6503091A (en)
SE (1) SE325981B (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20090020187A1 (en) * 2007-07-17 2009-01-22 Russell Steven W Method and apparatus for protecting metal from oxidaton

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2751312A (en) * 1950-08-01 1956-06-19 Metallurg Processes Co Lubricant composition containing powdered lithium carbonate and method of its application to metal bodies
GB903957A (en) * 1960-02-03 1962-08-22 Ti Group Services Ltd Lubrication of hot deformation processes on metals

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2751312A (en) * 1950-08-01 1956-06-19 Metallurg Processes Co Lubricant composition containing powdered lithium carbonate and method of its application to metal bodies
GB903957A (en) * 1960-02-03 1962-08-22 Ti Group Services Ltd Lubrication of hot deformation processes on metals

Also Published As

Publication number Publication date
NL6503091A (en) 1965-09-21
AT257794B (en) 1967-10-25
DE1594495A1 (en) 1971-06-09
ES310730A1 (en) 1965-08-16
BE661471A (en) 1965-07-16
GB1107183A (en) 1968-03-20
FR1448029A (en) 1966-08-05
SE325981B (en) 1970-07-13

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