DE1162322B - Process for matting textile fiber structures - Google Patents
Process for matting textile fiber structuresInfo
- Publication number
- DE1162322B DE1162322B DEC25206A DEC0025206A DE1162322B DE 1162322 B DE1162322 B DE 1162322B DE C25206 A DEC25206 A DE C25206A DE C0025206 A DEC0025206 A DE C0025206A DE 1162322 B DE1162322 B DE 1162322B
- Authority
- DE
- Germany
- Prior art keywords
- matting
- titanium
- titanium silicate
- textile fiber
- fiber structures
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000835 fiber Substances 0.000 title claims description 10
- 238000000034 method Methods 0.000 title claims description 9
- 239000004753 textile Substances 0.000 title claims description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 14
- GNKTZDSRQHMHLZ-UHFFFAOYSA-N [Si].[Si].[Si].[Ti].[Ti].[Ti].[Ti].[Ti] Chemical compound [Si].[Si].[Si].[Ti].[Ti].[Ti].[Ti].[Ti] GNKTZDSRQHMHLZ-UHFFFAOYSA-N 0.000 claims description 12
- 238000009987 spinning Methods 0.000 claims description 6
- 239000006224 matting agent Substances 0.000 claims description 5
- 239000011230 binding agent Substances 0.000 claims description 4
- 229910052719 titanium Inorganic materials 0.000 claims description 4
- 239000010936 titanium Substances 0.000 claims description 4
- 230000001376 precipitating effect Effects 0.000 claims description 2
- 229920002994 synthetic fiber Polymers 0.000 claims description 2
- 239000012209 synthetic fiber Substances 0.000 claims description 2
- 229920003002 synthetic resin Polymers 0.000 claims description 2
- 239000000057 synthetic resin Substances 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 1
- 150000003377 silicon compounds Chemical class 0.000 claims 1
- 239000004952 Polyamide Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 229920002647 polyamide Polymers 0.000 description 6
- 239000004408 titanium dioxide Substances 0.000 description 6
- 239000004744 fabric Substances 0.000 description 5
- -1 lithopone Chemical compound 0.000 description 4
- 229920000728 polyester Polymers 0.000 description 3
- 239000012266 salt solution Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 239000012463 white pigment Substances 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 150000003608 titanium Chemical class 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 2
- OHVLMTFVQDZYHP-UHFFFAOYSA-N 1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)-2-[4-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidin-5-yl]piperazin-1-yl]ethanone Chemical compound N1N=NC=2CN(CCC=21)C(CN1CCN(CC1)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)=O OHVLMTFVQDZYHP-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- 239000005083 Zinc sulfide Substances 0.000 description 1
- AYJRCSIUFZENHW-DEQYMQKBSA-L barium(2+);oxomethanediolate Chemical compound [Ba+2].[O-][14C]([O-])=O AYJRCSIUFZENHW-DEQYMQKBSA-L 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000006735 deficit Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 230000001699 photocatalysis Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000004627 regenerated cellulose Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 229910052984 zinc sulfide Inorganic materials 0.000 description 1
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/06—Wet spinning methods
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/04—Pigments
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Description
Verfahren zum Mattieren von textilen Fasergebilden Es ist bekannt, daß textile Fasergebilde zur Beseitigung einer unerwünschten Transparenz mit Weißpigmenten mattiert werden. Als Weißpigment dienen z. B. Bariumcarbonat, Bariumsulfat, Calciumcarbonat, Calciumstearat, Calciumoxyd, Lithopone, Titandioxyd, Zinksulfid, Zinkoxyd und andere. Ein gutes Weißpiginent soll eine möglichst hohe Deckkraft sowie ein möglichst geringes spezifisches Gewicht besitzen. Es soll weiterhin eine große Oberfläche haben.Process for matting textile fiber structures It is known that textile fiber structures to eliminate unwanted transparency with white pigments to be matted. As a white pigment, z. B. barium carbonate, barium sulfate, calcium carbonate, Calcium stearate, calcium oxide, lithopone, titanium dioxide, zinc sulfide, zinc oxide and others. A good white pigment should have the highest possible opacity and the lowest possible have a specific weight. It should still have a large surface.
Die Mattierung kann durch zwei verschiedene Behandlungen erreicht werden.The matting can be achieved by two different treatments will.
1 . Durch Aufbringen (Applikation) des Mattierungsmittels auf die Faseroberfläche und 2. durch die sogenannte Spinnmattierung durch Zusatz des Mattierungsmittels zu den Spinnbädern. Dieses Verfahren kann sowohl bei vollsynthetischen Fasern als auch bei regenerierter Cellulose angewendet werden. 1 . By applying the matting agent to the fiber surface and 2. by so-called spinning matting by adding the matting agent to the spinning baths. This process can be used with fully synthetic fibers as well as with regenerated cellulose.
Beide Verfahren haben, zum Ziel, die Transparenz und den Glanz ohne eine Schädigung des Materials zu beheben.Both processes aim to achieve transparency and gloss without to repair damage to the material.
Es ist bekannt, daß das am häufigsten eingesetzte Weißpiginent, das Titandioxyd, z. B. in Polyamid-oder Polyesterfasem, in Gegenwart kurzwelliger Strahlen einen peroxydischen Abbau des Polymeren bewirkt. Eine solche Schäd-igung des Materials wird insbesondere beim Einsatz von Titandioxyd beobachtet -, als Folge einer fotokatalytischen Schädigung durch die Einwirkung von Sonnenlicht. Die Schädigang wirkt sich durch einen Verlust an Reißfestigkeit und Dehnung aus. Dieser störende Effekt wird besonders deutlich, wenn das Mattierungsmittel nicht auf die Faseroberfläche aufgebracht wird sondern in der ganzen Masse gleichmäßig verteilt ist, wie es bei einer Spinninattierung der Fall ist. Um diese Nachteile des Titandioxyds zu vermeiden, werden in der USA.-P#atentsch-rift 2 334 358 beispielsweise statt Titandioxyd die Titansalze organischer Säuren angewendet.It is known that the most commonly used white pigment, titanium dioxide, e.g. B. in polyamide or polyester fibers, causes peroxidic degradation of the polymer in the presence of short-wave radiation. Such damage to the material is observed in particular when titanium dioxide is used - as a result of photocatalytic damage from the action of sunlight. The damage results from a loss of tensile strength and elongation. This disruptive effect becomes particularly evident when the matting agent is not applied to the fiber surface but is evenly distributed throughout the entire mass, as is the case with spin finishing. In order to avoid these disadvantages of the titanium dioxide are rift atentsch-in USA.-P # 2334358, for example, instead of titanium dioxide, the titanium salts of organic acids used.
Es wurde gefunden, daß die mit den bekannten Weißpiginenten erzielbaren
Mattiereffekte bei weitem bei einer geringeren Schädigung des Fasermaterials übertroffen
werden, wenn man besondere Titansilicate zur Mattierung einsetzt. Solche besonderen
Titansilicate können z. B. durch Fällung aus einer Titaiisalzlösung mittels NatriumsiElcatlösung
hergestellt werden. Ein solches Produkt weist folgende physikalische Daten auf:
Beispiel 1 Polyamidgewebe wird mit einer Flotte, die 35 Teile eines Kunstharzbinders und 20 Teile Titansilicat in 1000 Teilen Wasser dispergiert enthält, iinprägnierL Nach dem Foulardieren wird im Spannrahmen M 2051 C ausgehärtet. Das erhaltene Polyamidg--webe zeigt einen hervorragenden Matteffekt. Der Reißfestigkeitsverlust nach 48 Stunden UV-Bestrahlung ist um 44% geringer als M mit Ti02 mattiertein Polyamid,gewebe.Example 1 Nylon is contains dispersed with a liquor containing 35 parts of a resin binder and 20 parts of titanium silicate in 1000 parts of water, iinprägnierL After padding is cured in a tenter M 2051 C. The polyamide fabric obtained shows an excellent matt effect. The loss of tensile strength after 48 hours of UV irradiation is 44% lower than that of a polyamide fabric matted with Ti02.
Beispiel 2 Polyestergewebe wird mit einer Flotte, die 3 0 Teile eines Kunstharzbinders und 15Teil-- Titansilicat in 1000Te,ilen Wasser disperglert enthält, imprägniert. Nach dem Foulardieren wird im Spannrahmen bei 1960 C ausgehärtet. Das erhaltene Polyestergewebe zeigt einen hervorragenden Matteffekt.Example 2 Polyester fabric is padded with a liquor containing 3 0 parts by weight of a resin binder and 15Teil-- titanosilicate in 1000Te, ilen water disperglert impregnated. After padding, it is cured in a stenter at 1960 C. The polyester fabric obtained shows an excellent matt effect.
Beispiel 3 Viskosekun-stseidegewebe wird mit einer Flotte, die 45 Teile eines Kunstharzbinders und 25 Teile Titansilicat in 1000 Teilen Wasser dispergiert enthält, imprägniert.Example 3 Viscose synthetic silk fabric is impregnated with a liquor which contains 45 parts of a synthetic resin binder and 25 parts of titanium silicate dispersed in 1000 parts of water.
Nach dem Foulardieren wird im Spannrahmen bei 150' C ausgelhärtet. Ergebnisse wie im Beispiel 1. Beispiel 4 Dem Polyamidspinnbad werden 2% Titansilicat zugesetzt. Die erhaltene Polyamid-faser zeigt hervorragenden Tiefmafteffekt. Der Reißfestigkeitsverlust nach 36stündiger UV-Bestrählung i,st um 53% geringer a-ls bei mit TiO, spinnmattierten Polyamidfasern.After padding, it is cured in a stenter at 150 ° C. Results as in Example 1. Example 4 2% titanium silicate are added to the polyamide spinning bath. The polyamide fiber obtained shows an excellent deep-tissue effect. The loss of tensile strength after 36 hours of UV irradiation is 53% less a-ls in the case of polyamide fibers spun-matted with TiO.
Claims (2)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEC25206A DE1162322B (en) | 1961-10-05 | 1961-10-05 | Process for matting textile fiber structures |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEC25206A DE1162322B (en) | 1961-10-05 | 1961-10-05 | Process for matting textile fiber structures |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1162322B true DE1162322B (en) | 1964-02-06 |
Family
ID=7017835
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEC25206A Pending DE1162322B (en) | 1961-10-05 | 1961-10-05 | Process for matting textile fiber structures |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE1162322B (en) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2334358A (en) * | 1938-11-16 | 1943-11-16 | American Enka Corp | Artificial cellulosic filament delustered with titanium salt |
-
1961
- 1961-10-05 DE DEC25206A patent/DE1162322B/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2334358A (en) * | 1938-11-16 | 1943-11-16 | American Enka Corp | Artificial cellulosic filament delustered with titanium salt |
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