DE1055223B - Process for the remuneration of wood soaked with impregnation oils - Google Patents
Process for the remuneration of wood soaked with impregnation oilsInfo
- Publication number
- DE1055223B DE1055223B DER23757A DER0023757A DE1055223B DE 1055223 B DE1055223 B DE 1055223B DE R23757 A DER23757 A DE R23757A DE R0023757 A DER0023757 A DE R0023757A DE 1055223 B DE1055223 B DE 1055223B
- Authority
- DE
- Germany
- Prior art keywords
- wood
- remuneration
- soaked
- oils
- impregnation oils
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002023 wood Substances 0.000 title claims description 12
- 239000003921 oil Substances 0.000 title claims description 11
- 238000000034 method Methods 0.000 title claims description 5
- 238000005470 impregnation Methods 0.000 title description 3
- WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical compound FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 claims description 8
- 229910015900 BF3 Inorganic materials 0.000 claims description 4
- 150000002170 ethers Chemical class 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 150000001298 alcohols Chemical class 0.000 claims description 3
- 150000002989 phenols Chemical class 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 2
- 239000007795 chemical reaction product Substances 0.000 claims description 2
- 150000007524 organic acids Chemical class 0.000 claims description 2
- 235000005985 organic acids Nutrition 0.000 claims description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims 2
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims 1
- 239000004327 boric acid Substances 0.000 claims 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 235000019253 formic acid Nutrition 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 230000000379 polymerizing effect Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005496 tempering Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/34—Organic impregnating agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/16—Inorganic impregnating agents
- B27K3/163—Compounds of boron
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/16—Inorganic impregnating agents
- B27K3/30—Compounds of fluorine
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Forests & Forestry (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
Description
Verfahren zur Vergütung von mit Imprägnierölen getränktem Holz In der nicht vorveröffenilichten deutschen Patentschrift 1029553 ist ein Verfahren zum Vergüten von mit Imprägnierölen getränkten. Holz mittels gasförmiger, auf das- Imprägnieröl polymerisierend wirkender Mittel beschrieben. Durch diese Behandlung wird erreicht, daß die Außenflächen des ölimprägnierten Holzes ihre Klebrigkeit verlieren. Als gasförmiges Mittel ist in der Patentschrift unter anderem Bortrifluorid angegeben. In vielen Fällen ist es wünschenswert, die Vergütung nicht mit gasförmigen Mitteln, sondern mit Flüssigkeiten vorzunehmen. Die Verwendung gasförmiger Mittel macht es in der Regel notwendig, daß man das imprägnierte Holz in einer besonderen Kammer behandelt. Auch hinsichtlich der besseren Dosierung und leichteren Verteilung des polymerisierend wirkenden Mittels ist es vorteilhafter, Flüssigkeiten zu verwenden.Process for the remuneration of wood soaked with impregnating oils In the not pre-published German patent specification 1029553 is a method for tempering impregnated oils. Wood by means of gaseous, Impregnating oil polymerizing agent described. Through this treatment it is achieved that the outer surfaces of the oil-impregnated wood their stickiness lose. Boron trifluoride is one of the gaseous agents in the patent specified. In many cases it is desirable not to use gaseous remuneration Means, but rather with liquids. The use of gaseous media usually makes it necessary to put the impregnated wood in a special Chamber treated. Also in terms of better dosage and easier distribution of the polymerizing agent, it is more advantageous to use liquids.
Es wurde nun gefunden, daß auch die Lösungen der Reaktionsprodukte von Bortrifluorid mit organischen Säuren, z. B. Ameisensäure, Essigsäure, oder mit Wasser, Alkoholen, Phenolen und Äthern eine Oberflächenverharzung des imprägnierten Holzes bewirken.It has now been found that the solutions of the reaction products of boron trifluoride with organic acids, e.g. B. formic acid, acetic acid, or with Water, alcohols, phenols and ethers create a surface resinification of the impregnated Effect wood.
Zu diesem Zweck wird beispielsweise B F3 in 85 g einer 100°/oigen Ameisensäure oder Essigsäure so lange unter Kühlung eingeleitet, bis 15 g des Gases aufgenommen sind. Taucht man nun in diese Lösung 5 Minuten lang ein mit Imprägnieröl getränktes Kiefernholzklötzchen (8X4X2 cm) und erwärmt danach dieses Klötzchen 1/z bis 1 Stunde im Trockenschrank auf 80 bis 100° C, so ist infolge der eingetretenen Polymerisation des Imprägnieröls das Holz an der Oberfläche vollkommen gehärtet. Nach dem Erkalten gibt das Klötzchen kein Imprägnieröl und, auf Filterpapier gebracht, keinen Ölfleck mehr ab. Die Härteflüssigkeit kann auch im Sprühverfahren auf das imprägnierte Holz aufgebracht werden.For this purpose, for example, B F3 in 85 g of 100% Formic acid or acetic acid introduced with cooling until 15 g of the gas are included. You then immerse yourself in this solution for 5 minutes with impregnating oil soaked pinewood block (8X4X2 cm) and then heat this block 1 / z up to 1 hour in the drying cabinet at 80 to 100 ° C, as a result of the Polymerization of the impregnation oil completely hardens the surface of the wood. After cooling, the block does not give any impregnation oil and, put on filter paper, no more oil stain. The hardening liquid can also be sprayed onto the impregnated wood can be applied.
In analoger Weise erhält man Behandlungslösungen durch Zusammenbringen von Bortrifluorid mit Äthern, Alkoholen, Phenolen.oder Wasser.Treatment solutions are obtained in an analogous manner by bringing them together of boron trifluoride with ethers, alcohols, phenols. or water.
Man gelangt zu dem gewünschten Härteeffekt auch, wenn man eine wäßrige Borfluorwasserstoffsäure H B F4 verwendet, die in bekannter Weise aus 13203 und H F hergestellt wird.You can also get the desired hardness effect if you use an aqueous one Fluorofluoric acid H B F4 is used, which in a known manner from 13203 and H F is produced.
Die Konzentration an B F3 in den Lösungen beträgt zweckmäßigerweise 15% und mehr. Bei-- der Verwendung von B F3 Wasser- bzw. . -Alkoholkomplexen ist es zweckmäßig, eine handelsübliche Sparbeize in einer Menge von 1 bis 1,5% zuzusetzen, um die korrodierende Wirkung herabzumindern. Der Zusatz von Sparbeize wirkt lediglich korrosionshindernd, hat aber keinen Einfluß auf die Polymerisation des Imprägnieröls. Die BF._ Ätherkomplexe zeigen kein korrosives Verhalten gegenüber Kesselblech.The concentration of B F3 in the solutions is expediently 15% and more. When using B F3 water or. -Alcohol complexes it is advisable to add a commercially available economy stain in an amount of 1 to 1.5%, to reduce the corrosive effect. The addition of saving stain only works prevents corrosion, but has no influence on the polymerization of the impregnating oil. The BF._ ether complexes show no corrosive behavior towards boiler sheet.
Claims (2)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DER23757A DE1055223B (en) | 1958-07-25 | 1958-07-25 | Process for the remuneration of wood soaked with impregnation oils |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DER23757A DE1055223B (en) | 1958-07-25 | 1958-07-25 | Process for the remuneration of wood soaked with impregnation oils |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1055223B true DE1055223B (en) | 1959-04-16 |
Family
ID=7401495
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DER23757A Pending DE1055223B (en) | 1958-07-25 | 1958-07-25 | Process for the remuneration of wood soaked with impregnation oils |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE1055223B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2355628A1 (en) * | 1976-06-30 | 1978-01-20 | Basf Ag | Oxyalkylation of orthoboric acid - with alkylene oxides under pressure in aprotic solvent |
-
1958
- 1958-07-25 DE DER23757A patent/DE1055223B/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2355628A1 (en) * | 1976-06-30 | 1978-01-20 | Basf Ag | Oxyalkylation of orthoboric acid - with alkylene oxides under pressure in aprotic solvent |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| GB1042690A (en) | Process for the pre-treatment of metal surfaces before enamelling | |
| DE1055223B (en) | Process for the remuneration of wood soaked with impregnation oils | |
| DE1546070A1 (en) | Process for the pretreatment of steel sheets or clad steel sheets for the purpose of phosphating | |
| DE338809C (en) | Process for completely even coloring and impregnation of wood and similar materials | |
| DE2263758B2 (en) | Process for the production of dimensionally stable wood and wood products made from it, e.g. veneers, chips | |
| US3039843A (en) | Corrosion inhibited wood treating solution | |
| DE1642173A1 (en) | Manufacturing process for wood-plastic combinations | |
| DE1125451B (en) | Process for the production of hectographic prints | |
| AT216748B (en) | Process for the compensation of wood soaked with impregnation oils | |
| AT159742B (en) | Process for preserving hard-to-drink woods such as spruce and fir. | |
| US3023125A (en) | Process of treating coal tar impregnated wood with a solution of a compound of boron trifluoride | |
| DE863996C (en) | Process for emulsion polymerization of unsaturated organic compounds | |
| US1043582A (en) | Process of preserving and coloring wood. | |
| DE485101C (en) | Method for protecting wool, fur and the like Like. Against moth damage | |
| DE498309C (en) | Method of preserving wood | |
| DE661496C (en) | Preservative for wood | |
| DE542785C (en) | Process for the production of urea-formaldehyde condensation products | |
| DE758940C (en) | Process for the degradation of cellulosic raw materials | |
| AT131122B (en) | Preservatives for wood. | |
| DE872860C (en) | Process for finishing wood | |
| DE908769C (en) | Process for drawing windings for electrolytic capacitors | |
| DE889220C (en) | Process for bleaching wood with hydrogen peroxide and additional paste to obtain a treatment agent for the process | |
| DE2210502A1 (en) | Case hardening of iron containing silicon | |
| AT200058B (en) | Process for increasing the resistance of concrete bodies to chemical corrosion | |
| DE584253C (en) | Process for embossing peeling wood veneers |