DE1047077B - Process for preparing steel sheets for deep drawing by applying a phosphate layer - Google Patents

Process for preparing steel sheets for deep drawing by applying a phosphate layer

Info

Publication number
DE1047077B
DE1047077B DEL16563A DEL0016563A DE1047077B DE 1047077 B DE1047077 B DE 1047077B DE L16563 A DEL16563 A DE L16563A DE L0016563 A DEL0016563 A DE L0016563A DE 1047077 B DE1047077 B DE 1047077B
Authority
DE
Germany
Prior art keywords
steel sheets
applying
deep drawing
phosphate layer
preparing steel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
DEL16563A
Other languages
German (de)
Inventor
Rudolf Stamm
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Licentia Patent Verwaltungs GmbH
Original Assignee
Licentia Patent Verwaltungs GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Licentia Patent Verwaltungs GmbH filed Critical Licentia Patent Verwaltungs GmbH
Priority to DEL16563A priority Critical patent/DE1047077B/en
Publication of DE1047077B publication Critical patent/DE1047077B/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/73Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals characterised by the process
    • C23C22/74Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals characterised by the process for obtaining burned-in conversion coatings

Landscapes

  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Chemical Treatment Of Metals (AREA)

Description

Verfahren zur Vorbereitung von Stahlblechen für das Tiefziehen durch Aufbringen einer Phosphatschicht Bekanntlich müssen Stahlbleche vor dem Tiefziehen eine Oberflächenbehandlung erfahren, um das Einreißen oder Festfressen im Werkzeug zu vermeiden. Ferner müssen Schmiermittel angewendet und Zwischenglühoperationen eingeschaltet werden.Process for preparing steel sheets for deep drawing Application of a phosphate layer It is well known that steel sheets must be deep-drawn undergone a surface treatment to prevent tearing or seizing in the tool to avoid. Furthermore, lubricants must be applied and intermediate annealing operations be switched on.

Um das kostspielige Zwischenglühen zu vermeiden, sind Verfahren entwickelt worden, nach denen Stahloberflächen vor dem Tiefziehen auf elektrolytischem Wege oder im Sud-Verfahren mit einer Metallschicht überzogen werden. Man wählt beispielsweise Blei, Kupfer, Messing oder Zink. Dieses Verfahren hat aber den Nachteil, daß es durch seinen großen Materialaufwand sehr teuer ist. Einen Fortschritt bildete das Phosphatieren der Stahloberfläche nach dem Parker-, Bonder- oder Atramentverfahren. Die aufgebrachte Phosphatschicht verbindet sich fest mit der Stahloberfläche und übernimmt die Aufgaben der vorgenannten Metallschichten. Die Voxbehandlung der Stahlbleche sowie die notwendigen Zwischenglühoperationen umfassen aber annähernd zehn Arbeitsgänge und sind aus diesem Grunde noch recht unwirtschaftlich. Hinzu kommt, daß die Phosphatierungsverfahren nicht für alle Stahlbleche befriedigen, beispielsweise nicht bei großen Härteschwankungen. Nach mehrmaligem Ziehen ist die Phosphatschicht verbraucht, zumindest aber beschädigt und muß unter Wiederholung aller Arbeitsvorgänge neu aufgebracht werden.Processes have been developed to avoid the costly intermediate annealing after which steel surfaces electrolytically before deep drawing or coated with a metal layer in the Sud process. One chooses, for example Lead, copper, brass or zinc. This method has the disadvantage that it is very expensive due to its large amount of material. That was a step forward Phosphating of the steel surface using the Parker, Bonder or Atrament processes. The applied phosphate layer bonds firmly to the steel surface and takes over the tasks of the aforementioned metal layers. The Vox treatment of steel sheets as well as the necessary intermediate annealing operations, however, comprise approximately ten work steps and for this reason are still quite uneconomical. In addition, the phosphating process not satisfactory for all steel sheets, for example not with large fluctuations in hardness. After pulling it several times, the phosphate layer is used up, or at least damaged and must be reapplied by repeating all operations.

Die Nachteile der vorgenannten Verfahren können erfindungsgemäß dadurch überwunden werden, daß ein im Tauch- oder Spritzverfahren auf die Oberfläche des Metallgegenstandes aufgebrachter und vorzugsweise bei einer Ofentemperatur von etwa 200° C trocknender, als nichtmetallisches Gleitmittel wirkender Überzug verwendet wird, der aus Polyvinylacetat als Bindemittel, basischem Zinkchromat als Pigment und verdünnter Phosphorsäure besteht. Bindemittel und Pigment werden vorteilhaft in einem Verhältnis 2:1 verwendet; als Zusatz wird 8- bis 101/oige Phosphorsäure benutzt. Eine diese Komponenten enthaltende Lösung kann aus 100 Teilen PVA, 50 Teilen basischem Zinkchromat und 5 Teilen 8- bis 10o/oiger Phosphorsäure bestehen. Der geringe Phosphorsäureüberschuß bereitet die Stahloberfläche für die Einlagerung der Pigmentteile vor. Wenn auch die Trocknung des Gleitmittels bei Zimmertemperatur möglich ist, so hat sich aber als vorteilhaft erwiesen, die Trocknung in einem Strahlungsofen bei etwa 200° C auszuführen.According to the invention, the disadvantages of the aforementioned methods can thereby be eliminated be overcome that a dip or spray process on the surface of the Metal object applied and preferably at an oven temperature of about 200 ° C drying, non-metallic lubricant coating used made of polyvinyl acetate as a binder and basic zinc chromate as a pigment and dilute phosphoric acid. The binder and pigment become advantageous used in a ratio of 2: 1; 8-10% phosphoric acid is used as an additive used. A solution containing these components can consist of 100 parts PVA, 50 parts basic zinc chromate and 5 parts of 8 to 10% phosphoric acid. Of the a slight excess of phosphoric acid prepares the steel surface for storage of the pigment parts. Albeit drying the lubricant at room temperature is possible, but has proven to be advantageous, drying in a radiation oven to be carried out at about 200 ° C.

Im Gegensatz zu den bekannten Verfahren bleibt dieser Überzug bei dem Ziehvorgang gut erhalten. Damit ist zugleich ein ausreichender Korrosionsschutz für gegebenenfalls notwendige Zwischenlagerungen gegeben. Ferner eignet sich die aufgebrachte Gleitmittelschicht als Grundierung für eine spätere Lackierung. Während beispielsweise bei Stahlblechen mit schwankender Härte die Phosphatierungsverfahren nicht ausreichen, um eine für den Ziehvorgang hinreichende Gleichmäßigkeit in der Oberflächenbeschaffenheit des Bleches herbeizuführen und daher eine besondere Vorbehandlung erforderlich machen, ermöglicht die Anwendung des neuen Verfahrens einen glatten Ziehvorgang.In contrast to the known processes, this coating is retained well preserved after the drawing process. This also provides sufficient protection against corrosion for any necessary interim storage. The applied lubricant layer as a primer for later painting. While For example, the phosphating process for steel sheets with fluctuating hardness are not sufficient to ensure sufficient uniformity in the for the drawing process To bring about the surface quality of the sheet and therefore a special pretreatment make the application of the new method a smooth one Drawing process.

Nach der erfindungsgemäßen Vorbehandlung des Stahlbleches können die einzelnen Arbeitsstufen des Tiefziehvorganges ohne Unterbrechung vorgenommen werden.After the pretreatment of the steel sheet according to the invention, the individual work stages of the deep-drawing process can be carried out without interruption.

Selbst wenn es in manchen Ausnahmefällen erforderlich sein sollte, die Schicht zu erneuern, ist dies in zwei Arbeitsgängen, Entfetten und Tauchen bzw. Spritzen, geschehen, so daß es nicht notwendig ist, die neue Schicht in etwa zehn Arbeitsgängen aufzubringen, wie das sonst beim Phosphatieren der Fall ist.Even if it should be necessary in some exceptional cases, To renew the layer, this is done in two steps, degreasing and immersion or Spraying is done so that it is not necessary to apply the new layer in about ten To apply operations, as is otherwise the case with phosphating.

Claims (1)

PATENTANSPPL`CII: Verfahren zur Vorbereitung von Stahlblechen für das Tiefziehen durch Aufbringen einer Phosphatschicht, dadurch gekennzeichnet, daß man auf das Stahlblech im Tauch- oder Spritzverfahren eine Polyvinylacetat und basisches Zinkchromat, vorteilhaft im Verhältnis 2:1, sowie 8- bis 102/oige Phosphorsäure enthaltende Lösung aufträgt und den Überzug vorzugsweise bei etwa 200° C trocknet. In Betracht gezogene Druckschriften: »Werkstoffe und Korrosion«, 1953, S. 196; »Metal Progress«, April 1953, S. 106 bis 108.PATENTANSPPL`CII: Process for preparing steel sheets for deep drawing by applying a phosphate layer, characterized in that one on the steel sheet in the dipping or spraying process a polyvinyl acetate and basic Zinc chromate, advantageously in a ratio of 2: 1, and 8-10% phosphoric acid containing solution and the coating preferably dries at about 200 ° C. Considered publications: "Werkstoffe und Korrosion", 1953, p. 196; “Metal Progress ”, April 1953, pp. 106 to 108.
DEL16563A 1953-09-07 1953-09-07 Process for preparing steel sheets for deep drawing by applying a phosphate layer Pending DE1047077B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DEL16563A DE1047077B (en) 1953-09-07 1953-09-07 Process for preparing steel sheets for deep drawing by applying a phosphate layer

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEL16563A DE1047077B (en) 1953-09-07 1953-09-07 Process for preparing steel sheets for deep drawing by applying a phosphate layer

Publications (1)

Publication Number Publication Date
DE1047077B true DE1047077B (en) 1958-12-18

Family

ID=7260472

Family Applications (1)

Application Number Title Priority Date Filing Date
DEL16563A Pending DE1047077B (en) 1953-09-07 1953-09-07 Process for preparing steel sheets for deep drawing by applying a phosphate layer

Country Status (1)

Country Link
DE (1) DE1047077B (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1141154B (en) * 1959-07-11 1962-12-13 Dr Fritz Singer Process for the production of films which facilitate cold forming on iron and steel
DE1274419B (en) * 1964-04-30 1968-08-01 Kussmann Ferro Chemie Process and mixture for the production of phosphate layers on the surfaces of iron and steel

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
None *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1141154B (en) * 1959-07-11 1962-12-13 Dr Fritz Singer Process for the production of films which facilitate cold forming on iron and steel
DE1274419B (en) * 1964-04-30 1968-08-01 Kussmann Ferro Chemie Process and mixture for the production of phosphate layers on the surfaces of iron and steel

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