DE10345902A1 - Verfahren zur Herstellung von Synthesegas aus Erdgas und Reaktor zur Durchführung des Verfahrens - Google Patents

Verfahren zur Herstellung von Synthesegas aus Erdgas und Reaktor zur Durchführung des Verfahrens Download PDF

Info

Publication number
DE10345902A1
DE10345902A1 DE2003145902 DE10345902A DE10345902A1 DE 10345902 A1 DE10345902 A1 DE 10345902A1 DE 2003145902 DE2003145902 DE 2003145902 DE 10345902 A DE10345902 A DE 10345902A DE 10345902 A1 DE10345902 A1 DE 10345902A1
Authority
DE
Germany
Prior art keywords
gas
synthesis gas
natural gas
reforming
cooling
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
DE2003145902
Other languages
English (en)
Other versions
DE10345902B4 (de
Inventor
William Davey
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Air Liquide Global E&C Solutions Germany GmbH
Original Assignee
Lurgi GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lurgi GmbH filed Critical Lurgi GmbH
Priority to DE2003145902 priority Critical patent/DE10345902B4/de
Publication of DE10345902A1 publication Critical patent/DE10345902A1/de
Application granted granted Critical
Publication of DE10345902B4 publication Critical patent/DE10345902B4/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0285—Heating or cooling the reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/008—Details of the reactor or of the particulate material; Processes to increase or to retard the rate of reaction
    • B01J8/009—Membranes, e.g. feeding or removing reactants or products to or from the catalyst bed through a membrane
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0242—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical
    • B01J8/025—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical in a cylindrical shaped bed
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/382—Multi-step processes
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D7/00—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
    • F28D7/0066—Multi-circuit heat-exchangers, e.g. integrating different heat exchange sections in the same unit or heat-exchangers for more than two fluids
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D7/00—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
    • F28D7/0066—Multi-circuit heat-exchangers, e.g. integrating different heat exchange sections in the same unit or heat-exchangers for more than two fluids
    • F28D7/0083—Multi-circuit heat-exchangers, e.g. integrating different heat exchange sections in the same unit or heat-exchangers for more than two fluids with units having particular arrangement relative to a supplementary heat exchange medium, e.g. with interleaved units or with adjacent units arranged in common flow of supplementary heat exchange medium
    • F28D7/0091—Multi-circuit heat-exchangers, e.g. integrating different heat exchange sections in the same unit or heat-exchangers for more than two fluids with units having particular arrangement relative to a supplementary heat exchange medium, e.g. with interleaved units or with adjacent units arranged in common flow of supplementary heat exchange medium the supplementary medium flowing in series through the units
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D7/00—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
    • F28D7/02—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits being helically coiled
    • F28D7/024—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits being helically coiled the conduits of only one medium being helically coiled tubes, the coils having a cylindrical configuration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00106—Controlling the temperature by indirect heat exchange
    • B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
    • B01J2208/00194—Tubes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00106—Controlling the temperature by indirect heat exchange
    • B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
    • B01J2208/00203—Coils
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00504—Controlling the temperature by means of a burner
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0244—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being an autothermal reforming step, e.g. secondary reforming processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0838—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel
    • C01B2203/0844—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel the non-combustive exothermic reaction being another reforming reaction as defined in groups C01B2203/02 - C01B2203/0294
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0872—Methods of cooling
    • C01B2203/0883—Methods of cooling by indirect heat exchange
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1241—Natural gas or methane
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/80—Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
    • C01B2203/82—Several process steps of C01B2203/02 - C01B2203/08 integrated into a single apparatus

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Thermal Sciences (AREA)
  • Fluid Mechanics (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)

Abstract

Bei einem Verfahren zur Herstellung von Synthesegas aus Erdgas wird ein aus Erdgas und Dampf bestehendes Gemisch zusammen mit Sauerstoff durch katalytisches autothermes Reformieren unter Druck für Synthesegas umgesetzt, danach durch eine Katalysatorschicht geleitet und anschließend auf eine Temperatur von bis zu 400 DEG C abgekühlt. Zur Verbesserung der Wärmeübergangsleistung zwischen dem erzeugten Synthesegas und dem Kühlmittel der Wärmeübergangsleistung zwischen dem erzeugten Synthesegas und dem Kühlmittel werden das Reformieren des Gemisches und das Kühlen des Synthesegases in einem geschlossenen vertikalen Reaktor durchgeführt.
DE2003145902 2003-10-02 2003-10-02 Verfahren zur Herstellung von Synthesegas aus Erdgas und Reaktor zur Durchführung des Verfahrens Expired - Fee Related DE10345902B4 (de)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DE2003145902 DE10345902B4 (de) 2003-10-02 2003-10-02 Verfahren zur Herstellung von Synthesegas aus Erdgas und Reaktor zur Durchführung des Verfahrens

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE2003145902 DE10345902B4 (de) 2003-10-02 2003-10-02 Verfahren zur Herstellung von Synthesegas aus Erdgas und Reaktor zur Durchführung des Verfahrens

Publications (2)

Publication Number Publication Date
DE10345902A1 true DE10345902A1 (de) 2005-05-04
DE10345902B4 DE10345902B4 (de) 2005-07-07

Family

ID=34399191

Family Applications (1)

Application Number Title Priority Date Filing Date
DE2003145902 Expired - Fee Related DE10345902B4 (de) 2003-10-02 2003-10-02 Verfahren zur Herstellung von Synthesegas aus Erdgas und Reaktor zur Durchführung des Verfahrens

Country Status (1)

Country Link
DE (1) DE10345902B4 (de)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102007025785A1 (de) * 2007-06-01 2009-02-19 Lurgi Gmbh Vorrichtung zum Behandeln von Synthesegas
WO2009052764A1 (fr) * 2007-10-19 2009-04-30 Ren Lou Appareillage de réaction composite et procédé chimique de production utilisant celui-ci
CN101519336B (zh) * 2008-02-29 2012-11-14 杭州林达化工技术工程有限公司 合成气制烃类的方法和设备
CN106931306A (zh) * 2017-03-09 2017-07-07 中国石油大学(华东) 一种缠绕管式lng中间介质气化器
DE102016114713A1 (de) * 2016-08-09 2018-02-15 Thyssenkrupp Ag Synthesevorrichtung und Verfahren zur Herstellung eines Produkts

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9595726B2 (en) 2014-01-07 2017-03-14 Advanced Cooling Technologies, Inc. Fuel reforming system and process
US10557391B1 (en) 2017-05-18 2020-02-11 Advanced Cooling Technologies, Inc. Incineration system and process

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3244252C2 (de) * 1982-11-30 1990-10-31 Uhde Gmbh, 4600 Dortmund, De
DE3345064C2 (de) * 1983-12-13 1992-01-23 Linde Ag, 6200 Wiesbaden, De

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3244252C2 (de) * 1982-11-30 1990-10-31 Uhde Gmbh, 4600 Dortmund, De
DE3345064C2 (de) * 1983-12-13 1992-01-23 Linde Ag, 6200 Wiesbaden, De

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102007025785A1 (de) * 2007-06-01 2009-02-19 Lurgi Gmbh Vorrichtung zum Behandeln von Synthesegas
DE102007025785B4 (de) * 2007-06-01 2013-02-21 Lurgi Gmbh Vorrichtung zum Behandeln von Synthesegas
WO2009052764A1 (fr) * 2007-10-19 2009-04-30 Ren Lou Appareillage de réaction composite et procédé chimique de production utilisant celui-ci
CN101519336B (zh) * 2008-02-29 2012-11-14 杭州林达化工技术工程有限公司 合成气制烃类的方法和设备
DE102016114713A1 (de) * 2016-08-09 2018-02-15 Thyssenkrupp Ag Synthesevorrichtung und Verfahren zur Herstellung eines Produkts
CN106931306A (zh) * 2017-03-09 2017-07-07 中国石油大学(华东) 一种缠绕管式lng中间介质气化器
CN106931306B (zh) * 2017-03-09 2020-03-31 中国石油大学(华东) 一种缠绕管式lng中间介质气化器

Also Published As

Publication number Publication date
DE10345902B4 (de) 2005-07-07

Similar Documents

Publication Publication Date Title
US6059995A (en) Process and preparation of hydrogen-rich gas
CA2111017C (en) Process for the preparation of carbon monoxide rich gas
US6525104B2 (en) Steam reforming
AU625488B1 (en) Autothermal steam reforming process
CA1321711C (en) Hydrogen
IL271938B2 (en) A method for making synthesis gas
BR112020001511A2 (pt) processo para a coprodução de metanol e amônia
NO20034284D0 (no) Fremgangsmåte til fremstilling av syntesegass
JP2006523596A5 (de)
JP2006523597A (ja) 合成ガスの製造方法
CA2534706A1 (en) Method and apparatus for the production of hydrogen-rich gas
NO20050958L (no) Hydrogen til dampreformering av naturgass til syntesegass
CA2619714A1 (en) Synthesis gas and carbon dioxide generation method
MY142112A (en) Process for producing synthesis gas for the fischer-tropsch synthesis and producing apparatus thereof
RU2003117224A (ru) Способ синтеза аммиака из смеси азота и водорода, полученной из природного газа
ZA200510336B (en) Reforming process
IL271941B1 (en) A method for making synthesis gas
WO2014180888A1 (en) Process for the preparation of syngas
NO922120L (no) Fremgangsmate for overforing av naturgass til hoyere hydrocarboner
CA2510442C (en) Partial oxidation reformer-reforming exchanger arrangement
DE10345902A1 (de) Verfahren zur Herstellung von Synthesegas aus Erdgas und Reaktor zur Durchführung des Verfahrens
JPH0798643B2 (ja) アンモニア合成ガスの製造方法
FR2848548B1 (fr) Procede de generation d'un melange de synthese co-h2 sous pression par oxydation partielle catalytique en minimisant la formation de suies
US10000379B2 (en) Process for the preparation of syngas
US20240002221A1 (en) A method for producing syngas using catalytic reverse water gas shift

Legal Events

Date Code Title Description
OP8 Request for examination as to paragraph 44 patent law
8364 No opposition during term of opposition
8327 Change in the person/name/address of the patent owner

Owner name: LURGI GMBH, 60439 FRANKFURT, DE

R081 Change of applicant/patentee

Owner name: AIR LIQUIDE GLOBAL E&C SOLUTIONS GERMANY GMBH, DE

Free format text: FORMER OWNER: LURGI GMBH, 60439 FRANKFURT, DE

Effective date: 20140505

R119 Application deemed withdrawn, or ip right lapsed, due to non-payment of renewal fee