DE1031269B - Process for removing cationic preparations from unprocessed textile material - Google Patents

Process for removing cationic preparations from unprocessed textile material

Info

Publication number
DE1031269B
DE1031269B DEB26383A DEB0026383A DE1031269B DE 1031269 B DE1031269 B DE 1031269B DE B26383 A DEB26383 A DE B26383A DE B0026383 A DEB0026383 A DE B0026383A DE 1031269 B DE1031269 B DE 1031269B
Authority
DE
Germany
Prior art keywords
unprocessed
textile material
textile
removing cationic
preparations
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
DEB26383A
Other languages
German (de)
Inventor
Dr Oskar Polhaus
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Joh A Benckiser GmbH
Original Assignee
Joh A Benckiser GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DEB22303A external-priority patent/DE1023003B/en
Application filed by Joh A Benckiser GmbH filed Critical Joh A Benckiser GmbH
Priority to DEB26383A priority Critical patent/DE1031269B/en
Publication of DE1031269B publication Critical patent/DE1031269B/en
Pending legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/673—Inorganic compounds
    • D06P1/67308—Hydroxylamine or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02—Inorganic compounds
    • C11D7/04—Water-soluble compounds
    • C11D7/10—Salts
    • C11D7/16—Phosphates including polyphosphates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
    • D06L1/12—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using aqueous solvents
    • D06L1/14—De-sizing

Description

Gegenstand der Patentanmeldung B 22303 IVd/ 8 k ist die Anwendung polymere Phosphate enthaltender alkalischer Flotten zum Entfernen von auf der Faser haftenden aus ternären und quarternären Amin- und Ammonium- sowie Sulfonium- und Phosphoniumverbindungen bestehenden kationaktiven Präparationen von unverarbeitetem Textilgut auf natürlicher oder synthetischer Basis.The subject of patent application B 22303 IVd / 8 k is the use of polymeric phosphates alkaline liquors for removing ternary and quaternary amine and Cation-active preparations consisting of ammonium, sulfonium and phosphonium compounds of unprocessed textile goods on a natural or synthetic basis.

Als polymere Phosphate kommen unter anderem und bevorzugt Pyro- oder Metaphosphate, Tri- oder Tetrapolyphosphate sowie Kondensationsprodukte aus Harnstoff und Phosphorpentoxyd oder Gemische von ihnen in Frage. Auch an sich unlösliche Polyphosphate können verwandt werden, wenn sie durch geeignete Zusätze löslich gemacht werden, wie z. B. die schwerlöslichen und auch als unlöslich bezeichneten Kaliummetaphosphate in bekannter Weise durch Natriumsalze. An Stelle definierter anhydrischer Phosphate können auch Produkte zur Anwendung gelangen, wie sie durch thermische Entwässerung von Gemischen aus Phosphaten mit höherem Gehalt an Konstitutionewasser, insbesondere von Gemischen aus Mono- und Dialkaliorthophosphat, bevorzugt in glasiger Form erhalten werden.Polymeric phosphates include and are preferably pyro- or metaphosphates, tri- or Tetrapolyphosphates and condensation products of urea and phosphorus pentoxide or mixtures of them in question. Even polyphosphates which are insoluble per se can be used if they are appropriately treated Additives are made soluble, such as. B. the poorly soluble and also as insoluble designated potassium metaphosphates in a known manner by sodium salts. Instead of defined anhydrous phosphates Products can also be used, such as those produced by thermal dewatering of mixtures from phosphates with a higher content of constitution water, in particular of mixtures of mono- and dialkali orthophosphate, preferably in glassy form can be obtained.

Wegen der thermischen Empfindlichkeit eines großen Teils der kationaktiven Avivagen, die bei höheren Temperaturen zur Polymerisation neigen, wurde dort eine Behandlung des Textilgutes bei gewöhnlicher oder mäßig erhöhter Temperatur bevorzugt. Because of the thermal sensitivity of a large part of the cationic finishing agents used in higher temperatures tend to polymerize, there was a treatment of the textile at normal or moderately elevated temperature preferred.

Es wurde nun gefunden, daß sich kationaktive ~ Avivagen bei höheren Temperaturen bis zur Siedehitze und selbst darüber hinaus unter Druck ganz besonders gut abziehen lassen. Vorliegende Erfindung betrifft demgemäß die Durchführung des Verfahrens der Hauptpatentanmeldung in der Hitze.It has now been found that cationic ~ finishes at higher temperatures up to the boiling point and can even pull off under pressure particularly well beyond. The present invention accordingly relates to the implementation of the method of the main patent application in the heat.

Beispiel 1example 1

30 g eines mit Decyltrimethylammoniumchlorid avivierten, vergilbten unverarbeiteten Gewirkes in Schlauchform auf Caprolactambasis werden in einer Flotte von 1 1, die mit Natronlauge auf pH = 12 eingestellt ist, unter Zugabe von 4 g Natriumhexametaphosphat 20 Minuten bei 95° C behandelt. Hierauf wird gründlich gespült mit Essigsäure, bis zur neutralen Reaktion der Ware abgesäuert und nochmals nachgespült.30 g of the lubricated with decyltrimethylammonium chloride, yellowed unprocessed knitted fabric in tubular form on Caprolactambasis are treated in a fleet of 1 1, which is adjusted with sodium hydroxide to p H = 12 with the addition of 4 g sodium hexametaphosphate 20 minutes at 95 ° C. This is followed by thorough rinsing with acetic acid, acidified until the product reacts neutral and rinsed again.

Neben der Entgilbung ist das behandelte Gewirke so weit entaviviert, daß es sich in einem 40° C warmen Bad ohne Hilfsmittelzugabe mit Telonlichtblau RR in guter Farbtiefe und Egalität anfärben läßt.In addition to de-yellowing, the treated knitted fabric is de-avivated to such an extent that it is at a temperature of 40 ° C in a warm bath without the addition of any aids, with Telonlichtblau RR in good color depth and levelness.

von kationaktiven Präparationenof cation-active preparations

von unverarbeitetem Textilgutof unprocessed textile goods

Zusatz zur Patentanmeldung B 22303 IVc / &k
(Auslegeschrift 1 02β 003)Addition to patent application B 22303 IVc / & k
(Interpretation document 1 02β 003)

Anmelder:
Jon. A. Benckiser G.m.b.H.,Applicant:
Jon. A. Benckiser GmbH,

Chemische Fabrik,
Ludwigshafen/Rhein, Frankenthaler Str. 3Chemical factory,
Ludwigshafen / Rhein, Frankenthaler Str. 3

Dr. Oskar Polhaus, M. Gladbach,
ist als Erfinder genannt wordenDr. Oskar Polhaus, M. Gladbach,
has been named as the inventor

Beispiel 2Example 2

5 Dutzend Paar Baumwollstrumpfrohlinge, die mit Monostearyläthylendiaminammoniumsulfat weich gemacht wurden, zeigten beim anschließenden Waschen mit anionenaktiver Seife eine unlösliche schmierige Ausfällung.5 dozen pairs of cotton stocking blanks softened with monostearylethylenediamine ammonium sulfate showed an insoluble greasy on subsequent washing with anionic soap Precipitation.

Zum \fergleich wurden weitere 5 Dutzend Paar Strumpfrohlinge derselben Partie in einem mit Natronlauge auf pH — 12 eingestellten Bad unter Zugabe von 5 g/l Pentanatriumtripolyphosphat 15 Minuten bei 100° C behandelt. Nachfolgend wurde mit 2 g/l Marseiller-Seife bei 50° C gewaschen. Das kationaktive Kondensationsprodukt war so weit abgezogen, daß keinerlei schmierige Ablagerungen entstanden. For \ fergleich further 5 dozen pair of hosiery blanks were the same batch in a sodium hydroxide solution to p H - treated 12 set bath with the addition of 5 g / l pentasodium 15 minutes at 100 ° C. This was followed by washing with 2 g / l Marseille soap at 50 ° C. The cation-active condensation product was drawn off to such an extent that no greasy deposits formed.

Claims (1)

PatentanspruchClaim Abänderung des Gegenstandes der Hauptpatentanmeldung B 22303 IVc/8k zum Entfernen von kationaktiven Präparationen von unverarbeitetem Textilgut, gekennzeichnet durch die Behandlung des Textilgutes in der Hitze.Modification of the subject matter of the main patent application B 22303 IVc / 8k to remove cation-active preparations of unprocessed textile goods, characterized by the treatment of the textile in the heat. In Betracht gezogene Druckschriften:
Deutsche Patentschriften Nr. 753 559, 746 448;
American Dyestuff Reporter, Vol. 28, 1939, S. 484Considered publications:
German Patent Nos. 753 559, 746 448;
American Dyestuff Reporter, Vol. 28, 1939, p. 484 bis 486;to 486; W al land. Die Chemie der textlien Hilfsstoffe,W al land. The chemistry of textile auxiliaries, 1948, S. XI.1948, p. XI. © 809 529/448 5. 58© 809 529/448 5. 58
DEB26383A 1952-10-04 1953-07-07 Process for removing cationic preparations from unprocessed textile material Pending DE1031269B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DEB26383A DE1031269B (en) 1952-10-04 1953-07-07 Process for removing cationic preparations from unprocessed textile material

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DEB22303A DE1023003B (en) 1952-10-04 1952-10-04 Removal of cationic preparations from unprocessed textiles on a natural or synthetic basis
DEB26383A DE1031269B (en) 1952-10-04 1953-07-07 Process for removing cationic preparations from unprocessed textile material

Publications (1)

Publication Number Publication Date
DE1031269B true DE1031269B (en) 1958-06-04

Family

ID=25964994

Family Applications (1)

Application Number Title Priority Date Filing Date
DEB26383A Pending DE1031269B (en) 1952-10-04 1953-07-07 Process for removing cationic preparations from unprocessed textile material

Country Status (1)

Country Link
DE (1) DE1031269B (en)

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE746448C (en) * 1940-07-27 1944-08-05 Albert Ag Chem Werke Method of washing
DE753559C (en) * 1934-05-03 1951-08-23 Henkel & Cie Gmbh Alkaline, caustic-free cleaning agent

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE753559C (en) * 1934-05-03 1951-08-23 Henkel & Cie Gmbh Alkaline, caustic-free cleaning agent
DE746448C (en) * 1940-07-27 1944-08-05 Albert Ag Chem Werke Method of washing

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