DE102020206648A1 - HAIR COMPOSITION INCLUDING A GLUCOSE-BASED HAIR CONDITIONER AND AN AMINO ACID OR A DERIVATIVE THEREOF - Google Patents

Abstract

The present invention provides a hair composition comprising: a) a glucose-based agent and b) an amino acid or derivative thereof.

Description

The invention relates to cosmetic compositions, in particular hair compositions, comprising a glucose-based hair conditioning agent and an amino acid or a salt, ester or acyl derivative thereof. The compositions show surprisingly effective strengthening of the internal structure of hair. The compositions can be used in the care of keratinous fibers. The invention also relates to a method of strengthening hair, comprising applying the hair composition to the hair.

It is generally known that a cosmetic treatment of human hair for reasons of fashion leads in many cases to damage to the hair structure. A treatment that can cause damage to a greater or lesser extent is, for example, permanent waving, repeated cold waving, bleaching and lightening processes and the coloring process with oxidative dyes, especially with simultaneous lightening. Damage to hair can also be caused by sun exposure and washing. All of these factors can cause damage at various levels and alter the structure of the hair, resulting in weaker hair. Such damage is expressed by a loss of the natural shine of the hair, an unattractive, dull appearance and, in the case of greater damage, by splitting the ends of the hair, breaking the hair or the appearance of small knots in the hair.

Attempts have already been made to improve the structure of hair damaged in this way by treatment with various agents, but no satisfactory solution has yet been found. It would be desirable to prevent such damage or to repair the hair day in and day out from the moment the hair grows out of the scalp so that hair split ends are delayed or avoided.

Previous attempts to provide products that help strengthen hair have not always been entirely satisfactory as their use may be limited due to formulation difficulties (e.g. stability, solubility, pH compatibility).

The provision of hair compositions which have an advantageous hair-strengthening effect is therefore a relevant goal in the field of hair cosmetics.

1. a) mindestens eine Verbindung, die eine der folgenden Formeln aufweist:
   
   
   wobei R₁ bis R₄ jeweils unabhängig Wasserstoff, ein Kohlenwasserstoffrest, der 1 bis 10 Kohlenstoffatome aufweist, eine Hydroxylgruppe, eine Aminogruppe, eine Sulfhydrylgruppe, eine Arylgruppe oder ein Halogen sind und R₅ und R₆ jeweils unabhängig Wasserstoff, eine aliphatische Kohlenwasserstoffgruppe, eine alizyklische Kohlenwasserstoffgruppe, eine Arylgruppe, eine Alkylarylgruppe oder eine heterozyklische Gruppe sind; und wobei R₁' bis R₄' jeweils unabhängig Wasserstoff, ein Kohlenwasserstoffrest, der 1 bis 10 Kohlenstoffatome aufweist, eine Hydroxylgruppe, eine Aminogruppe, eine Sulfhydrylgruppe, eine Arylgruppe oder ein Halogen sind; und R₅' und R₆' jeweils unabhängig Wasserstoff, eine aliphatische Kohlenwasserstoffgruppe, eine alizyklische Kohlenwasserstoffgruppe, eine Arylgruppe oder eine heterozyklische Gruppe sind, wobei ausgeschlossen ist, dass R₅' und R₆' gleichzeitig Wasserstoffe sind, wobei die aliphatische Kohlenwasserstoffgruppe, die alizyklische Kohlenwasserstoffgruppe, die Arylgruppe, die Alkylarylgruppe oder die heterozyklische Gruppe mit mindestens einer Hydroxylgruppe substituiert ist; und
2. b) eine Aminosäure oder ein Salz-, Ester- oder Acylderivat davon.

According to the invention, the object is achieved by a hair composition comprising:

1. a) at least one compound which has one of the following formulas:
   
   
   wherein R ₁ to R _{4 are} each independently hydrogen, a hydrocarbon radical having 1 to 10 carbon atoms, a hydroxyl group, an amino group, a sulfhydryl group, an aryl group or a halogen, and R ₅ and R _{6 are} each independently hydrogen, an aliphatic Are a hydrocarbon group, an alicyclic hydrocarbon group, an aryl group, an alkylaryl group or a heterocyclic group; and wherein R ₁ 'to R ₄ ' are each independently hydrogen, a hydrocarbon radical having 1 to 10 carbon atoms, a hydroxyl group, an amino group, a sulfhydryl group, an aryl group, or a halogen; and R ₅ 'and R ₆ ' are each independently hydrogen, an aliphatic hydrocarbon group, an alicyclic hydrocarbon group, an aryl group, or a heterocyclic group, with the exclusion of R ₅ 'and R ₆ ' being hydrogen at the same time, the aliphatic hydrocarbon group being the alicyclic hydrocarbon group, the aryl group, the alkylaryl group or the heterocyclic group is substituted with at least one hydroxyl group; and
2. b) an amino acid or a salt, ester or acyl derivative thereof.

The hair composition can take any shape; a shampoo, conditioner, or treatment is preferred.

It has been shown that the combination of component a) based on glucose and an amino acid or a derivative thereof as component b) imparts exceptionally good properties to the hair compositions. In particular, hair which has been treated with hair compositions as defined herein has a stronger internal structure, which is manifested in a higher denaturation temperature, an increased tensile strength and a reduced swelling in water. This is especially true for use on oxidatively damaged hair.

The present invention also provides a method of strengthening hair comprising applying a hair composition as defined herein to the hair.

The present invention also provides the use of a hair composition as defined herein for strengthening hair.

The invention, summarized above, is illustrated in more detail below.

Unless otherwise indicated, all amounts expressed in percent are percent by weight and are expressed based on the total weight of the hair composition.

Component (a) in the hair composition according to the invention is a glucose-based material as defined above. Such substances are for example in US 2017/0007518 disclosed.

A combination of different glucose-based materials is preferably used in the context of the present invention. Thus component a) includes at least one compound of the formula (I) and at least one compound of the formula (II). The molar ratio of formula (I) to formula (II) can be varied from 0.1: 1 to 99.9: 1, suitably 1:99 to 99: 1, more suitably 20:80 to 80:20. The molar ratio of formula (I) to formula (II) is preferably 40:60 to 60:40.

The compound of the formula (I) and / or the formulation (II) can comprise a reaction product of at least one lactone compound and at least one amino alcohol compound. Suitably the amino alcohol compound comprises one, two, three or more hydroxyl groups. Preferably the amino alcohol compound comprises only one or two hydroxyl groups.

The amino alcohol compound can be selected from the following: ethanolamine, 2-hydroxyethylhydrazine, 2-methoxyethylamine, 3-amino-1-propanol, amino-2-propanol, 3-amino-1,2-propanediol, serinol, 1,3-diamino -2-propanol, 1-amino-2-methyl-2-propanol, 2- (ethylamino) ethanol, 2-amino-1-butanol, 2-amino-2-methyl-1-propanol, 3-methylamino-1- propanol, 4-amino-1-butanol, 2- (2-aminoethoxy) ethanol, 3-methylamino-1,2-propanediol, diethanolamine, tris (hydroxymethyl) aminomethane, N- (2-hydroxyethyl) ethylenediamine, meso-1, 4-diamino-2,3-butanediol, 2-aminocyclopentanol, 2- (isopropylamino) ethanol, 2- (propylamino) ethanol, 2-amino-3-methyl-1-butanol, 5-amino-1-pentanol, 2- (3-aminopropylamino) ethanol, 1-amino-1-cyclopentanemethanol, 4-aminocyclohexanol, 2- (butylamino) ethanol, 6-amino-1-hexanol, DL-2-amino-1-hexanol, leucinol, N, N ' bis (2-hydroxyethyl) ethylenediamine, 2-aminobenzyl alcohol, 3-aminolbenzyl alcohol, 4-aminobenzyl alcohol, 2-amino-4-methoxyphenol, 3,4-dihydroxybenzylamine, dihydroxybenzylamine, 1-aminomethyl -1-cyclohexanol, 2-aminomethyl-1-cyclohexanol, N-Boc-ethanolamine, 5-amino-2,2-dimethylpentanol, 2-amino-1-phenylethanol, 2-amino-3-methylbenzyl alcohol, 2-amino-5 -methylbenzyl alcohol, 2-aminophenylethyl alcohol, 3-amino-2-methylbenzyl alcohol, 3-amino-4-methylbenzyl alcohol, 4- (1-hydroxyethyl) aniline, 4-aminophenethyl alcohol, N- (2-hydroxyethyl) aniline, 3-hydroxy-4- methoxybenzylamine, 3-hydroxytyramine, 6-hydroxydopamine, 4- (Z-amino) -1-butanol, 5- (Z-amino) -1-pentanol, 4- (Z-amino) cyclohexanol, 6- (Z-amino) -1-hexanol, 3- (Boc-Amino) -1-propanol, N-Boc-Serinol, 2-Benzylaminoethanol, 4- (Boc-Amino) -1-butanol, 2- (aminomethyl) -2- (hydroxymethyl) -1,3-propanediol and 2- (2-aminoethyl) -2- (hydroxymethyl) -1,3-propanediol.

wobei R_y und R_z jeweils unabhängig H, eine Alkylgruppe, die 1 bis 20 (vorzugsweise 1 bis 10, stärker bevorzugt 1 bis 5) Kohlenstoffatome aufweist, oder eine Alkylgruppe sind, die 1 bis 20 (vorzugsweise 1 bis 10, stärker bevorzugt 1 bis 5) Kohlenstoffatome aufweist, die mit mindestens einer Hydroxylgruppe substituiert sind; und R_x ein Alkyl oder Alkenyl, das 2 bis 16 Kohlenstoffatome aufweist, ist. Vorzugsweise ist der Aminoalkohol 3-Amino-1-propanol.The amino alcohol compound preferably has the formula (III):

where R _y and R _{z are} each independently H, an alkyl group having 1 to 20 (preferably 1 to 10, more preferably 1 to 5) carbon atoms, or an alkyl group having 1 to 20 (preferably 1 to 10, more preferably 1 to 5) has carbon atoms substituted with at least one hydroxyl group; and R _{x is} an alkyl or alkenyl having 2 to 16 carbon atoms. Preferably the amino alcohol is 3-amino-1-propanol.

wobei R''₁ bis R''₄ unabhängig H, ein C1- bis C10-Kohlenwasserstoffrest, der eine Hydroxylgruppe aufweist, eine Aminogruppe, eine Sulfhydrylgruppe, eine Arylgruppe oder ein Halogen sind.The lactone compound can be a cyclic ester of formula (IV):

where R " ₁ to R" _{4 are} independently H, a C1 to C10 hydrocarbon radical having a hydroxyl group, an amino group, a sulfhydryl group, an aryl group, or a halogen.

Preferably, R " ₁ to R" _{4 are} each independently a C1 to C5 hydrocarbon radical that is linear or branched, saturated or unsaturated, or substituted or unsubstituted.

The lactone can be selected from the following: Douglas marsh flower δ-lactone, δ-octalactone, δ-decalactone, δ-nonalactone, undecane-δ-lactone, δ-dodecalactone, Massoia lactone (or 5-pentylpent-2- en-5-olide), jasmine lactone (or Z-2-pentenylpentan-5-olide), 6-pentyl-alpha-pyrone (or 5-pentylpenta-2,4-dien-5-olide), δ-valerolactone, galactonolactone , Gluconic acid δ-lactone, hexadecanolactone and mevalonolactone. Preferably the lactone is gluconic acid δ-lactone.

Suitable processes for producing component a) are in US 2017/0007518 disclosed, the contents of which are hereby incorporated by reference.

A particularly preferred component a) for use in the context of the present invention is a mixture of hydroxypropyl gluconamide and hydroxypropylammonium gluconate. This mixture is present in the raw material Fiberhance ™ bm available from Ashland.

The total amount of component a) can range from 0.01 to 20.0% by weight, based on the total weight of the composition. The best effects have been observed when the amount of component a) is from 0.05 to 10.0% by weight based on the total weight of the composition, for example from 0.1 to 5.0% by weight, suitably from 0 , 15 to 3% by weight, was sufficient.

Component (b) in the hair composition according to the invention is an amino acid or a salt, ester or acyl derivative thereof. Component b) is suitably an amino acid. Alternatively, component b) is a salt of an amino acid. Alternatively, component b) is an ester of the amino acid. Alternatively, component b) is an acyl derivative of the amino acid.

Preferred amino acids / derivatives thereof are selected from: alanine, arginine, asparagine, aspartic acid, creatine, cysteic acid, cysteine, cystine, glutamic acid, glutamine, glycine, histidine, hydroxyproline, isoleucine, leucine, lysine, methionine, norleucine ,oline, ornithine, phenylalanine , Serine, threonine, tryptophan, Tyrosine, valine and mixtures thereof. Suitably one of the preferred amino acids is present as component b).

The amount of component b) can range from 0.001 to 10.0% by weight based on the total weight of the composition. The best effects have been observed when the amount of component b) is from 0.01 to 5.00% by weight based on the total weight of the composition, for example from 0.05 to 3.00% by weight, suitably from 0 From 0.05 to 1.00 wt%, more suitably from 0.05 to 0.8 wt%.

It has been found that the composition is particularly effective and the strengthening of the internal structure is particularly high if the hair composition comprises a mixture of hydroxypropyl gluconamide and hydroxypropylammonium gluconate as component a) and arginine, glutamic acid, glycine, histidine and lysine as component b).

The person skilled in the art is aware that cosmetic products often contain at least one surfactant selected from cationic, anionic, amphoteric, zwitterionic and / or nonionic surfactants.

• i) mindestens einem kationischen Tensid;
• ii) mindestens einem anionischen Tensid;
• iii) mindestens einem amphoteren und/oder zwitterionischen Tensid; und/oder
• iv) mindestens einem nicht ionischen Tensid.

Suitably the hair composition defined herein comprises one or more surfactants selected from the following:

• i) at least one cationic surfactant;
• ii) at least one anionic surfactant;
• iii) at least one amphoteric and / or zwitterionic surfactant; and or
• iv) at least one non-ionic surfactant.

Suitably the hair composition of the present invention is used as a hair rinse or hair treatment, in which case the hair composition preferably comprises at least one cationic surfactant and optionally at least one anionic, amphoteric, zwitterionic or nonionic surfactant.

Cationic surfactants carry a positive charge in their hydrophilic part. This positive charge causes the surfactant molecules to bind to the negatively charged skin and hair surface. In this way, they neutralize the charge, prevent the hair from flying, have a smoothing effect, increase hair shine and improve wet combability. They are primarily used in conditioners, hair conditioners, and treatments, rarely in shampoos. In addition, because of their bactericidal activity, cationic surfactants, i.e. H. their bacterial inhibitory effect, in cosmetic products a co-preserving effect.

In principle, all cationic surfactants are suitable for use on the human body as cationic surfactants in compositions according to the invention. These are by at least one water-solubilizing cationic group such as a quaternary ammonium group or by at least one water-solubilizing cationizable group such as an amine group and also at least one lipophilic alkyl group, which has about 6 to 30 carbon atoms, or by at least one imidazole group or at least one imidazylalkyl group marked.

In general, cationic surfactants are divided into groups according to their structural properties. Cationic surfactants a) from at least one of the groups alkylquats, esterquats, quaternary imidazolines, amidoamines and / or cationized amidoamines are particularly suitable for use in the hair composition defined herein.

1. i. Alkylquats,
2. ii. Esterquats,
3. iii. quartärem Imidazolin,
4. iv. Amidoaminen und/oder kationisierten Amidoaminen und
5. v. Gemischen daraus.

When present and regardless of the form of the hair composition, the cationic surfactant is at least one compound selected from the group consisting of the following:

1. i. Alkylquats,
2. ii. Esterquats,
3. iii. quaternary imidazoline,
4. iv. Amidoamines and / or cationized amidoamines and
5. v. Mixtures of it.

• - quartären Ammoniumverbindungen (Alkylquats), die mindestens einen C8- bis C24-Alkylrest aufweisen,
• - quartären Imidazolinen,
• - Esterquats,
• - Amidoaminen, die jeweils mindestens einen C8- bis C24-Acylrest aufweisen,
• - und Gemischen daraus.

The cationic surfactant component can comprise at least one compound selected from one or more of the following groups:

• - Quaternary ammonium compounds (alkyl quats) which have at least one C8 to C24 alkyl radical,
• - quaternary imidazolines,
• - Esterquats,
• - Amidoamines, each of which has at least one C8 to C24 acyl radical,
• - and mixtures thereof.

Particularly preferred quaternary ammonium compounds with at least one C8 to C24 alkyl radical are ammonium halides, specifically chlorides, and ammonium alkyl sulfates such as methosulfates or ethosulfates such as C8 to C24 alkyltrimethylammonium chlorides, C8 to C24 dialkyldimethylammonium chlorides, and C8 to C24-ammonium trialkylmethyl. B. behentrimonium chloride, cetrimonium chloride, steartrimonium chloride, distearyldimethylammonium chloride, lauryldimethylammonium chloride, lauryldimethylbenzylammonium chloride and tricetylmethylammonium chloride. The alkyl chains of the aforementioned surfactants preferably have 8 to 24 carbon atoms. The cationic surfactant component ii) preferably comprises cetrimonium chloride and / or behentrimonium chloride.

• - wobei
• - R₁₆ eine C1- bis C6-Alkylgruppe darstellt,
• - R₁₇, R₁₈ unabhängig voneinander eine C7- bis C27-Alkylgruppe, vorzugsweise eine C10- bis C22-Alkylgruppe, darstellen und
• - X- ein physiologisch verträgliches Anion ist. Geeignete derartige Verbindungen schließen Quaternium-87 (erhältlich von Evonik als Varisoft W 575 PG) ein.

If present, the quaternary imidazoline can have the following formula:

• - whereby
• - R _{16 represents} a C1 to C6 alkyl group,
• - R ₁₇ , R ₁₈ independently represent a C7 to C27 alkyl group, preferably a C10 to C22 alkyl group, and
• - X- is a physiologically acceptable anion. Suitable such compounds include Quaternium-87 (available from Evonik as Varisoft W 575 PG).

Suitable imidazolium compounds are known under the INCI names Quaternium-27, Quaternium-83, Quaternium-87 and Quaternium-91. A preferred compound is Quaternium-87.

• - wobei
• - R₁₉ und R₂₀ unabhängig voneinander eine C1- bis C6-Alkylgruppe oder eine C2- bis C6-Hydroxyalkylgruppe darstellen,
• - R₂₁, R₂₂ unabhängig voneinander eine C7- bis C27-Alkylgruppe, vorzugsweise eine C10- bis C22-Alkylgruppe, darstellen und
• - X^- ein physiologisch verträgliches Anion ist,

Esterquats are cationic surfactants which contain both at least one ester function and at least one quaternary ammonium group as a structural element and also at least one C8 to C24 alkyl radical or a C8 to C24 acyl radical. The ester quat can have the following formula:

• - whereby
• - R ₁₉ and R ₂₀ independently represent a C1 to C6 alkyl group or a C2 to C6 hydroxyalkyl group,
• - R ₂₁ , R ₂₂ independently represent a C7 to C27 alkyl group, preferably a C10 to C22 alkyl group, and
• - X ^{- is} a physiologically compatible anion,

Preferred ester quats are quaternized ester salts of fatty acids with triethanolamine, quaternized ester salts of fatty acids with diethanolalkylamines and quaternized ester salts of fatty acids with 1,2-dihydroxypropyldialkylamines. Such products are sold under the trademarks Stepantex®, Dehyquart® and Armocare®. N, N-bis (2-palmitoyloxyethyl) dimethylammonium chloride, distearoylethyldimonium methosulfate and distearoylethylhydroxyethylmonium methosulfate are preferred examples of such esterquats, especially distearoylethylhydroxyethylmonium methosulfate. Another preferred ester quat is behenoyl-PG-trimonium chloride.

Alkylamidoamines are usually produced by amidation of natural or synthetic C _{8 to} C ₂₄ fatty acids with di (C ₁ to C ₃ ) alkylaminoamines.

• - R₂₃, R₂₄ unabhängig voneinander eine C₁- bis C₆-Alkylgruppe, eine C₂- bis C₆-Alkenylgruppe oder eine C₂- bis C₆-Hydroxyalkylgruppe darstellen, und
• - R₂₅ eine C₈- bis C₂₈-Alkylgruppe, vorzugsweise eine C₁₀- bis C₂₂-Alkylgruppe, darstellt.

Suitable amines can have the following formula: NR ₂₃ R ₂₄ R ₂₅ whereby

• - R ₂₃ , R ₂₄ independently represent a C ₁ to C ₆ alkyl group, a C ₂ to C ₆ alkenyl group or a C ₂ to C ₆ hydroxyalkyl group, and
• - R _{25 represents} a C ₈ to C ₂₈ alkyl group, preferably a C ₁₀ to C ₂₂ alkyl group.

The cationic surfactants of the formula NR ₂₃ R ₂₄ R ₂₅ are amine derivatives, so-called pseudoquats. The organic radicals R ₂₃ , R ₂₄ and R ₂₅ are bonded directly to the nitrogen atom. In the acidic pH range, these are cationized, ie the nitrogen atom is then protonated. The physiologically compatible counterions are suitable as counterions. Stearamidopropyldimethylamine, behenamidopropyldimethylamine and brassicamidopropyldimethylamine are particularly preferred as these cationic surfactants.

The cationic component can comprise or consist of a mixture of one or more alkylquats and one or more amidoamines.

Suitably the hair composition of the present invention is used as a hair shampoo, so that the hair composition preferably comprises at least one anionic surfactant and optionally at least one cationic, amphoteric, zwitterionic or nonionic surfactant. Such a shampoo suitably comprises at least one anionic surfactant, at least one non-ionic surfactant and optionally at least one amphoteric, zwitterionic or cationic surfactant.

Regardless of the formation of the hair composition defined herein, examples of the anionic, amphoteric, zwitterionic and nonionic surfactants are as follows.

Anionic surface-active substances which are suitable for use on the human body are suitable as anionic surfactants in the compositions according to the invention. These are characterized by a water-solubilizing, anionic group such as a carboxylate, sulfate, sulfonate or phosphate group and a lipophilic alkyl group which has 8 to 30 carbon atoms. In addition, glycol or polyglycol ether groups, ester, ether and amide groups and also hydroxyl groups can be contained in the molecule. Examples of suitable anionic surfactants are linear and branched fatty acids which have 8 to 30 carbon atoms (soaps), alkyl ether carboxylic acids, acyl sarcosides, acyl taurides, acyl isethionates, sulfosuccinic acid monoesters and dialkyl esters and sulfosuccinic acid monoalkyl polyoxyethyl esters, and olefin sulfonates, alkylsulfonates, alkylsulfonates, linear alkanesulfates, alkylsulfonates, linear alkane sulfates, alkylsulfonates, and olefin sulfonates, alkylsulfonates also alkyl and / or alkenyl phosphates. Preferred anionic surfactants are alkyl sulfates, alkyl ether sulfates and alkyl ether carboxylic acids, each having 10 to 18 carbon atoms, preferably 12 to 14 carbon atoms, in the alkyl group and up to 12 glycol ether groups, preferably 2 to 6 glycol ether groups, in the molecule. The positively charged counterion can be selected from any cosmetically suitable counterion, as is sufficient for the person skilled in the art is known. Suitable counterions are alkali metals (preferably sodium or potassium) and ammonium. Examples of such surfactants are the compounds with the INCI names sodium laureth sulfate, ammonium lauryl sulfate, sodium lauryl sulfate, sodium myreth sulfate or sodium laureth carboxylate. Preferred anionic surfactants are sodium laureth sulfate, ammonium lauryl sulfate or a mixture thereof.

Surface-active compounds which have at least one quaternary ammonium group and at least one carboxylate, sulfonate or sulfate group in the molecule are referred to as zwitterionic surfactants. Particularly suitable zwitterionic surfactants are known as betaines, such as the N-alkyl-N, N-dimethylammonium glycinates, for example cocoalkyldimethylammonium glycinate, N-acylaminopropyl-N, N-dimethylammonium glycinates, for example cocoacylaminopropyldimethylammonium, 3-hydroxyymethyl-3-hydroxy-methyl-3-carcinate, and 2-boxethyl-3-alkyl each having 8 to 18 carbon atoms in the alkyl or acyl group, and also cocoacylaminoethylhydroxyethylcarboxymethylglycinate. A preferred zwitterionic surfactant is the fatty acid amide derivative known under the INCI name cocoamidopropyl betaine.

Amphoteric surfactants are known as surface-active compounds which, in addition to a C _{8 to} C ₂₄ alkyl or acyl group, contain at least one free amino group and at least one -COOH or -SO ₃ H group in the molecule and for forming internal salts in are able to. Examples of suitable amphoteric surfactants are N-alkylglycines, N-alkylpropionic acids, N-alkylaminobutyric acids, N-alkyliminodipropionic acids, N-hydroxyethyl-N-alkylamidopropylglycines, N-alkyltaurines, N-alkylsarcosines, 2-alkylaminopropionic acids and alkylaminoacetic acids, each from 8 to 24 C. -Atoms in the alkyl group. Particularly preferred amphoteric surfactants are N- to cocoalkylaminopropionate, cocoacylaminoethylaminopropionate and C ₁₂ to C ₁₈ acyl sarcosine.

• • Anlagerungsprodukte von etwa 4 bis etwa 30 Mol Ethylenoxid und/oder von etwa 0 bis etwa 5 Mol Propylenoxid mit linearen Fettalkoholen, die etwa 8 bis etwa 22 C-Atome enthalten, oder Fettsäuren, die etwa 12 bis etwa 22 C-Atome enthalten, oder Alkylphenolen, die etwa 8 bis etwa 15 C-Atome in der Alkylgruppe enthalten,
• • Anlagerungsprodukte von Ethylenoxid und Polyglycerin mit Methylglukosidfettsäureestern, Fettsäurealkanolamiden und Fettsäureglukamiden,
• • C8- bis C30-Fettsäuremono- und -diester von Anlagerungsprodukten von etwa 1 bis etwa 30 Mol Ethylenoxid oder Glycerin, beispielsweise jene mit den INCI-Bezeichnungen PEG(1-10)-Glycerylcocoat, insbesondere PEG-7-Glycerylcocoat.
• • Aminoxide, beispielsweise mindestens eine Verbindung mit der allgemeinen Formel (I) oder (II):
  
  • ◯ wobei R jeweils einen linearen oder verzweigten, gesättigten oder einfach oder mehrfach ungesättigten Alkyl- oder Alkenylrest darstellt, der etwa 6 bis etwa 24 Kohlenstoffatome enthält, beispielsweise etwa 8 bis etwa 18 Kohlenstoffatome.
  • ◯ Geeignete Tenside sind jene mit den vorgenannten Formeln (I) oder (II) mit den INCI-Bezeichnungen Cocaminoxid, Lauraminoxid und/oder Cocamidopropylaminoxid, die bei einer Reihe verschiedener Anbieter im Handel erhältlich sind.
• • Sorbitanfettsäureester und Anlagerungsprodukte von Ethylenoxid mit Sorbitanfettsäureestern wie Polysorbaten,
• • Fettsäurealkanolamide mit der folgenden allgemeinen Formel:
  
  • ◯ wobei R geeigneterweise einen linearen oder verzweigten, gesättigten oder ungesättigten Alkyl- oder Alkenylrest darstellt, der etwa 8 bis etwa 24 Kohlenstoffatome enthält, und die Reste R' Wasserstoff oder die Gruppe —(CH₂)_nOH darstellen, wobei n die Zahlen von etwa 2 oder etwa 3 darstellt, mit der Maßgabe, dass mindestens einer der Reste R' den vorstehend genannten Rest —(CH₂)_nOH darstellt,
  • ◯ insbesondere jene Verbindungen, die unter den INCI-Bezeichnungen Cocamid-MEA und/oder Cocamid-MIPA bekannt sind;
• • C8- bis C30-Fettsäuremono- und -diester von Anlagerungsprodukten von etwa 1 bis etwa 30 Mol Ethylenoxid mit Glycerin, insbesondere die unter der INCI-Bezeichnung PEG-7-Glycerylcocoat bekannte Verbindung; und/oder Anlagerungsprodukte von etwa 4 bis etwa 30 Mol Ethylenoxid und/oder von etwa 0 bis etwa 5 Mol Propylenoxid mit linearen Fettalkoholen, die etwa 8 bis etwa 22 C-Atome enthalten.
• • Fettsäureester von Zuckern und Anlagerungsprodukte von Ethylenoxid mit Fettsäureestern von Zucker,
• • Anlagerungsprodukte von Ethylenoxid mit Fettsäurealkanolamiden und Fettaminen,
• • Alkyl(oligo)glukoside, beispielsweise Verbindungen mit der allgemeinen Formel RO-[G]x, wobei [G] vorzugsweise von Aldosen und/oder Ketosen, die etwa 5 bis etwa 6 Kohlenstoffatome enthalten, vorzugsweise von Glukose, abgeleitet ist.
  • ◯ Der Index x stellt den Oligomerisierungsgrad (degree of oligomerization - DO), d. h. die Verteilung der Mono- und Oligoglykoside, dar. Der Index x weist vorzugsweise einen Wert im Bereich von etwa 1 bis etwa 10, beispielsweise im Bereich von etwa 1 bis etwa 3, auf, wobei es diesbezüglich keine ganze Zahl sein muss, sondern eine Bruchzahl sein kann, die analytisch bestimmt werden kann.
  • ◯ Geeignete Alkyl(oligo)glykoside weisen einen Oligomerisierungsgrad zwischen von etwa 1,2 und etwa 1,5 auf.
  • ◯ Der Rest R stellt geeigneterweise mindestens einen Alkyl- und/oder Alkenylrest dar, der von etwa 4 bis etwa 24 C-Atome enthält.
  • ◯ Beispiele für Alkyl(oligo)glukoside sind unter den INCI-Bezeichnungen Caprylyl/Caprylglukosid, Decylglukosid, Laurylglukosid und Cocoglukosid bekannt,
• • Gemische aus Alkyl(oligo)glukosiden und Fettalkoholen,
• • Anlagerungsprodukte von etwa 5 bis etwa 60 Mol Ethylenoxid mit Rizinusöl oder hydriertem Rizinusöl, beispielsweise hydriertem PEG-40-Rizinusöl,
• • Teilester von Polyolen, die etwa 3 bis etwa 6 Kohlenstoffatome enthalten, mit gesättigten Fettsäuren, die etwa 8 bis etwa 22 C-Atome enthalten,
• • Sterine. Unter „Sterinen“ ist eine Gruppe von Steroiden zu verstehen, die eine Hydroxygruppe an C3 der Steroidhauptkette tragen und sowohl aus tierischem Gewebe (Zoosterine) als auch aus pflanzlichen Fetten (Phytosterine) isoliert sind. Beispiele für Zoosterine sind Cholesterin und Lanosterin. Beispiele für geeignete Phytosterine sind Ergosterin, Stigmasterin und Sitosterin. Sterine sind auch aus Pilzen und Hefen isoliert; sie sind als Mykosterine bekannt.
• • Phospholipide. Damit sind in erster Linie Glukosephospolipide gemeint, die beispielsweise als Lecithine oder Phosphatidylcholine aus Eigelb oder aus Pflanzensamen (beispielsweise Sojabohnen) erhalten werden.
• • hydriertes Rizinusöl.

Nonionic surfactants can have a hydrophilic end that can be charge neutral, such as an ethoxylate, glycoside, or polyol; such surfactants may not be sensitive to water hardness. Suitable nonionic surfactants as contemplated herein include the following:

• Addition products of about 4 to about 30 mol of ethylene oxide and / or of about 0 to about 5 mol of propylene oxide with linear fatty alcohols containing about 8 to about 22 carbon atoms or fatty acids containing about 12 to about 22 carbon atoms, or alkylphenols which contain about 8 to about 15 carbon atoms in the alkyl group,
• • Addition products of ethylene oxide and polyglycerine with methyl glucoside fatty acid esters, fatty acid alkanolamides and fatty acid glucamides,
• • C8 to C30 fatty acid mono- and diesters of addition products of about 1 to about 30 moles of ethylene oxide or glycerol, for example those with the INCI names PEG (1-10) glyceryl cocoate, in particular PEG-7 glyceryl cocoate.
• • Amine oxides, for example at least one compound with the general formula (I) or (II):
  
  • ◯ where R is in each case a linear or branched, saturated or mono- or polyunsaturated alkyl or alkenyl radical which contains about 6 to about 24 carbon atoms, for example about 8 to about 18 carbon atoms.
  • ◯ Suitable surfactants are those with the aforementioned formulas (I) or (II) with the INCI names cocamine oxide, lauramine oxide and / or cocamidopropylamine oxide, which are commercially available from a number of different suppliers.
• • Sorbitan fatty acid esters and addition products of ethylene oxide with sorbitan fatty acid esters such as polysorbates,
• • Fatty acid alkanolamides with the following general formula:
  
  • ◯ where R suitably represents a linear or branched, saturated or unsaturated alkyl or alkenyl radical containing from about 8 to about 24 carbon atoms, and the radicals R 'represent hydrogen or the group - (CH ₂ ) _n OH, where n are the numbers of represents about 2 or about 3, with the proviso that at least one of the radicals R 'represents the aforementioned radical - (CH ₂ ) _n OH,
  • ◯ in particular those compounds which are known under the INCI names Cocamid-MEA and / or Cocamid-MIPA;
• • C8 to C30 fatty acid mono- and diesters of addition products of about 1 to about 30 mol of ethylene oxide with glycerol, in particular the compound known under the INCI name PEG-7 glyceryl cocoate; and / or addition products of about 4 to about 30 mol of ethylene oxide and / or of about 0 to about 5 mol of propylene oxide with linear fatty alcohols containing about 8 to about 22 carbon atoms.
• • fatty acid esters of sugars and addition products of ethylene oxide with fatty acid esters of sugar,
• • Addition products of ethylene oxide with fatty acid alkanolamides and fatty amines,
• • Alkyl (oligo) glucosides, for example compounds with the general formula RO- [G] x, where [G] is preferably derived from aldoses and / or ketoses containing about 5 to about 6 carbon atoms, preferably from glucose.
  • The index x represents the degree of oligomerization (DO), ie the distribution of the mono- and oligoglycosides. The index x preferably has a value in the range from about 1 to about 10, for example in the range from about 1 to about 3, whereby in this regard it does not have to be an integer, but can be a fraction that can be determined analytically.
  • ◯ Suitable alkyl (oligo) glycosides have a degree of oligomerization between about 1.2 and about 1.5.
  • ◯ The radical R suitably represents at least one alkyl and / or alkenyl radical which contains from about 4 to about 24 carbon atoms.
  • ◯ Examples of alkyl (oligo) glucosides are known under the INCI names Caprylyl / Caprylglucoside, Decylglucoside, Laurylglucoside and Cocoglucoside,
• • Mixtures of alkyl (oligo) glucosides and fatty alcohols,
• • Addition products of about 5 to about 60 mol of ethylene oxide with castor oil or hydrogenated castor oil, for example hydrogenated PEG-40 castor oil,
• • Partial esters of polyols that contain about 3 to about 6 carbon atoms with saturated fatty acids that contain about 8 to about 22 carbon atoms,
• • sterols. “Sterols” is a group of steroids that have a hydroxyl group on C3 of the steroid main chain and are isolated from both animal tissue (zoosterols) and vegetable fats (phytosterols). Examples of zoosterols are cholesterol and lanosterol. Examples of suitable phytosterols are ergosterol, stigmasterol and sitosterol. Sterols are also isolated from fungi and yeast; they are known as mycosterols.
• • phospholipids. This primarily means glucose phospholipids which are obtained, for example, as lecithins or phosphatidylcholines from egg yolk or from plant seeds (for example soybeans).
• • hydrogenated castor oil.

Preferred fatty alcohol ethoxylates are those in which the fatty alcohol content of the fatty alcohol ethoxylate has an alkyl chain length of C4 to C30, preferably C6 to C25, preferably C8 to C20, and / or in which the number of ethoxy groups in the fatty alcohol ethoxylate is 2 to 120, preferably 4 to 100, more preferably 6 to 80, more preferably 8 to 60, most preferably 10 to 40.

Preferably the or each fatty alcohol ethoxylate is selected from ethoxylates of beheneth, ceteareth, ceteth, pareth and deceth, preferably from ceteareth, more preferably ceteareth-20. The fatty alcohol propoxylate is preferably PPG-3 caprylyl ether.

Another suitable alkoxylate is one that is an alkoxylate of a non-fatty alcohol. For example, PPG-3 benzyl ether myristate is an alkoxylated derivative of benzyl alcohol and is useful as a nonionic surfactant.

A mixture of the following surfactants in a shampoo composition is particularly advantageous: sodium laureth sulfate; Cocoamidopropyl betaine; Ammonium lauryl sulfate; Cocamide MEA; and PEG-7 glyceryl cocoate.

A mixture of the following surfactants in a rinse composition is particularly advantageous: quaternium-87, behenoyl-PG-trimonium chloride, distearoylethylhydroxyethylmonium methosulfate and behentrimonium chloride.

As will be well known to those skilled in the art, it is common to include one or more fatty compounds in cosmetic compositions. With fatty compounds are meant fatty acids, fatty alcohols, natural and synthetic waxes, which can be present in solid form as well as liquids in aqueous dispersion, and natural and synthetic cosmetic oil components.

The hair compositions disclosed herein can comprise, as an optional ingredient, at least one saturated or unsaturated, branched or unbranched C8 to C30 alcohol.

Examples of suitable fatty alcohols include C12-13 alcohols, C12-15 alcohols, C12-16 alcohols, C14-22 alcohols, C16-17 isoalcohols, C20-22 alcohols, arachidyl alcohol, cetyl alcohol, cetearyl alcohol, myristyl alcohol, behenyl alcohol Hexyldecycloctadecanol, tetradecyleicosanol, coconut alcohol, isocetyl alcohol, isostearyl alcohol, stearyl alcohol and lauryl alcohol. The fatty alcohol can preferably be selected from the group consisting of arachidyl alcohol, cetyl alcohol, cetearyl alcohol, myristyl alcohol, behenyl alcohol, hexyldecycloctadecanol, tetradecylicosanol, coconut alcohol, isocetyl alcohol, isostearyl alcohol, stearyl alcohol and lauryl alcohol. More preferably, the fatty alcohol can be cetyl alcohol, stearyl alcohol, or mixtures thereof.

The hair compositions disclosed herein can also contain, as an optional component, saturated or unsaturated, branched or unbranched C8 to C30 carboxylic acids and / or their salts, preferably C10 to C22 carboxylic acids and / or their salts and in particular coconut acids, lauric acid, myristic acid, palmitic acid, Stearic acid, behenic acid, oleic acid and mixtures thereof and / or the salts of these acids. Stearic acid and palmitic acid and / or the salts of these acids, in particular stearic acid and palmitic acid, are particularly suitable.

• • mindestens einen Mono-, Di- oder Triester von Glycerin und eine Fettsäure, die 8 bis 30 Kohlenstoffatome aufweist, und/oder
• • mindestens einen Mono- oder Diester von Ethylenglykol und eine Fettsäure, die 8 bis 30 Kohlenstoffatome aufweist.

The hair compositions disclosed herein can include, as optional ingredients:

• • at least one mono-, di- or triester of glycerol and a fatty acid which has 8 to 30 carbon atoms, and / or
• • at least one mono- or diester of ethylene glycol and one fatty acid that has 8 to 30 carbon atoms.

The C8 to C30 component of the fatty acid can be saturated or unsaturated, branched or unbranched. Suitable examples include glyceryl stearate and glycol distearate.

The total amount of fatty compounds disclosed in the compositions disclosed herein ranges from 0.1 to 20% by weight, preferably from 1 to 15% by weight, particularly preferably from 2 to 10% by weight; in each case based on the weight of the composition.

As an alternative or in addition to the fatty compounds described above, the hair composition of the present invention can also comprise at least one fat or oil which has a melting point of 20 ° C. or higher. In the context of a solid fat or oil, “solid” means that the compound has a melting point of 20 ° C or higher. Suitably the or each fat or oil has a melting point of 25 ° C or higher, or 30 ° C or higher. Component (a) is preferred a naturally occurring solid fat or oil, or a mixture thereof. These are nourishing substances that help keep the skin and hair structure healthy. Naturally occurring raw materials have the advantage that they grow back and can therefore be used sustainably. This aspect is also becoming increasingly important for many users.

Solid fats and oils include fatty acids (triglycerides); both naturally derived products and hydrogenated derivatives thereof. Also included are fatty acids esterified with glycerine, which give mono-, di- and triglycerides.

Preferred solid fats and oils include a solid vegetable oil and / or solid vegetable butter. As already mentioned, naturally occurring raw materials have the advantage that they grow back and can therefore be used sustainably. This aspect is also becoming increasingly important for many users. In addition, some vegetable oils or butters, especially if carefully preserved at low temperatures, are extremely effective skin and hair care products because they also contain a variety of certain secondary ingredients such as vitamins. Plant butters with a melting point in the range of 20 ° C to 35 ° C such as shea butter (INCI name: Butyrospermum parkii butter (shea butter)), mango butter (Mangifera indica seed butter (mango seed butter)), Murumuru are particularly preferred. Butter (INCI name: Astrocaryum murumuru seed butter), cocoa butter (INCI name: Theobroma cacao seed butter (cocoa seed butter)) and / or Cupuacu butter (INCI name: Theobroma grandiflorum seed butter ), Cocos nucifera oil (coconut oil), Elaeis guineensis seed oil (palm kernel oil), Japan wax, synthetic Japan wax, castor communis seed oil (castor seed oil), Simmondsia chinensis butter (jojoba butter) and mixtures thereof. Shea butter (INCI name: Butyrospermum parkii butter (shea butter)) is particularly preferred.

• • quaternisierte Cellulosepolymere, namentlich Polyquaternium-10, wie sie im Handel unter den Bezeichnungen Celquat® und Polymer JR® erhältlich sind,
• • hydrophob modifizierte Cellulosederivate, beispielsweise die unter der Handelsbezeichnung SoftCat® vertriebenen kationischen Polymere,
• • kationische Alkylpolyglykoside,
• • kationisierter Honig, das Handelsprodukt Honeyquat® 50,
• • kationische Guarderivate, die von dem Hydroxypropylguarhydroxypropyltrimoniumchlorid-Bestandteil a), der in der erfindungsgemäßen Zusammensetzung verwendet wird, verschieden ist, wie die unter den Handelsbezeichnungen Cosmedia®Guar, N-Hance® und Jaguar® vertriebenen Produkte,
• • polymere Dimethyldiallylammoniumsalze und deren Copolymere mit Estern und Amiden von Acrylsäure und Methacrylsäure, insbesondere Polyquaternium-6 und Polyquaternium-7,
• • die unter den Bezeichnungen Merquat®100 (Poly(dimethyldiallylammoniumchlorid)) und Merquat®550 (Dimethyldiallylammoniumchlorid-Acrylamid-Copolymere) im Handel erhältlichen Produkte sind Beispiele für derartige kationischen Polymere,
• • Copolymere von Vinylpyrrolidon mit quaternisierten Derivaten von Dialkylaminoalkylacrylat und -methacrylat wie mit Diethylsulfat quaternisierte Vinylpyrrolidon-DimethylaminoethylMethacrylat-Copolymere. Derartige Verbindungen sind im Handel unter den Bezeichnungen Gafquat®734 und Gafquat®755 erhältlich.
• • Vinylpyrrolidon-Vinylimidazolium-Methochlorid-Copolymere, wie sie unter den Bezeichnungen Luviquat® FC 370, FC 550, FC 905 und HM 552 angeboten werden,
• • quaternisierter Polyvinylalkohol
• • und die als Polyquaternium 2, Polyquaternium 16, Polyquaternium 17, Polyquaternium 18, Polyquaternium-24, Polyquaternium 27, Polyquaternium-32, Polyquaternium-37, Polyquaternium 74 und Polyquaternium 89 bekannten Polymere.

The hair compositions disclosed herein can further comprise one or more cationic polymers. Such cationic polymers have conditioning properties, ie they give the skin or hair a pleasant feeling and thus offer added value. The following polymers are particularly suitable:

• • quaternized cellulose polymers, namely Polyquaternium-10, as they are commercially available under the names Celquat® and Polymer JR®,
• • hydrophobically modified cellulose derivatives, for example the cationic polymers sold under the trade name SoftCat®,
• • cationic alkyl polyglycosides,
• • cationized honey, the commercial product Honeyquat® 50,
• • Cationic guar derivatives which are different from the hydroxypropylguarhydroxypropyltrimonium chloride component a) used in the composition according to the invention, such as the products sold under the trade names Cosmedia®Guar, N-Hance® and Jaguar®,
• • polymeric dimethyldiallylammonium salts and their copolymers with esters and amides of acrylic acid and methacrylic acid, in particular Polyquaternium-6 and Polyquaternium-7,
• • the products available commercially under the names Merquat®100 (poly (dimethyldiallylammonium chloride)) and Merquat®550 (dimethyldiallylammonium chloride-acrylamide copolymers) are examples of such cationic polymers,
• • Copolymers of vinyl pyrrolidone with quaternized derivatives of dialkylaminoalkyl acrylate and methacrylate such as vinylpyrrolidone-dimethylaminoethyl methacrylate copolymers quaternized with diethyl sulfate. Such compounds are commercially available under the names Gafquat®734 and Gafquat®755.
• • Vinylpyrrolidone-vinylimidazolium-methochloride copolymers, as offered under the names Luviquat® FC 370, FC 550, FC 905 and HM 552,
• • quaternized polyvinyl alcohol
• • and the polymers known as Polyquaternium 2, Polyquaternium 16, Polyquaternium 17, Polyquaternium 18, Polyquaternium-24, Polyquaternium 27, Polyquaternium-32, Polyquaternium-37, Polyquaternium 74, and Polyquaternium 89.

Particularly preferred cationic polymers are quaternized cellulose polymers, hydrophobically modified quaternized cellulose polymers, cationic guar derivatives and / or cationic polymers Acrylic acid (derivative) base, which are particularly preferably selected from the polymers known under the INCI names Guarhydroxypropyltrimoniumchlorid, Polyquaternium-6, Polyquaternium-7, Polyquaternium-10, Polyquaternium-37 and / or Polyquaternium-67.

Preferred cationic polysaccharide polymers include guar hydroxypropyl trimonium chloride and doubly modified guars such as hydroxypropyl guar hydroxypropyl trimonium chloride.

Other cationic polymers obtained from natural sources (in addition to the guars mentioned above), such as a cationic inulin polymer, are also suitable. Inulin is a polysaccharide that belongs to the group of fructans. In addition to a terminal glucose component, it includes up to 60 fructose monomers in the chain, each of which is linked to one another via β-2,1-glycosidic bonds. Inulin can be obtained from the leaves, roots, fruits and / or flowers of sunflower and / or umbelliferous plants such as Jerusalem artichokes, artichokes and / or parsnips. Particularly suitable cationic inulin polymers according to the invention are cationically modified by reacting hydroxyl groups of the fructose building blocks with reactive quaternary ammonium compounds. Suitable quaternary ammonium compounds are preferably compounds of the following formula N ⁺ (R ₁ R ₂ R ₃ R ₄ ) X ^- where R ₁ , R ₂ and R _{3 are} methyl or ethyl groups and R _{4 is} an epoxy Rs or a halohydrin group Y-CH ₂ -CH (OH) -R ₅ -, R _{5 is} a C1- to C3-alkylene group, Y is a halide and X is an anion such as Cl ^- , Br ^- , I ^- or HSO ₄ -. Particularly suitable cationic inulin polymers (b) for the purposes of this invention correspond to the formula RO-CH ₂ -CH (OH) -R ₅ -N ⁺ (R ₁ R ₂ R ₃ ) X ^- , where R is inulin and the other radicals have the same meaning as above.

Suitable cationic inulin polymers are those which have been cationically modified with cationic hydroxy-C1-C3-alkyltrialkylammonium groups, in particular with hydroxypropyltrimethylammonium groups. Within this structure, preference is given to cationic inulin polymers, which are known under the INCI name hydroxypropyltrimonium inulin and are commercially available.

The degree of cationic substitution of cationic inulin polymers, in particular of cationic inulins known as hydroxypropyltrimonium inulin (INCI), can be varied and adjusted as required. For use in the cosmetic compositions invented, it has proven to be particularly preferred if such cationically modified inulin polymers show a higher degree of cationic modification (a higher degree of cationic substitution) because this results in better coacervate formation and ultimately better care performance to be achieved with the preparations enables.

Suitable cationic inulin polymers have a cationic charge density of> 1.5 meq / g, more preferably> 2.0 meq / g, namely preferably> 2.5 meq / g, very preferably> 3.0 meq / g and especially> 3 , 5 meq / g. Within this structure, it is particularly preferred if cationic inulin polymers, which are known under the INCI name hydroxypropyltrimonium inulin, b) a cationic charge density of> 1.5 meq / g, more preferably> 2.0 meq / g, namely preferably> 2 .5 meq / g, namely preferably> 3.0 meq / g and especially> 3.5 meq / g. Suitable cationic inulin polymers can also have an average molecular weight of 2,000 to 50,000 g / mol, more preferably 2,500 to 40,000 g / mol, more preferably 3,000 to 30,000 g / mol, more preferably 3,500 to 20,000 g / mol and in particular 4,000 to 10,000 g / mol , exhibit. Within this structure, it is particularly preferred if cationic inulin polymers, known under the INCI name hydroxypropyltrimonium inulin, have an average molecular weight of 2,000 to 50,000 g / mol, more preferably 2,500 to 40,000 g / mol, more preferably 3,000 to 30,000 g / mol , more preferably 3,500 to 20,000 g / mol and especially 4,000 to 10,000 g / mol.

Another cationic polymer selected from cationic polymers of natural origin, preferably cationic polygalactomannan derivatives. Galactomannans are polysaccharides that consist of combinations of mannose and galactose monomers in various levels. The mannose units are linked to one another via β (1-4) -glycosidic bonds; the galactos units via α (1-6) bonds. The ratio of mannose to galactose monomers varies according to the type and origin of the plant and the temperature at which it was grown. For Greek fenugreek gum this is Mannose-galactose ratio about 1: 1 (corresponding to a monomer mannose to a monomer galactose); for guar gum about 2: 1; with tare rubber about 3: 1; for locust bean gum about 4: 1 and for cassia gum about 5: 1. All galactomannans from these sources are suitable for cationic modification and use as polymers in the cosmetic compositions of the invention. Guar gum and / or cassia gum are particularly suitable for use in cosmetic products according to the invention.

Like cationic inulin polymers, galactomannans, preferably galactomannans from the sources listed above, can be cationically modified by reacting the hydroxyl groups of galactomannan polymers with reactive quaternary ammonium compounds. Suitable quaternary ammonium compounds are preferably compounds of the following formula N ⁺ (R ₁ R ₂ R ₃ R ₄ ) X ^- where R ₁ , R ₂ and R _{3 are} methyl or ethyl groups and R _{4 is} an epoxy Rs or a halohydrin group Y-CH ₂ -CH (OH) -R ₅ -, R _{5 is} a C1- to C3-alkylene group, Y is a halide and X is an anion such as Cl ^- , Br ^- , I ^- or HSO ₄ -. Particularly suitable cationic galactomannan polymers for the purposes of this invention correspond to the formula RO-CH ₂ -CH (OH) -R ₅ -N ⁺ (R ₁ R ₂ R ₃ ) X ^- , where R represents the respective galactomannan and the other radicals have the same meaning as defined above.

Guar and cassia polymers, which are known under the INCI names guar hydroxypropyltrimonium chloride, hydroxypropylguarhydroxypropyltrimonium chloride (which are different from that used as component (a) in the hair composition disclosed herein) and / or cassia hydroxypropyltrimonium chloride, are available from various suppliers, for example at the names Jaguar®, N-Hance®, Polycare®, Clearhance®, Activsoft®, Guarquat®, Vida-Care®. Jaguar® C-162, Jaguar® C500, Jaguar® Styl 100, N-Hance® 3196, N-Hance® HPCG 1000, Activsoft® C17, Guarquat® C130 KC, Guarquat® CP500 KC, Vida-Care® GHTC and / or Polycare® Split Therapy are specific examples of cationic polymers of natural origin that are particularly suitable according to the invention.

Cationic polymers suitable according to the invention are preferably used in the cosmetic compositions according to the invention in amounts of 0.01 to 3.00% by weight, more preferably 0.02 to 2.00% by weight, more preferably 0.03 to 1.00% by weight %, more preferably 0.04 to 0.70% by weight (based on their total weight) is used.

As is well known to those skilled in the art, hair compositions, particularly shampoos, conditioners and treatments, are often formulated as oil-in-water emulsions. The hair compositions of the present invention can therefore be in the form of oil-in-water emulsions. The water content of such emulsions can be at least 60% by weight based on the total weight of the composition, suitably at least 70% by weight. A suitable range for the water content is from 60 to 95% by weight, for example 70 to 90% by weight.

Suitable processes for producing the compositions of the present invention, for example in the form of oil-in-water emulsions, are well known to those skilled in the art.

In addition to the ingredients described above, the hair compositions according to the invention can contain at least one active ingredient, which is advantageously selected from the group consisting of plant extracts, liquid oils, bitter substances, humectants, protein hydrolyzates, perfumes, UV filters, structuring agents such as maleic acid, dyes for coloring the Composition, active ingredients such as bisabolol and / or allantoin, antioxidants, preservatives such as sodium benzoate or salicylic acid, additional viscosity regulators such as salts (NaCl) or polymers and pH regulators.

Suitable plant extracts are extracts that can be produced from all parts of a plant. Usually these extracts are made by extracting the whole plant. In some cases, however, it may also be preferable to make the extracts exclusively from the flowers and / or leaves of the plant. The most suitable extracts are Paeonia lactiflora, a flower from Rosa damascena, fruit from Malus domestica, peel powder from Argania spinosa, Laminaria saccharina, cannabis sativa, green tea, oak bark, nettle, witch hazel, hops, chamomile, burdock root, horsetail, hawthorn, linden tree, lychee, almond, aloe vera, spruce needle, horse chestnut, sandalwood, juniper, coconut, mango, apricot, lime, wheat, kiwi Melon, orange, grapefruit, sage, rosemary, birch, mallow, cuckoo herb, quendel, yarrow, thyme, lemon balm, hemlock, coltsfoot, marshmallow, ginseng, ginger root, echinacea purpurea, olea europea, roots of Boerhavia diffusa vulgarulum, foeniculum, foeniculum . The extracts from Paeonia lactiflora, a flower from Rosa damascena, fruit from Malus domestica, peel powder from Argania spinosa, Laminaria saccharina, Cannabis sativa, green tea, nettle, witch hazel, chamomile, aloevera, ginseng, Echinacea purpurea, Olea europea and / or roots from Boerhavia diffusa are particularly preferred for use in the compositions of the invention. Water, alcohols and mixtures thereof can be used as extraction agents for the production of the plant extracts mentioned. Among the alcohols, lower alcohols such as ethanol and isopropanol, but especially polyhydric alcohols such as ethylene glycol and propylene glycol, are preferred both as the sole extractant and mixed with water. Plant extracts based on water / propylene glycol in a ratio of 1:10 to 10: 1 have proven to be particularly suitable. The plant extracts can be used both in pure and in diluted form. When used in diluted form, they usually contain about 2 to 80% by weight of active ingredient and, as a solvent, the extractant or the mixture of extractants used in their extraction. The plant extracts can preferably be used in the hair compositions according to the invention in an amount of from 0.01 to 10% by weight, more preferably from 0.05 to 7.5% by weight and in particular from 0.1 to 5% by weight (based on on the total weight of the products).

Protein hydrolysates are product mixtures that are obtained by acid-catalyzed, base-catalyzed or enzymatically-catalyzed degradation of proteins. According to the invention, the term “protein hydrolyzate” is understood to mean that it also denotes total hydrolyzates. The molecular weight of the protein hydrolyzates which can be used according to the invention is between 75, the molecular weight for glycine, and 200,000 Daltons, and the molecular weight is preferably 75 to 50,000 Daltons and very particularly preferably 75 to 20,000 Daltons. Preferred protein hydrolyzates include hydrolyzed keratin, hydrolyzed collagen, hydrolyzed pearl, and hydrolyzed silk.

The hair composition according to the invention can also contain at least one vitamin, a provitamin, a vitamin precursor and / or one of the derivatives thereof as a care substance. Vitamins, provitamins and vitamin precursors which are usually assigned to groups A, B, C, E, F and H are preferred according to the invention. In particular, niacinamide (vitamin B3) and vitamin E (or a derivative thereof) are preferred.

The hair composition disclosed herein can also include a perfume. Suitably a perfume is included in an amount ranging from 0.1 to 0.8% by weight, preferably 0.2 to 0.6%, relative to the weight of the hair composition.

A bitter substance is particularly important in cosmetics, household products, etc., which are composed in such a way that their shape, color, feel, etc., can appeal to small children or babies and encourage them to play, which can also lead to swallowing. A bitter substance prevents this. Denatonium benzoate is an extremely strong bitter substance and is therefore particularly effective even at very low concentrations. In addition, it is not associated with any known harmful effects.

Suitable pH regulators which are particularly preferred for use in the compositions of the invention are citric acid, lactic acid, malic acid, glycolic acid, especially citric acid and / or lactic acid. The pH regulator can also be a base such as alkanolamines and / or sodium hydroxide.

Examples of oils include liquid oils, hydrocarbon oils and silicone oils. It is preferred that the compositions disclosed herein contain no silicone oils and no silicone in any form (i.e., that they are silicone free). It is particularly preferred that the compositions disclosed herein be silicone free and contain no hydrocarbon oils. Thus, the preferred liquid oils are especially those of natural origin.

Suitable oils are perfume oils and / or vegetable triglyceride oils such as coconut oil, (sweet) almond oil, walnut oil, peach kernel oil, apricot kernel oil, avocado oil, tea tree oil, soybean oil, cottonseed oil, sesame oil, sunflower oil, tsubaki oil, sand thorn oil, palm oil, rice bran oil, cranberry oil, evening primrose oil, palm oil, rice bran oil , Meadowfoam oil, safflower oil, macadamia nut oil, grapeseed oil, amaranth seed oil, Argan oil, bamboo oil, olive oil, wheat germ oil, pumpkin seed oil, mallow oil, hazelnut oil, safflower oil, corn oil, olive oil, rapeseed oil, rapeseed oil, sasanqua oil, jojoba oil, rambutan oil, marula oil, seed oil from Vitis Vinifera and / or quinoa oil.

By using the hair composition according to the invention, it is possible to dispense with organosilicon compounds, in particular silicones. In the context of the present invention, “silicone-free” means that the hair composition is free from organosilicon compounds, in particular free from silicones, trisiloxanes and silicone oils.

The invention also relates to a shampoo comprising the hair composition as disclosed herein.

The invention also relates to a conditioner comprising the hair composition as disclosed herein. The conditioner is suitable for the care of human hair, in particular for use after hair cleaning as a leave-on or rinse-off composition. The hair compositions disclosed herein can also be useful in hair treatments and hair packs.

The terms “leave-on” and “rinse-off” mean that the composition is left in the hair either for a relatively short time, for example for less than a minute if necessary, or for a few minutes or an hour until it is is rinsed out again, or that the composition remains in the hair until the next shampoo, which can be a few days. Both have certain advantages. If the composition remains on the hair for a long time, the full care potential of all ingredients can be exploited, whereas a composition that is to be rinsed out in a short time can also contain ingredients that have a good care effect but are uncomfortable to keep in the hair for extended periods were. Rinse-off compositions are preferred for the purposes of the present invention.

The present patent is also directed to a method of strengthening hair comprising applying a hair composition of the invention to the hair. The method includes applying the hair composition as disclosed herein to the hair. The method includes dispensing the hair composition as disclosed herein onto the user's hand and from the user's hand onto the hair. The method can additionally include rubbing the hair. The method may include the user spreading the hair composition on their hand or hands prior to application to the hair.

The method as disclosed herein can also include additional optional steps. In one example, such steps may include air drying the hair, drying the hair using heat, styling the hair, and any other suitable step known to one skilled in the hair treatment art.

The hair composition according to the invention is preferably used immediately before, during or after an oxidative or surfactant hair treatment. In the context of the invention, the expression “immediately before the oxidative or surfactant hair treatment” is understood as an application that immediately precedes the oxidative or surfactant hair treatment, the hair composition according to the invention having previously been rinsed out of the hair or preferably left on the hair and the hair preferably still is damp.

The expression “after the oxidative or the surfactant hair treatment” is understood in the context of the invention as indicative of an application that follows either the oxidative or the surfactant hair treatment, the hair composition according to the invention being applied to the preferably still damp, towel-dried hair as soon as the agent was rinsed out with an oxidative or surfactant effect, or applied to dry or damp hair after a few hours or days. In both cases, the hair composition according to the invention can be rinsed out again after a reaction time of a few seconds up to 45 minutes or can remain completely on the hair.

The method as disclosed herein can also include additional optional steps. In one example, such steps may include air drying the hair, drying the hair using heat, styling the hair, and any other suitable step known to one skilled in the hair treatment art.

1. 1. Haarzusammensetzung, umfassend:
   1. a) mindestens eine Verbindung, die eine der folgenden Formeln aufweist:
      
      
      wobei R₁ bis R₄ jeweils unabhängig Wasserstoff, ein Kohlenwasserstoffrest, der 1 bis 10 Kohlenstoffatome aufweist, eine Hydroxylgruppe, eine Aminogruppe, eine Sulfhydrylgruppe, eine Arylgruppe oder ein Halogen sind und R₅ und R₆ jeweils unabhängig Wasserstoff, eine aliphatische Kohlenwasserstoffgruppe, eine alizyklische Kohlenwasserstoffgruppe, eine Arylgruppe, eine Alkylarylgruppe oder eine heterozyklische Gruppe sind; und wobei R₁' bis R₄'jeweils unabhängig Wasserstoff, ein Kohlenwasserstoffrest, der 1 bis 10 Kohlenstoffatome aufweist, eine Hydroxylgruppe, eine Aminogruppe, eine Sulfhydrylgruppe, eine Arylgruppe oder ein Halogen sind; und R₅' und R₆' jeweils unabhängig Wasserstoff, eine aliphatische Kohlenwasserstoffgruppe, eine alizyklische Kohlenwasserstoffgruppe, eine Arylgruppe oder eine heterozyklische Gruppe sind, wobei ausgeschlossen ist, dass R₅' und R₆' gleichzeitig Wasserstoffe sind, wobei die aliphatische Kohlenwasserstoffgruppe, die alizyklische Kohlenwasserstoffgruppe, die Arylgruppe, die Alkylarylgruppe oder die heterozyklische Gruppe mit mindestens einer Hydroxylgruppe substituiert ist; und
   2. b) eine Aminosäure oder ein Salz-, Ester- oder Acylderivat davon.
2. 2. Haarzusammensetzung nach Aussage 1, wobei Bestandteil a) mindestens eine Verbindung, die die Formel (I) aufweist, und mindestens eine Verbindung, die die Formel (II) aufweist, umfasst.
3. 3. Haarzusammensetzung nach Aussage 2, wobei das Molverhältnis von Formel (I) zu Formel (II) von 0,1:1 bis 99,9:1, geeigneterweise von 1:99 bis 99:1, reicht.
4. 4. Haarzusammensetzung nach Aussage 3, wobei das Molverhältnis von Formel (I) zu Formel (II) von 20:80 bis 80:20 reicht.
5. 5. Haarzusammensetzung nach Aussage 4, wobei das Molverhältnis von Formel (I) zu Formel (II) von 40:60 bis 60:40 reicht.
6. 6. Haarzusammensetzung nach einer der vorhergehenden Aussagen, wobei die Verbindung der Formel (I) und/oder der Formulierung (II) ein Umsetzungsprodukt mindestens einer Laktonverbindung und mindestens einer Aminoalkoholverbindung umfasst.
7. 7. Haarzusammensetzung nach Aussage 6, wobei die Aminoalkoholverbindung eine, zwei, drei oder mehr Hydroxylgruppen umfasst, wobei vorzugsweise die Aminoalkoholverbindung nur eine oder zwei Hydroxylgruppen umfasst.
8. 8. Haarzusammensetzung nach Aussage 6 oder 7, wobei die Aminoalkoholverbindung aus den Folgenden ausgewählt ist: Ethanolamin, 2-Hydroxyethylhydrazin, 2-Methoxyethylamin, 3-Amino-1-propanol, Amino-2-propanol, 3-Amino-1,2-propandiol, Serinol, 1,3-Diamino-2-propanol, 1-Amino-2-methyl-2-propanol, 2-(Ethylamino)ethanol, 2-Amino-1-butanol, 2-Amino-2-methyl-1-propanol, 3-Methylamino-1-propanol, 4-Amino-1-butanol, 2-(2-Aminoethoxy)ethanol, 3-Methylamino-1,2-propandiol, Diethanolamin, Tris(hydroxymethyl)aminomethan, N-(2-Hydroxyethyl)ethylendiamin, Meso-1,4-diamino-2,3-butandiol, 2-Aminocyclopentanol, 2-(Isopropylamino)ethanol, 2-(Propylamino)ethanol, 2-Amino-3-methyl-1-butanol, 5-Amino-1-pentanol, 2-(3-Aminopropylamino)ethanol, 1-Amino-1-cyclopentanmethanol, 4-Aminocyclohexanol, 2-(Butylamino)ethanol, 6-Amino-1-hexanol, DL-2-Amino-1-hexanol, Leucinol, N,N'-bis(2-Hydroxyethyl)ethylendiamin, 2-Aminobenzylalkohol, 3-Aminolbenzylalkohol, 4-Aminobenzylalkohol, 2-Amino-4-methoxyphenol, 3,4-Dihydroxybenzylamin, Dihydroxybenzylamin, 1-Aminomethyl-1-cyclohexanol, 2-Aminomethyl-1-cyclohexanol, N-Boc-Ethanolamin, 5-Amino-2,2-dimethylpentanol, 2-Amino-1-phenylethanol, 2-Amino-3-methylbenzylalkohol, 2-Amino-5-methylbenzylalkohol, 2-Aminophenylethylalkohol 3-Amino-2-methylbenzylalkohol, 3-Amino-4-methylbenzylalkohol, 4-(1-Hydroxyethyl)anilin, 4-Aminophenethylalkohol, N-(2-Hydroxyethyl)anilin, 3-Hydroxy-4-methoxybenzylamin, 3-Hydroxytyramin, 6-Hydroxydopamin, 4-(Z-Amino)-1-butanol, 5-(Z-Amino)-1-pentanol, 4-(Z-Amino)cyclohexanol, 6-(Z-Amino)-1-hexanol, 3-(Boc-Amino)-1-propanol, N-Boc-Serinol, 2-Benzylaminoethanol, 4-(Boc-Amino)-1-butanol, 2-(Aminomethyl)-2-(hydroxymethyl)-1,3-propandiol und 2-(2-Aminoethyl)-2-(hydroxymethyl)-1,3-propandiol.
9. 9. Haarzusammensetzung nach Aussage 6, 7 oder 8, wobei die Aminoalkoholverbindung die Formel (III) aufweist:
   
   wobei R_y und R_z jeweils unabhängig H, eine Alkylgruppe, die 1 bis 20 (vorzugsweise 1 bis 10, stärker bevorzugt 1 bis 5) Kohlenstoffatome aufweist, oder eine Alkylgruppe sind, die 1 bis 20 (vorzugsweise 1 bis 10, stärker bevorzugt 1 bis 5) Kohlenstoffatome aufweist, die mit mindestens einer Hydroxylgruppe substituiert sind; und R_x ein Alkyl oder Alkenyl, das 2 bis 16 Kohlenstoffatome aufweist, ist.
10. 10. Haarzusammensetzung nach Aussage 9, wobei die Aminoalkoholverbindung 3-Amino-1-propanol ist.
11. 11. Haarzusammensetzung nach Aussage 6, wobei die Laktonverbindung ein zyklischer Ester der Formel (IV) ist:
    
    wobei R''₁ bis R''₄ unabhängig H, ein C1- bis C10-Kohlenwasserstoffrest, der eine Hydroxylgruppe aufweist, eine Aminogruppe, eine Sulfhydrylgruppe, eine Arylgruppe oder ein Halogen sind.
12. 12. Haarzusammensetzung nach Aussage 11, wobei R''1 bis R''₄ jeweils unabhängig ein C1- bis C5-Kohlenwasserstoffrest sind, der linear oder verzweigt, gesättigt oder ungesättigt oder substituiert oder unsubstituiert ist.
13. 13. Haarzusammensetzung nach Aussage 11 oder 12, wobei das Lakton aus den Folgenden ausgewählt ist: Douglas-Sumpfblumen-δ-Lakton, δ-Octalakton, δ-Decalakton, δ-Nonalakton, Undecan-δ-Lakton, δ-Dodecalakton, Massoia-Lakton (oder 5-Pentylpent-2-en-5-olid), Jasminlakton (oder Z-2-Pentenylpentan-5-olid), 6-Pentyl-alpha-pyron (oder 5-Pentylpenta-2,4-dien-5-olid), δ-Valerolakton, Galaktonolakton, Glukonsäure-δ-lakton, Hexadecanolakton und Mevalonolakton.
14. 14. Haarzusammensetzung nach Aussage 11 oder 12, wobei das Lakton Glukonsäure-δ-lakton ist.
15. 15. Haarzusammensetzung nach einer der vorhergehenden Aussagen, wobei Bestandteil a) ein Gemisch aus Hydroxypropylglukonamid und Hydroxypropylammoniumglukonat umfasst.
16. 16. Haarzusammensetzung nach einer der vorhergehenden Aussagen, wobei Bestandteil a) aus einem Gemisch aus Hydroxypropylglukonamid und Hydroxypropylammoniumglukonat besteht.
17. 17. Haarzusammensetzung nach einer der vorhergehenden Aussagen, wobei Bestandteil a) in einer Menge, die von 0,01 bis 20 Gew.-%, vorzugsweise von 0,05 bis 10 Gew.-%, bezogen auf das Gesamtgewicht der Zusammensetzung, reicht, vorhanden ist.
18. 18. Haarzusammensetzung nach einer der vorhergehenden Aussagen, wobei Bestandteil a) in einer Menge, die von 0,1 bis 5,0 Gew.-% bezogen auf das Gesamtgewicht der Zusammensetzung, reicht, vorhanden ist.
19. 19. Haarzusammensetzung nach einer der vorhergehenden Aussagen, wobei Bestandteil a) in einer Menge, die von 0,15 bis 3,0 Gew.-%, bezogen auf das Gesamtgewicht der Zusammensetzung, reicht, vorhanden ist.
20. 20. Haarpflegezusammensetzung nach einer der vorhergehenden Aussagen, wobei die Aminosäure/das Derivat davon aus Alanin, Arginin, Asparagin, Asparaginsäure, Kreatin, Cysteinsäure, Cystein, Cystin, Glutaminsäure, Glutamin, Glycin, Histidin, Hydroxyprolin, Isoleucin, Leucin, Lysin, Methionin, Norleucin, Ornithin, Phenylalanin, Prolin, Serin, Threonin, Tryptophan, Tyrosin, Valin und Gemischen daraus ausgewählt ist.
21. 21. Haarzusammensetzung nach einem der vorhergehenden Ansprüche, wobei Bestandteil b) Arginin umfasst oder daraus besteht.
22. 22. Haarzusammensetzung nach einem der vorhergehenden Ansprüche, wobei Bestandteil b) Glutaminsäure umfasst oder daraus besteht.
23. 23. Haarzusammensetzung nach einem der vorhergehenden Ansprüche, wobei Bestandteil b) Glycin umfasst oder daraus besteht.
24. 24. Haarzusammensetzung nach einem der vorhergehenden Ansprüche, wobei Bestandteil b) Histidin umfasst oder daraus besteht.
25. 25. Haarzusammensetzung nach einem der vorhergehenden Ansprüche, wobei Bestandteil b) Lysin umfasst oder daraus besteht.
26. 26. Haarzusammensetzung nach einer der vorhergehenden Aussagen, wobei Bestandteil b) in einer Menge, die von 0,001 bis 10,0 Gew.-% bezogen auf das Gesamtgewicht der Zusammensetzung, reicht, vorhanden ist.
27. 27. Haarzusammensetzung nach einer der vorhergehenden Aussagen, wobei Bestandteil b) in einer Menge, die von 0,01 bis 5,00 Gew.-% bezogen auf das Gesamtgewicht der Zusammensetzung, reicht, vorhanden ist.
28. 28. Haarzusammensetzung nach einer der vorhergehenden Aussagen, wobei Bestandteil b) in einer Menge, die von 0,05 bis 3,00 Gew.-% bezogen auf das Gesamtgewicht der Zusammensetzung, reicht, vorhanden ist.
29. 29. Haarzusammensetzung nach einer der vorhergehenden Aussagen, wobei Bestandteil b) in einer Menge, die von 0,05 bis 1,00 Gew.-% bezogen auf das Gesamtgewicht der Zusammensetzung, reicht, vorhanden ist.
30. 30. Haarpflegezusammensetzung nach einer der vorhergehenden Aussagen, die silikonfrei ist.
31. 31. Haarzusammensetzung nach einer der vorhergehenden Aussagen, ferner umfassend von 5,0 bis 50,0 Gew.-% mindestens eines anionischen, nicht ionischen, amphoteren oder zwitterionischen Tensids.
32. 32. Haarzusammensetzung nach einer der vorhergehenden Aussagen, ferner umfassend mindestens ein anionisches Tensid und optional mindestens ein nicht ionisches, amphoteres oder zwitterionisches Tensid.
33. 33. Haarzusammensetzung nach einer der vorhergehenden Aussagen, ferner umfassend mindestens ein anionisches Tensid, mindestens ein nicht ionisches Tensid und optional mindestens ein amphoteres oder zwitterionisches Tensid.
34. 34. Haarzusammensetzung nach einer der vorhergehenden Aussagen, umfassend ein anionisches Tensid, ausgewählt aus mindestens einer wasserlöslich machenden anionischen Gruppe wie einer Carboxylat-, Sulfat-, Sulfonat- oder Phosphatgruppe und einer lipophilen Alkylgruppe, die 8 bis 30 C-Atome aufweist, optional Glykol- oder Polyglykolethergruppen, Hydroxyl-, Ester-, Ether- oder Amidgruppen enthaltend.
35. 35. Haarzusammensetzung nach einer der vorhergehenden Aussagen, umfassend ein anionisches Tensid, umfassend mindestens eines der Folgenden:
    1. i. lineare und verzweigte Fettsäuren, die 8 bis 30 C-Atome aufweisen (Seifen),
    2. ii. Alkyletherkarbonsäuren,
    3. iii. Acylsarkoside,
    4. iv. Acyltauride,
    5. v. Acylisethionate,
    6. vi. Sulfobernsteinsäuremonoester und -dialkylester und Sulfobernsteinsäuremonoalkylpolyoxyethylester,
    7. vii. lineare Alkansulfonate,
    8. viii. lineare alpha-Olefinsulfonate,
    9. ix. Alkylsulfate und Alkylethersulfate und
    10. x. Alkyl- und/oder Alkenylphosphate.
36. 36. Haarzusammensetzung nach einer der vorhergehenden Aussagen, umfassend ein anionisches Tensid, das aus Natriumlaurethsulfat, Ammoniumlaurylsulfat, Natriumlaurylsulfat, Natriummyrethsulfat, Natriumlaurethcarboxylat und Gemischen daraus ausgewählt ist.
37. 37. Haarzusammensetzung nach einer der vorhergehenden Aussagen, umfassend ein anionisches Tensid, das aus Natriumlaurethsulfat, Ammoniumlaurylsulfat oder einem Gemisch daraus ausgewählt ist.
38. 38. Haarzusammensetzung nach einer der vorhergehenden Aussagen, umfassend ein zwitterionisches Tensid, das aus einem Betain, Cocoacylaminoethylhydroxyethylcarboxymethylglycinat, einem N-Alkyl-N,N-dimethylammoniumglycinat, einem N-Acylaminopropyl-N,N-dimethylammoniumglycinat, das 8 bis 18 C-Atome in der Alkylgruppe aufweist, und einem 2-Alkyl-3-carboxymethyl-3-hydroxyethylimidazolin, das 8 bis 18 C-Atome in der Acylgruppe aufweist, ausgewählt ist.
39. 39. Haarzusammensetzung nach einer der vorhergehenden Aussagen, umfassend ein zwitterionisches Tensid, umfassend Cocoamidopropylbetain.
40. 40. Haarzusammensetzung nach einer der vorhergehenden Aussagen, umfassend ein nicht ionisches Tensid, ausgewählt aus:
    • • Anlagerungsprodukten von etwa 4 bis etwa 30 Mol Ethylenoxid und/oder von etwa 0 bis etwa 5 Mol Propylenoxid mit linearen Fettalkoholen, die etwa 8 bis etwa 22 C-Atome enthalten,
    • • Fettsäuren, die etwa 12 bis etwa 22 C-Atome, oder Alkylphenolen, die etwa 8 bis etwa 15 C-Atome in der Alkylgruppe enthalten,
    • • Anlagerungsprodukte von Ethylenoxid und Polyglycerin mit Methylglukosidfettsäureestern, Fettsäurealkanolamiden und Fettsäureglukamiden,
    • • C8- bis C30-Fettsäuremono- und -diester von Anlagerungsprodukten von etwa 1 bis etwa 30 Mol Ethylenoxid oder Glycerin, beispielsweise jene mit den INCI-Bezeichnungen PEG(1-10)-Glycerylcocoat, insbesondere PEG-7-Glycerylcocoat.
    • • Aminoxide, beispielsweise mindestens eine Verbindung mit der allgemeinen Formel (I) oder (II):
      
      • ◯ wobei R jeweils einen linearen oder verzweigten, gesättigten oder einfach oder mehrfach ungesättigten Alkyl- oder Alkenylrest darstellt, der etwa 6 bis etwa 24 Kohlenstoffatome enthält, beispielsweise etwa 8 bis etwa 18 Kohlenstoffatome.
      • ◯ Geeignete Tenside sind jene mit den vorgenannten Formeln (I) oder (II) mit den INCI-Bezeichnungen Cocaminoxid, Lauraminoxid und/oder Cocamidopropylaminoxid, die bei einer Reihe verschiedener Anbieter im Handel erhältlich sind.
    • • Sorbitanfettsäureester und Anlagerungsprodukte von Ethylenoxid mit Sorbitanfettsäureestern wie Polysorbaten,
    • • Fettsäurealkanolamide mit der folgenden allgemeinen Formel:
      
      • ◯ wobei R geeigneterweise einen linearen oder verzweigten, gesättigten oder ungesättigten Alkyl- oder Alkenylrest darstellt, der etwa 8 bis etwa 24 Kohlenstoffatome enthält, und die Reste R' Wasserstoff oder die Gruppe —(CH₂)_nOH darstellen, wobei n die Zahlen von etwa 2 oder etwa 3 darstellt, mit der Maßgabe, dass mindestens einer der Reste R' den vorstehend genannten Rest —(CH₂)_nOH darstellt,
      • ◯ insbesondere jene Verbindungen, die unter den INCI-Bezeichnungen Cocamid-MEA und/oder Cocamid-MIPA bekannt sind;
    • • C8- bis C30-Fettsäuremono- und -diester von Anlagerungsprodukten von etwa 1 bis etwa 30 Mol Ethylenoxid mit Glycerin, insbesondere die unter der INCI-Bezeichnung PEG-7-Glycerylcocoat bekannte Verbindung; und/oder Anlagerungsprodukte von etwa 4 bis etwa 30 Mol Ethylenoxid und/oder von etwa 0 bis etwa 5 Mol Propylenoxid mit linearen Fettalkoholen, die etwa 8 bis etwa 22 C-Atome enthalten.
    • • Fettsäureester von Zuckern und Anlagerungsprodukte von Ethylenoxid mit Fettsäureestern von Zucker,
    • • Anlagerungsprodukte von Ethylenoxid mit Fettsäurealkanolamiden und Fettaminen,
    • • Alkyl(oligo)glukoside, beispielsweise Verbindungen mit der allgemeinen Formel RO-[G]x, wobei [G] vorzugsweise von Aldosen und/oder Ketosen, die etwa 5 bis etwa 6 Kohlenstoffatome enthalten, vorzugsweise von Glukose, abgeleitet ist.
      • ◯ Der Index x stellt den Oligomerisierungsgrad (degree of oligomerization - DO), d. h. die Verteilung der Mono- und Oligoglykoside, dar. Der Index x weist vorzugsweise einen Wert im Bereich von etwa 1 bis etwa 10, beispielsweise im Bereich von etwa 1 bis etwa 3, auf, wobei es diesbezüglich keine ganze Zahl sein muss, sondern eine Bruchzahl sein kann, die analytisch bestimmt werden kann.
      • ◯ Geeignete Alkyl(oligo)glykoside weisen einen Oligomerisierungsgrad zwischen von etwa 1,2 und etwa 1,5 auf.
      • ◯ Der Rest R stellt geeigneterweise mindestens einen Alkyl- und/oder Alkenylrest dar, der von etwa 4 bis etwa 24 C-Atome enthält.
      • ◯ Beispiele für Alkyl(oligo)glukoside sind unter den INCI-Bezeichnungen Caprylyl/Caprylglukosid, Decylglukosid, Laurylglukosid und Cocoglukosid bekannt,
    • • Gemische aus Alkyl(oligo)glukosiden und Fettalkoholen,
    • • Anlagerungsprodukte von etwa 5 bis etwa 60 Mol Ethylenoxid mit Rizinusöl oder hydriertem Rizinusöl, beispielsweise hydriertem PEG-40-Rizinusöl,
    • • Teilester von Polyolen, die etwa 3 bis etwa 6 Kohlenstoffatome enthalten, mit gesättigten Fettsäuren, die etwa 8 bis etwa 22 C-Atome enthalten,
    • • Sterine. Unter „Sterinen“ ist eine Gruppe von Steroiden zu verstehen, die eine Hydroxygruppe an C3 der Steroidhauptkette tragen und sowohl aus tierischem Gewebe (Zoosterine) als auch aus pflanzlichen Fetten (Phytosterine) isoliert sind. Beispiele für Zoosterine sind Cholesterin und Lanosterin. Beispiele für geeignete Phytosterine sind Ergosterin, Stigmasterin und Sitosterin. Sterine sind auch aus Pilzen und Hefen isoliert; sie sind als Mykosterine bekannt.
    • • Phospholipide. Damit sind in erster Linie Glukosephospolipide gemeint, die beispielsweise als Lecithine oder Phosphatidylcholine aus Eigelb oder aus Pflanzensamen (beispielsweise Sojabohnen) erhalten werden.
    • • hydriertes Rizinusöl.
41. 41. Haarzusammensetzung nach einer der vorhergehenden Aussagen, umfassend ein nicht ionisches Tensid, umfassend ein Betain, vorzugsweise Cocoamidopropylbetain.
42. 42. Haarzusammensetzung nach einer der vorhergehenden Aussagen, umfassend 0,1 bis 15,0 Gew.-% mindestens eines kationischen Tensids.
43. 43. Haarzusammensetzung nach einer der vorhergehenden Aussagen, umfassend 0,5 bis 10,0 Gew.-%, vorzugsweise 0,2 bis 5,0 Gew.-%, mindestens eines kationischen Tensids.
44. 44. Haarzusammensetzung nach einer der vorhergehenden Aussagen, umfassend ein kationisches Tensid, ausgewählt aus:
    1. i. Alkylquats,
    2. ii. Esterquats,
    3. iii. quartärem Imidazolin,
    4. iv. Amidoaminen und/oder kationisierten Amidoaminen,
    5. v. und Gemischen daraus.
45. 45. Haarzusammensetzung nach einer der vorhergehenden Aussagen, umfassend: Quaternium-87, Behenoyl-PG-trimoniumchlorid, Distearoylethylhydroxyethylmoniummethosulfat und/oder Behentrimoniumchlorid.
46. 46. Haarzusammensetzung nach einer der vorhergehenden Aussagen, die ein Haarshampoo ist. Diese Aussage kann auch als „Shampoo, umfassend eine Haarzusammensetzung nach einer der vorhergehenden Aussagen“ ausgedrückt werden.
47. 47. Haarzusammensetzung nach einer der Aussagen 1 bis 45, die eine Haarspülung ist. Diese Aussage kann auch als „Spülung, umfassend eine Haarzusammensetzung nach einer der Aussagen 1 bis 45“ ausgedrückt werden.
48. 48. Haarzusammensetzung nach Aussage 47, die eine Leave-on-Haarspülung ist.
49. 49. Haarzusammensetzung nach Aussage 47, die eine Rinse-off-Haarspülung ist.
50. 50. Haarzusammensetzung nach einer der Aussagen 1 bis 45, die ein Haarserum ist. Diese Aussage kann auch als „Serum, umfassend eine Haarzusammensetzung nach einer der Aussagen 1 bis 45“ ausgedrückt werden.
51. 51. Haarzusammensetzung nach einer der vorhergehenden Aussagen, ferner umfassend eine oder mehrere Fettverbindungen.
52. 52. Haarzusammensetzung nach einer der vorhergehenden Aussagen, ferner umfassend mindestens eine Fettsäure, Fettalkohol, natürliches oder synthetisches Wachs, ein/e feste/s pflanzliche/s Öl oder Butter oder ein natürliches oder synthetisches kosmetisches Öl.
53. 53. Haarzusammensetzung nach einer der vorhergehenden Aussagen, ferner umfassend ein oder mehrere zusätzliche kationische Polymere.
54. 54. Haarzusammensetzung nach einer der vorhergehenden Aussagen, ferner umfassend Wasser in einer Menge von mindestens 60 Gew.-% bezogen auf das Gesamtgewicht der Zusammensetzung, besser geeignet in einer Menge, die von 60 bis 95 Gew.-%, beispielsweise von 70 bis 90 Gew.-%, reicht.
55. 55. Haarzusammensetzung nach einer der vorhergehenden Aussagen, ferner umfassend mindestens einen Wirkstoff, der aus der Gruppe ausgewählt ist, die Pflanzenextrakte, Bitterstoffe, Feuchthaltemittel, Proteinhydrolysate, Parfüme, UV-Filter, Strukturierungsmittel, Farbstoffe zum Färben der Zusammensetzung, Wirkstoffe wie Bisabolol und/oder Allantoin, Antioxidanzien, Konservierungsmittel wie Natriumbenzoat oder Salicylsäure, zusätzliche Viskositätsregler wie Salze (NaCI) oder Polymere, und pH-Regulatoren umfasst.
56. 56. Verfahren zum Stärken von Haar, umfassend das Anwenden einer Haarzusammensetzung nach einer der Aussagen 1 bis 55 auf das Haar.
57. 57. Verfahren nach Aussage 56, wobei die Haarzusammensetzung direkt vor einer oxidativen oder Tensidhaarbehandlung auf das Haar angewendet wird.
58. 58. Verfahren nach Aussage 56 oder 57, wobei die Haarzusammensetzung direkt während einer oxidativen oder Tensidhaarbehandlung auf das Haar angewendet wird.
59. 59. Verfahren nach Aussage 56, 57 oder 58, wobei die Haarzusammensetzung direkt nach einer oxidativen oder Tensidhaarbehandlung auf das Haar angewendet wird.
60. 60. Verwendung einer Haarzusammensetzung nach einer der Aussagen 1 bis 55 zum Stärken von Haar.

The invention disclosed herein can also be defined by the following statements.

1. 1. Hair composition comprising:
   1. a) at least one compound which has one of the following formulas:
      
      
      wherein R ₁ to R _{4 are} each independently hydrogen, a hydrocarbon radical having 1 to 10 carbon atoms, a hydroxyl group, an amino group, a sulfhydryl group, an aryl group or a halogen, and R ₅ and R _{6 are} each independently hydrogen, an aliphatic hydrocarbon group, a an alicyclic hydrocarbon group, an aryl group, an alkylaryl group or a heterocyclic group; and wherein R ₁ 'to R ₄ ' are each independently hydrogen, a hydrocarbon radical having 1 to 10 carbon atoms, a hydroxyl group, an amino group, a sulfhydryl group, an aryl group, or a halogen; and R ₅ 'and R ₆ ' are each independently hydrogen, an aliphatic hydrocarbon group, an alicyclic hydrocarbon group, an aryl group, or a heterocyclic group, with the exclusion of R ₅ 'and R ₆ ' being hydrogen at the same time, the aliphatic hydrocarbon group being the alicyclic hydrocarbon group, the aryl group, the alkylaryl group or the heterocyclic group is substituted with at least one hydroxyl group; and
   2. b) an amino acid or a salt, ester or acyl derivative thereof.
2. 2. Hair composition according to statement 1, wherein component a) comprises at least one compound which has the formula (I) and at least one compound which has the formula (II).
3. 3. The hair composition according to claim 2, wherein the molar ratio of formula (I) to formula (II) ranges from 0.1: 1 to 99.9: 1, suitably from 1:99 to 99: 1.
4. 4. Hair composition according to statement 3, wherein the molar ratio of formula (I) to formula (II) ranges from 20:80 to 80:20.
5. 5. Hair composition according to statement 4, wherein the molar ratio of formula (I) to formula (II) ranges from 40:60 to 60:40.
6. 6. Hair composition according to one of the preceding statements, wherein the compound of the formula (I) and / or the formulation (II) comprises a reaction product of at least one lactone compound and at least one amino alcohol compound.
7. 7. The hair composition according to claim 6, wherein the amino alcohol compound comprises one, two, three or more hydroxyl groups, wherein preferably the amino alcohol compound comprises only one or two hydroxyl groups.
8. 8. Hair composition according to statement 6 or 7, wherein the amino alcohol compound is selected from the following: ethanolamine, 2-hydroxyethylhydrazine, 2-methoxyethylamine, 3-amino-1-propanol, amino-2-propanol, 3-amino-1,2- propanediol, serinol, 1,3-diamino-2-propanol, 1-amino-2-methyl-2-propanol, 2- (ethylamino) ethanol, 2-amino-1-butanol, 2-amino-2-methyl-1 -propanol, 3-methylamino-1-propanol, 4-amino-1-butanol, 2- (2-aminoethoxy) ethanol, 3-methylamino-1,2-propanediol, diethanolamine, tris (hydroxymethyl) aminomethane, N- (2 -Hydroxyethyl) ethylenediamine, meso-1,4-diamino-2,3-butanediol, 2-aminocyclopentanol, 2- (isopropylamino) ethanol, 2- (propylamino) ethanol, 2-amino-3-methyl-1-butanol, 5 -Amino-1-pentanol, 2- (3-aminopropylamino) ethanol, 1-amino-1-cyclopentanemethanol, 4- Aminocyclohexanol, 2- (butylamino) ethanol, 6-amino-1-hexanol, DL-2-amino-1-hexanol, leucinol, N, N'-bis (2-hydroxyethyl) ethylenediamine, 2-aminobenzyl alcohol, 3-aminolbenzyl alcohol, 4-aminobenzyl alcohol, 2-amino-4-methoxyphenol, 3,4-dihydroxybenzylamine, dihydroxybenzylamine, 1-aminomethyl-1-cyclohexanol, 2-aminomethyl-1-cyclohexanol, N-Boc-ethanolamine, 5-amino-2,2- dimethylpentanol, 2-amino-1-phenylethanol, 2-amino-3-methylbenzyl alcohol, 2-amino-5-methylbenzyl alcohol, 2-aminophenylethyl alcohol, 3-amino-2-methylbenzyl alcohol, 3-amino-4-methylbenzyl alcohol, 4- (1- Hydroxyethyl) aniline, 4-aminophenethyl alcohol, N- (2-hydroxyethyl) aniline, 3-hydroxy-4-methoxybenzylamine, 3-hydroxytyramine, 6-hydroxydopamine, 4- (Z-amino) -1-butanol, 5- (Z- Amino) -1-pentanol, 4- (Z-amino) cyclohexanol, 6- (Z-amino) -1-hexanol, 3- (Boc-amino) -1-propanol, N-Boc-serinol, 2-benzylaminoethanol, 4- (Boc-amino) -1-butanol, 2- (aminomethyl) -2- (hydroxymethyl) -1,3-propanediol, and 2- (2-aminoethyl) -2- (hydroxymethyl) -1,3-propanediol.
9. 9. Hair composition according to statement 6, 7 or 8, wherein the amino alcohol compound has the formula (III):
   
   where R _y and R _{z are} each independently H, an alkyl group having 1 to 20 (preferably 1 to 10, more preferably 1 to 5) carbon atoms, or an alkyl group having 1 to 20 (preferably 1 to 10, more preferably 1 to 5) has carbon atoms substituted with at least one hydroxyl group; and R _{x is} an alkyl or alkenyl having 2 to 16 carbon atoms.
10. 10. Hair composition according to statement 9, wherein the amino alcohol compound is 3-amino-1-propanol.
11. 11. Hair composition according to statement 6, wherein the lactone compound is a cyclic ester of the formula (IV):
    
    where R " ₁ to R" _{4 are} independently H, a C1 to C10 hydrocarbon radical having a hydroxyl group, an amino group, a sulfhydryl group, an aryl group, or a halogen.
12. 12. Hair composition according to statement 11, wherein R "1 to R" _{4 are} each independently a C1 to C5 hydrocarbon radical that is linear or branched, saturated or unsaturated or substituted or unsubstituted.
13. 13. Hair composition according to statement 11 or 12, wherein the lactone is selected from the following: Douglas marsh flower δ-lactone, δ-octalactone, δ-decalactone, δ-nonalactone, undecane-δ-lactone, δ-dodecalactone, Massoia- Lactone (or 5-pentylpent-2-en-5-olide), jasmine lactone (or Z-2-pentenylpentan-5-olide), 6-pentyl-alpha-pyrone (or 5-pentylpenta-2,4-diene-5 -olid), δ-valerolactone, galactonolactone, gluconic acid δ-lactone, hexadecanolactone and mevalonolactone.
14. 14. Hair composition according to statement 11 or 12, wherein the lactone is gluconic acid-δ-lactone.
15. 15. Hair composition according to one of the preceding statements, wherein component a) comprises a mixture of hydroxypropyl gluconamide and hydroxypropylammonium gluconate.
16. 16. Hair composition according to one of the preceding statements, wherein component a) consists of a mixture of hydroxypropyl gluconamide and hydroxypropylammonium gluconate.
17. 17. Hair composition according to one of the preceding statements, wherein component a) in an amount ranging from 0.01 to 20% by weight, preferably from 0.05 to 10% by weight, based on the total weight of the composition, is available.
18. 18. Hair composition according to one of the preceding statements, wherein component a) is present in an amount ranging from 0.1 to 5.0% by weight based on the total weight of the composition.
19. 19. Hair composition according to one of the preceding statements, wherein component a) is present in an amount ranging from 0.15 to 3.0% by weight, based on the total weight of the composition.
20. 20. Hair care composition according to one of the preceding statements, wherein the amino acid / derivative thereof is selected from alanine, arginine, asparagine, aspartic acid, creatine, cysteic acid, cysteine, cystine, glutamic acid, glutamine, glycine, histidine, hydroxyproline, isoleucine, leucine, lysine, methionine , Norleucine, ornithine, phenylalanine, proline, serine, threonine, tryptophan, tyrosine, valine and mixtures thereof.
21. 21. Hair composition according to one of the preceding claims, wherein component b) comprises or consists of arginine.
22. 22. Hair composition according to one of the preceding claims, wherein component b) comprises or consists of glutamic acid.
23. 23. Hair composition according to one of the preceding claims, wherein component b) comprises or consists of glycine.
24. 24. Hair composition according to one of the preceding claims, wherein component b) comprises or consists of histidine.
25. 25. Hair composition according to one of the preceding claims, wherein component b) comprises or consists of lysine.
26. 26. Hair composition according to one of the preceding statements, wherein component b) is present in an amount ranging from 0.001 to 10.0% by weight based on the total weight of the composition.
27. 27. Hair composition according to one of the preceding statements, wherein component b) is present in an amount ranging from 0.01 to 5.00% by weight based on the total weight of the composition.
28. 28. Hair composition according to one of the preceding statements, wherein component b) is present in an amount ranging from 0.05 to 3.00% by weight based on the total weight of the composition.
29. 29. Hair composition according to one of the preceding statements, wherein component b) is present in an amount ranging from 0.05 to 1.00% by weight based on the total weight of the composition.
30. 30. The hair care composition according to any preceding statement, which is silicone-free.
31. 31. Hair composition according to one of the preceding statements, further comprising from 5.0 to 50.0% by weight of at least one anionic, nonionic, amphoteric or zwitterionic surfactant.
32. 32. Hair composition according to one of the preceding statements, further comprising at least one anionic surfactant and optionally at least one non-ionic, amphoteric or zwitterionic surfactant.
33. 33. Hair composition according to one of the preceding statements, further comprising at least one anionic surfactant, at least one non-ionic surfactant and optionally at least one amphoteric or zwitterionic surfactant.
34. 34. Hair composition according to one of the preceding statements, comprising an anionic surfactant selected from at least one water-solubilizing anionic group such as a carboxylate, sulfate, sulfonate or phosphate group and a lipophilic alkyl group which has 8 to 30 carbon atoms, optionally glycol - Or polyglycol ether groups, containing hydroxyl, ester, ether or amide groups.
35. 35. Hair composition according to one of the preceding statements, comprising an anionic surfactant comprising at least one of the following:
    1. i. linear and branched fatty acids with 8 to 30 carbon atoms (soaps),
    2. ii. Alkyl ether carboxylic acids,
    3. iii. Acyl sarcosides,
    4. iv. Acyl taurides,
    5. v. Acyl isethionate,
    6. vi. Sulfosuccinic acid monoesters and dialkyl esters and sulfosuccinic acid monoalkyl polyoxyethyl esters,
    7. vii. linear alkanesulfonates,
    8. viii. linear alpha-olefin sulfonates,
    9. ix. Alkyl sulfates and alkyl ether sulfates and
    10. x. Alkyl and / or alkenyl phosphates.
36. 36. Hair composition according to one of the preceding statements, comprising an anionic surfactant selected from sodium laureth sulfate, ammonium lauryl sulfate, sodium lauryl sulfate, sodium myreth sulfate, sodium laureth carboxylate, and mixtures thereof.
37. 37. Hair composition according to one of the preceding statements, comprising an anionic surfactant which is selected from sodium laureth sulfate, ammonium lauryl sulfate or a mixture thereof.
38. 38. Hair composition according to one of the preceding statements, comprising a zwitterionic surfactant consisting of a betaine, cocoacylaminoethylhydroxyethylcarboxymethylglycinate, an N-alkyl-N, N-dimethylammonium glycinate, an N-acylaminopropyl-N, N-dimethylammonium glycinate, which has 8 to 18 carbon atoms in the alkyl group, and a 2-alkyl-3-carboxymethyl-3-hydroxyethylimidazoline which has 8 to 18 carbon atoms in the acyl group is selected.
39. 39. Hair composition according to one of the preceding statements, comprising a zwitterionic surfactant comprising cocoamidopropyl betaine.
40. 40. Hair composition according to one of the preceding statements, comprising a non-ionic surfactant selected from:
    • • addition products of about 4 to about 30 mol of ethylene oxide and / or of about 0 to about 5 mol of propylene oxide with linear fatty alcohols containing about 8 to about 22 carbon atoms,
    • • Fatty acids that contain about 12 to about 22 carbon atoms, or alkylphenols that contain about 8 to about 15 carbon atoms in the alkyl group,
    • • Addition products of ethylene oxide and polyglycerine with methyl glucoside fatty acid esters, fatty acid alkanolamides and fatty acid glucamides,
    • • C8 to C30 fatty acid mono- and diesters of addition products of about 1 to about 30 mol of ethylene oxide or glycerol, for example those with the INCI names PEG (1-10) glyceryl cocoate, in particular PEG-7 glyceryl cocoate.
    • • Amine oxides, for example at least one compound with the general formula (I) or (II):
      
      • ◯ where R is in each case a linear or branched, saturated or mono- or polyunsaturated alkyl or alkenyl radical which contains about 6 to about 24 carbon atoms, for example about 8 to about 18 carbon atoms.
      • ◯ Suitable surfactants are those with the aforementioned formulas (I) or (II) with the INCI names cocamine oxide, lauramine oxide and / or cocamidopropylamine oxide, which are commercially available from a number of different suppliers.
    • • Sorbitan fatty acid esters and addition products of ethylene oxide with sorbitan fatty acid esters such as polysorbates,
    • • Fatty acid alkanolamides with the following general formula:
      
      • ◯ where R suitably represents a linear or branched, saturated or unsaturated alkyl or alkenyl radical containing from about 8 to about 24 carbon atoms, and the radicals R 'represent hydrogen or the group - (CH ₂ ) _n OH, where n are the numbers of represents about 2 or about 3, with the proviso that at least one of the radicals R 'represents the aforementioned radical - (CH ₂ ) _n OH,
      • ◯ in particular those compounds which are known under the INCI names Cocamid-MEA and / or Cocamid-MIPA;
    • • C8 to C30 fatty acid mono- and diesters of addition products of about 1 to about 30 mol of ethylene oxide with glycerol, in particular the compound known under the INCI name PEG-7 glyceryl cocoate; and / or addition products of about 4 to about 30 mol of ethylene oxide and / or of about 0 to about 5 mol of propylene oxide with linear fatty alcohols containing about 8 to about 22 carbon atoms.
    • • fatty acid esters of sugars and addition products of ethylene oxide with fatty acid esters of sugar,
    • • Addition products of ethylene oxide with fatty acid alkanolamides and fatty amines,
    • • Alkyl (oligo) glucosides, for example compounds with the general formula RO- [G] x, where [G] is preferably derived from aldoses and / or ketoses containing about 5 to about 6 carbon atoms, preferably from glucose.
      • The index x represents the degree of oligomerization (DO), ie the distribution of the mono- and oligoglycosides. The index x preferably has a value in the range from about 1 to about 10, for example in the range from about 1 to about 3, whereby in this regard it does not have to be an integer, but can be a fraction that can be determined analytically.
      • ◯ Suitable alkyl (oligo) glycosides have a degree of oligomerization between about 1.2 and about 1.5.
      • ◯ The radical R suitably represents at least one alkyl and / or alkenyl radical which contains from about 4 to about 24 carbon atoms.
      • ◯ Examples of alkyl (oligo) glucosides are known under the INCI names Caprylyl / Caprylglucoside, Decylglucoside, Laurylglucoside and Cocoglucoside,
    • • Mixtures of alkyl (oligo) glucosides and fatty alcohols,
    • • Addition products of about 5 to about 60 mol of ethylene oxide with castor oil or hydrogenated castor oil, for example hydrogenated PEG-40 castor oil,
    • • Partial esters of polyols that contain about 3 to about 6 carbon atoms with saturated fatty acids that contain about 8 to about 22 carbon atoms,
    • • sterols. “Sterols” is a group of steroids that have a hydroxyl group on C3 of the steroid main chain and are isolated from both animal tissue (zoosterols) and vegetable fats (phytosterols). Examples of zoosterols are cholesterol and lanosterol. Examples of suitable phytosterols are ergosterol, stigmasterol and sitosterol. Sterols are also isolated from fungi and yeast; they are known as mycosterols.
    • • phospholipids. This primarily means glucose phospholipids which are obtained, for example, as lecithins or phosphatidylcholines from egg yolk or from plant seeds (for example soybeans).
    • • hydrogenated castor oil.
41. 41. Hair composition according to one of the preceding statements, comprising a non-ionic surfactant comprising a betaine, preferably cocoamidopropyl betaine.
42. 42. Hair composition according to one of the preceding statements, comprising 0.1 to 15.0% by weight of at least one cationic surfactant.
43. 43. Hair composition according to one of the preceding statements, comprising 0.5 to 10.0% by weight, preferably 0.2 to 5.0% by weight, of at least one cationic surfactant.
44. 44. Hair composition according to one of the preceding statements, comprising a cationic surfactant selected from:
    1. i. Alkylquats,
    2. ii. Esterquats,
    3. iii. quaternary imidazoline,
    4. iv. Amidoamines and / or cationized amidoamines,
    5. v. and mixtures thereof.
45. 45. Hair composition according to one of the preceding statements, comprising: quaternium-87, behenoyl-PG-trimonium chloride, distearoylethylhydroxyethylmonium methosulfate and / or behentrimonium chloride.
46. 46. Hair composition according to one of the preceding statements, which is a hair shampoo. This statement can also be expressed as “shampoo comprising a hair composition according to one of the preceding statements”.
47. 47. Hair composition according to any one of statements 1 to 45, which is a hair conditioner. This statement can also be expressed as “conditioner, comprising a hair composition according to one of statements 1 to 45”.
48. 48. Hair composition according to statement 47 which is a leave-on hair conditioner.
49. 49. Hair composition according to statement 47 which is a rinse-off hair conditioner.
50. 50. Hair composition according to any one of statements 1 to 45, which is a hair serum. This statement can also be expressed as “serum, comprising a hair composition according to one of statements 1 to 45”.
51. 51. Hair composition according to one of the preceding statements, further comprising one or more fatty compounds.
52. 52. Hair composition according to one of the preceding statements, further comprising at least one fatty acid, fatty alcohol, natural or synthetic wax, a solid vegetable oil or butter or a natural or synthetic cosmetic oil.
53. 53. Hair composition according to one of the preceding statements, further comprising one or more additional cationic polymers.
54. 54. Hair composition according to one of the preceding statements, further comprising water in an amount of at least 60% by weight based on the total weight of the composition, more suitably in an amount which is from 60 to 95% by weight, for example from 70 to 90 % By weight is sufficient.
55. 55. Hair composition according to one of the preceding statements, further comprising at least one active ingredient selected from the group consisting of plant extracts, bitter substances, humectants, protein hydrolysates, perfumes, UV filters, structuring agents, dyes for coloring the composition, active ingredients such as bisabolol and / or allantoin, antioxidants, preservatives such as sodium benzoate or salicylic acid, additional viscosity regulators such as salts (NaCl) or polymers, and pH regulators.
56. 56. A method of strengthening hair, comprising applying a hair composition according to any one of statements 1 to 55 to the hair.
57. 57. The method of statement 56, wherein the hair composition is applied to the hair immediately prior to an oxidative or surfactant hair treatment.
58. 58. The method of statement 56 or 57, wherein the hair composition is applied directly to the hair during an oxidative or surfactant hair treatment.
59. 59. The method according to statement 56, 57 or 58, wherein the hair composition is applied to the hair directly after an oxidative or surfactant hair treatment.
60. 60. Use of a hair composition according to any one of statements 1 to 55 for strengthening hair.

Examples

The following compositions were prepared and found to impart surprising improvements to the hair in terms of imparting a higher denaturation temperature, increased tensile strength and reduced swelling. Hair shampoo: ingredient % Sodium laureth sulfate 10 Cocamidopropyl betaine 4.0 Ammonium lauryl sulfate 4.0 Hydroxypropyl gluconamide and hydroxypropylammonium pluconate * 0.5 Cocamide MEA 0.8 PEG-7 glyceryl cocoate 1.0 Nicotinamide 0.3 citric acid 0.8 Glutamic acid 0.1 Panthenol 0.5 Sodium chloride 1.3 Water, preservatives, perfume to 100
* available from Ashland as FiberHance ™ bm hair conditioner: ingredient % Quaternium-87 0.75 Glycol distearate 1.0 Cetearyl alcohol 5.0 Hydroxypropyl gluconamide and hydroxypropylammonium pluconate * 1.0 Polyquaternium-37 0.4 Shea butter (INCI: Butyrospermum parkii butter (shea butter)) 1.5 Behenoyl-PG-trimonium chloride 1.5 Distearoyl ethyl hydroxyethyl monium methosulfate 0.3 Behentrimonium chloride 0.4 Lactic acid 0.1 Disodium EDTA 0.05 Arginine 0.3 Water, preservatives, perfume to 100
* available from Ashland as FiberHance ™ bm

QUOTES INCLUDED IN THE DESCRIPTION

This list of the documents listed by the applicant was generated automatically and is included solely for the better information of the reader. The list is not part of the German patent or utility model application. The DPMA assumes no liability for any errors or omissions.

Patent literature cited

• US 2017/0007518 [0013, 0021]

Claims (14)

A hair composition comprising: a) at least one compound having one of the following formulas:

wherein R ₁ to R _{4 are} each independently hydrogen, a hydrocarbon radical having 1 to 10 carbon atoms, a hydroxyl group, an amino group, a sulfhydryl group, an aryl group or a halogen, and R ₅ and R _{6 are} each independently hydrogen, an aliphatic hydrocarbon group, a an alicyclic hydrocarbon group, an aryl group, an alkylaryl group or a heterocyclic group; and wherein R ₁ 'to R ₄ ' are each independently hydrogen, a hydrocarbon radical having 1 to 10 carbon atoms, a hydroxyl group, an amino group, a sulfhydryl group, an aryl group, or a halogen; and R ₅ 'and R ₆ ' are each independently hydrogen, an aliphatic hydrocarbon group, an alicyclic hydrocarbon group, an aryl group, or a heterocyclic group, with the exclusion of R ₅ 'and R ₆ ' being hydrogen at the same time, the aliphatic hydrocarbon group being the alicyclic hydrocarbon group, the aryl group, the alkylaryl group or the heterocyclic group is substituted with at least one hydroxyl group; and b) an amino acid or a salt, ester or acyl derivative thereof. Hair composition according to Claim 1 wherein component a) comprises at least one compound which has the formula (I) and at least one compound which has the formula (II). Hair composition according to Claim 1 or 2 , wherein component a) comprises or consists of a mixture of hydroxypropyl gluconamide and hydroxypropylammonium gluconate. Hair composition according to any one of the preceding claims, wherein component a) is present in an amount ranging from 0.01 to 20.0% by weight based on the total weight of the composition. Hair composition according to one of the preceding claims, wherein the amino acid is selected from alanine, arginine, asparagine, aspartic acid, creatine, cysteic acid, cysteine, cystine, glutamic acid, glutamine, glycine, histidine, hydroxyproline, isoleucine, leucine, lysine, methionine, norleucine, ornithine, phenylalanine , Proline, serine, threonine, tryptophan, tyrosine, valine and mixtures thereof. The hair composition of any preceding claim, wherein the amino acid is selected from arginine, glutamic acid, glycine, histidine and lysine, and mixtures thereof. Hair composition according to one of the preceding claims, wherein component b) consists of arginine, glutamic acid, glycine, histidine or lysine. Hair composition according to any one of the preceding claims, wherein the total amount of component b) ranges from 0.001 to 10.0% by weight based on the total weight of the composition. A hair composition according to any preceding claim which is a hair shampoo. Hair composition according to Claim 9 , further comprising 5.0 to 50.0 wt .-% of at least one anionic, nonionic, amphoteric or zwitterionic surfactant. Hair composition according to one of the Claims 1 until 8th , which is a hair conditioner. Hair composition according to Claim 11 , further comprising 0.1 to 15.0% by weight of at least one cationic surfactant. A method of strengthening hair comprising applying to the hair a hair composition according to any one of Claims 1 until 12th . Use of a hair composition according to one of the Claims 1 until 12th to strengthen hair.