DE102006017315A1 - Aqueous cleaning agent - Google Patents

Abstract

A foamable, surfactant- and solvent-containing aqueous agent, when foamed from a foam dispenser, experiences an increase in volume of at least 300% compared to the unfoamed agent and can be used in appropriate cleaning processes for cleaning hard surfaces, as dishwashing detergent, for pretreating soiled textiles or as carpet cleaning agent.

Description

The The invention relates to a foamable aqueous Agent containing at least one surfactant and at least one water miscible organic solvent contains and when foaming a volume increase of at least 300% from a foam dispenser across from the unfoamed Means learn a product made from this product and a foam dispenser and the Use of this agent for cleaning hard surfaces, for manual dishwashing, for the pretreatment of textiles as well for cleaning carpets and for cleaning hard surfaces, for manual dishwashing, textile pretreatment and carpet cleaning using this agent.

at In various applications, it is desirable to have a surfactant-containing To obtain means in the form of a foam. For example for hand dishwashing detergents the foam height by the consumer as an essential feature of particularly good efficacy considered; the consumer usually sees the foam as the effective part of the rinsing liquor at. Also with other cleaners for hard surfaces, for example in glass cleaners, a consumer foam is considered special powerful classified, especially on vertical surfaces often than longer is perceived as attached. But also carpet cleaner or textile pretreatment agent in the form of a foam are appreciated by the consumer. It is therefore advantageous if such surfactant-containing agents directly be donated as a foam.

A Difficulty that occurs when a surfactant-containing agent as Foam are used and accordingly with a suitable Device foams is to be, is often too high viscosity of the agent. For common pump foam dispensers becomes the inflowing Air in the mixing chamber with the sucked through the riser Detergent swirled so that a foam is formed. The turbulence and thus the foaming is at too high viscosities, however worsened or even prevented. In addition, the promotion of the agent at higher viscosities difficult. If foams can be generated they are mostly compact and of a firmer consistency.

Either when cleaning hard surfaces, especially during manual dishwashing, as well as during the pre-cleaning of textiles or in carpet cleaning, the replacement is particular greasy soiling is a further problem since common surfactant compositions often show insufficient soil penetration.

It It was therefore an object of this invention to provide a surfactant-containing aqueous To formulate detergent, which is foamable and good soil penetration, especially in greasy soils.

It has now been found that the addition of water-soluble or water-miscible organic solvent to corresponding surfactant-containing compositions due to associated viscosity reduction a better foamability cause. At the same time the foams obtained are better able to solve greasy soiling than conventional ones Medium. When foaming with a foam dispenser, in particular with a pump foam dispenser, are also becoming coarser, looser foams with big, Volume obtained by the consumer already because of the perceived Foam amount can be felt to be particularly effective.

object The present invention therefore provides a foamable aqueous agent which is at least a surfactant and at least one water-miscible organic solvent contains and when foaming from a foam dispenser an increase in volume by at least 300% compared to unfoamed Means experiences.

In a particularly advantageous embodiment undergoes the Agent during foaming an increase in volume of at least 400%, more preferably 600 up to 800%.

The inventive agent is especially suitable for use in a foam dispenser. Another The subject of this application is therefore a product made from an agent according to the invention and a foam dispenser.

Further Subject Matter refer to the use of the agent according to the invention for Cleaning hard surfaces, for manual dishwashing, for pre-treating soiled textiles and for cleaning carpets as well as appropriate cleaning procedures.

in the The present invention relates to fatty acids or fatty alcohols or their derivatives - insofar not stated otherwise - representative for branched or unbranched carboxylic acids or alcohols or their derivatives having preferably 6 to 22 carbon atoms. The former are particular because of their vegetable base than on renewable raw materials based on ecological reasons, but without the teaching of the invention to limit to them. In particular, the example according to the ROLENSChen oxo synthesis available Oxo alcohols or their derivatives can be used accordingly.

When always in the following alkaline earth metals as counterions for monovalent Anions are called, so that means that the alkaline earth metal Naturally only in the half - to Charge balance sufficient - amount of substance as the anion is present.

Substances which also serve as ingredients of cosmetic products are hereinafter referred to as appropriate according to the International Nomenclature Cosmetic Ingredient (INCI) nomenclature. Chemical compounds carry an INCI name in English, and plant ingredients are listed exclusively in Linnaeus in Latin. So-called trivial names such as "water", "honey" or "sea salt" are also given in Latin. The INCI names are "International Cosmetic Ingredient Dictionary and Handbook Seventh Edition (1997)" refer to, by The Cosmetic, Toiletry and Fragrance Association (CTFA), 1101 17 ^th Street NW, Suite 300, Washington, DC 20036 , USA, and contains more than 9,000 INCI names, as well as references to more than 37,000 trade names and technical names, including distributors from over 31 countries. The International Cosmetic Ingredient Dictionary and Handbook associates the ingredients with one or more chemical classes, such as "Polymeric Ethers," and one or more functions, such as "surfactants-cleansing agents," which it further details , Where appropriate, reference will also be made hereinafter.

The Specification CAS means that it is the following sequence of numbers is a name of the Chemical Abstracts Service.

So far not explicitly stated otherwise, refer to indicated quantities in weight percent (wt.%) on the total agent. Refer to these percentage quantities are based on active contents.

surfactants

The inventive agent contains Surfactants in a total amount of usually 12 to 70% by weight, preferably 15 to 55 wt .-%, in particular 17 to 45 wt .-%.

Next Alkyl ether sulfates, alkyl sulfonates and betaines can be the agent according to the invention, in particular for improving the cleaning effect, drainage behavior and / or drying behavior, additionally one or more others anionic surfactants, amphoteric surfactants, nonionic surfactants and / or contain cationic surfactants.

The Alkyl ether sulfates and alkyl sulfonates and the other anionic Surfactants are commonly referred to as Alkali metal, alkaline earth metal and / or mono-, di- or trialkanolammonium salt and / or in the form of their with the corresponding alkali metal hydroxide, Alkaline earth metal hydroxide and / or mono-, di- or trialkanolamine used in situ to be neutralized corresponding acid. Preferred alkali metals here are potassium and in particular Sodium, as alkaline earth metals calcium and especially magnesium, as well as alkanolamines mono-, di- or triethanolamine. Especially preferred are the sodium salts.

alkyl ether

Alkyl ether sulfates (fatty alcohol ether sulfates, INCI alkyl ether sulfates) are products of sulfation reactions on alkoxylated alcohols. The person skilled in the art generally understands by alkoxylated alcohols the reaction products of alkylene oxide, preferably ethylene oxide, with alcohols, for the purposes of the present invention preferably with longer-chain alcohols, ie with aliphatic straight-chain or mono- or multi-branched, acyclic or cyclic, saturated or one or more unsaturated, preferably straight-chain, acyclic, saturated, alcohols having 6 to 22, preferably 8 to 18, in particular 10 to 16 and particularly preferably 12 to 14 carbon atoms. In general, from n moles of ethylene oxide and one mole of alcohol, depending on the reaction conditions, a complex mixture of addition products of different degrees of ethoxylation (n = 1 to 30, preferably 1 to 20, especially 1 to 10, particularly preferably 2 to 4). Another embodiment of the alkoxylation is the use of mixtures the alkylene oxides, preferably the mixture of ethylene oxide and propylene oxide. Very particularly preferred for the purposes of the present invention are low-ethoxylated fatty alcohols having 1 to 4 ethylene oxide units (EO), in particular 1 to 2 EO, for example 2 EO, such as Na-C _12-14 fatty alcohol + 2EO sulfate.

The inventive agent contains in a preferred embodiment one or more alkyl ether sulfates in an amount of 10 to 40 Wt .-%, preferably more than 13 to 35 wt .-%, in particular 15 to 30% by weight.

alkylsulfonates

The Alkyl sulfonates (INCI Sulfonic Acids) usually have an aliphatic straight-chain or mono- or polysubstituted, acyclic or cyclic, saturated or mono- or polyunsaturated, preferably branched, acyclic, saturated, alkyl radical having 6 to 22, preferably 9 to 20, especially 11 to 18 and especially preferably 13 to 17 carbon atoms.

suitable Accordingly, alkylsulfonates are the saturated alkanesulfonates unsaturated olefin sulfonates and the - himself formally derived from the alkyl ether sulfates underlying alkoxylated Alcohols - Ethersulfonates, where you are terminal Ether sulfonates (n-ether sulfonates) with bound to the polyether chain Sulfonate function and internal Ether sulfonates (i-ether sulfonates) with sulfonate function linked to the alkyl radical.

Preference according to the invention is given to the alkanesulfonates, in particular alkanesulfonates having a branched, preferably secondary, alkyl radical, for example the secondary alkanesulfonate sec. Na C _13-17 alkanesulfonate (INCI Sodium C14-17 Alkyl Sec Sulfonate).

The inventive agent contains one or more sec. Alkyl sulfonates in an amount of usually 1 to 20 wt .-%, preferably 3 to 12 wt .-%, in particular 4 to 8% by weight.

Betaine

Suitable betaines are the alkylbetaines, the alkylamidobetaines, the imidazolinium betaines, the sulfobetaines (INCI Sultaines) and the phosphobetaines and preferably satisfy formula I, R 1 - [CO-X- (CH 2 ) n ] x -N + (R 2 ) (R 3 ) - (CH 2 ) m - [CH (OH) -CH 2 ] y -Y - (I) in which R ¹ is a saturated or unsaturated C _6-22 alkyl, preferably C _8-18 alkyl group, preferably a saturated C _10-16 alkyl group, for example a saturated C _12-14 alkyl group,
X is NH, NR ⁴ with the C _1-4 -alkyl radical R ⁴ , O or S,
n is a number from 1 to 10, preferably 2 to 5, in particular 3,
x is 0 or 1, preferably 1,
R ² , R ³ independently of one another represent a C _1-4 -alkyl radical, optionally hydroxy-substituted, for example a hydroxyethyl radical, but in particular a methyl radical,
m is a number from 1 to 4, in particular 1, 2 or 3,
y is 0 or 1 and
Y is COO, SO ₃ , OPO (OR ⁵ ) O or P (O) (OR ⁵ ) O, wherein R ^{5 is} a hydrogen atom H or a C _1-4 alkyl radical.

The alkyl and alkylamido betaines, betaines of the formula I having a carboxylate group (Y ^- = COO ^- ) are also called carbobetaines.

Preferred betaines are the alkylbetaines of the formula (Ia), the alkylamidobetaines of the formula (Ib), the sulfobetaines of the formula (Ic) and the amidosulfobetaines of the formula (Id), R ¹ -N ⁺ (CH ₃ ) ₂ -CH ₂ COO ^- (Ia) R ¹ -CO-NH- (CH ₂ ) ₃ -N ⁺ (CH ₃ ) ₂ -CH ₂ COO ^- (Ib) R ^{1 is} -N ⁺ (CH ₃ ) ₂ -CH ₂ CH (OH) CH ₂ SO ₃ ^- (Ic) R ¹ -CO-NH- (CH ₂ ) ₃ -N ⁺ (CH ₃ ) ₂ -CH ₂ CH (OH) CH ₂ SO ₃ ^- (Id) in which R ^{1 has} the same meaning as in formula I.

Especially preferred betaines are the carbobetaines, in particular the carbobetaines of the formula (Ia) and (Ib), extremely preferred the alkylamidobetaines of the formula (Ib).

Examples suitable betaines and sulfobetaines are the following named according to INCI Compounds: Almondamidopropyl Betaine, Apricotamidopropyl Betaine, Avocadamidopropyl Betaine, Babassuamidopropyl Betaine, Behenamidopropyl Betaines, behenyl betaines, betaines, canolamidopropyl betaines, caprylic / capramidopropyl Betaines, carnitines, cetyl betaines, cocamidoethyl betaines, cocamidopropyl Betaine, Cocamidopropyl Hydroxysultaine, Coco-Betaine, Coco Hydroxysultaine, Coco / Oleamidopropyl Betaine, Coco-Sultaine, Decyl Betaine, Dihydroxyethyl Oleyl Glycinate, Dihydroxyethyl Soy Glycinate, Dihydroxyethyl Stearyl Glycinate, Dihydroxyethyl Tallow Glycinate, Dimethicone Propyl PG Betaine, Erucamidopropyl Hydroxysultaine, Hydrogenated Tallow Betaine, Isostearamidopropyl Betaine, Lauramidopropyl Betaine, Lauryl Betaine, Lauryl Hydroxysultaine, Lauryl Sultaine, Milkamidopropyl Betaine, Minkamidopropyl Betaine, Myristamidopropyl betaine, myristyl betaine, oleamidopropyl betaine, Oleamidopropyl Hydroxysultaine, Oleyl Betaine, Olivamidopropyl Betaine, Palmamidopropyl Betaine, Palmitamidopropyl Betaine, Palmitoyl Carnitine, Palm Kernelamidopropyl Betaine, Polytetrafluoroethylene Acetoxypropyl Betaine, Ricinoleamidopropyl Betaine, Sesamidopropyl Betaine, Soyamidopropyl Betaines, stearamidopropyl betaines, stearyl betaines, tallow amidopropyl Betaine, Tallowamidopropyl Hydroxysultaine, Tallow Betaine, Tallow Dihydroxyethyl betaines, undecylenamidopropyl betaines and wheat germamidopropyl Betaine. A preferred betaine is, for example, cocamidopropyl Betaine (cocoamidopropyl betaine).

The inventive agent contains one or more betaines in an amount of usually 1 to 15% by weight, preferably 3 to 10 wt .-%, in particular 4 to 8 wt .-%.

The in the agent according to the invention contained surfactants a) alkyl ether sulfate, b) secondary alkanesulfonate and c) betaine, are preferably in a ratio a): b): c) from 5: 2: 1 to 2: 1: 1 available.

solvent

Of the Water content of the aqueous according to the invention Mean is usually 15 to 83 wt .-%, preferably 20 to 80 wt .-%, in particular 30 to 75% by weight.

The inventive agent can advantageously additionally one or more water-soluble organic solvents usually in an amount of 5 to 35% by weight, preferably 7 to 25% by weight, in particular 8 to 20 wt .-%.

The solvent is within the scope of the teaching of the invention as required in particular as hydrotrope and viscosity regulator used. It has a solution-promoting effect especially for Surfactants and electrolyte as well as perfume and dye and so contributes their incorporation at, prevents the formation of liquid-crystalline Phases and contributes to the formation of clear products. The viscosity of the composition according to the invention decreases with increasing amount of solvent. Finally sinks with increasing amount of solvent the Kältetrübungs- and Clear point of the agent according to the invention.

Suitable solvents are, for example, saturated or unsaturated, preferably saturated, branched or unbranched C _1-20 -hydrocarbons, preferably C _2-15 -hydrocarbons, having at least one hydroxy group and optionally one or more ether functions COC, ie the carbon atom chain interrupting oxygen atoms.

Preferred solvents are the - optionally unilaterally etherified with a C _1-6 alkanol - C _2-6 alkylene glycols and poly-C _2-3 alkylene glycol having an average of 1 to 9 identical or different, preferably the same, alkylene glycol groups per molecule as well C _1-6 -alcohols, preferably ethanol, n-propanol or isopropanol, especially ethanol.

Exemplary solvents are the following INCI compounds: alcohol (ethanol), buteth-3, butoxy diglycol, butoxyethanol, butoxyisopropanol, butoxypropanol, n-butyl alcohol, t-butyl alcohol, butylene glycol, butyloctanol, diethylene glycol, dimethoxy diglycol, dimethyl ether, Dipropylene glycol, ethoxydiglycol, ethoxyethanol, ethyl hexanediol, glycol, hexanediol, 1,2,6-hexanetriol, hexyl alcohol, hexylene glycol, isobutoxypropanol, isopentyldiol, isopropyl alcohol (isopropanol), 3-methoxybutanol, methoxydiglycol, methoxyethanol, methoxyisopropanol, Methoxymethylbutanol, Methoxy PEG-10, Methylal, Me methyl alcohol, methyl hexyl ether, methylpropanediol, neopentyl glycol, PEG-4, PEG-6, PEG-7, PEG-8, PEG-9, PEG-6 methyl ether, pentylene glycol, phenoxyethanol, PPG-7, PPG-2 Buteth-3, PPG-2 Butyl Ether, PPG-3 Butyl Ether, PPG-2 Methyl Ether, PPG-3 Methyl Ether, PPG-2 Propyl Ether, Propanediol, Propyl Alcohol (n-Propanol), Propylene Glycol, Propylene Glycol Butyl ether, propylene glycol, propyl ether, tetrahydrofurfuryl alcohol, trimethylhexanol.

Farther preferred are longer chain Polyalkylene glycols, especially polypropylene glycols, such as PPG-400 or PPG-450.

Preferably is the solvent selected from the group comprising methanol, ethanol, propanol, isopropanol, Ethylene glycol, phenoxyethanol, propylene glycol, PPG and mixtures the same.

Most preferred solvents are the C _2-3 alcohols ethanol, n-propanol and / or iso-propanol, especially ethanol, and the polyalkylene glycols, especially polypropylene glycols, especially the PPG-400.

When solubilizers especially for Perfume and dyes can except the solvents described above for example, alkanolamines and alkylbenzenesulfonates with 1 to 3 carbon atoms are used in the alkyl radical.

By the solvent content the flash point of the agent may be 40 ° C or below; preferred embodiments have flame points of 30 ° C up to 35 ° C. Due to the high water content at the same time, however Proper use the agent is no danger.

Water-soluble salts

The inventive agent contains preferably further one or more water-soluble salts. It may be to act in inorganic and / or organic salts, in one preferred embodiment contains the agent thereby at least one inorganic salt.

Usable according to the invention inorganic salts are preferably selected from the group comprising colorless water-soluble halides, sulphates, Sulfites, carbonates, bicarbonates, nitrates, nitrites, phosphates and / or oxides of alkali metals, alkaline earth metals, aluminum and / or the transition metals; Furthermore, ammonium salts can be used. Particularly preferred while halides and sulfates of the alkali metals; is preferred the inorganic salt therefore selected from the group comprising Sodium chloride, potassium chloride, sodium sulfate, potassium sulfate as well Mixtures thereof.

at the inventively usable Organic salts are in particular colorless water-soluble alkali metal, Alkaline earth metal, ammonium, aluminum and / or transition metal salts the carboxylic acids. Preferably, the salts are selected from the group comprising Formate, acetate, propionate, citrate, malate, tartrate, succinate, malonate, Oxalate, lactate and mixtures thereof.

The Cleaning agents according to the invention contains in a preferred embodiment 1 to 20 wt .-%, preferably 1.5 to 15 wt .-%, particularly preferably 2 to 10 wt .-% of at least one water-soluble inorganic and / or 1 to 20 wt .-%, preferably 1.5 to 10 wt .-%, particularly preferably 0.5 to 7 wt .-%, in particular 0.8 to 5 wt .-% of at least one water-soluble organic salt.

The water-soluble Salt is used to set a lower viscosity for detergents for hard surfaces used, which has a high surfactant concentration, in particular a high alkyl ether sulfate concentration. In a procedure to reduce the viscosity highly surfactant-containing, in particular high alkyl ether sulfate-containing Cleaning agent for hard surfaces Accordingly, the agents will have one or more water-soluble salts added.

Other ingredients

In addition to the components mentioned so far, the compositions according to the invention may contain further ingredients. These include, for example, other surfactants, additives for improving the drainage and drying behavior, for adjusting the viscosity, for stabilization and other customary in manual dishwashing detergents and additives, such as hydrotropes, UV stabilizers, pearlescing agents, fragrances, dyes, corrosion inhibitors, preservatives, organic Salts, disinfectants, enzymes, pH adjusters as well as skin feel enhancing or nourishing additives.

Further anionic surfactants

The inventive agent can additionally contain one or more other anionic surfactants, usually in an amount of 0.001 to 5 wt .-%, preferably 0.01 to 4 wt .-%, in particular 0.1 to 3 wt .-%, particularly preferably 0.2 to 2 wt .-%, most preferably 0.5 to 1.5 wt .-%, for example, 1 wt .-%.

suitable Further anionic surfactants are in particular aliphatic sulfates such as fatty alcohol sulfates, monoglyceride sulfates and ester sulfonates (Sulfo fatty acid esters), Lignosulfonates, alkylbenzenesulfonates, fatty acid cyanamides, anionic sulfosuccinic acid surfactants, fatty, Acylaminoalkanesulfonates (fatty acid taurides), fatty acid sarcosinates, ether and alkyl (ether) phosphates.

Suitable further anionic surfactants are also anionic gemini surfactants having a diphenyl oxide basic structure, 2 sulfonate groups and an alkyl radical on one or both benzene rings according to the formula ^- O ₃ S (C ₆ H ₃ R) O (C ₆ H ₃ R ') SO ₃ ^- in which R is an alkyl radical with, for example, 6, 10, 12 or 16 carbon atoms and R 'is R or H (Dowfax ^® Dry hydrotropes Powder with C ₁₆ alkyl radical (s); INCI Sodium Hexyldiphenyl ether sulfonates, Disodium decyl phenyl ether disulfonates, Disodium lauryl phenyl ether disulfonates, Disodium Cetyl phenyl ether disulfonates) and fluorinated anionic surfactants, in particular perfluorinated alkylsulfonates such as ammonium C _9/10 -Perfluoroalkylsulfonat (Fluorad ^® FC 120) and perfluorooctane sulfonic acid potassium salt (Fluorad ^® FC 95 ).

anionic sulfosuccinic

Particularly preferred further anionic surfactants are the anionic sulfosuccinic acid surfactants sulfosuccinates, sulfosuccinamates and sulfosuccinamides, especially sulfosuccinates and sulfosuccinamates, most preferably sulfosuccinates. The sulfosuccinates are the salts of the mono- and diesters of sulfosuccinic acid HOOCCH (SO ₃ H) CH ₂ COOH, while the sulfosuccinamates mean the salts of the monoamides of sulfosuccinic acid and the sulfosuccinamines the salts of the diamides of sulfosuccinic acid. A detailed description of these known anionic surfactants is provided by A. Domsch and B. Irrgang in Anionic surfactants: organic chemistry (edited by HW Stache; Surfactant science series; volume 56; ISBN 0-8247-9394-3; Marcel Dekker, Inc., New York 1996, pp. 501-549).

at the salts are preferably alkali metal salts, ammonium salts as well as mono-, di- or Trialkanolammonium salts, for example mono-, di- or triethanolammonium salts, especially lithium, sodium, potassium or ammonium salts, particularly preferably sodium or ammonium salts, most preferably Sodium salts.

In the sulfosuccinates, one or both carboxyl groups of the sulfosuccinic acid is preferably with one or two identical or different unbranched or branched, saturated or unsaturated, acyclic or cyclic, optionally alkoxylated alcohols having 4 to 22, preferably 6 to 20, in particular 8 to 18 , more preferably 10 to 16, most preferably 12 to 14 carbon atoms esterified. Particularly preferred are the esters of unbranched and / or saturated and / or acyclic and / or alkoxylated alcohols, in particular unbranched, saturated fatty alcohols and / or unbranched, saturated, with ethylene and / or propylene oxide, preferably ethylene oxide, alkoxylated fatty alcohols having a degree of alkoxylation of 1 to 20, preferably 1 to 15, in particular 1 to 10, more preferably 1 to 6, most preferably 1 to 4. The monoesters are preferred in the context of the present invention over the diesters. A particularly preferred sulfosuccinate is Sulfobernsteinsäurelaurylpolyglykolester di-sodium salt (lauryl EO sulfosuccinate, di-sodium salt; INCI Disodium Laureth Sulfosuccinate), for example, as Tego ^® sulfosuccinate F 30 (Goldschmidt) with a sulfosuccinate of 30 parts by weight % is commercially available.

In form the sulfosuccinamates or sulfosuccinamides or form both carboxyl groups of sulfosuccinic acid preferably with a primary or secondary Amin, one or two identical or different, unbranched or branched, saturated or unsaturated, acyclic or cyclic, optionally alkoxylated alkyl radicals with 4 to 22, preferably 6 to 20, especially 8 to 18, especially preferably 10 to 16, most preferably Bears 12 to 14 carbon atoms, a carboxylic acid amide. Particular preference is given to unbranched and / or saturated and / or Acyclic alkyl radicals, in particular unbranched, saturated fatty alkyl radicals.

Also suitable are, for example, the following sulfosuccinates and sulfosuccinamates designated according to INCI: ammonium dinonyl sulfosuccinates, ammonium lauryl sulfosuccinates, diammonium dimethicone copolyol sulfosuccinates, diammonium lauramido-MEA sulfosuccinates, diammonium lauryl sulfosuccinates, diammonium oleamido PEG-2 Sulfosuccinate, Diamyl Sodium Sulfosuccinate, Dicapryl Sodium Sulfosuccinate, Dicyclohexyl Sodium Sulfosuccinate, Diheptyl Sodium Sulfosuccinate, Dihexyl Sodium Sulfosuccinate, Diisobutyl Sodium Sulfosuccinate, Dioctyl Sodium Sulfosuccinate, Disodium Cetearyl Sulfosuccinate, Disodium Cocamido MEA Sulfosuccinate, Disodium Cocamido MIPA Sulfosuccinate, Disodium Cocamido PEG-3 Sulfosuccinate, Disodium Coco-Glucoside Sulfosuccinate, Disodium Cocoyl Butyl Gluceth-10 Sulfosuccinate, Disodium C12-15 Pareth Sulfosuccinate, Disodium Deceth-5 Sulfosuccinate, Disodium Deceth-6 Sulfo Succinate, Disodium Dihydroxyethyl Sulfosuccinyl undecylenate, Disodium Dimethicone Copolyol Sulfosuccinate, Disodium Hydrogenated Cottonseed Glyceride Sulfosuccinate, Disodium Isodecyl Sulfosuccinate, Disodium Isostearamido MEA Sulfosuccinate, Disodium Isostearamido MIPA Sulfosuccinate, Disodium Isostearyl Sulfosuccinate, Disodium Laneth-5 Sulfosuccinate, Disodium Lauramido MEA Sulfosuccinate, Disodium Lauramido PEG-2 Sulfosuccinate, Disodium Lauramido PEG-5 Sulfosuccinate, Disodium Laureth-6 Sulfosuccinate, Disodium Laureth-9 Sulfosuccinate, Disodium Laureth-12 Sulfosuccinate, Disodium Lauryl Sulfosuccinate, Disodium Myristamido MEA Sulfosuccinate, Disodium Nonoxynol-10 Sulfosuccinate, Disodium Oleamido MEA -Sulfosuccinates, Disodium Oleamido MIPA Sulfosuccinates, Disodium Oleamido PEG-2 Sulfosuccinates, Disodium Oleth-3 Sulfosuccinates, Disodium Oleyl Sulfosuccinates, Disodium Palmitamido PEG-2 Sulfosuccinates, Disodium Palmitoleamido PEG-2 Sulfosuccinates, Disodium PEG-4 Cocamido MIPA Sulfo succinate, disodium PEG-5 lauryl citrate sulfosuccinate, disodium PEG-8 palm glycerides sulfosuccinate, disodium ricinoleamido MEA sulfosuccinate, disodium sitostereth-14 sulfosuccinate, disodium stearamido MEA sulfosuccinate, disodium stearyl sulfosuccinamate, disodium stearyl sulfosuccinate, disodium tallamido MEA sulfosuccinate, disodium Tallowamido MEA Sulfosuccinate, Disodium Tallow Sulfosuccinamate, Disodium Tridecyl Sulfosuccinate, Disodium Undecylenamido MEA Sulfosuccinate, Disodium Undecylenamido PEG-2 Sulfosuccinate, Disodium Wheat Germamido MEA Sulfosuccinate, Disodium Wheat Germamido PEG-2 Sulfosuccinate, Di-TEA Oleamido PEG-2 Sulfosuccinate, Ditridecyl Sodium Sulfosuccinate, Sodium Bisglycol Ricinosulfosuccinate, Sodium / MEA Laureth-2 Sulfosuccinate and Tetrasodium Dicarboxyethyl Stearyl Sulfosuccinamate. Yet another suitable sulfosuccinamate is disodium C _16-18 alkoxypropylene sulfosuccinamate.

Preferred anionic sulfosuccinic are imidosuccinate, mono-Na-sulfosuccinic acid diisobutyl ester (Monawet MB ^® 45), mono-Na-sulfosuccinic acid di-octyl ester (Monawet MO-84 ^® R2W, Rewopol SB ^® DO 75), mono-Na sulfosuccinic acid di-tridecyl (Monawet ^® MT 70) Fettalkoholpolyglykolsulfosuccinat-Na-NH ₄ salt (sulfosuccinate S-2), di-sodium sulfosuccinic acid mono-C _12/14 3EO ester (Texapon ^® SB-3), Natruimsulfobernsteinsäurediisooctylester ^(® Texin DOS 75) and di-sodium sulfosuccinic acid mono-C _12/18 ester (Texin 128-P ^®), in particular with the inventive ternary surfactant with respect to the drain and / or drying behavior synergistically acting mono-Na sulfosuccinic acid di-octyl ester.

In a particular embodiment contains the agent of the invention as anionic sulfosuccinic acid surfactants one or more sulfosuccinates, sulfosuccinamates and / or sulfosuccinamides, preferably sulfosuccinates and / or sulfosuccinamates, in particular Sulfosuccinates, in an amount of usually 0.001 to 5 wt .-%, preferably 0.01 to 4 wt .-%, in particular 0.1 to 3 wt .-%, especially preferably 0.2 to 2 wt .-%, most preferably 0.5 to 1.5 wt .-%, for example, 1 wt .-%.

Other amphoteric surfactants

To the amphoteric surfactants (amphoteric surfactants, zwitterionic surfactants), the invention used can be counting Alkylamidoalkylamines, alkyl-substituted amino acids, acylated amino acids or Biosurfactants, of which the betaines are within the scope of the teaching of the invention to be favoured.

alkylamidoalkylamines

The alkylamidoalkylamines (INCI alkylamido alkylamines) are amphoteric surfactants of the formula (III) R ⁹ -CO-NR ¹⁰ - (CH ₂ ) _i -N (R ¹¹ ) - (CH ₂ CH ₂ O) _j - (CH ₂ ) _k - [CH (OH)] _l -CH ₂ -Z-OM ( III) in which R ⁹ is a saturated or unsaturated C _6-22 alkyl, preferably C _8-18 alkyl group, preferably a saturated C _10-16 alkyl group, for example a saturated C _12-14 alkyl group,
R ^{10 is} a hydrogen atom H or a C _1-4 -alkyl radical, preferably H,
i is a number from 1 to 10, preferably 2 to 5, in particular 2 or 3,
R ^{11 is} a hydrogen atom H or CH ₂ COOM (to M su),
j is a number from 1 to 4, preferably 1 or 2, in particular 1,
k is a number from 0 to 4, preferably 0 or 1,
l is 0 or 1, where k = 1 when l = 1,
Z is CO, SO ₂ , OPO (OR ¹² ) or P (O) (OR ¹² ), wherein R ^{12 is} a C _1-4 alkyl radical or M (su), and
M is a hydrogen, an alkali metal, an alkaline earth metal or a protonated alkanolamine, for example protonated mono-, di- or triethanolamine.

Preferred representatives satisfy the formulas IIIa to IIId, R ⁹ -CO-NH- (CH ₂ ) ₂ -N (R ¹¹ ) -CH ₂ CH ₂ O-CH ₂ -COOM (IIIa) R ⁹ -CO-NH- (CH ₂ ) ₂ -N (R ¹¹ ) -CH ₂ CH ₂ O-CH ₂ CH ₂ -COOM (IIIb) R ⁹ -CO-NH- (CH ₂ ) ₂ -N (R ¹¹ ) -CH ₂ CH ₂ O-CH ₂ CH (OH) CH ₂ -SO ₃ M (IIIc) R ⁹ -CO-NH- (CH ₂ ) ₂ -N (R ¹¹ ) -CH ₂ CH ₂ O-CH ₂ CH (OH) CH ₂ -OPO ₃ HM (IIId) in which R ¹¹ and M have the same meaning as in formula (III).

exemplary Alkylamidoalkylamines are the following compounds named according to INCI: Cocoamphidipropionic acid, cocobetainamido amphopropionate, DEA-cocoamphodipropionate, Disodium caproamphodiacetate, disodium caproamphodipropionate, disodium Capryloamphodiacetate, Disodium Capryloamphodipropionate, Disodium Cocoamphocarboxyethylhydroxypropylsulfonates, Disodium Cocoamphodiacetate, Disodium Cocoamphodipropionate, Disodium Isostearoamphodiacetate, Disodium isostearoamphodipropionate, disodium laureth-5 carboxyamphodiacetate, Disodium lauroamphodiacetate, disodium lauroamphodipropionate, disodium Oleoamphodipropionate, disodium PPG-2-isodeceth-7 carboxyamphodiacetate, disodium Stearoamphodiacetate, Disodium Tallowamphodiacetate, Disodium Wheatgermamphodiacetate, Lauroamphodipropionic Acid, Quaternium-85, Sodium Caproamphoacetate, Sodium Caproamphohydroxypropylsulfonate, Sodium Caproamphopropionate, Sodium Capryloamphoacetate, Sodium Capryloamphohydroxypropyl sulfonates, sodium capryloamphopropionate, Sodium Cocoamphoacetate, Sodium Cocoamphohydroxypropylsulfonate, Sodium Cocoamphopropionate, Sodium Cornamphopropionate, Sodium Isostearoamphoacetate, Sodium isostearoamphopropionate, sodium lauroamphoacetate, sodium Lauroamphohydroxypropylsulfonates, Sodium Lauroampho PG-Acetate Phosphates, Sodium Lauroamphopropionate, Sodium Myristoamphoacetate, Sodium Oleoamphoacetate, Sodium Oleoamphohydroxypropylsulfonate, Sodium Oleoamphopropionate, Sodium Ricinoleoamphoacetate, Sodium Stearoamphoacetate, Sodium Stearoamphohydroxypropylsulfonate, Sodium Stearoamphopropionate, Sodium Tallamphopropionate, Sodium Tallowamphoacetate, Sodium Undecylenoamphoacetate, Sodium Undecylenoamphopropionate, Sodium Wheat Germamphoacetate and Trisodium Lauroampho PG Acetates Chloride phosphates.

alkyl amino acids

Preferred alkyl-substituted amino acids (INCI alkyl-substituted amino acids) according to the invention are monoalkyl-substituted amino acids according to formula (IV), R ¹³ -NH-CH (R ¹⁴ ) - (CH ₂ ) _u -COOM '(IV) in which R ¹³ is a saturated or unsaturated C _6-22 alkyl, preferably C _8-18 alkyl group, preferably a saturated C _10-16 alkyl group, for example a saturated C _12-14 alkyl group,
R ^{14 is} a hydrogen atom H or a C _1-4 -alkyl radical, preferably H,
u is a number from 0 to 4, preferably 0 or 1, in particular 1, and
M 'is a hydrogen, an alkali metal, an alkaline earth metal or a protonated alkanolamine, for example protonated mono-, di- or triethanolamine,
alkyl-substituted imino acids according to formula (V), R ¹⁵ -N - [(CH ₂ ) _v -COOM ''] ₂ (V) in which R ¹⁵ represents a saturated or unsaturated C _6-22 alkyl, preferably C _8-18 alkyl group, preferably a saturated C _10-16 alkyl group, for example a saturated C _12-14 alkyl group,
v is a number from 1 to 5, preferably 2 or 3, in particular 2, and
M '' is a hydrogen, an alkali metal, an alkaline earth metal or a protonated alkanolamine, for example protonated mono-, di- or triethanolamine, where M '' in the two carboxy groups may have the same or two different meanings, for example hydrogen and sodium or twice sodium can be, is
and mono- or dialkyl-substituted natural amino acids according to formula (VI), R ¹⁶ -N (R ¹⁷ ) -CH (R ¹⁸ ) -COOM '''(VI) in which R ¹⁶ is a saturated or unsaturated C _6-22 alkyl, preferably C _8-18 alkyl group, preferably a saturated C _10-16 alkyl group, for example a saturated C _12-14 alkyl group,
R ^{17 is} a hydrogen atom or a C _1-4 -alkyl radical, optionally hydroxyl- or amine-substituted, for example a methyl, ethyl, hydroxyethyl or aminopropyl radical,
R ^{18 is} the residue of one of the 20 natural α-amino acids H ₂ NCH (R ¹⁸ ) COOH, and
M '''is a hydrogen, an alkali metal, an alkaline earth metal or a protonated alkanolamine, for example protonated mono-, di- or triethanolamine.

Particularly preferred alkyl-substituted amino acids are the aminopropionates according to formula (IVa), R ¹³ -NH-CH ₂ CH ₂ COOM '(IVa) in which R ¹³ and M 'have the same meaning as in formula (IV).

exemplary alkyl-substituted amino acids are the following named according to INCI Compounds: Aminopropyl Laurylglutamine, Cocaminobutyric Acid, Cocaminopropionic acid, DEA-lauraminopropionate, disodium cocaminopropyl Iminodiacetate, disodium dicarboxyethyl cocopropylenediamine, disodium lauriminodipropionate, Disodium Steariminodipropionate, Disodium Tallowiminodipropionate, Lauraminopropionic Acid, Lauryl Aminopropylglycine, Lauryl Diethylenediaminoglycine, Myristaminopropionic acid, sodium C12-15 alkoxypropyl iminodipropionate, Sodium Cocaminopropionate, Sodium Lauraminopropionate, Sodium Lauriminodipropionate, Sodium Lauroyl Methylaminopropionate, TEA Lauraminopropionate and TEA Myristaminopropionate.

acylated amino acids

Acylated amino acids are amino acids, in particular the 20 natural α-amino acids which carry on the amino nitrogen the acyl radical R ¹⁹ CO of a saturated or unsaturated fatty acid R ¹⁹ COOH, where R ^{19 is} a saturated or unsaturated C _6-22 alkyl radical, preferably C _8-18 Alkyl, in particular a saturated C _10-16 alkyl radical, for example a saturated C _12-14 alkyl radical. The acylated amino acids can also be used as the alkali metal salt, alkaline earth metal salt or alkanolammonium salt, for example mono-, di- or triethanolammonium salt. Exemplary acylated amino acids are the acyl derivatives summarized in accordance with INCI under Amino Acids, for example sodium cocoyl glutamate, lauroyl glutamic acid, capryloyl glycine or myristoyl methylalanine.

Amphotensidkombinationen

In a particular embodiment The invention will be a combination of two or more different Amphoteric surfactants, in particular a binary Amphotensidkombination used.

The Amphotensidkombination contains preferably at least one betaine, in particular at least one Alkylamidobetaine, more preferably Cocoamidopropylbetaine.

Further, the amphoteric surfactants preferably contains at least one amphoteric surfactant is selected from the group comprising Natriumcarboxyethylkokosphosphoethylimidazolin (Phosphoteric ^® TC- 6), C _8/10 -Amidopropylbetain (INCI caprylic / Capramidopropyl Betaine, Betaine Tego ^® 810), N-2-hydroxyethyl-N-carboxymethyl -fettsäureamido-ethylamine-Na (Rewoteric ^® AMV) and N-caprylic / Caprinamidoethyl-N-ethyl-propionate-Na (Rewoteric AMVSF ^®) and the betaine 3- (3-cocoamidopropyl) dimethylammonium-2-hydroxypropane (INCI sultaines; Rewoteric AM CAS ^®) and the Alkylamidoalkylamin N- [N '(N''-2-hydroxyethyl-N''- carboxyethylaminoethyl) -essigsäureamido] -N, N-dimethyl-N-coco-ammonium betaine (Rewoteric QAM ^® 50), in particular together with cocoamidopropylbetaine.

In a further particular embodiment, the agent according to the invention contains one or more Amphoteric surfactants in an amount of more than 8 wt .-%. In yet another particular embodiment, the agent according to the invention contains one or more amphoteric surfactants in an amount of less than 2% by weight.

nonionic surfactants

The inventive agent can additionally contain one or more nonionic surfactants, usually in an amount of 0.001 to 10% by weight, preferably 0.01 to 8 Wt .-%, in particular 0.1 to 4 wt .-%, particularly preferably 0.2 to 2% by weight.

nonionic Surfactants in the context of the invention are alkoxylates, such as polyglycol ethers, Fatty alcohol polyglycol ethers, alkylphenol polyglycol ethers, end-capped Polyglycol ethers, mixed ethers and hydroxy mixed ethers and fatty acid polyglycol esters. Also suitable are block polymers of ethylene oxide and propylene oxide and fatty acid alkanolamides and fatty acid polyglycol ethers. Important classes of nonionic according to the invention Surfactants are furthermore the amine oxides and the sugar surfactants, in particular the alkyl polyglucosides.

Fettalkoholpolyglykolether

Under Fettalkoholpolyglykolethern according to the invention with ethylene (EO) and / or propylene oxide (PO) alkoxylated, unbranched or branched, saturated or unsaturated C _10-22 alcohols having a degree of alkoxylation up to 30 to understand, preferably ethoxylated C _10-18 fatty alcohols a degree of ethoxylation of less than 30, preferably with a degree of ethoxylation of 1 to 20, in particular from 1 to 12, particularly preferably from 1 to 8, most preferably from 2 to 5, for example C _12-14 fatty alcohol ethoxylates with 2, 3 or 4 EO or a mixture of the C _12-14 fatty alcohol ethoxylates with 3 and 4 EO in the weight ratio of 1 to 1 or isotridecyl alcohol ethoxylate with 5, 8 or 12 EO.

amine oxides

The amine oxides suitable in accordance with the invention include alkylamine oxides, in particular alkyldimethylamine oxides, alkylamidoamine oxides and alkoxyalkylamine oxides. Preferred amine oxides satisfy formula II, R ⁶ R ⁷ R ⁸ N ⁺ -O ^- (II) R ⁶ - [CO-NH- (CH ₂ ) _w ] _z -N ⁺ (R ⁷ ) (R ⁸ ) -O ^- (II) in which R ⁶ is a saturated or unsaturated C _6-22 alkyl, preferably C _8-18 alkyl group, preferably a saturated C _10-16 alkyl group, for example a saturated C _12-14 alkyl group, in the alkylamidoamine oxides over a carbonylamidoalkylene -CO-NH- (CH ₂ ) _z - and in the alkoxyalkylamine oxides via an oxaalkylene group-O- (CH ₂ ) _z - is bonded to the nitrogen atom N, where z is in each case a number from 1 to 10, preferably 2 to 5, in particular 3,
R ⁷ , R ^{8 are} independently of one another a C _1-4 -alkyl radical, if appropriate hydroxy-substituted, for example a hydroxyethyl radical, in particular a methyl radical.

Examples Suitable amine oxides are the following compounds named according to INCI: Almondamidopropylamine Oxide, Babassuamidopropylamine Oxide, Behenamine Oxides, Cocamidopropyl Amine Oxide, Cocamidopropylamine Oxide, Cocamine Oxides, coco-morpholine oxides, decylamines oxides, decyltetradecylamines Oxides, diaminopyrimidine oxides, dihydroxyethyl C8-10 alkoxypropylamines Oxides, dihydroxyethyl C9-11 Alkoxypropylamines oxides, dihydroxyethyl C12-15 alkoxypropylamines oxides, Dihydroxyethyl Cocamine Oxide, Dihydroxyethyl Lauramine Oxide, Dihydroxyethyl Stearamine Oxide, Dihydroxyethyl Tallowamine Oxide, Hydrogenated Palm Kernel Amine Oxide, Hydrogenated Tallowamine Oxide, Hydroxyethyl Hydroxypropyl C12-15 Alkoxypropylamines oxides, isostearamidopropylamines oxides, isostearamidopropyl Morpholine oxides, Lauramidopropylamine oxides, Lauramine oxides, methyl Morpholine Oxide, Milkamidopropyl Amine Oxide, Minkamidopropylamine Oxides, myristamidopropylamine oxides, myristamine oxides, myristyl / cetyl Amine oxides, Oleamidopropylamine oxides, Oleamine oxides, Olivamidopropylamine Oxides, palmitamidopropylamine oxides, palmitamine oxides, PEG-3 lauramines Oxides, Potassium Dihydroxyethyl Cocamine Oxides Phosphate, Potassium Trisphosphonomethylamine oxides, sesamidopropylamine oxides, soyamidopropylamines Oxides, stearamidopropylamines oxides, stearamines oxides, tallow amidopropyl amines Oxides, tallowamine oxides, undecylenamidopropylamine oxides and wheat Germamidopropylamine oxides. A preferred amine oxide is, for example Cocamidopropylamine oxides (cocoamidopropylamine oxide).

sugar surfactants

Sugar surfactants are known surface-active compounds, which include, for example, the sugar surfactant classes of the alkyl glucose esters, aldobionamides, gluconamides (sugar acid amides), glycerolamides, glycerol glycolipids, polyhydroxy fatty acid amide sugar surfactants (sugar amides) and alkyl polyglycosides. Preferred sugar surfactants within the scope of the teaching according to the invention are the alkyl polyglycosides and the sugar amides and their derivatives, in particular their ethers and esters. The ethers are the products of the reaction of one or more, preferably one, sugar hydroxy group with a compound containing one or more hydroxy groups, for example C _1-22 alcohols or glycols such as ethylene and / or propylene glycol, the sugar hydroxy group also being polyethylene glycol - And / or polypropylene glycol can carry. The esters are the reaction products of one or more, preferably one, sugar hydroxy group with a carboxylic acid, in particular a C _6-22 fatty acid.

sugar amides

Particularly preferred sugar amides satisfy the formula R'C (O) N (R '') [Z], in which R 'is a linear or branched, saturated or unsaturated acyl radical, preferably a linear unsaturated acyl radical, with 5 to 21, preferably 5 to 17, in particular 7 to 15, particularly preferably 7 to 13 carbon atoms, R "represents a linear or branched, saturated or unsaturated alkyl radical, preferably a linear unsaturated alkyl radical, having 6 to 22, preferably 6 to 18, in particular 8 to 16, particularly preferably 8 to 14 carbon atoms, a C _1-5 -alkyl radical, in particular a methyl, ethyl, propyl, isopropyl, n-butyl, isobutyl, tert-butyl or n-pentyl radical, or hydrogen and Z represent a sugar residue, ie a monosaccharide residue. Particularly preferred sugar amides are the amides of glucose, the glucamides, for example lauroylmethyl-glucamide.

Alkylpolyglykoside

The alkylpolyglycosides (APG) are particularly preferred sugar surfactants within the scope of the teaching according to the invention and preferably satisfy the general formula R ⁱ O (AO) _a [G] _x in which R ^{i is} a linear or branched, saturated or unsaturated alkyl radical having 6 to 22 , preferably 6 to 18, in particular 8 to 16, particularly preferably 8 to 14 carbon atoms, [G] for a glycosidically linked sugar residue and x for a number from 1 to 10 and AO for an alkyleneoxy group, for example an ethyleneoxy or propyleneoxy group, and a represent the average degree of alkoxylation of 0 to 20. In this case, the group (AO) _{a may} also contain different alkyleneoxy units, for example ethyleneoxy or propyleneoxy units, in which case a is the average total degree of alkoxylation, ie the sum of degree of ethoxylation and degree of propoxylation. Unless otherwise stated below, the alkyl radicals R ^{1 of} the APG are linear unsaturated radicals having the stated number of carbon atoms.

APG are nonionic surfactants and are known substances that according to the relevant Process of preparative organic chemistry can be obtained. The index number x gives the degree of oligomerization (DP degree), i. the distribution of Mono- and oligoglycosides, and stands for a number between 1 and 10. While x must always be an integer in a given connection and here Above all, the values x = 1 to 6 can assume x is the value for a particular Alkyl glycoside an analytically determined arithmetic size, the usually represents a fractional number. Preferably, alkyl glycosides used with a mean degree of oligomerization x of 1.1 to 3.0. From an application point of view, such alkyl glycosides are preferred, whose degree of oligomerization is less than 1.7 and in particular between 1.2 and 1.6. As glycosidic sugar is preferably Xylose, but especially glucose used.

The alkyl or alkenyl radical R ⁱ can be derived from primary alcohols having 8 to 18, preferably 8 to 14 carbon atoms. Typical examples are caproic alcohol, caprylic alcohol, capric alcohol and undecyl alcohol, as well as their technical mixtures, as obtained, for example, in the course of the hydrogenation of technical fatty acid methyl esters or in the course of the hydrogenation of aldehydes from ROLEN's oxosynthesis.

Preferably, however, the alkyl or alkenyl radical R ⁱ is derived from lauryl alcohol, myristyl alcohol, cetyl alcohol, palmoleyl alcohol, stearyl alcohol, isostearyl alcohol or oleyl alcohol. Also to be mentioned are elaidyl alcohol, petroselinyl alcohol, arachidyl alcohol, gadoleyl alcohol, behenyl alcohol, erucyl alcohol and technical mixtures thereof.

Particularly preferred APG are not alkoxylated (a = 0) and satisfy the formula RO [G] _x , in which R is as previously for a linear or branched, saturated or unsaturated alkyl radical having 4 to 22 carbon atoms, [G] for a glycosidically linked sugar radical, preferably glucose radical, and x for a number from 1 to 10, preferably 1.1 to 3, in particular 1.2 to 1.6, stand. Accordingly, preferred alkyl polyglycosides are, for example, C _8-10 and C _12-14 alkyl polyglucoside having a DP degree of 1.4 or 1.5, especially C _8-10 alkyl-1,5-glucoside and C _12-14 alkyl-1,4-glucoside.

cationic surfactants

The inventive agent can additionally one or more cationic surfactants (cationic surfactants, INCI Quaternary Ammonium compounds), usually in an amount of 0.001 to 5 wt .-%, preferably 0.01 to 4 wt .-%, in particular 0.1 to 3 wt .-%, particularly preferably 0.2 to 2 wt .-%, most preferably 0.5 to 1.5 wt .-%, for example, 1 wt .-%.

preferred cationic surfactants are the quaternary surface-active compounds, in particular with an ammonium, sulfonium, phosphonium, iodonium or arsonium group, as, for example, K. H. Wallhäußer in "Praxis der Sterilisation, Desinfektion - Konservierung: Germ Identification - Company Hygiene "(5th ed. - Stuttgart; New York: Thieme, 1995) as antimicrobial agents. Through the use of quaternary surfactants Compounds with antimicrobial activity may be the agent with a antimicrobial effect be designed or its optionally due to other ingredients already existing antimicrobial Effect can be improved.

Particularly preferred cationic surfactants are the quaternary ammonium compounds (QAV, INCI quaternary ammonium compounds) according to the general formula (R ^I ) (R ^II ) (R ^III ) (R ^IV ) N ⁺ X ^- , in which R ^I to R ^{IV are the} same or various C _1-22 -alkyl radicals, C _7-28 -Aralkylreste or heterocyclic radicals, wherein two or in the case of an aromatic inclusion as in pyridine even three radicals together with the nitrogen atom, the heterocycle, for example a pyridinium or Imidazoliniumverbindung form, and represent X ^{- are} halide ions, sulfate ions, hydroxide ions or similar anions. For optimum antimicrobial activity, preferably at least one of the radicals has a chain length of 8 to 18, in particular 12 to 16, carbon atoms.

QAC are tertiary by implementation Amines with alkylating agents, e.g. Methyl chloride, benzyl chloride, Dimethyl sulfate, dodecyl bromide, but also ethylene oxide produced. The alkylation of tertiary Amines with a long alkyl radical and two methyl groups succeed especially easy, also the quaternization of tertiary amines with two long residues and one methyl group can help with Methyl chloride be carried out under mild conditions. Amines, over three are long alkyl radicals or hydroxy-substituted alkyl radicals little reactive and are preferably quaternized with dimethyl sulfate.

Suitable QACs are, for example, benzalkonium chloride (N-alkyl-N, N-dimethylbenzylammonium chloride, CAS No. 8001-54-5), benzalkone B (m, p-dichlorobenzyl-dimethyl-C ₁₂ -alkylammonium chloride, CAS No. 58390-78 -6), benzoxonium chloride (benzyl-dodecyl-bis (2-hydroxyethyl) -ammonium chloride), cetrimonium bromide (N-hexadecyl-N, N-timethyl-ammonium bromide, CAS No. 57-09-0), benzetonium chloride (N, N Dimethyl N- [2- [2- [p- (1,1,3,3-tetramethylbutyl) phenoxy-ethoxy] ethyl] benzyl ammonium chloride, CAS No. 121-54-0), dialkyl dimethyl ammonium chlorides such as di-n-decyl dimethyl ammonium chloride (CAS No. 7173-51-5-5), didecyldimethylammonium bromide (CAS No. 2390-68-3), dioctyldimethylammonium chloride, 1-cetylpyridinium chloride (CAS No. 123-03-5) and thiazoline iodide (CAS No 15764-48-1) and mixtures thereof. Preferred QACs are the benzalkonium chlorides having C ₈ -C ₁₈ -alkyl radicals, in particular C ₁₂ -C ₁₄ -alkyl-benzyl-dimethylammonium chloride. A particularly preferred QAC Kokospentaethoxymethylammoniummethosulfat (INCI PEG-5 Cocomonium Methosulfate; Rewoquat CPEM ^®).

to Avoidance of possible incompatibilities the cationic surfactants with the anionic surfactants present invention be possible most compatible and / or as possible little cationic surfactant used or in a particular embodiment the invention entirely dispensed with cationic surfactants.

additives

to further improvement of the drainage and / or drying behavior can the agent of the invention one or more additives from the group of surfactants, the polymers and builders, usually in an amount from 0.001 to 5 wt .-%, preferably 0.01 to 4 wt .-%, in particular 0.1 to 3 wt .-%, particularly preferably 0.2 to 2 wt .-%, most preferably 0.5 to 1.5 wt .-%, for example, 1 wt .-%.

When Additive suitable surfactants are certain of those already above described amphoteric surfactants, other anionic surfactants, nonionic surfactants and cationic surfactants, which are repeated at this point become. The content of surfactant additives is preferably so to choose, the total surfactant content is in the quantitative ranges set out above.

To Some of the additives listed below are one or more Trade names are given in brackets, among which the respective commercial available is.

As additives suitable amphoteric surfactants are, in particular Natriumcarboxyethylkokosphosphoethylimidazolin (Phosphoteric ^® TC-6), C _8/10 -Amidopropylbetain (INCI caprylic / Capramidopropyl Betaine, Betaine Tego ^® 810), N-2-hydroxyethyl-N-carboxymethyl-ethylamine fettsäureamido-Na (Rewoteric ^® AMV) and N-caprylic / capric amidoethyl-N-ethyl-propionate-Na (Rewoteric AMVSF ^®) and the betaine 3- (3-cocoamido-propyl) dimethylammonium-2-hydroxypropane (INCI Sul taine; Rewoteric ^® AM CAS) and the Alkylamidoalkylamin N- [N '(N''-2-hydroxyethyl-N''- carboxyethylaminoethyl) -essigsäureamido] -N, N-dimethyl-N-coco-ammonium betaine (Rewoteric QAM ^® 50).

Further suitable anionic surfactants which are suitable as additives are, in particular, anionic gemini surfactants having a diphenyl oxide basic structure, 2 sulfonate groups and one alkyl radical on one or both benzene rings according to the formula ^- O ₃ S (C ₆ H ₃ R) O (C ₆ H ₃ R ' ) SO ₃ ^-, in which R is an alkyl radical having, for example, 6, 10, 12 or 16 carbon atoms and R 'is R or H (Dowfax ^® Dry hydrotropes Powder with C ₁₆ alkyl radical (s); INCI Sodium Hexyldiphenyl ether sulfonates, Disodium decyl phenyl ether disulfonates, Disodium lauryl phenyl ether disulfonates, Disodium Cetyl phenyl ether disulfonates) and the fluorinated anionic surfactants ammonium-C _9/10 -Perfluoroalkylsulfonat (Fluorad ^® FC 120), perfluorooctane sulfonic acid potassium salt (Fluorad ^® FC 95) and the sulfosuccinic imidosuccinate, mono-Na-sulfosuccinic acid diisobutyl ester (Monawet ^® MB 45), mono-Na-sulfosuccinic acid di-octyl ester (Monawet ^® MO 84 R2W, Rewopol ^® SB DO 75), mono-Na-sulfosuccinic acid di -tridecylester (Monawet ^® MT 70) Fettalkoholpolyglykolsulfosuccinat-Na-NH ₄ salt (sulfosuccinate S-2), di-Na-sulfosuccinic acid mono-C _12/14 3EO ester (Texapon ^® SB-3), Natruimsulfobernsteinsäurediisooctylester ( Texin DOS 75 ^®) and di-sodium sulfosuccinic acid mono-C _12/18 ester (Texin ^® 128 P).

As additives suitable nonionic surfactants are in particular C ₁₀ dimethyl amine oxide (Ammonyx ^® DO), C _10/14 -fatty alcohol + 1,2PO + 6,4EO (Dehydol ^® 980), C _12/14 -fatty alcohol + 6 EO (Dehydol ^® LS6) , C ₈ fatty alcohol + 1,2PO + 9EO (Dehydol ^® O10), C _16/20 -Guerbetalkohol + 8EO, n-butyl-closed (Dehypon ^® G2084), mixture of several n-butyl-sealed nonionic surfactants and C _{8 / 10} APG (Dehypon ^® Ke 2555) C _8/10 fatty alcohol + 1PO + 22EO- (2-hydroxydecyl) ether (Dehypon Ke ^® 3447), C _12/14 -fatty alcohol + 5EO + 4PO (Dehypon LS 54 ^® G) C _12/14 fatty alcohol + 5EO + 3PO, methyl closed (Dehypon LS ^® 531), C _12/14 -fatty alcohol + 10EO, n-butyl closed (Dehypon LS ^® L 104), C ₁₁ oxo alcohol + 8EO (Genapol ^® UD 088), C ₁₃ oxo alcohol + 8EO (Genapol ^® X 089), C _13/15 fatty alcohol-EO adduct, n-butyl closed (Plurafac LF ^® 221), and alkoxylated fatty alcohol (Tegotens ^® EC 11).

As additives suitable cationic surfactants are particularly compatible with anionic surfactants, cationic surfactants such as quaternary ammonium compounds, for example Kokospentaethoxymethylammoniummethosulfat (INCI PEG-5 Cocomonium Methosulfate; Rewoquat CPEM ^®).

Polymers suitable as additives in particular maleic acid-acrylic acid copolymer, Na salt (Sokalan ^® CP 5), modified polyacrylic acid Na salt are (Sokalan ^® CP 10), modified polycarboxylate Na salt (Sokalan ^® HP 25), polyalkylene oxide, modified heptamethyltrisiloxane (Silwet ^® L-77), polyalkylene oxide-modified heptamethyltrisiloxane (Silwet ^® L-7608) and polyether (copolymers of polydimethylsiloxanes having ethylene oxide / propylene oxide segments (polyether)), preferably water-soluble linear polyether having terminal polyether as Tegopren ^® 5840, Tegopren ^® 5843, Tegopren ^® 5847, Tegopren ^® 5851, Tegopren ^® 5863 or Tegopren ^® 5878.

As additives suitable builders are, in particular polyaspartic acid-Na-salt, Ethylendiamintriacetatkokosalkylacetamid (Rewopol ^® CHT 12), methylglycine-Tri-Na-salt (Trilon ES ^® 9964) and acetophosphonic (Turpinal SL ^®).

Blends with surfactant or polymeric additives show in the case of Monawet MO-84 ^® R2W, Tegopren ^® 5843 and Tegopren 5863 ^® synergism. However, the use of Tegopren grades 5843 and 5863 is less preferred when applied to hard surfaces of glass, especially glassware, since these can apply silicone surfactants to glass.

In a particular embodiment The invention dispenses with the stated additives.

viscosity

The viscosity which is favorable for the composition according to the invention is 20 ° C. and a shear rate of 30 min ^-1 - measured with a Brookfield LV DV II viscometer and spindle 31 - in the range from 5 to 200 mPa · s, preferably 10 to 100 mPa · S, in particular 15 to 80 mPa · s, more preferably 20 to 70 mPa · s.

The viscosity the agent according to the invention can - in particular at a low surfactant content of the agent - increased by thickening agents and / or - in particular at a high surfactant content of the agent - by the optionally contained water-soluble inorganic salts and can be reduced by solvents.

thickener

to Thickening, the inventive composition additionally or more polymeric thickening agents.

polymers Thickening agents in the context of the present invention are as Polyelectrolytes thickening polycarboxylates, preferably Homo- and copolymers of acrylic acid, especially acrylic acid copolymers such as acrylic acid-methacrylic acid copolymers, and the polysaccharides, in particular heteropolysaccharides, as well as other usual thickening polymers.

suitable Polysaccharides or heteropolysaccharides are the polysaccharide gums, For example, gum arabic, agar, alginates, carrageenans and their Salts, Guar, Guaran, Tragacant, Gellan, Ramsan, Dextran or Xanthan and their derivatives, e.g. propoxylated guar, as well as their mixtures. Other polysaccharide thickeners, such as starches or cellulose derivatives, can alternatively, but preferably in addition to a polysaccharide gum used, for example, strengths of different origin and starch derivatives, e.g. hydroxyethyl starch, Stärkephosphatester or starch acetates, or carboxymethylcellulose or its sodium salt, methyl, ethyl, Hydroxyethyl, hydroxypropyl, hydroxypropyl methyl or hydroxyethyl methyl cellulose or cellulose acetate.

A preferred polymeric thickener is the microbial anionic heteropolysaccharide xanthan gum, the conditions of Xanthomonas campestris and some other species under aerobic Be having a molecular weight of 2-15 x 10 ⁶ is produced and, for example, by the company. Kelco under the trade name Keltrol ^® eg as cream-colored powder Keltrol ^® T (transparent) or as white granules Keltrol ^® RD (Readily Dispersable).

Acrylic acid polymers suitable as polymeric thickeners are, for example, high molecular weight homopolymers of acrylic acid crosslinked with a polyalkenyl polyether, in particular an allyl ether of sucrose, pentaerythritol or propylene (INCI Carbomer), which are also referred to as carboxyvinyl polymers. Such polyacrylic acids are obtainable inter alia from Fa. BFGoodrich under the tradename Carbopol ^®, such as Carbopol ^® 940 (molecular weight about 4,000,000), Carbopol ^® 941 (molecular weight approximately 1,250,000) or Carbopol ^® 934 (molecular weight approximately 3,000. 000).

However, particularly suitable polymeric thickeners are the following acrylic acid copolymers: (i) Copolymers of two or more monomers from the group of acrylic acid, methacrylic acid and their simple, preferably with C _1-4 alkanols formed esters (INCI acrylates copolymer), to which example, the copolymers of methacrylic acid, butyl acrylate and methyl methacrylate (CAS 25035-69-2) or of butyl acrylate and methyl methacrylate (CAS 25852-37-3) and available, for example from Messrs. Rohm & Haas under the trade names Aculyn ^® and Acusol ^® are, for example, the anionic non-associative polymers Aculyn ^® 33 (crosslinked), Acusol ^® 810 and Acusol ^® 830 (CAS 25852-37-3); (ii) crosslinked high molecular weight acrylic acid copolymers, such as those crosslinked with an allyl ether of sucrose or pentaerythritol copolymers of C _10-30 alkyl acrylates with one or more monomers selected from the group of acrylic acid, methacrylic acid and their simple, preferably with C _1-4 alkanols formed, esters (INCI acrylates / -C10-30 alkyl acrylate Crosspolymer) and which are for example available from the company. BFGoodrich under the tradename Carbopol ^®, for example hydrophobized Carbopol ^® and ETD2623 Carbopol ^® 1382 (INCI acrylates / C10 30 alkyl acrylate Crosspolymer) and Carbopol AQUA ^® 30 (formerly Carbopol ^® EX 473).

Of the Content of polymeric thickener is preferably between 0.01 and 4 wt .-%, particularly preferably between 0.1 and 2 wt .-%, in particular between 0.5 and 1.5 wt .-%.

In a preferred embodiment However, according to the invention, the agent is free of polymeric thickeners.

Dicarboxylic acids (salts)

To stabilize the composition of the invention, particularly at high surfactant content, one or more dicarboxylic acids and / or salts thereof may be added, in particular a composition of Na salts of adipic, succinic and glutaric acid, for example as available under the trade name Sokalan ^® DSC is. The use is advantageously carried out in amounts of 0.1 to 8 wt .-%, preferably 0.5 to 7 wt .-%, in particular 1.3 to 6 wt .-% and particularly preferably 2 to 4 wt .-%.

A change of the dicarboxylic acid (salt) content can - in particular in amounts above 2 wt .-% - too a clear solution contribute to the ingredients. Also within certain limits an influence on the viscosity the mixture by this means possible. Furthermore influenced this component is the solubility the mixture. This component is particularly preferred at high Tensidgehalten used, especially at Tensidgehalten above 30% by weight.

can However, they are dispensed with their use, so the agent of the invention preferably free from dicarboxylic acid (salts) n.

Auxiliary and additives

In addition, one or more further - in particular in hand dishwashing detergents and cleaners for hard surfaces - conventional auxiliaries and additives, especially hydrotropes, such as xylene or cumene sulfonate, octyl sulfate, butyl glucoside or butyl glycol, UV stabilizers, perfume, pearlescing agents (INCI Opacifying Agents ;.., for example glycol distearate, for example Cutina ^® AGS from Cognis, or mixtures comprising, for example, the Euperlane ^® Cognis), dyes, corrosion inhibitors, preservatives (for example, the technical also referred to as Bronopol 2-bromo-2-nitropropane 1,3-diol (CAS 52-51-7) which is commercially available for example as Myacide ^® BT or BT as Boots Bronopol from Boots), organic salts, disinfectants, enzymes, pH-adjusting agents and skin feel-improving or caring Additives (eg dermatologically active substances such as vitamin A, vitamin B2, vitamin B12, vitamin C, vitamin E, D-panthenol, sericin, collage n-partial hydrolyzate, various vegetable protein partial hydrolysates, protein hydrolyzate-fatty acid condensates, liposomes, cholesterol, vegetable and animal oils such as lecithin, soybean oil, etc., plant extracts such as aloe vera, azulene, witch hazel extracts, algae extracts, etc , Allantoin, AHA complexes) in amounts of usually not more than 5% by weight.

PH value

Of the pH of the agent according to the invention can by means of usual pH regulators, for example acids like mineral acids or citric acid and / or alkalis such as sodium or potassium hydroxide, in particular at desired Hand compatibility - one area from 4 to 9, preferably 5 to 8, in particular 5.5 to 7.5, preferred is.

For adjusting and / or stabilizing the pH, the agent according to the invention may contain one or more buffer substances (INCI Buffering Agents), usually in amounts of 0.001 to 5 wt .-%, preferably 0.005 to 3 wt .-%, in particular 0 , 01 to 2 wt .-%, particularly preferably 0.05 to 1 wt .-%, most preferably 0.1 to 0.5 wt .-%, for example, 0.2 wt .-%. Preference is given to buffer substances which are at the same time complexing agents or even chelating agents (INCI chelating agents). Particularly preferred buffer substances are the citric acid or the citrates, in particular the sodium and potassium citrates, for example trisodium citrate.2H ₂ O and tripotassium citrate H ₂ O.

manufacturing

The inventive agent let yourself by stirring together make the individual components in any order. The order of approach is for the preparation of the agent is not critical.

Preferably, in this case, water, surfactants and optionally further of the aforementioned In held together. If perfume and / or dye are used, then their addition to the resulting solution. Subsequently, the pH is adjusted as described above.

product

For use, the composition according to the invention in the form of a foam should be applied either directly to the surface to be cleaned or on a sponge, a cloth, a brush or another, optionally moistened, cleaning aid. For generating foam in a special way, a manually activated spray dispenser, in particular selected from the group comprising aerosol spray dispenser, self-pressure spray dispenser, pump spray dispenser and trigger spray dispensers, in particular pump foam dispenser, as for example from the company Airspray, the company Taplast, the company Keltec or the Daiwa Can Company. In addition to trigger bottles, pump spray dispensers and trigger spray dispensers with a polyethylene, polypropylene or polyethylene terephthalate container are also suitable. Such trigger bottles are offered for example by the company Afa-Polytec. The spray head is preferably equipped with a foam nozzle. In addition, the agent can also be filled with the addition of a suitable propellant (eg n-butane, a propane / butane mixture, carbon dioxide, nitrogen or a CO ₂ / N ₂ mixture) in a corresponding aerosol spray bottle. However, such a spray dispenser is less preferred.

One Another subject of the invention is accordingly a product from an aqueous according to the invention Detergent and a foam dispenser, in particular from a aqueous according to the invention Detergent and a pump foam dispenser.

use

The inventive agent Can be used to clean hard surfaces be used. A further subject of the invention is accordingly the use of an agent or a product according to the invention from the agent according to the invention and a foam dispenser for cleaning hard surfaces.

Farther can the agent of the invention or the product according to the invention as dishwashing detergent, especially for manual dishwashing, are used. Another object of the invention is therefore the use of a agent according to the invention or a product of the agent of the invention and a foam dispenser as dishwashing detergent, especially for manual dishwashing.

A further use is the pretreatment of soiled textiles. Yet another one The subject of the invention is therefore the use of an agent according to the invention or a product of the agent of the invention and a foam dispenser for the pretreatment of soiled textiles.

A fourth use is the cleaning of carpets. Another subject of the invention is therefore the use of an agent or a product according to the invention from the agent according to the invention and a foam dispenser as a carpet cleaner.

cleaning process

The inventive agent Can be used to clean hard surfaces and in particular for manual dishwashing. For this There are two alternative methods of purification in which the frothed Means either first to a cleaning aid, ie a substrate such as a cleaning sponge or a brush, applied and spent with this on the surface to be cleaned or the foam applied directly to the surface to be cleaned before it is distributed and then rinsed off again.

One Another subject of the invention is therefore a method for cleaning hard surfaces, in particular for manual dishwashing consisting of the steps Applying a foamed using a foam dispenser inventive composition on a sponge, a cloth, a brush or another, if necessary moistened, cleaning aid, distribution or trituration on the surface to be cleaned, rinse with water, if necessary draining, if necessary wiping off and Rub dry.

Yet Another subject of the invention is a process for purification hard surfaces, in particular for manual dishwashing consisting of the steps Applying a foamed using a foam dispenser inventive composition on the surface to be cleaned, Distribute or rub on the surface to be cleaned, rinse with Water, if necessary draining, if necessary wiping and dry rubbing.

Farther can the agent of the invention used for the pretreatment of textiles by the foam applied to the stain and optionally rubbed and immediately or after drying in a washing machine given and on usual Way is washed.

One Another subject of the invention is therefore a method for pretreatment of textiles, consisting of the steps applying one with help foamed a foam dispenser agent according to the invention on the staining, if necessary rubbing in, if necessary drying, Insert into a washing machine and carry out a usual Wash program.

The inventive agent can also be used for carpet cleaning, the foam on the applied soiled spot, optionally with a cleaning agent like a brush or a sponge is incorporated and after drying with the vacuum cleaner is removed.

One further subject of the invention is therefore a method for carpet cleaning, consisting of the steps applying one with the help of a foam dispenser frothed agent according to the invention on the polluted area, possibly rubbed in using a sponge, a brush, a cloth or other, optionally moistened cleaning aid, Allow to dry and remove the dried product with the Vacuum cleaner.

embodiments

• a: Sokalan DCS-Na (BASF), Gemisch aus Natriumsalzen der Adipinsäure, Glutarsäure, Bernsteinsäure

Inventive compositions E1 to E8 were prepared, which in addition to water also contained various organic solvents (ethanol, PPG-400). In addition, comparative solvents V1 and V2 free of organic solvents were prepared. The compositions are shown in the table below, all amounts are in wt .-% active material based on the total composition.

• a: Sokalan DCS-Na (BASF), mixture of sodium salts of adipic acid, glutaric acid, succinic acid

With the inventive compositions E1 to E3, the soil penetration of the agent was determined in the form of fat dissolving force. For this purpose, a 1: 1 mixture of lard and sunflower oil was applied in a layer thickness of 200 microns on a steel plate and provided with 1.5 g of the respective foamed cleaning agent. After exposure times of 4, 7, 10 and 15 minutes each of the foam was rinsed with water and the steel plate inspected. Behan on the treated with the inventive compositions E1 and E3 After 4 minutes, an initial soil release was observed, which was already very advanced at E1 after 7 and at E3 after 10 minutes and after 15 minutes was almost complete in both. The E2-treated plate showed a slightly slower soil release, which after 15 minutes was nearly as complete as that of the other two agents after 10 minutes. Thus, the composition according to the invention shows a particularly good soil removal just in front of the stubborn fat known.

analog Experiments were carried out with the inventive compositions E6, E7 and E8 and performed with the Veraleichsmittel V2. Again, the soil release was on a 1: 1 mixture of milk dust (24 hours at room temperature stored). Both agents showed the agents according to the invention after a few minutes, a good soil release, while the solvent-free comparison formulation even after 15 minutes, no dirt release yet.

The Foaming of agents according to the invention was also examined. For this purpose, the exemplary formulations E4 and E5 and the not according to the invention Comparative Example V1 im SITA Foam Tester R-2000 tested. In each case, 50 g of the corresponding agent with 40 ° C warm Water of a hardness from 16 ° d diluted to a volume of 1000 ml and the 40 ° C warm solution Stirred for 60 seconds at 1400 U / min. Immediately afterwards became the foam volume determined. This was the comparison mean V1 only 955 ml, with E4 1040 and with E5 even 1055 ml. The addition of solvents Ethanol (in E4) or PPG-400 (in E5) thus has an improvement the foaming kinetics, measurable in the rapid generation of a larger foam volume causes.

Claims (22)

Foamable aqueous agent, characterized in that it contains at least one surfactant and at least one water-miscible organic solvent and when foaming from a foam dispenser experiences an increase in volume of at least 300% compared to the unsoaked agent. Means according to claim 1, characterized in that it is 5 to 35 wt .-% water-miscible organic solvent contains. Means according to one the claims 1 and 2, characterized in that it comprises a surfactant combination one or more anionic and one or more amphoteric surfactants contains. Means according to claim 3, characterized in that the anionic surfactant is preferably selected from the group comprising alkyl sulfates, alkyl ether sulfates, secondary alkanesulfonates, Monoglyceride sulfates and ester sulfonates (sulfo fatty acid esters), Lignosulfonates, alkylbenzenesulfonates, fatty acid cyanamides, anionic sulfosuccinic acid surfactants, fatty, Acylaminoalkanesulfonates (fatty acid taurides), fatty acid sarcosinates, ether and alkyl (ether) phosphates and mixtures thereof Means according to one the claims 3 and 4, characterized in that the anionic surfactant is an alkyl ether sulfate and / or an alkyl sulfate and / or a secondary alkanesulfonate and / or an alkylbenzenesulfonate is included. Means according to one the claims 3 to 5, characterized in that it is one or more anionic surfactant Alkyl ether sulfates and / or one or more secondary alkanesulfonates contains. Means according to one the claims 3 to 6, characterized in that it is a betaine as amphoteric surfactant contains. Means according to one the preceding claims, characterized in that the water-miscible organic solvent preferably selected is from the group comprising alcohols, glycols, glycol ethers, polyalkylene glycol ethers and mixtures thereof. Means according to claim 8, characterized in that the water-miscible organic solvent preferably selected is from the group comprising methanol, ethanol, propanol, isopropanol, ethylene glycol, Butyl glycol, propylene glycol, ethylene glycol propyl ether, propylene glycol butyl ether, Propylene glycol propyl ether, polyethylene glycol, polypropylene glycol, and mixtures thereof, particularly preferably ethanol and / or polypropylene glycol, among the polypropylene glycols, the PPG-400 is particularly preferred. Means according to one the preceding claims, characterized in that it contains perfume oil in quantities of 0.1 to 10 Wt .-% contains. Means according to one the preceding claims, characterized in that it further comprises one or more inorganic and / or organic salts. Means according to claim 11, characterized in that the or the inorganic and / or organic salts are preferably selected from the group comprising colorless water-soluble Halides, sulfates, sulfites, carbonates, bicarbonates, nitrates, Nitrites, phosphates and / or oxides of alkali metals, alkaline earth metals, of aluminum and / or transition metals and ammonium salts, colorless water-soluble alkali metal, alkaline earth metal, Ammonium, aluminum and / or transition metal salts the carboxylic acids, especially those selected from the group comprising formate, acetate, propionate, citrate, malate, Tartrate, succinate, malonate, oxalate, lactate and mixtures thereof. Means according to one the preceding claims, characterized in that it comprises one or more further components contains preferably selected from the group comprising surfactants, additives, thickeners, hydrotropes, UV stabilizers, perfume, Pearlescing agents, dyes, corrosion inhibitors, preservatives, Disinfectants, enzymes, pH adjusters and mixtures thereof. Product of an agent according to one of claims 1 to 13 and a foam dispenser. Use of an agent according to one of claims 1 to 13 or a product according to claim 14 for cleaning hard surfaces. Use of an agent according to one of claims 1 to 13 or a product according to claim 14 as a dishwashing detergent, preferably for manual dishwashing. Use of an agent according to one of claims 1 to 13 or a product according to claim 14 for the pretreatment of soiled textiles. Use of an agent according to one of claims 1 to 13 or a product according to claim 14 as a carpet cleaner. Process for cleaning hard surfaces, in particular for manual dishwashing, consisting of the steps a) Apply one with the help of a Foam dispenser foamed Means according to one the claims 1 to 13 on a sponge, a cloth, a brush or another, if necessary moistened, cleaning agent, b) distribution or trituration on the surface to be cleaned, c) rinse with water, d) if necessary draining, e) If necessary Wiping and dry rubbing Process for cleaning hard surfaces, in particular for manual dishwashing, consisting of the steps a) Apply one with the help of a Foam dispenser foamed Means according to one the claims 1 to 13 on the surface to be cleaned, b) Distribute or Trituration on the surface to be cleaned, c) Rinse with Water, d) if necessary draining, e) If necessary Wiping and dry rubbing Process for the pretreatment of textiles, consisting from the steps a) applying one with the help of a foam dispenser frothed Means according to one the claims 1 to 13 on the stain, b) rubbing if necessary c) If necessary, allow to dry d) placing in a washing machine and implementation a usual one Wash program. Method for carpet cleaning, consisting of the steps a) applying a foamed with the aid of a foam dispenser according to any one of claims 1 to 13 on the polluted site, b) optionally rubbing using a sponge, a brush, a cloth or other, optionally moistened cleaning aid, c) allow to dry d ) Remove the dried product with the vacuum cleaner.