DE102006008521A1 - Verwendung von Katalysatoren mit erhöhter Aktivität für die NBR-Metathese - Google Patents
Verwendung von Katalysatoren mit erhöhter Aktivität für die NBR-Metathese Download PDFInfo
- Publication number
- DE102006008521A1 DE102006008521A1 DE102006008521A DE102006008521A DE102006008521A1 DE 102006008521 A1 DE102006008521 A1 DE 102006008521A1 DE 102006008521 A DE102006008521 A DE 102006008521A DE 102006008521 A DE102006008521 A DE 102006008521A DE 102006008521 A1 DE102006008521 A1 DE 102006008521A1
- Authority
- DE
- Germany
- Prior art keywords
- alkyl
- aryl
- catalyst
- general formula
- use according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/02—Hydrogenation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/46—Ruthenium, rhodium, osmium or iridium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/08—Depolymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
Priority Applications (16)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102006008521A DE102006008521A1 (de) | 2006-02-22 | 2006-02-22 | Verwendung von Katalysatoren mit erhöhter Aktivität für die NBR-Metathese |
| DE502007005995T DE502007005995D1 (de) | 2006-02-22 | 2007-02-13 | Verwendung von Katalysatoren mit erhöhter Aktivität für die Metathese von Nitrilkautschuken |
| PL07002963T PL1826220T3 (pl) | 2006-02-22 | 2007-02-13 | Zastosowanie katalizatorów o zwiększonej aktywności do metatezy kauczuków nitrylowych |
| EP07002963A EP1826220B1 (de) | 2006-02-22 | 2007-02-13 | Verwendung von Katalysatoren mit erhöhter Aktivität für die Metathese von Nitrilkautschuken |
| AT07002963T ATE492567T1 (de) | 2006-02-22 | 2007-02-13 | Verwendung von katalysatoren mit erhöhter aktivität für die metathese von nitrilkautschuken |
| TW096105898A TWI402275B (zh) | 2006-02-22 | 2007-02-16 | 具高活性的催化劑於腈橡膠置換反應之用途 |
| US11/707,423 US8609782B2 (en) | 2006-02-22 | 2007-02-16 | Process for degrading nitrile rubbers in the presence of catalysts having an increased activity |
| KR1020070017475A KR101367536B1 (ko) | 2006-02-22 | 2007-02-21 | 니트릴 고무의 복분해에 대해 증가된 활성을 갖는 촉매의용도 |
| JP2007041079A JP5618455B2 (ja) | 2006-02-22 | 2007-02-21 | ニトリルゴムのメタセシスのための増大された活性を有する触媒の使用 |
| BRPI0700452-4A BRPI0700452A (pt) | 2006-02-22 | 2007-02-22 | uso de catalisadores tendo uma atividade aumentada para a metátese de borrachas de nitrila |
| MX2007002174A MX2007002174A (es) | 2006-02-22 | 2007-02-22 | Uso de catalizadores que tienen una actividad incrementada para la metatesis de caucho de nitrilo. |
| CN2007100031813A CN101024703B (zh) | 2006-02-22 | 2007-02-25 | 对丁腈橡胶复分解有增强的活性的催化剂的用途 |
| CN2011100866034A CN102199311A (zh) | 2006-02-22 | 2007-02-25 | 对丁腈橡胶复分解有增强的活性的催化剂的用途 |
| US13/300,874 US20120116026A1 (en) | 2006-02-22 | 2011-11-21 | Process for degrading nitrile rubbers in the presence of catalysts having an increased activity |
| US14/069,852 US9115219B2 (en) | 2006-02-22 | 2013-11-01 | Process for degrading nitrile rubbers in the presence of catalysts having an increased activity |
| US14/793,986 US9593168B2 (en) | 2006-02-22 | 2015-07-08 | Process for degrading nitrile rubbers in the presence of catalysts having an increased activity |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102006008521A DE102006008521A1 (de) | 2006-02-22 | 2006-02-22 | Verwendung von Katalysatoren mit erhöhter Aktivität für die NBR-Metathese |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE102006008521A1 true DE102006008521A1 (de) | 2007-08-23 |
Family
ID=38068324
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE102006008521A Withdrawn DE102006008521A1 (de) | 2006-02-22 | 2006-02-22 | Verwendung von Katalysatoren mit erhöhter Aktivität für die NBR-Metathese |
| DE502007005995T Active DE502007005995D1 (de) | 2006-02-22 | 2007-02-13 | Verwendung von Katalysatoren mit erhöhter Aktivität für die Metathese von Nitrilkautschuken |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE502007005995T Active DE502007005995D1 (de) | 2006-02-22 | 2007-02-13 | Verwendung von Katalysatoren mit erhöhter Aktivität für die Metathese von Nitrilkautschuken |
Country Status (11)
| Country | Link |
|---|---|
| US (4) | US8609782B2 (https=) |
| EP (1) | EP1826220B1 (https=) |
| JP (1) | JP5618455B2 (https=) |
| KR (1) | KR101367536B1 (https=) |
| CN (2) | CN102199311A (https=) |
| AT (1) | ATE492567T1 (https=) |
| BR (1) | BRPI0700452A (https=) |
| DE (2) | DE102006008521A1 (https=) |
| MX (1) | MX2007002174A (https=) |
| PL (1) | PL1826220T3 (https=) |
| TW (1) | TWI402275B (https=) |
Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102006008520A1 (de) * | 2006-02-22 | 2007-08-23 | Lanxess Deutschland Gmbh | Neue Katalysator-Systeme und deren Verwendung für Metathese-Reaktionen |
| DE102006008521A1 (de) * | 2006-02-22 | 2007-08-23 | Lanxess Deutschland Gmbh | Verwendung von Katalysatoren mit erhöhter Aktivität für die NBR-Metathese |
| DE102006040569A1 (de) * | 2006-08-30 | 2008-03-06 | Lanxess Deutschland Gmbh | Verfahren zum Metathese-Abbau von Nitrilkautschuken |
| DE102007039525A1 (de) * | 2007-08-21 | 2009-02-26 | Lanxess Deutschland Gmbh | Verfahren zum Metathese-Abbau von Nitrilkautschuk |
| EP2143489A1 (de) * | 2008-07-08 | 2010-01-13 | Lanxess Deutschland GmbH | Katalysator-Systeme und deren Verwendung für Metathese-Reaktionen |
| EP2289623A1 (en) * | 2009-08-31 | 2011-03-02 | LANXESS Deutschland GmbH | Metathesis of nitrile rubbers in the presence of transition metal catalysts |
| EP2289621A1 (en) * | 2009-08-31 | 2011-03-02 | LANXESS Deutschland GmbH | Process for the preparation of low molecular weight hydrogenated nitrile rubber |
| EP2473279B1 (en) | 2009-08-31 | 2014-04-02 | LANXESS Deutschland GmbH | Metathesis of a nitrile rubber in the presence of a transition metal catalyst |
| EP2289622A1 (en) * | 2009-08-31 | 2011-03-02 | LANXESS Deutschland GmbH | Ruthenium based catalysts for the metathesis of nitrile rubbers |
| CN102498140B (zh) | 2009-09-17 | 2015-06-24 | 朗盛德国有限责任公司 | 丁腈橡胶及其在有机溶剂中的生产 |
| EP2298824A1 (de) * | 2009-09-17 | 2011-03-23 | LANXESS Deutschland GmbH | Nitrilkautschuke und deren Herstellung in organischen Lösungsmitteln |
| EP2385074A1 (de) * | 2010-05-07 | 2011-11-09 | LANXESS Deutschland GmbH | Nitrilkautschuke und deren Herstellung in organischen Lösungsmitteln |
| WO2011079439A1 (en) * | 2009-12-30 | 2011-07-07 | Zannan Scitech Co., Ltd. | Highly active metathesis catalysts selective for romp and rcm reactions |
| CA2806424A1 (en) * | 2010-07-28 | 2012-02-02 | Lanxess Deutschland Gmbh | Hydrogenation of diene-based polymers |
| EP2418225A1 (de) | 2010-08-09 | 2012-02-15 | LANXESS Deutschland GmbH | Teilhydrierte Nitrilkautschuke |
| EP2484700B1 (de) | 2011-02-04 | 2013-10-09 | LANXESS Deutschland GmbH | Funktionalisierte Nitrilkautschuke und ihre Herstellung |
| CN104023845B (zh) * | 2011-10-21 | 2016-10-05 | 朗盛德国有限责任公司 | 包括格鲁布斯-荷维达型络合物和末端烯烃的催化剂组合物及其用于氢化丁腈橡胶的用途 |
| WO2013056400A1 (en) * | 2011-10-21 | 2013-04-25 | Lanxess Deutschland Gmbh | Catalyst compositions and their use for hydrogenation of nitrile rubber |
| EP2676969B1 (en) * | 2012-06-22 | 2016-06-01 | University Of Waterloo | Tandem metathesis and hydrogenation of diene-based polymers in latex |
| EP2725030A1 (en) * | 2012-10-29 | 2014-04-30 | Umicore AG & Co. KG | Ruthenium-based metathesis catalysts, precursors for their preparation and their use |
| TWI566835B (zh) | 2014-12-25 | 2017-01-21 | 財團法人工業技術研究院 | 烯烴複分解觸媒及低分子量丁腈橡膠之製備方法 |
| JP7248677B2 (ja) * | 2017-12-08 | 2023-03-29 | アランセオ・ドイチュランド・ゲーエムベーハー | ルテニウム錯体触媒を使用してニトリルゴムを製造するためのプロセス |
| WO2019207096A1 (en) | 2018-04-27 | 2019-10-31 | Arlanxeo Deutschland Gmbh | Use of ruthenium and osmium catalysts for the metathesis of nitrile rubber |
| WO2020020629A1 (en) | 2018-07-23 | 2020-01-30 | Arlanxeo Deutschland Gmbh | Use of catalysts for the metathesis of nitrile rubber |
| US11673130B2 (en) * | 2018-12-12 | 2023-06-13 | Arlanxeo Deutschland Gmbh | Catalyst system containing a metathesis catalyst and at least one phenolic compound and a process for metathesis of nitrile-butadiene rubber (NBR) using the catalyst system |
| KR20210104663A (ko) | 2018-12-17 | 2021-08-25 | 아란세오 도이치란드 게엠베하 | Peg 아크릴레이트-hnbr 공중합체의 생성 공정 |
Family Cites Families (34)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3700637A (en) | 1970-05-08 | 1972-10-24 | Shell Oil Co | Diene-nitrile rubbers |
| DE2539132C2 (de) | 1975-09-03 | 1987-04-09 | Bayer Ag, 5090 Leverkusen | Verwendung hydrierter Dien-Copolymere als temperaturbeständige Materialien auf dem Dichtungssektor |
| CA1220300A (en) | 1982-12-08 | 1987-04-07 | Polysar Limited | Polymer hydrogenation process |
| CA1203047A (en) | 1982-12-08 | 1986-04-08 | Hormoz Azizian | Polymer hydrogenation process |
| DE3329974A1 (de) | 1983-08-19 | 1985-02-28 | Bayer Ag, 5090 Leverkusen | Herstellung von hydrierten nitrilkautschuken |
| DE3433392A1 (de) | 1984-09-12 | 1986-03-20 | Bayer Ag, 5090 Leverkusen | Hydrierung nitrilgruppenhaltiger ungesaettigter polymerer |
| DE3529252A1 (de) | 1985-08-16 | 1987-02-19 | Bayer Ag | Verfahren zur selektiven hydrierung ungesaettigter verbindungen |
| DE3540918A1 (de) | 1985-11-19 | 1987-05-21 | Bayer Ag | Verfahren zur selektiven hydrierung ungesaettigter verbindungen |
| DE3541689A1 (de) | 1985-11-26 | 1987-05-27 | Bayer Ag | Verfahren zur selektiven hydrierung nitrilgruppenhaltiger ungesaettigter polymerer |
| US4816525A (en) | 1987-07-06 | 1989-03-28 | University Of Waterloo | Polymer hydrogenation process |
| DE3932019C1 (https=) | 1989-09-26 | 1991-05-08 | Bayer Ag, 5090 Leverkusen, De | |
| DE4025781A1 (de) | 1990-08-15 | 1992-02-20 | Bayer Ag | Hydrierte butadien/isopren/(meth-)acrylnitril- copolymerisate |
| DE4032597A1 (de) * | 1990-10-13 | 1992-04-16 | Bayer Ag | Rueckgewinnung von hydrierkatalysatoren aus loesungen von hydriertem nitrilkautschuk |
| JP3067031B2 (ja) | 1992-04-03 | 2000-07-17 | カリフォルニア インスティチュート オブ テクノロジー | オレフィンメタセシス重合方法 |
| US5831108A (en) | 1995-08-03 | 1998-11-03 | California Institute Of Technology | High metathesis activity ruthenium and osmium metal carbene complexes |
| US6403802B1 (en) * | 1998-09-10 | 2002-06-11 | University Of New Orleans Research & Technology Foundation | Use of catalyst system comprising nickel, palladium, or platinum and imidazoline-2-ylidene or imidazolidine-2-ylidene in amination reactions |
| EP1180108B1 (en) | 1999-05-24 | 2003-08-27 | California Institute Of Technology | Imidazolidine-based metal carbene metathesis catalysts |
| US6794534B2 (en) * | 2000-06-23 | 2004-09-21 | California Institute Of Technology | Synthesis of functionalized and unfunctionalized olefins via cross and ring-closing metathesis |
| JP3943015B2 (ja) * | 2000-08-10 | 2007-07-11 | トラスティーズ オブ ボストン カレッジ | リサイクル可能メタセシス触媒 |
| CA2329844A1 (en) | 2000-12-28 | 2002-06-28 | Bayer Inc. | Esbo enhanced hydrogenation |
| US6838489B2 (en) * | 2001-03-23 | 2005-01-04 | Cymetech, Llc | High activity metal carbene metathesis catalysts generated using a thermally activated N-heterocyclic carbene precursor |
| US6673881B2 (en) | 2001-06-12 | 2004-01-06 | Bayer Inc. | Process for the preparation of low molecular weight hydrogenated nitrile rubber |
| CA2350280A1 (en) | 2001-06-12 | 2002-12-12 | Bayer Inc. | Low molecular weight hydrogenated nitrile rubber |
| US6841623B2 (en) | 2001-06-29 | 2005-01-11 | Bayer Inc. | Low molecular weight nitrile rubber |
| US6620955B1 (en) * | 2001-11-15 | 2003-09-16 | Richard L. Pederson | Chelating carbene ligand precursors and their use in the synthesis of metathesis catalysts |
| PL199412B1 (pl) * | 2002-10-15 | 2008-09-30 | Boehringer Ingelheim Int | Nowe kompleksy rutenu jako (pre)katalizatory reakcji metatezy, pochodne 2-alkoksy-5-nitrostyrenu jako związki pośrednie i sposób ich wytwarzania |
| CA2409434A1 (en) * | 2002-10-17 | 2004-04-17 | Bayer Inc. | Polymer blends comprising low molecular weight nitrile rubber |
| CA2413607A1 (en) | 2002-12-05 | 2004-06-05 | Bayer Inc. | Process for the preparation of low molecular weight hydrogenated nitrile rubber |
| CA2462011A1 (en) * | 2004-02-23 | 2005-08-23 | Bayer Inc. | Process for the preparation of low molecular weight nitrile rubber |
| CA2462005A1 (en) * | 2004-02-23 | 2005-08-23 | Bayer Inc. | Process for the preparation of low molecular weight hydrogenated nitrile rubber |
| WO2007003135A1 (en) * | 2005-07-04 | 2007-01-11 | Zheng-Yun Zhan | Ruthenium complex ligand, ruthenium complex, carried ruthenium complex catalyst and the preparing methods and the use thereof |
| EP1757623A1 (en) * | 2005-07-14 | 2007-02-28 | Lanxess Inc. | Process for the preparation of low mooney nitrile terpolymers |
| ATE538139T1 (de) * | 2005-08-30 | 2012-01-15 | Lanxess Deutschland Gmbh | Verwendung von katalysatoren für den metatheseabbau von nitrilkautschuk |
| DE102006008521A1 (de) * | 2006-02-22 | 2007-08-23 | Lanxess Deutschland Gmbh | Verwendung von Katalysatoren mit erhöhter Aktivität für die NBR-Metathese |
-
2006
- 2006-02-22 DE DE102006008521A patent/DE102006008521A1/de not_active Withdrawn
-
2007
- 2007-02-13 PL PL07002963T patent/PL1826220T3/pl unknown
- 2007-02-13 AT AT07002963T patent/ATE492567T1/de active
- 2007-02-13 EP EP07002963A patent/EP1826220B1/de active Active
- 2007-02-13 DE DE502007005995T patent/DE502007005995D1/de active Active
- 2007-02-16 US US11/707,423 patent/US8609782B2/en active Active
- 2007-02-16 TW TW096105898A patent/TWI402275B/zh not_active IP Right Cessation
- 2007-02-21 JP JP2007041079A patent/JP5618455B2/ja active Active
- 2007-02-21 KR KR1020070017475A patent/KR101367536B1/ko active Active
- 2007-02-22 MX MX2007002174A patent/MX2007002174A/es active IP Right Grant
- 2007-02-22 BR BRPI0700452-4A patent/BRPI0700452A/pt not_active IP Right Cessation
- 2007-02-25 CN CN2011100866034A patent/CN102199311A/zh active Pending
- 2007-02-25 CN CN2007100031813A patent/CN101024703B/zh active Active
-
2011
- 2011-11-21 US US13/300,874 patent/US20120116026A1/en not_active Abandoned
-
2013
- 2013-11-01 US US14/069,852 patent/US9115219B2/en active Active
-
2015
- 2015-07-08 US US14/793,986 patent/US9593168B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN101024703A (zh) | 2007-08-29 |
| PL1826220T3 (pl) | 2011-05-31 |
| KR101367536B1 (ko) | 2014-02-26 |
| US9593168B2 (en) | 2017-03-14 |
| JP5618455B2 (ja) | 2014-11-05 |
| EP1826220A3 (de) | 2009-11-04 |
| US9115219B2 (en) | 2015-08-25 |
| US8609782B2 (en) | 2013-12-17 |
| JP2007224303A (ja) | 2007-09-06 |
| CN102199311A (zh) | 2011-09-28 |
| CN101024703B (zh) | 2012-09-26 |
| TWI402275B (zh) | 2013-07-21 |
| EP1826220B1 (de) | 2010-12-22 |
| MX2007002174A (es) | 2008-10-30 |
| DE502007005995D1 (de) | 2011-02-03 |
| BRPI0700452A (pt) | 2007-11-06 |
| EP1826220A8 (de) | 2009-02-25 |
| TW200801045A (en) | 2008-01-01 |
| ATE492567T1 (de) | 2011-01-15 |
| US20120116026A1 (en) | 2012-05-10 |
| US20150307636A1 (en) | 2015-10-29 |
| EP1826220A2 (de) | 2007-08-29 |
| KR20070085161A (ko) | 2007-08-27 |
| US20140066575A1 (en) | 2014-03-06 |
| US20080064822A1 (en) | 2008-03-13 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8181 | Inventor (new situation) |
Inventor name: OBRECHT, WERNER, PROF. DR., 47447 MOERS, DE Inventor name: NUYKEN, OSKAR, PROF. DR.-ING., 81927 MUENCHEN, DE Inventor name: MUELLER, JULIA MARIA, 89134 BLAUSTEIN, DE |
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| 8127 | New person/name/address of the applicant |
Owner name: TECHNISCHE UNIVERSITAET MUENCHEN, 80333 MUENCH, DE Owner name: LANXESS DEUTSCHLAND GMBH, 51373 LEVERKUSEN, DE |
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| 8181 | Inventor (new situation) |
Inventor name: NUYKEN, OSKAR, PROF. DR.-ING., 81927 MUENCHEN, DE Inventor name: OBRECHT, WERNER, PROF. DR., 47447 MOERS, DE Inventor name: ONG, CHRISTOPHER, DR., 51375 LEVERKUSEN, DE Inventor name: MUELLER, JULIA MARIA, 89134 BLAUSTEIN, DE |
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| 8139 | Disposal/non-payment of the annual fee |