DE102004029327A1 - Gel, useful in hair styling, comprises transparent or translucent gel aqueous phase (comprising polyacrylate thickener and/or cellulose derivative thickener, fixative, polymer film formers); and emulsion droplet in the aqueous phase - Google Patents

Abstract

Gel (A), useful in hair-styling, comprises: a transparent or translucent gel forming aqueous phase (I) (comprising polyacrylate thickener (II) and/or cellulose derivative thickener (III), one or more fixative (IV) and polymer film formers (V)); and a droplet (formed from a cosmetic emulsion) (VI) floating in the aqueous phase. An independent claim is also included for the preparation of (A).

Description

The The present invention relates to a transparent or translucent Hair styling gel in which emulsion droplets float.

Of the whole human body with the exception of the lips, the palms and the soles of the feet hairy, for the most part but with hardly visible woolly hair. Because of the many nerve endings At the hair root, hair is sensitive to external influences such as Wind or touch and are therefore a not to be underestimated part of the sense of touch. However, the most important function of the human hair is likely today, the appearance of man in more characteristic To shape the way. Similar how the skin meets it's a social function, since it's over its appearance greatly enhances the self-esteem of the individual contributes.

The Hair consists of the hair shaft that protrudes freely from the skin - the keratinized one (dead) part, which represents the actually visible hair - and the the root of hair in the skin - the living part in which the visible hair constantly is formed again. The hair shaft in turn is composed of three layers: a central part - the so-called Haarmark (medulla), which, however, regressed in humans is and often completely missing - further the marrow (cortex) and the outer, to to ten layers strong cuticle (cuticle), the whole Hair wrapped.

natural Hair hangs mostly sleeping and without volume from the head. A goal of hair care It is therefore, the hair fullness and hairstyle. To the temporary Deformation of the hair and styling more versatile Hairstyles are using styling agents (hair fixatives), mostly in form mousses, hair gels or hair sprays. Mousse (also Haarschaumfestiger called) are usually used for hairstyle distributed in damp hair, hair sprays for fixation on the (dry) ready styled hairstyle sprayed. In addition to increasing because of their easy and pleasant applicability popular foam hair fixatives and liquid hair fixatives also hair setting gels (hair gels) offered.

The Both basic building blocks of hair setting agents are the film formers (i.e. fixing polymers) and the solvent. As film formers are usually nonionic, anionic, cationic or amphoteric polymers used. Film makers stay after the Evaporation of the solvent (usually water and / or ethanol) as a film on the hair and fix its shape. The deposited on the hair film are a variety of Requirements: It should be clear, insensitive to moisture, Firming, stable and not sticky and easily through commercial Wash hair shampoos. In addition to the film makers included Styling preparations thickeners that give the product the desired consistency give.

gels for the Hairstyle design (= hair gels, styling gels) are often external uniform, homogeneous preparations. These are usually transparent or translucent. However, they are increasing by consumers as monotonous and boring. To make the preparations visually attractive to the user to shape Effect substances are added to them. This is usually around solid capsules or glitter particles. Capsules and glitter particles However, they have the disadvantage that they wash out a considerable Pose a burden in wastewater, as is usually not biological are degradable. Another disadvantage is that the particles on the hair are visible and often like unsightly Residues look like.

Around with hair gels (= gels for the hairstyle design, styling gels) a cosmetic care effect to achieve the cosmetic preparations and care agents are added to the preparations. Are such active ingredients and care substances hydrophobic or water-sensitive or leads their incorporation into a haze the usually transparent-gel preparation remains according to the prior art as a way out only the encapsulation of substances with the help of solid capsules. The usual capsules with active ingredients however, consumers often find it too harsh to use felt. Further open when applying only a portion of the capsules, leaving only inadequate Quantities are effectively contacted with the hair. Also provides the even distribution the active and / or Caring substances in the hair is a problem. Sharp-edged fragments open Scratch capsules and damage when distributing the preparation on the hair the cuticle. Not Lastly, after application of gels, remnants of the capsules often remain in the hair, what as aesthetic unattractive.

The Object of the present invention was therefore to overcome the disadvantages of State of the art eliminate and environmentally friendly, visually attractive gels for to develop the hairstyle design in which also water-sensitive and / or hydrophobic active ingredients and care substances in cosmetically effective Incorporate quantities into the preparations. Furthermore, the Hair gels after applying no visible residue on the hair back let and apply to the hair and spread without that damaged the cuticle becomes.

• a) einer transparenten oder transluzenten gelförmigen wässrigen oder wässrig/alkoholischen Phase enthaltend, i) Polyacrylatverdicker und/oder Cellulosederivatverdicker, ii) einem oder mehreren fixierenden, polymeren Filmbildnern, sowie
• b) in dieser wässrigen Phase schwebenden Tröpfchen, wobei die Tröpfchen aus einer kosmetischen Emulsion gebildet werden.

Surprisingly, the tasks are solved by a gel for the hairstyle design

• a) containing a transparent or translucent gel-like aqueous or aqueous / alcoholic phase, i) polyacrylate thickener and / or cellulose derivative thickener, ii) one or more fixing, polymeric film formers, and
• b) droplets floating in said aqueous phase, said droplets being formed from a cosmetic emulsion.

According to the invention preferred is a transparent, gel-like, aqueous or aqueous / alcoholic Phase.

The preparations according to the invention do not solve only the tasks according to the invention in an impressive way. They are also exceptionally stable (stable to transport, storage stable, temperature stable). This was special therefore for surprising the expert, since the emulsion itself contains its own water phase, the not in contrast to the expectations of the expert, with the gel-aqueous phase but rather obtained as an independent phase of the emulsion remains. This phenomenon was even with O / W emulsions, i. in emulsions with an external aqueous Phase, observed.

Although the describes DE 101 11 536 thickened aqueous preparations containing liquid droplets, but this document could not point the way to the present invention.

Furthermore, the describes DE 197 14 424 acrylate-alkyl acrylate thickened detergent compositions in which gaseous, solid and or liquid objects may be embedded in the gels. Again, this document could not point the way to vorliegneden invention.

advantageous Gelling agent in the context of the present invention from the group of Cellulose derivative thickeners are hydroxyalkylcelluloses. There are Hydroxyethylcellulose (CAS 9004-62-0, e.g., Natrosol), hydroxypropylcellulose (CAS 9004-64-2, e.g., Klucel HF) and hydroxymethylpropylcellulose (CAS 9004-65-3, e.g., Methocel) is particularly preferred in the present invention.

Polyacrylates are also advantageous for use in the context of the present invention gelators. According to the invention advantageous polyacrylates are acrylate-alkyl acrylate copolymers, in particular those from the group of so-called carbomers or carbopols (Carbopol ^® is actually a registered trademark of NOVEON Inc.) are selected. In particular, the acrylate-alkyl acrylate copolymers which are advantageous according to the invention have the following structure:

In this put R 'one long-chain alkyl radical and x and y are numbers which the respective stoichiometric Symbolize the proportion of the respective comonomers.

Preferred are acrylate copolymers and / or acrylate-alkyl acrylate copolymers sold under the trade names Carbopol ^® 1382, Carbopol ^® 981 and Carbopol ^® 5984, Aqua SF-1 from NOVEON Inc. or as Aculyn ^® 33 from International Specialty Products Corp. are available.

Further advantageous are copolymers of C10-30-alkyl acrylates and a or more monomers of acrylic acid, methacrylic acid or their esters cross-linked with an allyl ether of sucrose or an allyl ether of pentaerythritol.

Advantageous are compounds that have the INCI name "Acrylates / C10-30 Alkyl Acrylates Crosspolymer "wear. Particularly advantageous are those under the trade names Carbopol 1382, Carbopol ETD 2020, Carbopol Ultrez 21, Pemulen TR1 and Pemulen TR2 available from NOVEON Inc.

Also advantageous are compounds having the INCI name "acrylates / C12-24 pareth-25 acrylate copolymer" (under the trade names Synthalen ^® W2000 in 3V Inc.), the methacrylate, the INCI name "acrylates / steareth-20 copolymer "(available under the trade names Aculyn ^® 22 from International Specialty Products Corp.), the INCI name" acrylates / beheneth-25 methacrylate copolymer "(available under the trade name Aculyn ^® 28 from International Specialty Products Corp.), the the INCI name "acrylates / steareth-20 itaconate copolymer" (available under the trade names Structure 2001 ^® available from National Starch), which the INCI name "acrylates / aminoacrylates / C10-30 alkyl PEG-20 itaconate copolymer" (under the trade name Structure Plus ^® at the National Starch) and similar polymers.

According to the invention preferred embodiments of the present invention are characterized in that as Polyacrylate thickening acrylate-alkyl acrylate copolymers used become.

The particularly according to the invention preferred hydrocolloids are: Carbomer (Carbopol 981 or Carbopol 980) and acrylates / C10-30 alkyl acrylate crosspolymer (Carbopol ETD 2020 or Carbopol Ultrez 21).

It is advantageous according to the invention if the concentration of polyacrylate and / or cellulose derivative thickener in the gel, aqueous Phase from 0.01 to 10% by weight, preferably from 0.05 to 5% by weight and particularly preferably from 0.1 to 1.1% by weight, in each case on the total weight of the gel, aqueous Phase, is.

It is advantageous in the context of the present invention, when the gel-like aqueous phase according to the invention and the drop-forming emulsion has certain yield strengths and tan δ values.

The yield stress of the invention is considered to be the critical shear stress of the flow curve. It can be determined according to the invention as follows:
The flow curve is measured on a shear stress-controlled rheometer at 25 ° C ± 1 ° C with 25 mm plate / plate geometry at a gap between 0.8 mm and 1.2 mm, filling the structure gently. A suitable constant shear stress time ramp is specified and a corresponding structure recovery time is maintained before the test and the critical shear stress is specified at the maximum of the flow curve.

The Product is carefully removed with a spatula and placed in the meter brought in. The product should not be sheared in order to a destruction or to avoid influencing the structures.

Under a tan δ becomes According to the invention, the quotient from the loss module and the memory module understood.

The tan δ is determined as follows:
The loss and storage modulus are measured by a dynamic frequency test on a shear stress controlled rheometer at 40 ° C ± 1 ° C with a 25 mm plate / plate geometry at a gap between 0.8 mm and 1.2 mm, filling the structure gently. According to the state of the art, the frequency test is carried out with a corresponding structure recovery time before the test and the tan δ is specified in the frequency range between 0.05 rad / s and 3.0 rad / s, preferably between 0.08 rad / s and 1, 0 rad / s.

The gel, aqueous Phase has advantageous according to the invention a yield point from 0.5 Pa to 60 Pa, according to the invention preferably a yield point from 1 to 50 Pa and according to the invention particularly preferred one yield from 5 to 40 Pa.

According to the invention, the emulsion droplets according to the invention advantageously have a yield strength of from 0.5 Pa to 300 Pa, preferably a yield value of from 0.5 to 100 Pa and according to the invention particularly preferably a flow limit of 1 to 60 Pa.

The gel, aqueous Phase has advantageous according to the invention a tan δ value from 0.02 to 0.8. It is inventively preferred if tan δ between 0.03 and 0.6, the range being from 0.05 to 0.5 especially is preferred.

The have emulsion droplets according to the invention According to the invention advantageous a tan δ of 0.01 to 0.8. It is inventively preferred if tan δ between 0.01 and 0.6, with the range of 0.1 to 0.5 being especially is preferred.

The Emulsion droplets according to the invention can be advantageous according to the invention in the form of W / O, O / W, W / O / W or O / W / O emulsions. Such formulations can also in the form of a microemulsion (eg a PIT emulsion), a Solid emulsion (i.e., an emulsion formed by solids is stabilized, for. B. a Pickering emulsion or hydrodispersion) be formed. It is inventively preferred if the emulsion droplets in Form of an O / W emulsion.

The gel, aqueous Phase of the preparation and the aqueous phase of the droplet-shaped emulsion in addition to water according to the invention, other Ingredients include, for example, alcohols, diols or polyols low C number, and their ethers, preferably ethanol, isopropanol, Propylene glycol, glycerol, ethylene glycol, ethylene glycol monoethyl or -monobutyl ether, propylene glycol monomethyl, -monoethyl- or monobutyl ether, diethylene glycol monomethyl or monoethyl ether and analogous products, furthermore lower C number alcohols, e.g. ethanol, Isopropanol, 1,2-propanediol and glycerol.

Invention gels are advantageous according to the invention characterized in that the gel-like, aqueous phase has an alcohol content from 0.5 to 25% by weight, based on the total weight of the preparation, having.

When inventive fixing, polymeric film formers (also called polymers) may according to the invention anionic, cationic, amphoteric and / or nonionic polymers used become.

It is advantageous according to the invention when the fixing, polymeric film formers in a total concentration from 0.01 to 20% by weight, preferably in a concentration of 0.1 to 10% by weight and most preferably in a concentration from 1 to 5% by weight, based in each case on the total weight of Preparation can be used.

Fixing cationic polymers:

As cationic polymers which are advantageous according to the invention, it is possible to use one or more of the following compounds:
Copolymers of amine-substituted vinyl monomers and non-amine-substituted, non-cationic monomers. Amine-substituted vinyl monomers are, for example, dialkylaminoalkyl acrylate, dialkylaminoalkyl methacrylate, monoalkylaminoalkyl acrylate, monoalkylaminoalkyl methacrylate, where the alkyl groups of these monomers are preferably lower alkyl groups, for example C 1 -C 7 -alkyl groups, particularly preferably C 1 -C 3 -alkyl groups.

suitable Ammonium substituted vinyl monomers are e.g. trialkylmethacryloxyalkylammonium, Trialkylacryloxyalkylammonium, dialkyldiallylammonium and quaternary vinylammonium monomers with cyclic, cationic nitrogen-containing groups such as Pyridinium or imidazolium, e.g. Alkylvinylpyridinium or Alkylvinylimidazolium Salts. The alkyl groups of these monomers are preferably lower Alkyl groups such as e.g. C1-C7-alkyl groups, more preferably C1-C3-alkyl groups. Suitable polymers are below the names poly quaternium described as quaternized Copolymers of vinylimidazole, vinylpyrrolidone and / or vinylcaprolactam (Polyquaternium-16, -44 or -46), quaternized vinyl pyrrolidone / dimethylaminoethyl methacrylate Copolymer (Polyquaternium-11), homo- and copolymers of dimethyldiallylammonium chloride (Polyquaternium-6, -7 or -22), quaternized hydroxyethylcellulose (Polyquaternium-10) or quaternized guar derivatives.

Non-amine-substituted noncationic comonomers include, for example, acrylamide, methacrylamide, alkyl- and dialkylacrylamide, alkyl- and dialkylmethacrylamide, acrylacrylate, alkylmethacrylate, vinylcaprolactone, vinylpyrrolidone, vinylester, vinylalcohol, maleicreanhydride, propyleneglycol or ethylene glycol, wherein the alkyl groups of these monomers are preferably lower alkyl groups such as C1 -C 7 alkyl groups, more preferred C1-C3 alkyl groups.

Further cationic polymers are: quaternized vinyl pyrrolidone / dialkylaminoalkyl methacrylate Copolymers, in particular quaternized vinylpyrrolidone / dimethylaminoethylmethylacrylate Copolymer (INCI: Polyquaternium-11), e.g.

Gafquat 755 from ISP or Luviquat PQ-11 from BASF or quaternized vinylpyrrolidone / dimethylaminopropyl methacrylate / lauryl Dimethylaminopropyl methacrylate copolymer (INCI: Polyquaternium-55), e.g. Styleze W-20 from ISP; Methylvinylimidazolium / vinylpyrrolidone Copolymer (INCI: Polyquaternium-16), e.g. the Luviquat types FC 370, FC 550, FC 905 or HM552 from BASF; Methylvinylimidazolium Methylsulfate / vinylpyrrolidone copolymer (INCI: Polyquaternium-44), e.g. Luviquat Care or Luviquat MS 370 from BASF; or the copolymer from vinylcaprolactam, vinylpyrrolidone and quaternized vinylimidazole (INCI Polyquaternium-46), e.g. Luviquat Hold by BASF.

Particularly according to the invention Also advantageous is the use of a cationic polymer which as quaternized vinylpyrrolidone / dimethylaminoethylmethylacrylate Copolymer (INCI: Polyquaternium-11), e.g. Gafquat 755 from ISP or Luviquat PQ-11 from BASF.

Fixative nonionic polymers:

suitable Nonionic polymers are e.g. Homopolymers of vinylpyrrolidone, e.g. Luviskol K from BASF or homopolymers of N-vinylformamide e.g. PVF from National Starch.

Further suitable polymers are copolymers of vinylpyrrolidone and Vinyl acetate e.g. Luviskol VA grades from BASF (INCI: VP / VA Copolymer), Terpolymers of vinyl pyrrolidone, vinyl acetate and propionate such as e.g. Luviskol VAP from BASF, polyvinylcaprolactam (Luviskol Plus from BASF), Polyvinylamides and their salts and copolymers of vinylpyrrolidone and dimethylaminoethyl methacrylate (Copolymer 845 and Copolymer 937 from ISP Corp.), terpolymers of vinylcaprolactam, vinylpyrrolidone and dimethylaminomethacrylate; Polysiloxanes and the like.

Preferred according to the invention fixing nonionic polymers are Luviskol types from BASF (INCI: PVP or VP / VA copolymer).

According to the invention advantageous anionic polymers are homopolymers or copolymers containing acid groups Monomer units optionally with comonomers which do not acid groups contain copolymerized. Suitable monomers are unsaturated, radically polymerizable compounds which contain at least one acid group own, in particular carboxyvinyl monomers. Suitable acid groups containing Monomers are, for example, acrylic acid, methacrylic acid, crotonic acid, maleic acid or maleic anhydride or their monoesters, aldehydecarboxylic acids or ketocarboxylic acids.

Not with acid groups substituted comonomers are, for example, acrylamide, methacrylamide, Alkyl and dialkylacrylamide, alkyl and dialkylmethylacrylamide, Alkyl acrylate, alkyl methacrylate, vinylcaprolactam, vinylpyrrolidone, Vinyl ester, vinyl alcohol, propylene glycol or ethylene glycol, amine-substituted Vinyl monomers such as e.g. Dialkylaminoalkyl acrylate, dialkylaminoalkyl methacrylate, Monoalkylaminoalkylacrylate and monoalkylaminoalkylmethacrylate.

preferred Polymers with acid groups are in particular copolymers of acrylic acid or methacrylic acid with Monomers selected from acrylic acid or methacrylic acid esters, Acrylamides, methacrylamides and vinylpyrrolidones, homopolymers the crotonic acid and copolymers of crotonic acid selected from monomers from vinyl esters, acrylic acid or methacrylic acid esters, Acrylamides and methacrylamides.

Further suitable polymers are: crosslinked or uncrosslinked vinyl acetate / crotonic acid copolymers (INCI: VA / crotonates copolymer), for example Resyn 28-1310 from National Starch or Luviset CA66 from BASF; Terpolymers of vinyl acetate, crotonate and vinyl alkanoate, in particular vinyl acetate / crotonate / vinyl novecanoate copolymers (INCI: VA / crotonates / vinyl neodecanoate copolymer), for example Resyn 28-2930 from National Starch; partially esterified copolymers between vinyl methyl ether and maleic anhydride (INCI: ethyl, isopropyl, butyl ester of PVM / MA copolymer) eg Gantrez ES 225 or Gantrez ES 425 from ISP; Copolymers of acrylic acid or methacrylic acid with alkyl acrylates and / or N-alkylacrylamides, in particular copolymers of methacrylic acid and alkyl acrylates and terpolymers of acrylic acid, alkyl acrylates and N-alkylacrylacrylates such as acrylic acid / ethyl acrylate / N-tert-butylacrylamide terpolymer (INCI: acrylates / acrylamide copolymer) eg Ultrahold 8 from BASF or tert-butyl acrylate / ethyl acrylate / methacrylic acid terpolymer (INCI: Acrylates Copolymer), eg Luvimer from BASF; Polystyrenesulfonates (INCI: Sodium Polystyrene Sulfonate) eg Flexan 130 from National Starch and Polyester.

suitable Anionic polymers are also water-soluble or dispersible anionic polyurethanes, e.g. Luviset PUR from BASF.

One particularly according to the invention preferred anionic polymer provides with 2-amino-2-methyl-1-propanol neutralized acrylate copolymer (e.g., Luviflex Soft from BASF or Luvimer 100P from BASF).

According to the invention advantageous Amphoteric polymers are, for example, octylacrylamides / acrylates / butylaminoethyl Methacrylate copolymer (Amphomer 28-4910, National Starch) or Methacryloyl ethylbetaine / methacrylate copolymer (Diaformer; Mitsubishi). Also suitable are copolymers of carboxyl groups or Sulfonic group-containing monomers, e.g. (Meth) acrylic acid and itaconic with basic, in particular amino-containing monomers such as e.g. Mono- or dialkylamino-alkyl (meth) acrylates and / or mono- or dialkylamino-alkyl (meth) acrylamides, Copolymers of N-octylacrylamide, methylmethacrylate, hydroxypropylmethacrylate, N-tert-butylaminoethyl methacrylate and acrylic acid.

Particularly according to the invention preferred is octylacrylamide / acrylates / butylaminoethyl methacrylate copolymer (Amphomer 28-4910).

The gel-like, aqueous phase of the preparation and the aqueous phase of the droplet-shaped emulsion may advantageously contain moistening or moisturizing agents (so-called moisturizers). Advantageous moisturizing agents for the purposes of the present invention are, for example, glycerol, lactic acid and / or lactates, in particular sodium lactate, butylene glycol, propylene glycol, biosaccharide gum-1, glycine soya, ethylhexyloxyglycerol, pyrrolidonecarboxylic acid and urea. Furthermore, it is particularly advantageous to use polymeric moisturizers from the group of water-soluble and / or water-swellable and / or water-gellable polysaccharides. Hyaluronic acid, chitosan and / or a fucose-rich polysaccharide, for example, which are filed in the Chemical Abstracts under the registry number 178463-23-5 and z. B. under the name Fucogel ^® 1000 of the company SOLABIA SA is available.

According to the invention advantageous can the gels according to the invention also those familiar to the expert Contains ingredients which give the hair a moist or "gelled" appearance (a so-called "wet look").

Lies the potty emulsion according to the invention in the form of a W / O emulsion can, as advantageous according to the invention W / O emulsifiers surface-active Compounds are used which have an HLB value of 3 to 8.

According to the invention, preference is given to using one or more W / O emulsifiers selected from the group of the following compounds:
Sorbitan stearate, sorbitan oleate, lecithin, glyceryl lanolate, lanolin, ozokerite, hydrogenated castor oil, glyceryl isostearate, polyglyceryl-3-oleate, wool wax acid mixtures, wool wax alcohol mixtures, pentaerythritol isostearate, polyglyceryl-3-diisostearate, methyl glucose dioleate, PEG-7 hydrogenated castor oil, polyglyceryl-4-isostearate, Hexyl laurate, acrylate / C _10-30 alkyl acrylate crosspolymer, sorbitan isostearate, poloxamer 101, polyglyceryl-2-dipolyhydroxystearate, polyglyceryl-4-dipolyhydroxystearate, PEG-30 dipolyhydroxystearate, diisostearoylpolyglyceryl-3-diisostearate, polyglyceryl-3-dipolyhydroxystearate, polyglyceryl 3 dioleate.

Lies the potty emulsion according to the invention in the form of an O / W emulsion can, as advantageous according to the invention O / W emulsifiers surface-active Compounds are used which have an HLB value of 8 to 18 exhibit.

• i) Glycerylstearatcitrat,
• ii) Cetearylalkohol + PEG-40 hydriertes Rizinusöl + Natriumcetearylsulfat + Glycerylstearat,
• iii) Polyglyceryl-3-methylglucosedistearat,
• iv) Stearinsäure,
• v) Kaliumcetylphosphat,
• vi) Glycerylmonostearat enthält.

Embodiments of the present invention which are preferred according to the invention are characterized in that the droplet-shaped O / W emulsion comprises one or more emulsifier / emulsifier systems selected from the group

• i) glyceryl stearate citrate,
• ii) cetearyl alcohol + PEG-40 hydrogenated castor oil + sodium cetearyl sulfate + glyceryl stearate,
• iii) polyglyceryl-3-methyl glucose distearate,
• iv) stearic acid,
• v) potassium cetyl phosphate,
• vi) contains glyceryl monostearate.

The oil phase of emulsion according to the invention is chosen favorably from the group of polar oils, for example from the group of lecithins and fatty acid triglycerides, namely the triglycerol esters of saturated and / or unsaturated branched and / or unbranched alkanecarboxylic acids of a chain length of 8 to 24, in particular 12 to 18 carbon atoms. The fatty acid triglycerides may be, for example chosen favorably are selected from the group of synthetic, semisynthetic and natural oils, such as z. B. cocoglyceride, olive oil, Sunflower oil, Soybean oil, Peanut oil, rapeseed oil, almond oil, palm oil, coconut oil, castor oil, wheat germ oil, grapeseed oil, thistle oil, evening primrose oil, macadamia nut oil and the like more.

According to the invention advantageous are also z. Natural Waxes of animal and vegetable origin, such as Beeswax and other insect waxes as well as berry wax, shea butter and / or Lanolin (wool wax).

Further advantageous polar oil components can for the purposes of the present invention are further selected from the group of Esters of saturated and / or unsaturated, branched and / or unbranched alkanecarboxylic acids of a chain length of 3 to 30 carbon atoms and saturated and / or unsaturated, branched and / or unbranched alcohols of a chain length of 3 to 30 carbon atoms and from the group of esters of aromatic carboxylic acids and saturated and / or unsaturated, branched and / or unbranched alcohols of a chain length of 3 to 30 carbon atoms. Such ester oils can then chosen advantageous are from the group octyl palmitate, octyl cocoate, octyl isostearate, Octyldodeceyl myristate, octyldodecanol, cetearyl isononanoate, isopropyl myristate, Isopropyl palmitate, isopropyl stearate, isopropyl oleate, n-butyl stearate, n-hexyl laurate, n-decyl oleate, isooctyl stearate, isononyl stearate, isononyl isononanoate, 2-ethylhexyl palmitate, 2-ethylhexyl laurate, 2-hexyldecyl stearate, 2-octyl dodecyl palmitate, Stearylheptanoate, oleyl oleate, oleyl erucate, erucyl oleate, erucyl erucate, Tridecyl stearate, tridecyl trimellitate, as well as synthetic, semisynthetic and natural Mixtures of such esters, such as. B. jojoba oil.

Further can the oil phase the emulsion according to the invention chosen favorably are from the group of dialkyl ethers and dialkyl, advantageous are z. B. dicaprylyl ether (Cetiol OE) and / or dicaprylyl carbonate, for example, under the trade name Cetiol CC at the Cognis available.

It is further preferred that the oil component from the group consisting of isoeicosane, neopentyl glycol, propylene glycol dicaprylate / dicaprate, caprylic / capric / diglyceryl succinate, butylene glycol dicaprylate / dicaprate, cocoglycerides (z. B. Myritol ^® 331 from Henkel), C _12-13 alkyl lactate , Di-C _12-13 alkyl tartrate, triisostearin, dipentaerythrityl hexacaprylate / hexacaprate, propylene glycol monoisostearate, tricaprylin, dimethyl isosorbide. It is particularly advantageous if the oil phase of the formulations according to the invention has a content of C _12-15 -alkyl benzoate or consists entirely of this.

Advantageous oil components are also z. B. butyloctyl salicylate (for example that available under the trade designation Hallbrite BHB Fa. CP Hall), hexadecyl and butyloctyl benzoate and mixtures thereof (Hall AB) and / or diethylhexyl (Corapan ^® TQ by Haarmann & Reimer).

Also any mixtures of such oil and wax components are advantageous in the sense of the present Use invention.

Further can the oil phase also advantageously contain nonpolar oils, for example those who chose are from the group of branched and unbranched hydrocarbons and waxes, in particular mineral oil, Vaseline (petrolatum), paraffin oil, squalane and squalene, polyolefins, hydrogenated polyisobutenes and isohexadecane. Among the polyolefins, polydecenes are the preferred substances.

Advantageous can the oil phase also have a content of cyclic or linear silicone oils or Completely from such oils although it is preferred, except the silicone oil or silicone oils additional Content of other oil phase components to use.

werden auch als Polydimethylsiloxan bzw. Dimethicon (INCI) bezeichnet. Dimethicone gibt es in verschiedenen Kettenlängen bzw. mit verschiedenen Molekulargewichten.Silicone oils are high molecular weight synthetic polymeric compounds in which silicon atoms via oxygen atoms chain and / or net-like linked and the remaining valences of silicon by hydrocarbon radicals (usually methyl, more rarely ethyl, propyl, phenyl groups, etc.) are saturated. Systematically, the silicone oils are called polyorganosiloxanes. The methyl-substituted polyorganosiloxanes ne, which are the quantitatively most important compounds of this group and are distinguished by the following structural formula

are also referred to as polydimethylsiloxane or dimethicone (INCI). Dimethicones are available in different chain lengths or with different molecular weights.

Especially advantageous polyorganosiloxanes in the context of the present invention are, for example, dimethylpolysiloxanes [poly (dimethylsiloxane)], which, for example, under the trade names Abil 10 bis 10,000 available from Th. Goldschmidt are. Also advantageous are phenylmethylpolysiloxanes (INCI: phenyl dimethicone, Phenyl trimethicone), cyclic silicones (octamethylcyclotetrasiloxane or decamethylcyclopentasiloxane), which according to INCI also called cyclomethicones amino-modified silicones (INCI: amodimethicone) and silicone waxes, e.g. B. Polysiloxane-polyalkylene copolymers (INCI: Stearyl dimethicones and cetyl dimethicones) and dialkoxydimethylpolysiloxanes (Stearoxy dimethicone and behenoxy stearyl dimethicone) which as different Abil wax types are available from Th. Goldschmidt. But also other silicone oils are advantageous for the purposes of the present invention to use for example, cetyl dimethicone, hexamethylcyclotrisiloxane, polydimethylsiloxane, Poly (methylphenylsiloxane).

Especially advantageous preparations are also obtained if, as additional or agents used antioxidants. Included in the invention the preparations advantageously one or more antioxidants. As cheap, but yet optional antioxidants can all be used for cosmetic Applications suitable or common Antioxidants are used. According to the invention, the antioxidants are preferred in the emulsion according to the invention incorporated.

Especially For the purposes of the present invention, water-soluble antioxidants may be advantageous be used, such as vitamins, eg. As ascorbic acid and their derivatives.

preferred Antioxidants are also vitamin E and its derivatives as well as vitamin A and its derivatives, niacinamide, gamma-oryzanol and panthenol.

The Amount of antioxidants (one or more compounds) in the Preparations is preferably from 0.001 to 30% by weight, particularly preferably from 0.05 to 20 Wt .-%, in particular 0.1 to 10 wt .-%, based on the total weight the preparation.

Provided Vitamin E and / or derivatives thereof are the antioxidant (s), is advantageous, their respective concentrations from the field from 0.001 to 10% by weight, based on the total weight of the formulation, to choose.

Provided Vitamin A or vitamin A derivatives, or carotenes or their derivatives the one or more antioxidants are advantageous, their respective Concentrations from the range of 0.001 to 10 wt .-%, based on the total weight of the formulation to choose.

It is particularly advantageous when the cosmetic preparations according to the present Contain cosmetic active ingredients, preferred agents Antioxidants are what protect the hair from oxidative stress protect can. The active compounds according to the invention become advantageous according to the invention in the emulsion according to the invention incorporated.

Further advantageous active ingredients in the context of the present invention are natural active ingredients and / or derivatives thereof, such as. Alpha-lipoic acid, phytoene, D-biotin, coenzyme Q10, alpha-glucosylrutin, carnitine, carnosine, natural and / or synthetic isoflavonoids, creatine, creatinine, taurine and / or beta-alanine, and 8-hexadecene-1,16- dicarboxylic acid (dioic acid, CAS number 20701-68-2, provisional INCI name octadecenedioic acid) and / or licochalcone A, which is characterized by the following structural formula:

licochalcone may also be used advantageously as a component of plant extracts, in particular of aqueous radix Glycyrrhizae inflatae, are used.

It is advantageous according to the invention when the cosmetic preparations 0.001 to 10 wt .-%, in particular 0.05 to 5 wt .-%, especially 0.01 to 2 wt .-% of an extract from Radix Glycyrrhizae inflatae, in each case based on the Total weight of the emulsion.

All it is particularly advantageous to start from an extract which under the name Polyol Soluble Licorice Extract PU (INCI name Glycyrrhiza Inflata) can be obtained from the company Maruzen. The extract from Radix Glycyrrhizae inflatae contains about 25% % Licochalcone A.

optional conventional Additives can also be included in the formulation to the composition to impart certain modifying properties: these are silicones or silicone derivatives, wetting agents, humectants, plasticizers such as glycerol, glycol and phthalic esters and ethers, emollients, Fragrances and perfumes, UV, absorbers, dyes, pigments, and other colorants, anticorrosive Agents, neutralizing agents, antioxidants, anti-sticking agents, Combination agents and conditioning agents, antistatic agents, Brighteners, preservatives, proteins and derivatives thereof, Amino acids, Vitamins, emulsifiers, surface-active Agent, viscosity modifier, Thickener and rheology modifier, gelling agent, opacifier, Stabilizers, sequestering agents, complexing agents, pearlescing agents, aesthetic Amplifier, fatty acids, Fatty alcohols, triglycerides, botanical extracts, clarifying agents and film educators.

These Additives are generally in a concentration of about 0.01 % to 10% by weight based on the total weight of the composition available.

The inventive preparation contains advantageously one or more conditioners (conditioning Active ingredients).

conditioning Active ingredients are selected from the group containing cationic surfactants, cationic polymers, alkylamidoamines and synthetic oils contain.

When conditioning agents can cationic polymers are preferred. These are usually polymers, the one quaternary Nitrogen atom, for example in the form of an ammonium group.

• – quaternisierte Cellulose-Derivate, wie sie unter den Bezeichnungen Celquat^® und Polymer JR^® im Handel erhältlich sind. Die Verbindungen Celquat^® H 100, Celquat^® L 200 und Polymer JR^®400 sind bevorzugte quaternierte Cellulose-Derivate.
• – polymere Dimethyldiallylammoniumsalze und deren Copolymere mit Estern und Amiden von Acrylsäure und Methacrylsäure. Die unter den Bezeichnungen Merquat^®100 (Poly(dimethyldiallylammoniumchlorid)) und Merquat^®550 (Dimethyldiallylammoniumchlorid-Acrylamid-Copolymer) im Handel erhältlichen Produkte sind Beispiele für solche kationischen Polymere.
• – Copolymere des Vinylpyrrolidons mit quaternierten Derivaten des Dialkylaminoacrylats- und -methacrylats, wie beispielsweise mit Diethylsulfat quaternierte Vinylpyrrolidon-Dimethylaminomethacrylat-Copolymere. Solche Verbindungen sind unter den Bezeichnungen Gafquat^®734 und Gafquat^®755 im Handel erhältlich.
• – Vinylpyrrolidon-Methoimidazoliniumchlorid-Copolymere, wie sie unter der Bezeichnung Luviquat^® angeboten werden.
• – quaternierter Polyvinylalkohol

sowie die unter den Bezeichnungen

• – Polyquaternium 2,
• – Polyquaternium 17,
• – Polyquaternium 18 und
• – Polyquaternium 27 bekannten Polymeren mit quartären Stickstoffatomen in der Polymerhauptkette.

Preferred cationic polymers are, for example:

• - Quaternized cellulose derivatives, such as those under the names Celquat ^® and Polymer JR ^® commercially available. The compounds Celquat ^® H 100, Celquat L 200 and Polymer JR ^{® ®} 400 are preferred quaternized cellulose derivatives.
• - Dimethyldiallylammoniumsalze polymeric and their copolymers with esters and amides of acrylic acid and methacrylic acid. The products sold under the names Merquat ^® 100 (Poly (dimethyldiallylammonium chloride)) and Merquat ^® 550 (dimethyldiallylammonium chloride-acrylamide copolymer) are examples of such cationic polymers.
• - Copolymers of vinylpyrrolidone with quaternized derivatives of Dialkylaminoacrylats- and -methacrylats, such as diethyl sulfate quaternized vinylpyrrolidone-dimethylaminomethacrylate copolymers. Such compounds are sold under the names Gafquat ^® 734 and Gafquat ^® 755 commercially.
• - Vinylpyrrolidone-Methoimidazoliniumchlorid copolymers, such as those offered under the name Luviquat ^® .
• - Quaternized polyvinyl alcohol

as well as those under the designations

• - Polyquaternium 2,
• - Polyquaternium 17,
• - Polyquaternium 18 and
• Polyquaternium 27 known polymers with quaternary nitrogen atoms in the polymer main chain.

Especially preferred are cationic polymers of the first four groups. Preferred cationic surfactants are those of the quaternary ammonium compound type, e.g. Ammonium halides, especially chlorides and bromides, such Alkyltrimethylammonium chlorides, dialkyldimethylammonium chlorides and trialkylmethylammonium chlorides, e.g. cetyltrimethylammonium (INCI CTAC), stearyltrimethylammonium chloride, distearyldimethylammonium chloride, Lauryldimethylammonium chloride, Lauryldimethylbenzylammoniumchlorid and tricetylmethylammonium chloride, behenyltrimethylammonium methosulfate, as well as those under the INCI names Quaternium-27 and Quaternium-83 known imidazolium compounds.

In particular, for environmental reasons these quaternary ammonium compounds can also be so-called esterquats such as N obtainable under the name Armocare® ^® VGH-70 commercially, N-bis (2-palmitoyloxyethyl) dimethyl be used instead. Another conditioning agent is the CTAC, cetyl trimethyllammonium chloride.

Another, also particularly interesting for ecological reasons group of conditioning agents are Alkylamidoamine as stearamidopropyl obtainable under the name Tegoamid ^® S 18 in the trade.

Also suitable as conditioning active ingredients are silicone oils, in particular dialkyl and alkylaryl siloxanes, for example dimethylpolysiloxane and methylphenylpolysiloxane, and also their alkoxylated and quaternized analogs. Examples of such silicones are the products marketed by Dow Corning under the names DC 190, DC 200, DC 344, DC 345 and DC 1401 and the commercial products 02-7224 (manufacturer: Dow Corning, a stabilized trimethylsilylamodimethicone), Dow ^Corning® 929 emulsion (containing a hydroxylamino-modified silicone which is also known as amodimethicone), SM-2059 (manufacturer: General Electric), SLM-55067 (manufacturer: Wacker) and Abil ^® -Quat 3270 and 3272 (manufacturer: Th Goldschmidt; diquaternary. Polydimethylsiloxanes, quaternium-80). Also usable as conditioning agents are paraffin oils and vegetable oils such as jojoba oil, sunflower oil, orange oil, almond oil, wheat germ oil and peach kernel oil. Likewise suitable hair-conditioning compounds are phospholipids, for example soya lecithin, egg lecithin and cephalins.

In the agents according to the invention For example, the conditioning agent may be present in amounts of about 0.05 to about 15, preferably from about 0.5 to about 10, and more preferably from about 1 to about 5% by weight, based on the total agent be.

When according to the invention preferred Conditioners from the group of polyquaternium compounds can, for example Polyquaternium-4 or Polyquaternium-11.

It is also advantageous, the preparations according to the invention complexing agents add. Advantageously, the complexing agents are selected from the group consisting of ethylenediaminetetraacetic acid (EDTA) and their anions, nitrilotriacetic acid (NTA) and their anions, hydroxyethylenediaminotriacetic acid (HOEDTA) and their anions, diethyleneaminopentaacetic acid (DPTA) and their anions, trans-1,2-diaminocyclohexanetetraacetic acid (CDTA) and its anions, Tetrasodium Iminodisuccinate, Trisodium Etylenediamine Disuccinate.

According to the invention, the preparation according to the invention can advantageously contain one or more preservatives. Advantageous preservatives for the purposes of the present invention are, for example, formaldehyde releasers (such as DMDM hydantoin, which is available, for example, under the trade name Glydant ^™ from Lonza), iodopropyl butylcarbamates (for example those sold under the trade names Glycacil-L, Glycacil -S. From the company. Lonza available and / or Dekaben LMB from Jan Dekker), parabens (ie p-Hydroxybenzoesäurealkylester, such as methyl, ethyl, propyl and / or Butylparaben), phenoxyethanol, ethanol, benzoic acid and the like. The preservative system according to the invention also advantageously also comprises preserving aids, such as, for example, octoxyglycerol, glycine soy etc. The following table gives an overview of some preservatives which are advantageous according to the invention:

Further advantageous in cosmetics are common preservatives or preservatives, such as dibromodicyanobutane (2-bromo-2-bromomethylglutarodinitrile), Phenoxyethanol, 3-iodo-2-propynyl butylcarbamate, 2-bromo-2-nitro-propane-1,3-diol, Imidazolidinyl urea, 5-chloro-2-methyl-4-isothiazolin-3-one, 2-chloroacetamide, Benzalkonium chloride, benzyl alcohol.

It is according to the invention particularly preferred, if as preservatives benzoic acid and / or salicylic acid and / or their derivatives or salts are used.

parabens and mixtures with phenoxyethanol / DMDM hydantoin are preferred according to the invention.

According to the invention advantageous are one or more preservatives in one concentration from 2% by weight or less than 2% by weight, preferably 1.5% by weight or less than 1.5% by weight, and more preferably 1% by weight or less than 1% by weight, based in each case on the total weight the preparation in the composition which this at the time of applying to the substrate, in the preparation according to the invention contain.

Advantageous can preparations according to the invention Furthermore Contain substances that absorb UV radiation in the UVB range, the total amount of filter substances being e.g. 0.1% by weight to 30% by weight, preferably 0.5 to 10% by weight, in particular 1.0 to 6.0% by weight is, based on the total weight of the preparations to cosmetic Preparations available to put the hair or the skin in front of the entire area protect the ultraviolet radiation. You can also as a sunscreen for To serve hair.

• – 3-Benzylidencampher-Derivate, vorzugsweise 3-(4-Methylbenzyliden)campher, 3-Benzylidencampher;
• – 4-Aminobenzoesäure-Derivate, vorzugsweise 4-(Dimethylamino)-benzoesäure(2-ethylhexyl)ester, 4-(Dimethylamino)benzoesäureamylester;
• – Ester der Zimtsäure, vorzugsweise 4-Methoxyzimtsäure(2-ethylhexyl)ester, 4-Methoxyzimtsäureisopentylester;
• – Ester der Salicylsäure, vorzugsweise Salicylsäure(2-ethylhexyl)ester, Salicylsäure(4-isopropylbenzyl)ester, Salicylsäurehomomenthylester,
• – Derivate des Benzophenons, vorzugsweise 2-Hydroxy-4-methoxybenzophenon, 2-Hydroxy-4-methoxy-4'-methylbenzophenon, 2,2'-Dihydroxy-4-methoxybenzophenon;
• – Ester der Benzalmalonsäure, vorzugsweise 4-Methoxybenzalmalonsäuredi(2-ethylhexyl)ester,
• – Ester der 2-Cyano-3,3-Diphenylacrylsäure, bevorzugt Ethylhexyl-2-cyano-3,3-diphenylacrylat,
• – Diethylhexyl-butamidotriazon, 2,4,6-Trianilino-(p-carbo-2'-ethyl-1'-hexyloxy)-1,3,5-triazin.

If the preparations according to the invention contain UVB filter substances, they may be oil-soluble or water-soluble. Oil-soluble UVB filters which are advantageous according to the invention are, for example:

• 3-benzylidene camphor derivatives, preferably 3- (4-methylbenzylidene) camphor, 3-benzylidene camphor;
• 4-aminobenzoic acid derivatives, preferably 2-ethylhexyl 4- (dimethylamino) benzoate, 4- (dimethylamino) benzoic acid amyl ester;
• Esters of cinnamic acid, preferably 4-methoxycinnamic acid (2-ethylhexyl) ester, 4-methoxycinnamic acid isopentyl ester;
• Esters of salicylic acid, preferably 2-ethylhexyl salicylate, 4-isopropylbenzyl salicylate, homomenthyl salicylate,
• Derivatives of benzophenone, preferably 2-hydroxy-4-methoxybenzophenone, 2-hydroxy-4-methoxy-4'-methylbenzophenone, 2,2'-dihydroxy-4-methoxybenzophenone;
• Esters of benzalmalonic acid, preferably di-2-ethylhexyl 4-methoxybenzalmalonate,
• Esters of 2-cyano-3,3-diphenylacrylic acid, preferably ethylhexyl 2-cyano-3,3-diphenylacrylate,
• Diethylhexylbutamidotriazone, 2,4,6-trianilino- (p-carbo-2'-ethyl-1'-hexyloxy) -1,3,5-triazine.

• – Salze der 2-Phenylbenzimidazol-5-sulfonsäure wie ihr Natrium-, Kalium- oder ihr Triethanolammonium-Salz, sowie die Sulfonsäure selbst;
• – Sulfonsäure-Derivate von Benzophenonen, vorzugsweise 2-Hydroxy-4-methoxybenzophenon-5-sulfonsäure und ihre Salze;
• – Sulfonsäure-Derivate des 3-Benzylidencamphers, wie z.B. 4-(2-Oxo-3-bornylidenmethyl)benzolsulfonsäure, 2-Methyl-5-(2-oxo-3-bornylidenmethyl)sulfonsäure und ihre Salze sowie das 1,4-di(2-oxo-10-Sulfo-3-bornylidenmethyl)-Benzol und dessen Salze (die entprehenden 10-Sulfato-verbindungen, beispielsweise das entsprechende Natrium-, Kalium- oder Triethanolammonium-Salz), auch als Benzol-1,4-di(2-oxo-3-bornylidenmethyl-10-Sulfonsäure bezeichnet

Advantageous water-soluble UVB filters are, for example:

• Salts of 2-phenylbenzimidazole-5-sulphonic acid, such as its sodium, potassium or triethanolammonium salt, and the sulphonic acid itself;
• Sulfonic acid derivatives of benzophenones, preferably 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid and its salts;
• - Sulfonic acid derivatives of 3-Benzylidencamphers, such as 4- (2-oxo-3-bomylidenemethyl) benzenesulfonic acid, 2-methyl-5- (2-oxo-3-bomylidenemethyl) sulfonic acid and its salts, and the 1,4-di (2-oxo-10-sulfo-3-bomylidenemethyl) benzene and its salts (the debasing 10-sulfato compounds, for example the corresponding sodium, potassium or triethanolammonium salt), also as benzene-1,4-di (2-oxo-3-bornylidenemethyl-10-sulfonic acid

The List of said UVB filters, in combination with the active compound combinations according to the invention can be used should of course not limiting. It can also be beneficial to UVA filters to use, usually contained in cosmetic preparations. For these substances they are preferably derivatives of dibenzoylmethane, in particular 1- (4'-tert-butylphenyl) -3- (4'-methoxyphenyl) -propane-1,3-dione and 1-phenyl-3- (4'-isopropylphenyl) propane-1,3-dione.

Further advantageous UVA filters originate from the group of triazines, for example 2,4-bis - {[4- (2-ethyl-hexyloxy) -2-hydroxy] -phenyl} -6- (4-methoxyphenyl) -1, 3,5-triazine (trade name Tinosorb S ^®) and the group of the triazoles, such as 2,2'-methylene-bis- [6-2H-benzotriazol-2-yl] -4- (1,1,3,3- tetramethylbutyl) phenol) (trade designation Tinosorb ^® M). An advantageous water-soluble UV-A filter represents the 2'-bis (1,4-phenylene) -1H-benzimidazole-4,6-disulfonic acid sodium salt (trade name Neo Neliopan AP ^®).

It can the for the amounts used in the UVB combination are used.

It is advantageous according to the invention if the gel aqueous Phase and / or the emulsion droplets colored differently are.

It is according to the invention of advantage the preparation according to the invention Add vitamins and plant extracts. Such is for example the addition of calcium-vitamin complexes Particularly advantageous according to the invention.

Advantageously in accordance with the invention, the average droplet size of the emulsion droplets is 0.5 to 5 mm. In this case, it is preferred according to the invention if all emulsion droplets have approximately the same size. A pictorial idea of the appearance of the preparations according to the invention, the 1 in which a) the transparent or translucent gel-like aqueous phase and b) the teardrop-shaped emulsion is referred to.

According to the invention advantageous embodiments The present invention is characterized in that a transparent storage container made of glass or plastic (also in tube form) is kept.

Also according to the invention the process for the preparation of the cosmetic preparation according to the invention, which is characterized in that the emulsion in the gel-like, aqueous phase dripped into it.

The The following examples are intended to illustrate the present invention, without restricting it. All Quantities, percentages and percentages are, unless otherwise stated indicated on the weight and the total amount or on the total weight the preparations.

Example Recipes Gel recipe examples

Example Formulations Emulsions O / W Emulsions

O / W emulsions

O / W emulsions

Foamy O / W emulsions:

hydrodispersions

gel creams

Solid-state emulsions

shower emulsion

W / O emulsions,

W / O emulsions,

W / S emulsions

W / S emulsions

W / O emulsions,

W / O emulsions,

Silicone in water emulsion

Claims (14)

Gel for the hairstyle design a) a transparent or translucent gel aqueous Containing phase i) polyacrylate thickener and / or cellulose derivative thickener, ii) one or more fixing, polymeric film formers, as well b) in this aqueous Phase floating droplets, taking the droplets be formed from a cosmetic emulsion. Gel according to claim 1, characterized in that the concentration of polyacrylate and / or cellulose derivative thickener, in the gel, aqueous Phase from 0.01 to 10% by weight, based on the total weight the gel-shaped, aqueous Phase, is. Gel according to one of the preceding claims, characterized characterized in that as polyacrylate thickener acrylate-alkyl acrylate copolymers be used. Gel according to one of the preceding claims, characterized characterized in that the gel-like, aqueous Phase a yield point from 0.5 Pa to 60 Pa. Cosmetic preparation according to one of the preceding Claims, characterized in that the emulsion droplets have a flow limit from 0.5 Pa to 300 Pa. Gel according to one of the preceding claims, characterized characterized in that the gel-like, aqueous Phase a tan δ value from 0.02 to 0.8. Gel according to one of the preceding claims, characterized characterized in that the emulsion droplets have a tan δ of 0.01 to 0.8. Gel according to one of the preceding claims, characterized characterized in that the gel-like, aqueous Phase-fixing, polymeric film-forming agents in a concentration of 0.01 to 20% by weight, based on the total weight of the gelled aqueous Phase, contains. Gel according to one of the preceding claims, characterized characterized in that nonionic as a fixing, polymeric film former be used. Gel according to one of the preceding claims, characterized characterized in that as nonionic vinylpyrrolidone / vinyl acetate Copolymer can be used. Gel according to one of the preceding claims, characterized characterized in that the gel-like, aqueous Phase an alcohol content of 0.5 to 25% by weight, based on the total weight of the preparation. Gel according to one of the preceding claims, characterized characterized in that the gel-like aqueous Phase and / or the emulsion droplets colored are. Gel according to one of the preceding claims, characterized in that it consists of a transparent storage container Glass or plastic is stored. Process for the preparation of a gel according to of the preceding claims, characterized in that the emulsion in the gel, aqueous phase dripped into it.