DE10108475A1 - Verfahren zur Herstellung von Aldehyden - Google Patents

Verfahren zur Herstellung von Aldehyden

Info

Publication number
DE10108475A1
DE10108475A1 DE10108475A DE10108475A DE10108475A1 DE 10108475 A1 DE10108475 A1 DE 10108475A1 DE 10108475 A DE10108475 A DE 10108475A DE 10108475 A DE10108475 A DE 10108475A DE 10108475 A1 DE10108475 A1 DE 10108475A1
Authority
DE
Germany
Prior art keywords
mixture
reaction
rhodium
butene
radicals
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
DE10108475A
Other languages
German (de)
English (en)
Inventor
Hans Bohnen
Juergen Herwig
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Celanese Sales Germany GmbH
Original Assignee
Celanese Chemicals Europe GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Celanese Chemicals Europe GmbH filed Critical Celanese Chemicals Europe GmbH
Priority to DE10108475A priority Critical patent/DE10108475A1/de
Priority to PCT/EP2002/001379 priority patent/WO2002068371A1/fr
Publication of DE10108475A1 publication Critical patent/DE10108475A1/de
Withdrawn legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2442Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems
    • B01J31/2461Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as ring members in the condensed ring system or in a further ring
    • B01J31/2471Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as ring members in the condensed ring system or in a further ring with more than one complexing phosphine-P atom
    • B01J31/2476Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as ring members in the condensed ring system or in a further ring with more than one complexing phosphine-P atom comprising aliphatic or saturated rings
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/16Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxo-reaction combined with reduction
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32Addition reactions to C=C or C-C triple bonds
    • B01J2231/321Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82Metals of the platinum group
    • B01J2531/822Rhodium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
DE10108475A 2001-02-22 2001-02-22 Verfahren zur Herstellung von Aldehyden Withdrawn DE10108475A1 (de)

Priority Applications (2)

Application Number Priority Date Filing Date Title
DE10108475A DE10108475A1 (de) 2001-02-22 2001-02-22 Verfahren zur Herstellung von Aldehyden
PCT/EP2002/001379 WO2002068371A1 (fr) 2001-02-22 2002-02-09 Procede de fabrication d'aldehydes

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE10108475A DE10108475A1 (de) 2001-02-22 2001-02-22 Verfahren zur Herstellung von Aldehyden

Publications (1)

Publication Number Publication Date
DE10108475A1 true DE10108475A1 (de) 2002-09-12

Family

ID=7675077

Family Applications (1)

Application Number Title Priority Date Filing Date
DE10108475A Withdrawn DE10108475A1 (de) 2001-02-22 2001-02-22 Verfahren zur Herstellung von Aldehyden

Country Status (2)

Country Link
DE (1) DE10108475A1 (fr)
WO (1) WO2002068371A1 (fr)

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102008002188A1 (de) 2008-06-03 2009-12-10 Evonik Oxeno Gmbh Verfahren zur Abtrennung von 1-Buten aus C4-haltigen Kohlenwasserstoffströmen durch Hydroformylierung
DE102008002187A1 (de) 2008-06-03 2009-12-10 Evonik Oxeno Gmbh Verfahren zur Herstellung von C5-Aldehydgemischen mit hohem n-Pentanalanteil
DE102009001594A1 (de) 2009-03-17 2010-09-30 Evonik Oxeno Gmbh Verfahren zur Herstellung von alpha, beta-ungesättigten C10-Aldehyden
DE102009027978A1 (de) 2009-07-23 2011-01-27 Evonik Oxeno Gmbh Verfahren zur Herstellung von Decancarbonsäuren
WO2012041846A1 (fr) 2010-09-30 2012-04-05 Evonik Oxeno Gmbh Utilisation de systèmes de catalyseurs silp (supported ionic liquid phase) dans l'hydroformylation de mélanges contenant des oléfines pour former des mélanges d'aldéhydes présentant une teneur élevée en aldéhydes non ramifiés en position 2
WO2014056732A1 (fr) 2012-10-12 2014-04-17 Evonik Industries Ag Procédé de production d'aldéhydes c5 stable à long terme
DE102013113719A1 (de) 2013-12-09 2015-06-11 Oxea Gmbh Verfahren zur Herstellung von Pentanderivaten und Derivaten α,β-ungesättigter Decenale
DE102013020322A1 (de) 2013-12-05 2015-06-11 Oxea Gmbh Verfahren zur Herstellung von 2-Methylbutanal aus den bei der Herstellung von Gemischen isomerer a,ß-ungesättigter Decenale anfallenden Nebenströmen
DE102013020320A1 (de) 2013-12-05 2015-06-11 Oxea Gmbh Verfahren zur Herstellung von 2-Methylbuttersäure mit einem vermindertem Gehalt an 3-Methylbuttersäure aus den bei der Herstellung von Pentansäuren anfallenden Nebenströmen
DE102013113724A1 (de) 2013-12-09 2015-06-11 Oxea Gmbh Verfahren zur Herstellung von Pentanderivaten und Derivaten alpha, beta-ungesättigter Decenale aus Propylen
DE102014203960A1 (de) 2014-03-05 2015-09-10 Evonik Degussa Gmbh Verfahren zur Herstellung von Aldehyden aus Alkanen und Synthesegas
US9517995B2 (en) 2013-12-05 2016-12-13 Oxea Gmbh Method for producing isomeric hexanoic acids from the subsidiary flows arising during the production of pentanals
CN114426469A (zh) * 2020-09-28 2022-05-03 中国石油化工股份有限公司 一种烯烃氢甲酰化制备醇和醛的方法

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005042458A2 (fr) * 2003-10-21 2005-05-12 Basf Aktiengesellschaft Procede de production en continu d'aldehydes
RU2561171C1 (ru) * 2014-09-12 2015-08-27 Открытое акционерное общество "Нефтяная компания "Роснефть" Способ непрерывного двухступенчатого гидроформилирования олефинов с3, с4 и технологическая установка для его осуществления
CN105749969B (zh) * 2014-12-18 2017-12-05 中国科学院大连化学物理研究所 一种氢甲酰化固体催化剂的制备方法及催化剂和应用

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4593127A (en) * 1985-01-11 1986-06-03 Union Carbide Corporation Hydroformylation process
DE4333324A1 (de) * 1993-09-30 1995-04-06 Hoechst Ag Decylalkoholgemische, daraus erhältliche Phthalsäureester und ihre Verwendung als Weichmacher
DE19617257A1 (de) * 1996-04-30 1997-11-06 Hoechst Ag Verfahren zur Hydroformylierung olefinisch ungesättigter Verbindungen
DE19838742A1 (de) * 1998-08-26 2000-03-02 Celanese Chem Europe Gmbh Valeraldehyd und Verfahren zu seiner Herstellung

Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102008002188A1 (de) 2008-06-03 2009-12-10 Evonik Oxeno Gmbh Verfahren zur Abtrennung von 1-Buten aus C4-haltigen Kohlenwasserstoffströmen durch Hydroformylierung
DE102008002187A1 (de) 2008-06-03 2009-12-10 Evonik Oxeno Gmbh Verfahren zur Herstellung von C5-Aldehydgemischen mit hohem n-Pentanalanteil
WO2009146984A1 (fr) 2008-06-03 2009-12-10 Evonik Oxeno Gmbh Procédé pour séparer, par hydroformylation, du 1-butène de flux d’hydrocarbures en c<sb>4</sb>
EP2567949A1 (fr) 2008-06-03 2013-03-13 Evonik Oxeno GmbH Procédé de séparation de 1-butène à partir de flux d'hydrocarbures contenant du C4 par hydroformylation
DE102009001594A1 (de) 2009-03-17 2010-09-30 Evonik Oxeno Gmbh Verfahren zur Herstellung von alpha, beta-ungesättigten C10-Aldehyden
DE102009027978A1 (de) 2009-07-23 2011-01-27 Evonik Oxeno Gmbh Verfahren zur Herstellung von Decancarbonsäuren
WO2012041846A1 (fr) 2010-09-30 2012-04-05 Evonik Oxeno Gmbh Utilisation de systèmes de catalyseurs silp (supported ionic liquid phase) dans l'hydroformylation de mélanges contenant des oléfines pour former des mélanges d'aldéhydes présentant une teneur élevée en aldéhydes non ramifiés en position 2
DE102010041821A1 (de) 2010-09-30 2012-04-05 Evonik Oxeno Gmbh Einsatz von Supported Ionic Liquid Phase (SILP) Katalysatorsystemen in der Hydroformylierung von olefinhaltigen Gemischen zu Aldehydgemischen mit hohem Anteil von in 2-Stellung unverzweigten Aldehyden
WO2014056732A1 (fr) 2012-10-12 2014-04-17 Evonik Industries Ag Procédé de production d'aldéhydes c5 stable à long terme
DE102013020322A1 (de) 2013-12-05 2015-06-11 Oxea Gmbh Verfahren zur Herstellung von 2-Methylbutanal aus den bei der Herstellung von Gemischen isomerer a,ß-ungesättigter Decenale anfallenden Nebenströmen
DE102013020320A1 (de) 2013-12-05 2015-06-11 Oxea Gmbh Verfahren zur Herstellung von 2-Methylbuttersäure mit einem vermindertem Gehalt an 3-Methylbuttersäure aus den bei der Herstellung von Pentansäuren anfallenden Nebenströmen
US9517995B2 (en) 2013-12-05 2016-12-13 Oxea Gmbh Method for producing isomeric hexanoic acids from the subsidiary flows arising during the production of pentanals
US9517991B2 (en) 2013-12-05 2016-12-13 Oxea Gmbh Method for producing 2-methylbutanal from the secondary flows arising in the production of mixtures of isomeric alpha, beta-unsaturated decenals
US9896406B2 (en) 2013-12-05 2018-02-20 Oxea Gmbh Method for producing 2-methylbutyric acid having a reduced content of 3-methylbutyric acid from the secondary flows arising in the production of pentanoic acids
DE102013020320B4 (de) 2013-12-05 2019-04-04 Oxea Gmbh Verfahren zur Herstellung von 2-Methylbuttersäure mit einem vermindertem Gehalt an 3-Methylbuttersäure aus den bei der Herstellung von Pentansäuren anfallenden Nebenströmen
DE102013020322B4 (de) 2013-12-05 2019-04-18 Oxea Gmbh Verfahren zur Gewinnung von 2-Methylbutanal aus den bei der Herstellung von Gemischen isomerer a,ß-ungesättigter Decenale anfallenden Nebenströmen
DE102013113719A1 (de) 2013-12-09 2015-06-11 Oxea Gmbh Verfahren zur Herstellung von Pentanderivaten und Derivaten α,β-ungesättigter Decenale
DE102013113724A1 (de) 2013-12-09 2015-06-11 Oxea Gmbh Verfahren zur Herstellung von Pentanderivaten und Derivaten alpha, beta-ungesättigter Decenale aus Propylen
DE102014203960A1 (de) 2014-03-05 2015-09-10 Evonik Degussa Gmbh Verfahren zur Herstellung von Aldehyden aus Alkanen und Synthesegas
CN114426469A (zh) * 2020-09-28 2022-05-03 中国石油化工股份有限公司 一种烯烃氢甲酰化制备醇和醛的方法

Also Published As

Publication number Publication date
WO2002068371A1 (fr) 2002-09-06

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Legal Events

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8139 Disposal/non-payment of the annual fee