CZ191194A3 - Process of disposing waste from the production of olive oil - Google Patents

Process of disposing waste from the production of olive oil Download PDF

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Publication number
CZ191194A3
CZ191194A3 CZ941911A CZ191194A CZ191194A3 CZ 191194 A3 CZ191194 A3 CZ 191194A3 CZ 941911 A CZ941911 A CZ 941911A CZ 191194 A CZ191194 A CZ 191194A CZ 191194 A3 CZ191194 A3 CZ 191194A3
Authority
CZ
Czechia
Prior art keywords
waste
olive oil
production
phase
olive
Prior art date
Application number
CZ941911A
Other languages
Czech (cs)
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CZ280400B6 (en
Inventor
Emil Ing Hrusa
Ludvik Ing Siegel
Jaroslav Ing Poduska
Original Assignee
Vodni Stavby A S
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Vodni Stavby A S filed Critical Vodni Stavby A S
Priority to CZ941911A priority Critical patent/CZ280400B6/en
Priority to PCT/CZ1995/000016 priority patent/WO1996005145A2/en
Priority to EP95927616A priority patent/EP0722425A1/en
Publication of CZ191194A3 publication Critical patent/CZ191194A3/en
Publication of CZ280400B6 publication Critical patent/CZ280400B6/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F5/00Fertilisers from distillery wastes, molasses, vinasses, sugar plant or similar wastes or residues, e.g. from waste originating from industrial processing of raw material of agricultural origin or derived products thereof
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/12Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • C02F11/16Treatment of sludge; Devices therefor by de-watering, drying or thickening using drying or composting beds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/32Nature of the water, waste water, sewage or sludge to be treated from the food or foodstuff industry, e.g. brewery waste waters
    • C02F2103/322Nature of the water, waste water, sewage or sludge to be treated from the food or foodstuff industry, e.g. brewery waste waters from vegetable oil production, e.g. olive oil production
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A40/00Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
    • Y02A40/10Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
    • Y02A40/20Fertilizers of biological origin, e.g. guano or fertilizers made from animal corpses

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  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Water Supply & Treatment (AREA)
  • Hydrology & Water Resources (AREA)
  • Botany (AREA)
  • Processing Of Solid Wastes (AREA)
  • Micro-Organisms Or Cultivation Processes Thereof (AREA)
  • Fats And Perfumes (AREA)
  • Lubricants (AREA)
  • Fertilizers (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Treatment Of Sludge (AREA)

Abstract

The way of disposal of waste from olive oil production using intensive grinding and mixing of effluent water with natural bentonite, which is thus activated. The solution is based on a continuous mixing of the liquid phase of waste, whose density is between 800 to 1000 kg/m<3>, at a ratio of up to 300 kg of natural bentonite, to 1 m<3> of the liquid phase of waste, followed by the admixture of solid phase of waste after which the mixture is inoculated and subject to forced aeration.

Description

Způsob likvidace odpadu 2 výroby olivového olejeWaste disposal method 2 of olive oil production

Oblast technikyTechnical field

Vynález se týká způsobu likvidace odpadu 2 výroby olivového oleje.The invention relates to a process for the disposal of olive oil waste 2.

Dosavadní stav technikyBACKGROUND OF THE INVENTION

Výroba olivového oleje probíhá 2 převažující části v lisovnách oliv, situovaných do blí2kosti olivových hájů. Olej se lisuje 2 dužiny oliv, nebo 2 pokrutin oliv a nebo 2 olivovových jader. Odpadem, který při procesu výroby olivového oleje vzniká, je vylisovaná hmota 2 dužiny, slupky, skořápky jader, listy a 2bytky větviček a také šťáva, která 2byla po oddělení oleje. Likvidace tohoto odpadu se dosud provádí spalováním tuhých částí na místě a vyléváním šťávy, pojmenované v technologickém postupu výroby olivového prostředí, neboť stavba Protože šťáva oleje jako marga, vyhnívacích nádrží obsahuje mj.The production of olive oil takes place in two pressing plants situated in the vicinity of olive groves. The oil is pressed with 2 olive pulps, or 2 olive pomace or 2 olive kernels. The waste resulting from the olive oil production process is the compressed mass of 2 flesh, husks, shells of kernels, leaves and twigs of twigs, and also the juice that has been left after the oil has been separated. So far, this waste has been disposed of by burning the solid parts on site and pouring the juice, named in the technological process for the production of the olive environment, since the construction of the oil juice as marga, the digester contains, among other things.

do přírodního se považuje 2a 2načný podíl skupiny nák1adnou. fosfát idů, které podléhají hnilobným procesům.a significant proportion of the cost group is considered to be natural. phosphate ids subject to putrefaction processes.

dochá2 í k ekologickým škodám - šíření zápachu, kontaminaci vod i půdy.They cause environmental damage - odor spread, water and soil contamination.

Z literatury jsou známy další možné způsob likvidace odpadů organického původu např. jejich očkováním kejdou skotu, nebo kaly z čistíren odpadních vod, což by mělo mít vliv na množení metanogenních bakterií^a tím na produkci bioplynu. Protože však produkce bioplynu nebyla konstantní a někdy i zanikala, zkoušelo se např. očkování bachorovými obsahy nebo bachorovou tekutinou, získanou z poražených jatečních zvířat. To sice umožnilo v určitém rozsahu řízení aktivity bakterií, ale pro účely likvidace odpadu výše popsaného složení a umístění není takovýto způsob běžně využitelný.Other possible ways of disposing of organic waste are known from the literature, for example by seeding them with cattle sludge or sewage sludge, which should have an effect on the multiplication of methanogenic bacteria and thus on the production of biogas. However, because biogas production was not constant and sometimes disappeared, for example, vaccination with rumen contents or rumen fluids obtained from slaughtered animals was tested. While this has allowed the control of bacterial activity to some extent, such a method is not commonly applicable for the purposes of waste disposal of the composition and location described above.

Jsou také 2námy chemické postupy likvidace obdobných odpadů např. kyselinami s následnou neutralizací, které jsou však vesměs velmi nákladné a složité a navíc s sebou přinášejí riziko předávkování a tím i ekologických škod.There are also known chemical procedures for disposal of similar waste, eg acids with subsequent neutralization, which, however, are very expensive and complicated and, in addition, carry the risk of overdose and thus environmental damage.

vpodstatě jejich pyrolytickým obsažen jistý podílbasically their pyrolytic contained a certain proportion

Jiným postupem jsou například likvidovány kaly po čeření vína, tzv. modré kaly. Tento postup záleží v kalcinaci kalů při vysokých teplotách, tedy rozkladem. Využívá se toho, že v kalu je bentonitu a konečný produkt je pak použitelný jako přídavná surovina v cihlářském, keramickém, cementářském a jiném průmyslu. Ani tento způsob likvidace není pro účel vynálezu reálný, protože předpokládá blízkost vysokotepe1ného zdroje a obsah např. ka1c i nac i.For example, another method is to dispose of the sludge after wine clarification, the so-called blue sludge. This procedure depends on the calcination of the sludge at high temperatures, i.e. by decomposition. It is utilized that bentonite is present in the sludge and the end product can then be used as an additional raw material in the brick, ceramic, cement and other industries. Even this method of disposal is not realistic for the purpose of the invention since it assumes the proximity of the high-temperature source and the content of e.g.

ferokyanidů v odpadu, aby mohlo dojít ke a mlecí a mísící všech potřebnýchferrocyanides in the waste so that it can occur and grinding and mixing all needed

Podstata vynálezuSUMMARY OF THE INVENTION

Uvedené nedostatky v podstatě eliminuje způsob likvidace odpadu z výroby olivového oleje, který využívá intenzivního mletí a míšení odpadní vody s přírodním bentonitem, jež se tím akt i vuj e.These deficiencies are essentially eliminated by the method of waste disposal of olive oil production, which utilizes intensive milling and mixing of waste water with natural bentonite, thereby activating it.

Podstata vynálezu spočívá v tom,že tekutá fáze odpadu, jejíž hustota činí 800 až 1 000 kg/m3, se plynule mísí v poměru až 300 kg přírodního bentonitu na 1 m3 tekuté fáze odpadu, načež se přimísí pevná fáze odpadu a směs se inokuluje a podrobí se nucené aeraci.The liquid waste phase, which has a density of 800 to 1000 kg / m 3 , is continuously mixed at a rate of up to 300 kg of natural bentonite per m 3 of liquid waste phase, the solid waste phase is admixed and the mixture is mixed. inoculate and undergo forced aeration.

Výhodou způsobu likvidace odpadu z výroby olivového oleje je jednoduché a levné zařízení, jímž může být například jen nádrž čerpadlo, absence chemikálií a dostupnost surovin i energie, zejména vhodného lze snadno připravit ze zeminy inokulačního materiálu. Ten obsahující mikroorganismy dlouhodobě modifikované působením o1 ivovníkových produktů a b i odegradačn í m i v1astnostmi. hrudkovitá hmota, která je tudíž vybavené specifickými Výsledným produktem je sypká vhodná k zemědělskému využití.The advantage of the olive oil waste disposal method is a simple and inexpensive device, which can be, for example, only a pump tank, the absence of chemicals, and the availability of raw materials and energy, particularly suitable, can easily be prepared from soil inoculum material. It contains microorganisms modified in the long term by the action of animal products and also by degradation measures. the lumpy mass, which is therefore provided with a specific end product, is a loose material suitable for agricultural use.

Hmota se dále nerozkládá a ani ve vlhkém prostředí nezapáchá.The material does not decompose and does not smell even in humid environments.

Příklad provedeni vynálezuDETAILED DESCRIPTION OF THE INVENTION

Způsob likvidace odpadu podle vynálezu byl využit v provozních podm í nkách.The waste disposal method according to the invention has been utilized in operating conditions.

Byl použit odpad z výroby olivového oleje ve složení 28,6 hm. % výlisků z oliv, 17^4 hm. % šťávy z oliv po separaci z oleje, tzv. niargy, 54 hm. % rostlinného odpadu, ttarga, jakožto tekutá fáze odpadu o hustotě 970 kg/m3, byla upravena míšením s přírodním bentonitem, pocházejícím 2 ložiska Obrnice, a to fWaste from the production of olive oil in the composition of 28.6 wt. % olive pomace, 17 ^ 4 wt. % of olive juice after separation from oil, so-called niargy, 54 wt. % of vegetable waste, ttarga, as the liquid phase of waste with a density of 970 kg / m 3 , was treated by mixing with natural bentonite coming from 2 Obrnice deposits, namely f

« v poměru 200 kg bentonitu na 1 m3 margy. Směs byla dále w rozmíchána s pevnou fází, tj. s výlisky a s rostlinným odpadem za přidání inokulačního materiálu. Inokulační materiál byl získán tak, že bylo nejprve odebráno 25 kg svrchní zeminy z bezprostřední blízkosti olivovníku a dobře promícháno s 55 1 sladkovodní neupravované vody. Po sedimentaci nerozpustných podílů byla vodná část odlita a bezprostředně používána.«At a rate of 200 kg of bentonite per m 3 of marga. The mixture was further stirred with w solid phase, i.e. with moldings and vegetable waste for post inoculation material. The inoculation material was obtained by first collecting 25 kg of top soil from the immediate vicinity of the olive tree and mixing well with 55 l of freshwater untreated water. After the insoluble matter was sedimented, the aqueous portion was discarded and used immediately.

Takto upravená kompostovací vsádka o teplotě 31 °C byla vložena do bioreaktoru s řízeným aeračním režimem a měřením koncentrace oxidu uhličitého na odplynu bioreaktoru.The treated composting batch at 31 ° C was charged into a controlled aeration mode bioreactor and measuring the carbon dioxide concentration of the bioreactor offgas.

Teplota uloženého odpadu dosáhla po 7 dnech maximální hodnoty 65 °C a zároveň obsah oxidu uhličitého stoupl na maximum v průběhu celého procesu. Po dalších 7 dní hodnoty obou těchto sledovaných parametrů klesaly. Teplota kompostovaného materiálu pak v konečné fázi nepřesahovala 45 °C. což ukazuje na zrychlený rozklad biohmoty.The temperature of the deposited waste reached a maximum value of 65 ° C after 7 days and at the same time the carbon dioxide content rose to a maximum during the whole process. For the next 7 days the values of both of these monitored parameters decreased. The temperature of the composted material then did not exceed 45 ° C in the final phase. indicating accelerated decomposition of bio-matter.

Vzhled produktu jednoznačně vypovídá o tom že došlo ke kvalitnímu proreagování výchozích surovin. Po dobu fermentace ani po ní nedošlo ke vzniku rozkladných procesů, které běžně doprovázejí zahnívání olivových odpadů za vzniku nežádoucích značně zapáchajících těkavých látek.The appearance of the product clearly suggests that the quality of the raw materials was proreagent. No decomposition processes, which normally accompany the digestion of olive wastes to produce undesirable, highly odorous volatile substances, have occurred during or after the fermentation.

Claims (1)

PATENTOVÉ NÁROKYPATENT CLAIMS Způsob likvidace odpadu z intenzivního mletí a ním bentonitem, který jící se t í m, že činí 800 až 1 000 kg/m3, přírodního bentonitu na výroby olivového oleje, využívající míšení odpadní vody s přírodse tím aktivuje, v y z n a č utekutá fáze odpadu, jejíž hustota se plynule mísí v poměru až 300 kg seA method of disposing of waste from intensive grinding and bentonite, which is 800 to 1,000 kg / m 3 , of natural bentonite for olive oil production, utilizing the mixing of waste water with nature, thereby activating the marked waste phase, the density of which is continuously mixed at a rate of up to 300 kg 1 m3 tekuté fáze odpadu, načeš přimísí pevná fáze odpadu a směs se inokuluje a podrobí se nucené aeraci.1 m 3 of the liquid waste phase, whereupon the solid waste phase is admixed and the mixture is inoculated and subjected to forced aeration.
CZ941911A 1994-08-08 1994-08-08 Process of disposing waste from the production of olive oil CZ280400B6 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
CZ941911A CZ280400B6 (en) 1994-08-08 1994-08-08 Process of disposing waste from the production of olive oil
PCT/CZ1995/000016 WO1996005145A2 (en) 1994-08-08 1995-08-03 Disposal of waste from olive oil production
EP95927616A EP0722425A1 (en) 1994-08-08 1995-08-03 The way of disposal of waste from olive oil production

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CZ941911A CZ280400B6 (en) 1994-08-08 1994-08-08 Process of disposing waste from the production of olive oil

Publications (2)

Publication Number Publication Date
CZ191194A3 true CZ191194A3 (en) 1996-01-17
CZ280400B6 CZ280400B6 (en) 1996-01-17

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Application Number Title Priority Date Filing Date
CZ941911A CZ280400B6 (en) 1994-08-08 1994-08-08 Process of disposing waste from the production of olive oil

Country Status (3)

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EP (1) EP0722425A1 (en)
CZ (1) CZ280400B6 (en)
WO (1) WO1996005145A2 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1035091A1 (en) * 1999-03-08 2000-09-13 STOCKHAUSEN GmbH & CO. KG Vegetal waste composition from oil production stable during storage and transport
CN102718312A (en) * 2012-07-14 2012-10-10 哈尔滨工业大学 Preparation and regeneration methods of iron-based activated sludge and method for treating domestic sewage by regenerated iron-based activated sludge
EP2789598A1 (en) 2013-04-12 2014-10-15 Manios, Thrassyvoulos Process for obtaining compost from wastewaters produced by olive oil mills

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2640156A1 (en) * 1976-09-07 1978-03-16 Erich Dr Asendorf Food industry wastes clarification esp. for olive oil prodn. - comprises two aeration stages with dilution by recycled activated sludge water
FR2607490B1 (en) * 1986-11-28 1990-04-27 Brun Christian BIOLOGICAL PROCESS FOR THE TREATMENT OF VEGETABLE AND ANIMAL FAT BY BACTERIA IN PURIFICATION PLANTS AND THE IMPLEMENTATION OF SAID PROCESS
IT1239280B (en) * 1989-10-04 1993-10-19 Achille Poglio ENERGY RECOVERY OF WASTEWATER FROM OLIVE OIL MILLS THROUGH TREATMENT OF THE SAME WATER WITH SPECIAL CATALYSTS AND POLYENZYMATIC MIXTURE FOR FINAL PRODUCTION OF HUMIC EXTRACTS IN AQUEOUS SOLUTION, OR AMENDERS IN AQUEOUS SOLUTION, OR ANTI-WASTEWATER AM;
IT1240759B (en) * 1990-02-09 1993-12-17 S.I.B.E. Societa' Ingegneria Bernardini Ernesto PROCEDURE TO REDUCE POLLUTION IN WATERS ARISING FROM OLIVE PROCESSING PLANTS AND RELATED PLANT.

Also Published As

Publication number Publication date
WO1996005145A3 (en) 1996-04-25
WO1996005145A2 (en) 1996-02-22
CZ280400B6 (en) 1996-01-17
EP0722425A1 (en) 1996-07-24

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