CS267323B1 - Combined coagulating agent - Google Patents

Combined coagulating agent Download PDF

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Publication number
CS267323B1
CS267323B1 CS8710101A CS1010187A CS267323B1 CS 267323 B1 CS267323 B1 CS 267323B1 CS 8710101 A CS8710101 A CS 8710101A CS 1010187 A CS1010187 A CS 1010187A CS 267323 B1 CS267323 B1 CS 267323B1
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Czechoslovakia
Prior art keywords
zeolite powder
technology
parts
combined
treatment
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CS8710101A
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Czech (cs)
Slovak (sk)
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CS1010187A1 (en
Inventor
Jozef Ing Murin
Alexander Ing Zubac
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Jozef Ing Murin
Alexander Ing Zubac
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Application filed by Jozef Ing Murin, Alexander Ing Zubac filed Critical Jozef Ing Murin
Priority to CS8710101A priority Critical patent/CS267323B1/en
Publication of CS1010187A1 publication Critical patent/CS1010187A1/en
Publication of CS267323B1 publication Critical patent/CS267323B1/en

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  • Separation Of Suspended Particles By Flocculating Agents (AREA)
  • Water Treatment By Sorption (AREA)

Abstract

Prostriedok je vhodný j>re technológiu úpravy pitných νβά obsahujúcich amonné iony. Pozostáva zo 60 až 70 hmotnostných dielov síranu hlinitého (AlgíSO^),) a 40 až 30 hmotnoetných dielov jemne mletého práškového zeolitu. Je výhodné, ak sa použije jemne mletý práškový zeolit s obsahom 48 až 52 % klinoplitolitu. Aplikáciou kombinovaného koagulačného prostriedku podlá vynálezu sa na požadovánu noruju znižujě obsah amonných ionov, ktoré su vo vodnom zdroji přítomné prevažne v dSsledku znečistenia vplyvom poínohospodérskej činnosti ,a znižuju sa j-ι celkové náklady na technologiu úpravy.The composition is suitable for technology treatment of ammonium ion-containing drinking liquids. It consists of 60 to 70 parts by weight of aluminum sulfate And (40 to 30 wt.%) finely divided zeolite powder. It is preferred that finely ground be used zeolite powder containing 48 to 52% clinoplitolite. By applying the combined coagulation of the present invention noruju required to reduce ammonium content ions present in the water source predominantly due to pollution economic activity, and I am decreasing j-the total cost of the treatment technology.

Description

Vynález ga týká kombinovaného koagulačného prostřiedku na báze síranu hlinitého, vhodného najma pře technológiu úpravy pitných vod, obsahujúcich amóniové zlúčeniny.The invention relates to a combined coagulant based on aluminum sulphate, suitable in particular for the technology of treatment of drinking water containing ammonium compounds.

Při technológiách úpravy sa na odstránenie koloidných nečistot a látok dispergovaných alebo emulgovaných vo vodě používajú koagulačné prostriedky, najma soli hliníka a železa.Coagulation agents, especially aluminum and iron salts, are used in treatment technologies to remove colloidal impurities and substances dispersed or emulsified in water.

Pokial' upravovaná voda gpravidla v dosledku znečistenia vodného zdroja vplyvom polnohospodárskej činnosti, obsahuje amonné iony, nie je ich možné technológiou odstrániť.If the treated water usually contains ammonium ions due to pollution of the water source due to agricultural activity, it is not possible to remove them by technology.

Teraz sa zistilo, že popísáný nedostatok rieši kombinovaný koagulačný prostřiedok na báze síranu hlinitého podlá vynálezu. Podstata vynálezu spočívá v tom, že kombinovaný koagulačný prostriedok pozostáva zo až 70 hmotnostných dielov síranu hlinitého (Al^SO^) a 40 až 30 hmotnostných dielov jemne mletého práškového zeolitu.It has now been found that the described deficiency is solved by a combined aluminum sulphate coagulant according to the invention. The essence of the invention consists in that the combined coagulant composition consists of up to 70 parts by weight of aluminum sulphate (Al 2 SO 4) and 40 to 30 parts by weight of finely ground zeolite powder.

Je výhodné, ak sa použije jemne mletý práškový zeolit s obsahom 48 až 52 % klinoptilolitu.It is preferred to use a finely ground zeolite powder containing 48 to 52% clinoptilolite.

Aplikáciou kombinovaného koagulačného prostriedku podlá vynálezu sa znižuje obsah amonných iónov přítomných v upravovanéj vodě na požadovánu normu, celkový účinok koagulácie vzhladom na přítomnost? ostatných nečistot je vysoký, znižuje sa množstvo přidávaného hliníka, čo má kladný vplyv na kvalitu upravenej vody a v neposlednom radě sa, najma pri využití vhodnej lokality výskytu zeolitov, znižujú sa celkové náklady technologie.The application of the combined coagulant according to the invention reduces the content of ammonium ions present in the treated water to the required standard, the overall effect of coagulation with respect to the presence of? other impurities is high, the amount of added aluminum is reduced, which has a positive effect on the quality of treated water and last but not least, especially when using a suitable site of zeolites, the overall cost of technology is reduced.

Vzhl'adom na zníženie obsahu amonných iónov na požadovánu normu, nie je do procesu technologie úpravy vody nutné zařadit' další technologický stupeň.Due to the reduction of the ammonium ion content to the required standard, it is not necessary to include another technological stage in the process of water treatment technology.

Kombinovaný koagulačný prostriedok podlá vynálezu, jeho aplikáciu pri úpravě a účinok na odstraňovanie amonných iónov vody ilustrujú, ale neobmedzujú nasledujúce příklady.The combined coagulant composition of the invention, its application in the treatment and its effect on the removal of ammonium ions in water are illustrated, but not limited, by the following examples.

Příklad 1Example 1

Pri technologii úpravy vody z lokality Ondava sa na koaguláciu použil kombinovaný koagulačný prostriedok s obsahom 60 hm. dielov síranu hlinitého a 40 hm. dielov práškového zeolitu s velkostíou častíc 90.% pod 90 ^u a 2 % nad 20 ^u s obsahom klinoptilolitu 0 50 %.In the technology of water treatment from the Ondava locality, a combined coagulation agent with a content of 60 wt. parts of aluminum sulphate and 40 wt. parts of zeolite powder with a particle size of 90% below 90% and 2% above 20% with a clinoptilolite content of 50%.

Výsledky sú uvedené v následujúcej tabulkeThe results are shown in the following table

OS 267323 BlOS 267323 Bl

Tabulka 1Table 1

Dá turn a hodina odběru He gives a turn and an hour of collection _______Surová voda _______ Raw water Upravená voda Treated water oxidov. v mg.I1 oxides. in mg.I 1 obsah NH. -I4 , v mg.lNH content. -I 4 , in mg.l oxidov. v mg.l-1 oxides. in mg.l -1 obsah NH. _i4 v mg.l x NH content. _i4 in mg.l x 22.3.1987 3/22/1987 1.00 1.00 15,76 15.76 5,5 5.5 3,0 3.0 0,26 0.26 3.00 3.00 16,40 16.40 5,6 5.6 2,96 2.96 0,285 0.285 5.00 5.00 17,28 17.28 7,40 7.40 3,00 3.00 0,3 0.3 7.00 7.00 14,72 14.72 4,80 4.80 3,00 3.00 0,275 0.275 9.00 9.00 14,0 14.0 4,8 4.8 3,00 3.00 0,37 0.37 11.00 11.00 12,96 12.96 4,5 4.5 3,00 3.00 0,225 0.225 13.00 13.00 12,40 12.40 4,25 4.25 3,00 3.00 0,29 0.29 15.00 15.00 14,88 14.88 3,35 3.35 2,96 2.96 0,395 0.395 17.00 17.00 16,08 16.08 2,10 2.10 2,98 2.98 0,28 0.28 19.00 19.00 11,84 11.84 2,7 2.7 3,00 3.00 0,335 0.335 21.00 21.00 12,0 12.0 2,5 2.5 3,00 3.00 0,335 0.335

Příklad 2Example 2

Pri technologii úpravy vody z lokality Ondava sa na koaguláciu použil kombinovaný koagulačný prostriedok s obsahom 70 hm. dielov síranu hlinitého a 30 hm. dielov práškového zeolitu s veťkosťou častíc 90 % pod 90 ^u, 10 % nad 90 /U a 2 % nad 20 s obsahom klinoplitolitu 0 50 %.In the technology of water treatment from the Ondava locality, a combined coagulation agent with a content of 70 wt. parts of aluminum sulphate and 30 wt. parts of zeolite powder with a particle size of 90% below 90%, 10% above 90% and 2% above 20 with a clinoplitolite content of 50%.

Výsledky sú uvedené v následujúcej tabulke.The results are shown in the following table.

Tabulka 2Table 2

Dá turn a hodina odběru He gives a turn and an hour of collection Surová voda Raw water Upravená voda Treated water oxidov. v mg.l“1 oxides. in mg.l “ 1 obsah NH. _i4 v mg.l NH content. _i4 in mg.l oxidov. v mg.I“1 oxides. in mg.I “ 1 obsah NH. _η4 v mg.l NH content. _η4 in mg.l 22.5.1987 1.00 5/22/1987 1.00 14,8 14.8 3,8 3.8 2,16 2.16 0,04 0.04 3.00 3.00 12,0 12.0 3,43 3.43 1,52 1.52 0,05 0.05 5.00 5.00 9,28 9.28 3,05 3.05 1,2 1.2 0,06 0.06 7.00 7.00 6,24 6.24 2,75 2.75 .. 1.-2 .. 1.-2 0,04 0.04 9.00 9.00 6,4 6.4 3,2 3.2 1,36 1.36 0,04 0.04 11.00 11.00 i 618 and 618 1,15 1.15 1,68 1.68 0,02 0.02 13.00 13.00 6.72 6.72 1,01 1.01 1,76 1.76 0,02 0.02 15.00 15.00 6,64 6.64 1,15 1.15 1,68 1.68 0,02 0.02 17.00 17.00 6,24 6.24 0,925 0.925 1,76 1.76 0,01 0.01 19.00 19.00 5,2 5.2 1,05 1.05 1,52 1.52 0,085 0.085 21.00 21.00 5,12 5.12 1,18 1.18 1,52 1.52 0,075 0.075

CS 267323 BlCS 267323 Bl

Claims (2)

1. Kombinovaný koagulačný prostriedok na báze síranu hlinitého vhodný najma pre technológiu úpravy pitných vod, obsahujúcich aménne ióny, vyznačený tým, že pozostává zo1. A combined coagulant based on aluminum sulphate, suitable in particular for the technology of treatment of drinking water containing amine ions, characterized in that it consists of: 60 až 70 hmotnostných dielov síranu hlinitého (Alj(80^)j) a 40 až 30 hmotnostných dielov jenne mletého práškového.zeolitu·60 to 70 parts by weight of aluminum sulphate (Alj (80)) and 40 to 30 parts by weight of ground-milled zeolite powder. 2. Kombinovaný koagulačný prostriedok podlá bodu 1, vyznačený tým, že jemne mletý práškový zeolit připadne obsahuje 48 až 52 % klinoplitolitu.2. The combined coagulant composition according to item 1, characterized in that the finely ground zeolite powder optionally contains 48 to 52% of clinoplitolite.
CS8710101A 1987-12-29 1987-12-29 Combined coagulating agent CS267323B1 (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0551061A1 (en) * 1991-12-12 1993-07-14 Kemira Kemi Aktiebolag Process for the preparation of a coagulating chemical

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0551061A1 (en) * 1991-12-12 1993-07-14 Kemira Kemi Aktiebolag Process for the preparation of a coagulating chemical

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