CS262384B1 - Steel for castings with high toughness and resistence against abrasive wear - Google Patents
Steel for castings with high toughness and resistence against abrasive wear Download PDFInfo
- Publication number
- CS262384B1 CS262384B1 CS871079A CS107987A CS262384B1 CS 262384 B1 CS262384 B1 CS 262384B1 CS 871079 A CS871079 A CS 871079A CS 107987 A CS107987 A CS 107987A CS 262384 B1 CS262384 B1 CS 262384B1
- Authority
- CS
- Czechoslovakia
- Prior art keywords
- steel
- abrasive wear
- castings
- wear
- high toughness
- Prior art date
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- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 9
- 239000010959 steel Substances 0.000 title claims abstract description 9
- 238000005266 casting Methods 0.000 title claims abstract description 8
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 5
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims abstract description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 4
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims abstract description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000011575 calcium Substances 0.000 claims abstract description 4
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 4
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 4
- 239000011733 molybdenum Substances 0.000 claims abstract description 4
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 4
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 4
- 239000011574 phosphorus Substances 0.000 claims abstract description 4
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 4
- 239000011593 sulfur Substances 0.000 claims abstract description 4
- 239000010936 titanium Substances 0.000 claims abstract description 4
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229910052684 Cerium Inorganic materials 0.000 claims abstract description 3
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 3
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 3
- 239000011651 chromium Substances 0.000 claims abstract description 3
- 229910052742 iron Inorganic materials 0.000 claims abstract description 3
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims abstract description 3
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 3
- 239000010703 silicon Substances 0.000 claims abstract description 3
- 229910001208 Crucible steel Inorganic materials 0.000 abstract description 2
- 239000002245 particle Substances 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- -1 aluminum nitrides Chemical class 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical class [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 235000019738 Limestone Nutrition 0.000 description 1
- QFGIVKNKFPCKAW-UHFFFAOYSA-N [Mn].[C] Chemical compound [Mn].[C] QFGIVKNKFPCKAW-UHFFFAOYSA-N 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000009533 lab test Methods 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 238000005496 tempering Methods 0.000 description 1
Landscapes
- Heat Treatment Of Steel (AREA)
Abstract
Řešení se týká oceli na odlitky odolné proti opotřebení, která je vhodná pro vysoce dynamicky namáhané strojní součásti, vystavené intenzivnímu abrazivnlmu opotřebení médiem s tvrdými částicemi. Ocel na odlitky odolná proti abrazivnlmu opotřebení obsahuje v hmotnostní koncentraci 0,30 až 0,40 % uhlíku, 0,60 až 0,90 % manganu, 0,20 až 0,50 % křemíku, 0,80 až 1,10 % chrómu, 0,90 až 1,25 % niklu, 0,15 až 0,25 % molybdenu, 0,01 až 0,028 % fosforu, 0,01 až 0,028 % síry a zbytek železo. Dále obsahuje v hmotnostní koncentraci 0,01 až 0,05 % titanu, 0,005 až 0,03 % ceru, 0,005 až 0,03 » vápníku a 0,01 až 0,08 % hliníku.The solution relates to steel for casting resistant against wear that is suitable for highly dynamically stressed machine parts exposed to intense abrasive wear with hard particle media. Abrasive-resistant cast steel wear contains in mass concentration 0.30 to 0.40% carbon, 0.60 to 0.90% manganese, 0.20 to 0.50% silicon, 0.80 to 1.10% chromium, 0.90-1.25% nickel, 0.15 to 0.25% molybdenum, 0.01 to 0.028% phosphorus, 0.01 to 0.028% sulfur and the remainder iron. It also contains in mass concentration 0.01 to 0.05% titanium, 0.005 to 0.03% cerium, 0.005 to 0.03% calcium a 0.01 to 0.08% aluminum.
Description
Vynález se týká oceli na odlitky s vysokou houževnatostí a odolnosti proti abrazivnímu opotřebení, která je zvlášt vhodná pro mezistěny trubnatých mlýnů na mletí cementu, kladiva tlukadlových mlýnů na drcení vápence a další vysoce namahané strojní součásti.BACKGROUND OF THE INVENTION The present invention relates to casting steel of high toughness and abrasive wear resistance, which is particularly suitable for the walls of cement mill mills, limestone grinder hammers and other highly stressed machine parts.
Doposud se používají na výrobu značně dynamicky zatěžovaných součástí, vystavených abrazivnímu opotřebeni, nízko a středně legované podeutektoidní oceli se sorbitiokou strukturou. Nevýhodou uvedených ocelí je, že se po dezoxidaci hliníkem vyloučí křehké kys.ličníky hliníku ve tvaru ostrohraných nekovových vměstků na hranicích primárních zrn.Up to now, low and medium alloyed under-eutectoid steels with sorbitol structure have been used for the production of highly dynamically loaded components subjected to abrasive wear. A disadvantage of said steels is that, after deoxidation with aluminum, brittle aluminum oxides in the form of sharp-edged non-metallic inclusions at the primary grain boundaries are eliminated.
Při vyšším obsahu dusíku se při tepelném zpracování vyloučí na hranicích primárních zrn křehké nitridy hliníku. V zušlechtěném stavu při tvrdosti 47 HRC se sorbitickou strukturou -2 dosahují oceli nízké rázové houževnatosti KCV = 0,07 až 0,15 MJ.m . Následkem toho po určité době provozního využití odlitků dochází k praskání součástí, což snižuje jejich životnost. Hodnota poměrné odolnosti proti abrazivnímu opotřebeni je max. 1,7.At a higher nitrogen content, brittle aluminum nitrides are deposited at the primary grain boundary during heat treatment. In the heat-treated state at a hardness of 47 HRC with a sorbitic structure of -2, steels of low impact strength KCV = 0.07 to 0.15 MJ.m are achieved. As a result, after a certain period of operational use of the castings, the components crack, reducing their service life. The value of relative abrasive wear resistance is max. 1.7.
Uvedené nedostatky odstraňuje ocel na odlitky odolná proti abrazivnímu opotřebení s vysokou rázovou houževnatostí a vyšší odolností proti abrazivnímu opotřebení, obsahující v hmotnostní koncentraci 0,30 až 0,40 % uhlíku, 0,60 až 0,90 % manganu, 0,20 až 0,50 % křemíku, 0,80 až 1,10 % chrómu, 0,90 až 1,25 % niklu, 0,15 až 0,25 % molybdenu, 0,01 až 0,028 % fosforu, 0,01 až 0,028 % síry, zbytek tvoří železo, podle vynálezu. Jeho podstata spočívá v tom, že obsahuje hmotnostní koncentraci 0,01 až 0,05 % titanu, 0,005 až 0,04 % ceru,Above mentioned drawbacks are eliminated by abrasive wear resistant casting steel with high impact resistance and higher abrasive wear resistance, containing in the concentration of 0.30 to 0.40% carbon, 0.60 to 0.90% manganese, 0.20 to 0 50% silicon, 0.80-1.10% chromium, 0.90-1.25% nickel, 0.15-0.25% molybdenum, 0.01-0.028% phosphorus, 0.01-0.028% sulfur the remainder being iron according to the invention. It consists of a concentration of 0.01 to 0.05% by weight of titanium, 0.005 to 0.04% of cerium,
0,005 až 0,03 % vápníku a 0,01 až 0,08 % hliníku.0.005 to 0.03% calcium and 0.01 to 0.08% aluminum.
Základní výhoda oceli na odlitky podle vynálezu spočívá v zvýšené houževnatosti, způsobené tím, že se nekovové vměstky rozptýlí ve struktuře a nachází se uvnitř zrn.The basic advantage of the cast steel according to the invention is the increased toughness caused by the non-metallic inclusions being dispersed in the structure and located within the grains.
Úplně se odstraní vyloučení křehkých oxidů a nitridů na hranicích primárních zrn. Při zušlechtění na tvrdost 47 HRC se hodnota vrubové houževnatosti zvýší na hodnotu KCV = _o = 0,200 až 0,300 MJ.m . Rovněž hodnota poměrné odolnosti proti abrazivnímu opotřebení x, je vyšší 2,0 až 2,2.Elimination of brittle oxides and nitrides at primary grain boundaries is completely eliminated. When hardening to 47 HRC hardness, the notch toughness value is increased to a value of KCV = _o = 0.200 to 0.300 MJ.m. Also, the value of relative abrasive wear resistance x is greater than 2.0 to 2.2.
Vynález bude dále popsán na dvou příkladech provedení.The invention will now be described with reference to two exemplary embodiments.
Příklad 1Example 1
Ocel na odlitky odolná proti abrazivnímu opotřebeni s vysokou rázovou houževnatostí, určená na výrobu mezistěn a kladiv:Abrasive wear resistant casting steel with high impact resistance, designed for the production of partition walls and hammers:
Prvek Hmotnostní koncentraceElement Mass concentration
uhlík mangan křemík chrom nikl molybden fosfor síra hliník titan vápník cercarbon manganese silicon chromium nickel molybdenum phosphorus sulfur aluminum titanium calcium cer
0,370.37
0,850.85
0,440.44
1,091.09
1,161.16
0,220.22
0,0240.024
0,0250,025
0,0700,070
0,0500.050
0,0300.030
0,0120.012
Příklad 2 uhlík mangan [% hmot]Example 2 Carbon Manganese [wt%]
0,340.34
1,051.05
Z výše uvedených taveb byly vyrobeny vzorky pro laboratorní zkoušky a odlitky pro provozní zkoušky. Tepelné zpracování: vzorky byly žíhány na měkko 780 °C, 4 h, ochlazení v peci. Kalení: ohřev 830 °C, ochlazená voda. Popouštění: ohřev 400 °C, 3 h, následovalo _2 ochlazení ve vodě. Tvrdost 47 až 49 HRC, rázová houževnatost KCV = 0,215 až 0,280 MJ.m Pevnost v ohybu σρθ = 1 800 až 1 950 MPa. Poměrná odolnost proti abrazivnímu opotřebení /CSN 01 5084/ JL= 2,0 = 2,2.Samples for laboratory tests and castings for operational tests were made from the above melts. Heat treatment: samples were annealed to 780 ° C for 4 h, cooled in an oven. Hardening: heating 830 ° C, cooled water. Tempering: heating 400 ° C, 3 h, followed by 2 cooling in water. Hardness 47 to 49 HRC, impact strength KCV = 0,215 to 0,280 MJ.m Flexural strength σ ρ θ = 1 800 to 1 950 MPa. Relative wear resistance / CSN 01 5084 / JL = 2.0 = 2.2.
Claims (1)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CS871079A CS262384B1 (en) | 1987-02-19 | 1987-02-19 | Steel for castings with high toughness and resistence against abrasive wear |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CS871079A CS262384B1 (en) | 1987-02-19 | 1987-02-19 | Steel for castings with high toughness and resistence against abrasive wear |
Publications (2)
Publication Number | Publication Date |
---|---|
CS107987A1 CS107987A1 (en) | 1988-08-16 |
CS262384B1 true CS262384B1 (en) | 1989-03-14 |
Family
ID=5344235
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CS871079A CS262384B1 (en) | 1987-02-19 | 1987-02-19 | Steel for castings with high toughness and resistence against abrasive wear |
Country Status (1)
Country | Link |
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CS (1) | CS262384B1 (en) |
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1987
- 1987-02-19 CS CS871079A patent/CS262384B1/en unknown
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CS107987A1 (en) | 1988-08-16 |
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