CS246593B1 - Paper stock for production of a base of dioso-type tracing paper - Google Patents

Paper stock for production of a base of dioso-type tracing paper Download PDF

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Publication number
CS246593B1
CS246593B1 CS833657A CS365783A CS246593B1 CS 246593 B1 CS246593 B1 CS 246593B1 CS 833657 A CS833657 A CS 833657A CS 365783 A CS365783 A CS 365783A CS 246593 B1 CS246593 B1 CS 246593B1
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CS
Czechoslovakia
Prior art keywords
cellulose
paper
product
dioso
production
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CS833657A
Other languages
Czech (cs)
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CS365783A1 (en
Inventor
Leonid A Scerbin
Anatolij D Nechajcuk
Gennadij P Strejs
Gennadij B Razin
Gennadij N Andrejev
Alexandr I Jakuskin
Original Assignee
Leonid A Scerbin
Anatolij D Nechajcuk
Gennadij P Strejs
Gennadij B Razin
Gennadij N Andrejev
Alexandr I Jakuskin
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Application filed by Leonid A Scerbin, Anatolij D Nechajcuk, Gennadij P Strejs, Gennadij B Razin, Gennadij N Andrejev, Alexandr I Jakuskin filed Critical Leonid A Scerbin
Publication of CS365783A1 publication Critical patent/CS365783A1/en
Publication of CS246593B1 publication Critical patent/CS246593B1/en

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Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/47—Condensation polymers of aldehydes or ketones
    • D21H17/49—Condensation polymers of aldehydes or ketones with compounds containing hydrogen bound to nitrogen
    • D21H17/50—Acyclic compounds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
    • D21H17/24—Polysaccharides
    • D21H17/25—Cellulose
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
    • D21H17/24—Polysaccharides
    • D21H17/28—Starch
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/37—Polymers of unsaturated acids or derivatives thereof, e.g. polyacrylates
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/41—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing ionic groups
    • D21H17/42—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing ionic groups anionic
    • D21H17/43—Carboxyl groups or derivatives thereof

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Saccharide Compounds (AREA)
  • Paper (AREA)
  • Crystals, And After-Treatments Of Crystals (AREA)

Description

HaasaHne Η3θ6ρβτβΗΗ«: ΕΪΜΑΜΑΉ MA.CCA βΠΗ Η3Γ0Τ0ΒΠΕΗΗΗ OCHOBbl ΗΗΑ3ΟΤΗΠΗΟΗKAJlbKH Η3θ6ρβΤβΗΗβ OTHOCHTCfl Κ IÍ&njII0JIO3HO“6yMa»HOň npOMbnnJieHHOCTH, Β naCTHOCTHΚ npOHSBOflCTBy ĎyMarH-OCHOBbl flHa3OTHnHOfl KanbKH. H3BecTHa 6yMa»HaH Macca pjin Η3Γοτοβπθηηη KanbKH, BKrnonaroman uenniono3y,CBH3ytómee h onTHnecKHň oT6e.nHBaTe.nb. B KanecTBe CBH3yioinero Tanan ĎyMajKHanMacca coflepjKHT 4-6Z Kap6oKCHMeTHnuenmono3bi. flHa30KanbKa, nonyneHHaH H3H3BecTHoň 6yMa«Hoň Maccbi, Taxace ημθθτ HH3xyio coxpaHneMOCTb ·/1 /.HaasaHne Η3θ6ρβτβΗΗ ": ΕΪΜΑΜΑΉ MA.CCA βΠΗ Η3Γ0Τ0ΒΠΕΗΗΗ OCHOBbl ΗΗΑ3ΟΤΗΠΗΟΗKAJlbKH Η3θ6ρβΤβΗΗβ OTHOCHTCfl Κ II & njII0JIO3HO" 6yMa »Hon npOMbnnJieHHOCTH, Β naCTHOCTHΚ npOHSBOflCTBy ĎyMarH-OCHOBbl flHa3OTHnHOfl KanbKH. H3BecTHa 6yMa HaH Macca pjin Η3Γοτοβπθηηη KanbKH, BKrnonaroman uenniono3y, CBH3ytómee h onTHnecKHn oT6e.nHBaTe.nb. B KanecTBe CBH3yioinero Tanan ĎyMajKHanMacca coflepjKHT 4-6Z Kap6oKCHMeTHnuenmono3bi. flHa30KanbKa, nonyneHHaH H3H3BecTHoň 6yMa «Than Maccbi, Taxation HH3xyio coxpaHneMOCTb · / 1 /.

BjiH«aňiHHM ananoroM HacTOHqero Η3θ6ρβτβΗΗΗ no TexHHnecKoň cymHocTH h flo-CTHraeMOMy nonoacHTenbHOMy 3<ix}>eKTy BBJíaeTCH 6yMa«Han Macca «jih Η3γοτοβπθηηηochobu ^na3OTHnHofl KanbKH, coflepjfcaman uejiniono3HbiH nojiy<}>a6pHKaT, KaHHýonbHbiňKJieň, MOflHiJjHHHpoBaHHbiň xpaxMan h KoarynnHT /2/.BjiH «aňiHHM ananoroM HacTOHqero Η3θ6ρβτβΗΗΗ well TexHHnecKoň cymHocTH h flo-CTHraeMOMy nonoacHTenbHOMy 3 <ix}> eKTy BBJíaeTCH 6yMa« Han Macca «South Η3γοτοβπθηηηochobu ^ na3OTHnHofl KanbKH, coflepjfcaman uejiniono3HbiH nojiy <}> a6pHKaT, KaHHýonbHbiňKJieň, MOflHiJjHHHpoBaHHbiň xpaxMan h KoarynnHT / 2 /.

OcnoBa flHa3OTHnHoň KanbKH, H3roTOBJíeHHaH H3 Taxoň 6yMaJKHoň Maccu, o6na-flaeT HeflocTaTOHHO bhcokoh coxpaHneMOCTbio.OcnoBa flHa3OTHnHoH KanbKH, H3roTOBJeHHaH H3 Taxon 6yMaJKHoň Maccu, o6na-flaeT HeflocTaTOHHO bhcokoh coxpaHneMOCTbio.

UenbK) HacTOHinero Η3ο6ρθτθηηβ HBnneTcn noBbiuieHHe coxpaHneMOCTH flHaaoKanb-KH ΠρΗ ΟΛΗΟΒρβΜβΗΗΟΜ yjiyHUieHHH ΟΠΤΗΗβΟΚΗΧ H npOHHOCTHblX ee CBOňCTB . nocTaBJíeHHaa uenb flocTHraeTcn τβΜ, hto HáBecTHan 6yMa®Han Macca «na H3-roTOBJíeHHH flHaaoTHnHoň KanbKH, BKrnonaroman uenniono3HbiH nony<i)a6pHKaT, μο«η-Φηηηροβηηημη KpaxMan HKoarynaHT,flononHHTenbHo coflepjKHT npoflyKT KOHfleHcaijHHflHUHaHflHaMHfla, ypoTponHHa h (JjopManbflerHfla h BOflopacTBopHMbiň cononHMep βκρπ-noHHTpHna, MeTHnaKpnnaTa h HTaKOHOBoň KHcnoTbi πρκ cneayioineM cooTHomeHHHΚΟΜΠΟΗθΗΤΟΒ, MaCC.Zí ’ UenmonosHbiň nonyifcaĎpHKaT 90,5-98,3UenbK) HacTOHinero Η3ο6ρθτθηηβ HBnneTcn noBbiuieHHe coxpaHneMOCTH flHaaoKanb-KH ΠρΗ ΟΛΗΟΒρβΜβΗΗΟΜ yjiyHUieHHH ΟΠΤΗΗβΟΚΗΧ H npOHHOCTHblX ee CBOňCTB. nocTaBJíeHHaa uenb flocTHraeTcn τβΜ, HTO HáBecTHan 6yMa®Han Macca «H3-roTOBJíeHHH flHaaoTHnHoň KanbKH, BKrnonaroman uenniono3HbiH nonyl <i) a6pHKaT, μο« η-Φηηηροβηηημη KpaxMan HKoarynaHT, flononHHTenbHo coflepjKHT npoflyKT KOHfleHcaijHHflHUHaHflHaMHfla, ypoTponHHa h (h JjopManbflerHfla BOflopacTBopHMbiň cononHMep βκρπ-noHHTpHna , MeTHnaKpnnaTa h HTaKOHOBoň KHcnoTbi πρκ cneayioineM cooTHomeHHHΚΟΜΠΟΗθΗΤΟΒ, MaCC.Zí 'UenmonosHbiň nonyifcaĎpHKaT 90,5-98,3

MoflHýHííHpoBaHHbiň'KpaxMan 0,5-3,5 ňpoajyKT KOHfleHcauHH 0,1-0,5MoflHýHííHpoBaHHbiňKpaxMan 0,5-3,5 ópoajyKT KOHfleHcauHH 0,1-0,5

BoflopacTBopHMbiň cononHMep 0,1-2,0BoflopacTBopHMbi cononHMep 0.1-2.0

KoarynnHT 1,0-3,5.KoarynnHT 1.0-3.5.

B xanecTBe uenňiano3Horo nony<i>a6pHKaTa 6yMa»Han Macca coaep»HT cMecb cynbφΗΤΗοή xbohhoh óeneHoň ijennjono3bi h cynbφaτHoí^ xbohhoíí óenenoň uenniono3bi npHHX COOTHOIlieHHH, Mace. ZB xanecTBe uenniano3Horo nony <i> a6pHKaTa 6yMa »Han Macca coaep» HT cMecb cynbΗΤΗΗΤΗή xbohhoh ÃeneeneHoň ijennjono3bi h cynbaaHHhà ^i xbohhoià enenenun uenniono3bi npHHX COOTHOIlieHHH, Mace. FROM

CynbφHTHaH χβοηηηη 6eneHaa nenniono3a 30-85CynbφHTHaH χβοηηηη 6eneHaa nenniono3a 30-85

CynbφaτnaH XBOHHan 6enenan nennKinosa 15-70. 246593 6θΜβΤ3ΗΜβ ΜΟΑΗφπρΗρΟΒΗΗΗΟΓΟ Kp3XM3Jia, BOflOpaCTBOpHMOlO COnOJTOMepa Η Πρθ~flyKTa KOHflencaííHH b ĎyMaacHoň Macce πο3βοπηθτ yjiymiiHTb noBepxHoc.THo—CTpyxTypHbie CBOHCTBa ocnoBbi h cnn3HTb ,n,H<l>4)y3HK> flna3ococTaBa b ocHOBy, a Taxace yjjyn-niHTb pacTexaHHe h paBHOMepHocTb pacnpeflejieHHH ero no noBepxHocra SyMarn-OCHOBbl. IIo.nn(i>yHKiuioHa.nbHbiň xapaxTep ββοαημμχ b 6yMa«Hyio Maccy κομποηθητοβ cno-co6cTByeT yjiynuiCHHio aflrc3HOHHo-3JiaKTpocTaTHnaČKHX B3anMO,neňcTBnň hx c bojiokhom flenjnojio3bi b npopecce Φορμηροββηηη 6yMarn-ocHOBbi.Cynbialin XBOHHan 6enenan nennKinosa 15-70. 246593 6θΜβΤ3ΗΜβ ΜΟΑΗφπρΗρΟΒΗΗΗΟΓΟ Kp3XM3Jia, BOflOpaCTBOpHMOlO COnOJTOMepa Η Πρθ ~ flyKTa KOHflencaííHH b ĎyMaacHoň MACC πο3βοπηθτ yjiymiiHTb noBepxHoc.THo-CTpyxTypHbie CBOHCTBa ocnoBbi cnn3HTb H, N, H <l> 4) y3HK> flna3ococTaBa b ocHOBy and Taxation yjjyn-niHTb pacTexaHHe h paBHOMepHocTb pacnpeflejieHHH ero no noBepxHocra SyMarn-OCHOBbl. IIo.nn (i> b yHKiuioHa.nbHbiň xapaxTep ββοαημμχ 6yMa «Hyio MACC κομποηθητοβ cno-co6cTByeT yjiynuiCHHio aflrc3HOHHo-3JiaKTpocTaTHnaČKHX B3anMO, neňcTBnň hx c bojiokhom flenjnojio3bi b npopecce Φορμηροββηηη 6yMarn-ocHOBbi.

ConeTaHne b ρεηηιαπο3ΗθΜ πο,πγφΗβρΗίοτε 6eneHoň cyJ^bφnτHOH xbohhoh h 6e-JieHoň ονηΒφβτΗοή xboííhoh flajmiojio3bi flonojiHHTCJibHO cnoco6cTByeT ynymueHwoĎapbepHbix cbohctb ocHOBbi, a coneTaHHe c ocTajibHbíMH KOMnoHeHTaMH 6yMa»HoňMaccbi ynynniaeT b pejioM coxpaHHeMOCTb pna3OKaJibKH.ConeTaHne b ρεηηιαπο3ΗθΜ πο, πγφΗβρΗίοτε 6eneHoň cyJ bφnτHOH xbohhoh ^ H-6e JieHoň ονηΒφβτΗοή xboííhoh flajmiojio3bi flonojiHHTCJibHO cnoco6cTByeT ynymueHwoĎapbepHbix cbohctb ocHOBbi and coneTaHHe c ocTajibHbíMH KOMnoHeHTaMH 6yMa »HoňMaccbi ynynniaeT b pejioM coxpaHHeMOCTb pna3OKaJibKH.

KpoMe toto, ynynuiaioTCH Taoce MexaHmecKue η οπτΗΜεοκκε CBoňcTBa flnaao-'xanbKH. B xanecTBe μοαηΦηαηροβηηηογο xpaxMana Hcnonb3yioT κερτοφετίΒΗΜΗ hjih xyKy-pyaHbiň xpaxMan,. nojiyncHHbiH b προρεεεε majionHoň CTyneHnaToň τερΜοοβρεδοτκΗc nocnapyiomaň HaňTpann3apnaň h3jihiuhcíí manonn pacTBopoM pa36aBJieHHoň khcjio-Tbi. B xanecTBe rhcjiotm mojkbt 6biTb Hcnojib3OBaHa φοοφορΗΒΗ, connHaa, cepnaH,JiHMOHHaH hjih maBejieBan rhcjiotm. IlpoflyKT KOHflaHcapHH, npHMBHHCMbiň b SyMaac-Hoň Maccc, cooTBeTCTByaT CTaHflapTy.KpoMe toto, ynynuiaioTCH Taoce MexaHmecKue η οπτΗΜεοκκε CBoňcTBa flnaao-'xanbKH. B xanecTBe μοαηΦηαηροβηηηογο xpaxMana Hcnonb3yioT κερτοφετίΒΗΜΗ hjih xyKy-pyaHbiň xpaxMan ,. nojiyncHHbiH b προρεεεε majionHoň CTyneHnaToň τερΜοοβρεδοτκΗc nocnapyiomaň HaňTpann3apnaň h3jihiuhcíí manonn pacTBopoM pa36aBJieHHoň khcjio-Tbi. B xanecTBe rhcjiotm mojkbt 6biTb Hcnojib3OBaHa φοοφορΗΒΗ, connHaa, cepnaH, JiHMOHHaH hjih maBejieBan rhcjiotm. IlpoflyKT KOHflaHcapHH, npHMBHHCMbbi b SyMaac-Hoa Maccc, cooTBeTCTByaT CTaHflapTy.

ByMaacHyio Maccy πρηγοτοβμιοτ cncflyroniHM o6pa3OM.ByMaacHyio Maccy πρηγοτοβμιοτ cncflyroniHM o6pa3OM.

UeJlJIHM103Hblň nor^aBpHKaT CMeiUHBaiOT B yKa3aHHOM COOTHOIlieHHH. B CMeCbBBOflHT npopyKT KOHflCHcapnH h nonyncHHyio Maccy pa3MajibiBaioT b kohhucckhxMeribHHpax po noMona 85-90° IUP. BecoBoň noRa3aTejib ajihhm 50-56 prp. ΜθΑΗφΗρΗρθΒ3ΗΗΜΗ IflejIOHHOH KpaXMan CMeiUHBaiOT C BOflOpaCTBOpHMblM ΟΟΠΟΠΗΜε-poM b yKa3aHHbix KOJiwcTBax, pa36aBJiHK>T boaoh no KOHpcHTpayHH 1-6%. B pas-MOJlOTblH fleJIJIKUIO3HbIH ΠΟΤΐγφ3ί5ρΗΚ3Τ BBOflHT CMBCb ΜΟΑ,ΗφΗΙξΗρΟΒΒΗΗΟΓΟ IflejIOHHOrOKpaxMana h BOflopacTBopHMoro conoJiHMepa. Β μθηιηηηομ 6acceňHe b 6yMaacHyio Mac-,cy BBOflHT KoaryjiHHT h noJiyneHHyio 6yMaa<Hyw Maccy OTjiHBaioT Ha sRcnepHMeHTajib-hoh ManiHHc o6biHHbiM cnocoSoM. FIoJiynaioT ĎyMary-ocHOBy flHaBoxajibKH Maccoň 60 γ/μ* . Ha nojiHBoqHoň MauiHHe Ha 6yMary-ocHOBy HaHocnT αηη3οτηπημη cocTaB.nonyneHHyH) flna3oxajibKy noflBepraioT HcnbiTaHHHM.UeJIJIHM103Hbn nor aBpHKaT CMeiUHBaiOT B yKa3aHHOM COOTHIAlHHH. B CMeCbBBOflHT npopyKT KOHflCHcapnH h nonyncHHyio Maccy pa3MajibiBaioT b kohhucckhxMeribHHpax after noMona 85-90 ° IUP. BecoBoň noRa3aTejib ajihhm 50-56 prp. LejθΑΗφΗρΗρθΒ3ΗΗΜΗ IflejIOHHOH KpaXMan CMeiUHBaiOT C BOflOpaCTBOpHMblM ΟΟΠΟΠΗΜε-poMb yKa3aHHbix KOJiwcTBax, pa36aBJiHK> T boaoh no KOHpcHTpayHH 1-6%. B pas-MOJlOTblH fleJIJIKUIO3HbIH ΠΟΤΐγφ3ί5ρΗΚ3Τ BBOflHT CMBCb ΜΟΑ, ΗΙφΗΙξΗρΟΒΒΗΗΟΓΟ IflejIOHHOrOKpaxMana h BOflopacTBopHMoro conoJiHMepa. 6 θ θ ac ac ac ac ac ac ac Mac Mac Mac cy cy cy cy cy cy cy w w w w w w w w w w w s s s s s s s s s s s s s s s s s s s s s s s s s s. FIoJiynaioT ĎyMary-ocHOBy flHaBoxajibKH Maccoň 60 γ / μ *. Ha nojiHBoqHoň MauiHHe Ha 6yMary-ocHOBy HaHocnT αηη3οτηπημη cocTaB.nonyneHHyH) flna3oxajibKy noflBepraioT HcnbiTaHHHM.

Pa3yjibTaTbi HcnbiTaHHň o6pa3flOB flHa3OKajibKH, H3roTOBJieHHoň H3 SyMaacHoflMaccbi npcflCTaBjíCHbí b TaSjíHfle. ΠρΗΜερ 1. Ιϊο H3B8CTHoň τεχΗΟΡΟΓΗΗ γοτοβητ ByMaatHyio Maccy, coflcpacaiflyro, Macc.%:HejiJiio.no3Hbiň ποηγφβΒρΗΧΗΤ 90,5 ΜΟΑΗφΗΑΗρΟΒΗΗΗΜΗ KpaxMaji 3,5 npoflyxT KOHflCHcaflHH 0,5Pa3yjibTaTbi HcnbiTaHHn o6pa3flOB flHa3OKajibKH, H3roToSHoR H3 SyMaacHoflMaccbi npcflCTaBiBbbHyHHlHfl. ΠρΗΜερ 1. Hο H3B8CTHoň ε ň M M M M ByMaatHyio Maccy, coflcpacaiflyro, Macc.

BoflopacTBopuMbiň conoJiHMep 2,0BoflopacTBopuMbi conoJiHMep 2.0

KoaryjiHHT 3,5.KoaryjiHHT 3,5.

HeJiJiK>Jio3Hbiň no.n^a6pnKaT coctoht H3 CMecH, coflepacaifleň 85% ογιΐΒφΗΤΗοή6ejieHoň xbohhoh flcjunojio3bi h 15% ουπβΦβτηοη 6cjichoh xbohhoh ρετυηαποβω. ΠρΗΜερ 2. Πο H3BecTHoň TexHOJiorHH γοτοβητ SyMaatHyio Maccy, coflepacamyro, 'Macc.%:'»Hejunoji03HbiH no.n^a6pHKaT 98,3HeJiJiK> Jio3Hbi no.n ^ a6pnKaT coctoht H3 CMecH, coflepacaifleň 85% ογιΐΒφΗΤΗοή6ejieHoo xbohhoh flcjunojio3bi h 15% ουπβΦβτηοη 6cjichoh xbohhoh ρετυηαποβω. 2. Πο H3BecTHoň TexHOJiorHH γοτοβητ SyMaatHyio Maccy, coflepacamyro, 'Macc.%:' »Hejunoji03HbiH no.n ^ a6pHKaT 98.3

Mop^HflHpoBaHHbiň xpaxMaJi 0,5 npoflyxT KOHflencaflHH 0,1Mop ^ HflHpoBaHHbi xpaxMaJi 0.5 npoflyxT KOHflencaflHH 0.1

BoflopacTBopHMbiň conoJiHMep 0, 1BoflopacTBopHMbi conoJiHMep 0, 1

KoaryjiHHT 1,0.KoaryjiHHT 1.0.

Hejijnano3HbiH πο.πγφ36ρΗΚ3Τ coctoht H3 CMecH, copepacameň 30% ογιΐΒφΗΤΗοή 6e-JieHOH XBOňHOH U,ejIJII0JlO3bI H 70% Ογ,ΠΒφΒΤΗΟΗ XBOHHOH ĎeJieHOH fleJlJH0JlO3bi. 246593 ΠρΗΜβρ 3. Γοτοβητ SyMaJKHyio Maccy, coflepacamyro, Macc.%:Ij ij ano oc oc oc 3 3 3 oc oc oc ij ij%%%%%% 70% 70%%%%%%%%%%%%% B B B B B B B B B B B B B B B B B B B. 246593 Πρτβρ 3. τοτοβητ SyMaJKHyio Maccy, coflepacamyro, Macc.%:

Uenjnano3HbiH nonyýa6pHKaT 92,2 MoflH^HmHpoBaHHbiH KpaxMaji 3,0 IIpoflyKT KOHfleHcaixHH 0,3 BOflOpaCTBOpHMblH COnOJIHMep 1,5 KoarynHHT 3,0.Uenjnano3HbiH nony6HHbHaB 92.2 MoflH3HmHpoBaHHbiH KpaxMaji 3.0 IIpofylKT KOHfleHcaixHH 0.3 BOflOpaCTBOpHMblH COnOHIHMep 1.5 KoarynHHT 3.0.

UejiJiiono3Hbiň nony<ba6pHKaT coctoht H3 CMecH, coflepacaujeň 6O5S cyjibíiHTHoň 6eJieHOH XBOňHOH IíejUIK)JIO3bI. H 40% CyjIh<j)aTHOň XBOHHOH SeJieHOň IíeJJJnonO3bI.The thiocyanate is a phosphonate of coctoht H3 CMecH, cofounding with 6O5S cyanophthalene, HOH XBO6HOH, and SiO3bI. H 40% CyIHiOHiOn XBOHHOH SeiOnIlO3bI.

HpHMep 4 (no npoTOTuny). Γοτοβητ 6yMaatHyio Maccy, conepwamyio, Macc.%:'HpHMep 4 (no npoTOTONS). Yοτοβητ 6yMaatHyio Maccy, conepwamyio, Macc.%: '

BeneHan cyjib<}>HTHaH xBoňHannejijnano3a 68BeneHan cyjib <}> HTHaH xBoňHannejijnano3a 68

Cynb$aTHaH 6ejieHan xBoňHannejuiKMioaa 24,6Cynb $ aTHaH 6ejieHan xBoňHannejuiKMioaa 24.6

KaHH(|>OJIbHbIH KJieň 1 , 1KaHH (1: 1)

MoflH<J)HnHpoBaHHbiň KpaxMan 3,4MoflH <J) HnHpoBaHHbi KpaxMan 3.4

KoaryjiHHT 2,9. IIpHMep 5 (KOHTpOJIbHblň) , Γοτοβητ SyMamyra Maccy, coflepacamara, Macc.%:KoaryjiHHT 2.9. IIpHMep 5 (KOHTpOJIbHblň), SyMamyra Maccy, coflepacamara, Macc.%:

Uejiniojio3Hbiň noJiytfiaSpHKaT 97,5Ujiniojio3Hbiň noJiytfiaSpHKaT 97.5

Mo,n;H(l>nnnpOBaHHbiň KpaxMaji 0,5 ripoflyKT KOHfleHcanHH 0,5Mo, n; H (l> nnnpOBaHHbiB KpaxMaji 0.5 ripoflyKT KOHfleHcanHH 0.5

KoaryjiHHT 1,5.KoaryjiHHT 1.5.

ByMaacHan Macca b xanecTBe nenjnano3Horo nojiyifcaBpHKaTa conepxHT CMecbcyjibtfcHTHOH SeneHoň XBOHHoň nejunanoabi 70% h cyjib<l>aTHOH 6eneHOÉ XBoňHoň pen-JlK)JIO3bl 30%. IIpHMep 6 (KOHTpOJIbHblň) . Γοτοβητ SyMaatHyio Maccy, conepacamyio, Macc.%: IIejiJiiono3Hbiň nojiy<|)a6pHKaT 97,5ByMaacHan Macca b xanecTBe nenjnano3Horo nojiyifcaBpHKaTa conepxHT CMecbcyjibtfcHTHOH SeneHoň XBOHHoň nejunanoabi 70% h cyjib <1> aTHOH 6eneHOÉ XBoňHoň pen-JlK) JIO3bl 30%. IIpHMep 6 (KOHTpOJIbHblň). Mοτοβητ SyMaatHyio Maccy, conepacamyio, Macc.%: IIejiJiiono3Hbiň nojiy <|) a6pHKaT 97.5

MoflHíJiHnHpoBaHHbiň KpaxMan 0,5 BOflOpaCTBOpHMblň COnOJIHMep 0,5MoflHiJiHnHpoBaHHbi KpaxMan 0.5 BOflOpaCTBOpHMbln COnOJIHMep 0.5

KoarynHHT 1,5,KoarynHHT 1.5,

ByMaxcHan Macca b xanecTBe nejiJiK«io3Horo nojiy<l>a6pHKaTa coflépjKHT CMecbnejunono3 aHanorHHHo npHMepy 5.ByMaxcHan Macca b xanecTBe io3Horo noji <l> a6pHKaTa coflpjKHT CMecbnejunono3 aHanorHHHo npHMepy 5.

ByMajKHyro Maccy, 6yMary-ocHOBy h flHa30Kajibxy nojiyqawT aHajiorHHHO npHMe-py 1. Ν’ ΠρΗ-Mep IIpO3paHHOCTb, % ConpoTHBJíeHHe H3JioMy,HHCJIO flBOHHbIX ΠθρβΓΗδΟΒ CoxpaHneMOCTb, Mec. 1 2 3 4 1 43,0 860 6,5 2 37,1 900 5,5 3 40,5 890 6,0 4 32,5 725 4,0 ΠρΟΤΟΤΗΠ 246593 ti ÍIpoflOJi«eHHe Ta6nnubi i ' ; 5 35,0 6 36,5 730 4,5 728 4,5ByMajKHyro Maccy, 6yMary-ocHOBy h flHa30Kajibxy nojiyqawT aHajiorHHHO npHMe-py 1. Ν 'ΠρΗ-Mep IIpO3paHHOCTb,% ConpoTHBJiHHe H3JioMy, HHCJIO flBOHHbIX ΠθρβΓΗδΟΒ CoxpaHneMOCTb, Mec. 1 2 3 4 1 43,0 860 6,5 2 37,1 900 5,5 3 40,5 890 6,0 4 32,5 725 4,0 ΠρΟΤΟΤΗΠ 246593 Í p OJ OJ e e 6 6 6 6; 5 35.0 6 36.5 730 4.5 728 4.5

Ahžuih3 TaOjimjbi noxaabiBaeT, mto flHaaoKajribKa, πρηγοτοβπθηη3η H3 6yMa»HoňMaccbi, ΗΜββτ nywmyio coxpaHHeMOCTb no cpaBHeHwo c προτοτηπομ. ynymuaioTCHTaione onTHnecKHe h MexaHHwecKHe noKa3aTejiH nnaaoKanbKH.Ahžuih3 TaOjimjbi noxaabiBaeT, mto flHaaoKajribKa, πρηγοτοβπθηη3η H3 6yMa »HoňMaccbi, βββτ nywmyio coxpaHHeMOCTb no cpaBHeHwo c προτοτηπομ. ynymuaioTCHTaione onTHnecKHe h MexaHHwecKHe noKa3aTejiH nnaaoKanbKH.

BbifípaHHoe βοοτΗοηιβΗΗβ κοΜποΗβΗτοΒ GyMáxHoň Maccu ΗΒΠΗβτεΗ onTHManbHbíM,Tax xax npn Bbixofle κοΜποΗβΗτοΒ Maccu 3a yxa3aHHbie npeflenbi b CTopoHy yMeHb-ineHHH HJIH yBejIHMeHHH He ΠΟ3ΒΟΠΗβΤ flOCŤHMb 6θΙΙββ BblCOKOH COXpaHHeMOCTH (60-jiee 5 MecHneB) h Ββ/jeT tojibko Jinnib κ nepepacxony χημηκβτοβ. ΠρΗΜβρω 5-6CBHfleTenbCTByjOT O TOM, MTO npn ΗΟΚΠΙΟΜβΗΗΗ ΟβΗΟΓΟ H3 BHOBb ββοπημμχ ΚΟΜΠΟ—ΗβΗτοΒ cocTaBa coxpaHHéMOCTb Taxxe naaaeT. 3to CBHfleTGJibCTByeT o tom, mtocymecTByeT B3anMHoe βπμηηηθ κομποηθητοβ npyr na npyra b GyMaxHoe Macce. 246593 ΦΟΡΜΥΠΑ Η3ΟΒΡΕΤΕΗΜΉ 1. ByMawHaa Macca ujih H3roTOBJieHna ochobm una3OTHnHoň xanbKH, BKmonaioman iíejuiRwio3Hbiň nony4>a6pHKaT, μοήηΦηιιηροββηημη xpaxMaa h KoarynaHT, o τjiHMaromaacH τβΜ, ητο, c uejibio noBbiuieHHa coxpaHaeMocTH una3OKa.nbKH npH ΟβΗΟΒρβΜβΗΗΟΜ yJiyHIIieHHH OnTHHeCKHX H npoaHOCTHbIX ee CBOňCTB, MaccaAonojiHHTenbHO coflepKHT npouyKT KOHfleHcaijHH flHUHaHAHaMHfla, ypoTponHHa h$opMaabflerHfla h BOflopacTBopuMbiň conojiHMep aKpnjioHHTpmia, MeTHJiaKpmiaTa hHTaKOHOBOň KHCJIOTbl npH CJieflyiOmeM COOTHOIUeHHH ΚΟΜΠΟΗβΗΤΟΒ, Mace. Z:BbifípaHHoe βοοτΗοηιβΗΗβ κοΜποΗβΗτοΒ GyMáxHoň MACC ΗΒΠΗβτεΗ onTHManbHbíM, Tax XAX npn Bbixofle κοΜποΗβΗτοΒ MACC 3a yxa3aHHbie npeflenbi b CTopoHy yMeHb-ineHHH HJIH yBejIHMeHHH He ΠΟ3ΒΟΠΗβΤ flOCŤHMb 6θΙΙββ BblCOKOH COXpaHHeMOCTH (60 jiee MecHneB 5) h Ββ / Jet tojibko Jinnib κ nepepacxony χημηκβτοβ. ΠρΗΜβρω 5-6CBHfleTenbCTByjOT About TOM, MTO npn ΗΟΚΠΙΟΜβΗΗΗ ΟβΗΟΓΟ H3 BHOBb ββοπημμχ ΚΟΜΠΟ — ΗβΗτοΒ cocTaBa coxpaHHéMOCTb Taxxe naaaeT. 3to CBHfleTGJibCTByeT about mtocymecTByeT B3anMHoe βπμηηηθ κομποηθητοβ npyr na npyra b GyMaxHoe Macce. 246593 ΦΟΡΜΥΠΑ Η3ΟΒΡΕΤΕΗΜΉ first ByMawHaa Macca ujih H3roTOBJieHna ochobm una3OTHnHoň xanbKH, BKmonaioman iíejuiRwio3Hbiň nony4> a6pHKaT, μοήηΦηιιηροββηημη xpaxMaa h KoarynaHT about τjiHMaromaacH τβΜ, ητο c uejibio noBbiuieHHa coxpaHaeMocTH una3OKa.nbKH NPH ΟβΗΟΒρβΜβΗΗΟΜ yJiyHIIieHHH OnTHHeCKHX H npoaHOCTHbIX ee CBOňCTB, MaccaAonojiHHTenbHO coflepKHT npouyKT KOHfleHcaijHH flHUHaHAHaMHfla, ypoTponHHa h $ opMaabflerHfla h BOflopacTBopuMBon conojiHMep aKpnjioHHTpmia, MeTHJiaKpmiaTa hHTaKOHOBOn KHCJIOTbl npH CJieflyiOmeM COOTHOIUeHHH ΚΟΜΠΟΗβΗΤΟΒ, Mace. FROM:

UejiJiiojiO3Hbiň no.ny<l>a6pHKaTMoflHKfcHUHpOBaHHblň KpaxManIIpoflyKT KOHfleHcauHH. uHUHaH-fluaMHfla, ypoTponHHa η φορ-MaJihfleriwaUHiSHiOnHyHyHyHyHyHyHyHyHyHHyHyHnHyHHnHnHyPHyPHyPHyLH KHfleHcauHH. uHUHaH-fluaMHfla, ypoTponHHa η φορ-MaJihfleriwa

BoflopacTBopHMbiň conojiHMepaKpujioHHTpHjia, MeTHJiaKpn-jiaTa h HTaxoHOBoň khcjiotmKoarynaHT 2. Macca no n. 1, OTaHnaromaaca no3Horo ποπνφβδρΗΚΒΤβ oHa coflepacHT CMecb ον-ΠΒφΗΤΗοή xbohhoíí SeneHoň uen-jhojiosm h cyJ^bφaτHoň XBoňHoň SejieHoň nejunojio3bi npH hx οοοτηοπιθηηη, -Macc.íSCyj^HTHaa XBoňHaa 6ejie-BoflopacTBopHMbiň conojiHMepaKpujioHHTpHjia, MeTHJiaKpn-Fusing h HTaxoHOBoň khcjiotmKoarynaHT second n Macca no. 1 OTaHnaromaaca no3Horo ποπνφβδρΗΚΒΤβ OHA coflepacHT CMecb ον ΠΒφΗΤΗοή xbohhoíí SeneHoň-toluene-jhojiosm cyJ h ^ bφaτHoň XBoňHoň SejieHoň nejunojio3bi NPH hx οοοτηοπιθηηη, -Macc.íSCyj ^ HTHaa XBoňHaa 6ejie -

Haa uejunojio3a 30-85 0νπΒφ3ΤΗ3Β XBoňHaa 6ejie-Haa uejunojio3a 30-85 0νπΒφ3ΤΗ3Β XBoňHaa 6ejie-

Haa ueji.nio.no3a ,15-70. 90,5-98,3 0,5-3,5 0,1-0,5 0,1-2,0 1,0-3,-5 τθμ, hto b xanecTBe uejuno- 246593 Η3θ6ρετβΗΗβ othochtch κ ueJimano3HO-6yMa?KHoň npoMbnnjieHHocTH.Haa ueji.nio.no3a, 15-70. 90,5-98,3 0,5-3,5 0,1-0,5 0,1-2,0 1,0-3, -5 τθμ, hto b xanecTBe uejuno- 246593 Η3θ6ρετβΗΗβ othochtch κ ueJimano3HO-6yMa ? KHoň npoMbnnjieHHocTH.

Uenb H3o6peTeHHH - noBbímeHHe coxpaHHeMocTii flna3OKa.nbKH řípu onnoppe- ΜβΗΗΟΜ ynyqmeHHH ΟΠΤΜΗβΟΚΗΧ H npOHHOCTHMX ee CBOHCTB.Uenb H3o6peTeHHH - noBbHHe coxpaHHeMocTii flna3OKa.nbKH ripple onnoppe- ΜβΗΗΟΜ ynyqmeHHH ΟΠΤΜΗβΟΚΗΧ H npOHHOCTHMX ee CBOHCTB.

EyMajKHan Mácca o jih η3γοτοβπ6ηηη ochobh xrna3OTWiHoň KanbKH, BKmonaioiuaH iíejimojio3Hbiň nony<l)a6pnKaT, MOflmfcHUHpoBaHHbiň KpaxMan h KoarynHHT, cornacHoΗ3θ6ρβΤβΗΗΙ0, flOnOJIHHTejlbHO COflepjKHT npOflyKT KOHfleHCailHH flHIJHaHjaHaMHfla,ypoTponHHa h <J)opMajibflern,aa h BonopacTBopuMbiň cononuMep aKpHJioHHTpHJia, MeTHJI3KpHJiaTa Η ΗΤΗΚΟΗΟΒΟΙΙ KHCJIOTbl npn CJieflywmeM COOTHOineHHH ΚΟΜΠΟΗβΗΤΟΒ,Macc.%:EyMajKHan MACC the south η3γοτοβπ6ηηη ochobh xrna3OTWiHoň KanbKH, BKmonaioiuaH iíejimojio3Hbiň nonyl <l) a6pnKaT, MOflmfcHUHpoBaHHbiň KpaxMan h KoarynHHT, cornacHoΗ3θ6ρβΤβΗΗΙ0, flOnOJIHHTejlbHO COflepjKHT npOflyKT KOHfleHCailHH flHIJHaHjaHaMHfla, ypoTponHHa h <J) opMajibflern aa h BonopacTBopuMbiň cononuMep aKpHJioHHTpHJia, MeTHJI3KpHJiaTa Η ΗΤΗΚΟΗΟΒΟΙΙ KHCJIOTbl npn CJieflywmeM COOTHOineHHH ΚΟΜΠΟΗβΗΤΟΒ, Macc.

UejiJH0Jio3Hbiír nony<i)a6pHKaTMoflH(}>nynpoBaHHbiň KpaxMannpoflyKT KOHfleHcauHH ,hh-UHaHflHaMHHa, ypoTponHHaΗ (JlOpMaJlbfferHflaUejiJH0Jio3Hbiír nony <i) a6pHKaTMoflH (}> nynpoBaHHbi KpaxMannpoflyKT KOHfleHcauHH, hh-UHaHflHaMHHa, ypoTponHHaΗ (JlOpMaJlbfferHfla

BOflOpaCTBOPHMblíí ΟΟΠΟΠΗΜβρaKpHJiOHHTpHJia, MeTHjiaKpH-naTa h HTaKOHOBoň kucjiothKoaryjiHHT 90,5-98,3 0,5-3,5 0,1-0,5 0,1-2,01,0-3,5BOflOpaCTBOPHMbíí ΟΟΠΟΠΗΜβρaKpHJiOHHTpHJia, MeTHjiaKpH-naTa h HTaKOHOBoň kucjiothKoaryjiHHT 90,5-98,3 0,5-3,5 0,1-0,5 0,1-2,01,0-3,5

IlpH3HaHo n3o6peTeHneM no pe3ynbTaTaM 3KcnepTH3bi, ocymecTBjíeHHoň Eocy-·flapcTBeHHbíM ΚοΜΗτετοΜ CCCP no nejiaM Η3θ6ρβτβΗΗΗ η οτκρητηη. 246593IlpH3HaHo n3o6peTeHneM no pe3ynbTaTaM 3KcnepTH3bi, ocymecTBjíeHHoň Eocy- · flapcTBeHHbíM ΚοΜΗτετοΜ CCCP no nejiaM Η3θ6ρβτβΗΗΗ η οτκρητηη. 246593

Claims (2)

PfiBDMfiT VYNÁLEZU 246 593EMBODIMENTS OF THE INVENTION 246 593 1. Papírovina pro výrobu základu diazotypového pauzo-vacího papíru, zahrnující celulózový polotovar, modifiko-vaný škrob a koagulant, vyznačující se tím, že za účelemzvýšení skladovátelnosti diazotypového pauzovacího papírupři současném zlepšení optických vlastnosti a pevnosti,obsahuje hmota produkt kondenzace dikyandiamidu, urotropinua formaldehydu a vodorozpustný kopolymer akrylonitrilu,metylakrylátu a itakonové kyseliny při poměru složek vehmot. % : celulozový polotovar 90,5 až 98,3 modifikovaný škrob 0,5 až 5,5 kondenzační produkt dikyandiamidu,úrotropinu a formaldehydu 0,1 až 0,5 ve vodě rozpustný kopolymer akryloni-trílu, metylakrylátu a kyselinyitakonové 0,1 až 2,0 koagulant 1,0 až 5,5What is claimed is: 1. A pulp for the manufacture of a diazotype pausing paper base comprising a cellulosic preform, modified starch and coagulant, characterized in that, in order to enhance the storability of the diazotype tracing paper in the simultaneous improvement of optical properties and strength, the mass comprises a product of condensation of dicyandiamide, urotropin and formaldehyde; a water-soluble copolymer of acrylonitrile, methyl acrylate, and itaconic acid at a ratio of excipients to. %: cellulose semi-finished product 90.5 to 98.3 modified starch 0.5 to 5.5 condensation product dicyandiamide, úrotropin and formaldehyde 0.1 to 0.5 water-soluble copolymer of acrylonitrile, methyl acrylate and aciditaconic acid 0.1 to 2 0 coagulant 1.0 to 5.5 2. Papírovina podle bodu 1, vyznačující se tím, že jekocelulozový polotovar obsahuje směs sulfitové a sulfátové'jehličnanové bělené celulózy při složení ve hmot. % sulfátová jehličnanová bělená celulóza 50 až 85sulfátová jehličnanová bělená celulóza 15 až 702. A pulp furnish according to claim 1, wherein the cellulose semifinished product comprises a mixture of sulphite and sulphate bleached cellulose at a composition by weight. % kraft coniferous bleached cellulose 50 to 85sulfate coniferous bleached cellulose 15 to 70
CS833657A 1982-06-15 1983-05-23 Paper stock for production of a base of dioso-type tracing paper CS246593B1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
SU823452405A SU1054476A1 (en) 1982-06-15 1982-06-15 Pulp composition for making diasotype tracing-paper substrate

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CS365783A1 CS365783A1 (en) 1985-10-16
CS246593B1 true CS246593B1 (en) 1986-10-16

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SU1054476A1 (en) 1983-11-15
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DD239510A3 (en) 1986-10-01

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