CS233302B1 - Process for preparing rhenic acid - Google Patents

Process for preparing rhenic acid Download PDF

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Publication number
CS233302B1
CS233302B1 CS559478A CS559478A CS233302B1 CS 233302 B1 CS233302 B1 CS 233302B1 CS 559478 A CS559478 A CS 559478A CS 559478 A CS559478 A CS 559478A CS 233302 B1 CS233302 B1 CS 233302B1
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CS
Czechoslovakia
Prior art keywords
reaction zone
sparingly soluble
acid
preparing
bcero
Prior art date
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CS559478A
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Czech (cs)
Inventor
Rudolf Hering
Karl Becker
Hans D Neubauer
Original Assignee
Rudolf Hering
Karl Becker
Hans D Neubauer
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Application filed by Rudolf Hering, Karl Becker, Hans D Neubauer filed Critical Rudolf Hering
Publication of CS233302B1 publication Critical patent/CS233302B1/en

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  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

Vynález se týká způsobu přípravy kyse- , liny rhenisté s vyšší koncentrací z težce rozpustných rhenistanů. Podstata vynálezu ) spořívá v tom, že se suspenze těžce roz - *pustného rhenistanů,, s výhodou rhenistanů draselného, při zvýšené teplotě, s výhodou při teplotě 90 až 100 ®0, uvede do styku se silně kyselým katexem v kyselém cyklu zpočátku v mechanicky míchaném loži v prvním pásmu reakce a potom se vznikající roztok uvede ve styk v druhém pásmu reakce s pevným ložem uvedeného ionexu.The invention relates to a method for preparing rhenic acid with a higher concentration from sparingly soluble rhenistans. The essence of the invention is that a suspension of sparingly soluble rhenistan, preferably potassium rhenistan, is brought into contact with a strongly acidic cation exchange resin in an acid cycle at an elevated temperature, preferably at a temperature of 90 to 100 °C, initially in a mechanically stirred bed in the first reaction zone and then the resulting solution is brought into contact in the second reaction zone with a fixed bed of the said ion exchange resin.

Description

(54)(54)

Způsob přípravy kyseliny rhenisté f Vynález se týká způsobu přípravy kyse, liny rhenisté s vyšší koncentrací z težce rozpustných rhenistanů. Podstata vynálezu ) spořívá v tom, že se suspenze těžce roz *pustného rhenistanů,, s výhodou rhenistanů draselného, při zvýšené teplotě, s výhodou při teplotě 90 až 100 ®0, uvede do styku se silně kyselým katexem v kyselém cyklu zpočátku v mechanicky míchaném loži v prvním pásmu reakce a potom se vznikající roztok uvede ve styk v druhém pásmu reakce s pevným ložem uvedeného ionexu.The present invention relates to a process for the preparation of rhenistic acid with a higher concentration of sparingly soluble rhenates. SUMMARY OF THE INVENTION The principle of the invention is that a suspension of the sparingly soluble perrhenates, preferably potassium perrhenates, at elevated temperature, preferably at 90 to 100 ° C, is contacted with a strongly acid cation exchanger in an acid cycle initially in a mechanically stirred The solution is then contacted in a second fixed-bed reaction zone of said ion exchange resin.

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Η3Ο<5ρθΤΘΗΗΘ Kacae:TQH_CnObOÓa νΠΟ^ΠΘΗΕίί: CpSQBHHT&HBHb KOKUeHTpHpOBaHHOií neppeHHeBQfiLKHCJIÓTH ,0_ ÉHCOKOŽ JCTeUSHiK HHCTOTH H3 TpyaHOpaCTBOpHMHX IieppeHaTOB ΠρΗΜΘΗΘΗΗβΜ ΗΟΗΟΟόΜβΗΗΗΧ . cmoji. Oho oTJiinaeTCH τθμ, ητο ποκοοόΜβΗ προΒΟβΗτ b bw khcjioth chjibho khcjihx KaTHOHHTOB npz TeMnepaTypax npeuMyinecTβθηηο 90 - 100° C, npjHeM CHanana .npeBpaiwT cycneH3Hio neppeHaTa b MexaHHnecKH nepeMeiuaHHoii nepBoft 30He pearcuroi, nocjie · ήθγο npeBpameHHe bo BTopofi 3οηθ Ha TBepno pacnoJioseHHoii hohoΟόΜβΗΗΟδ CMOJTe KOHHaeTCH.Aca3Ο <5ρθΤΘΗΗΘ Kacae : TQH _ CnObOoa νΠΟ ^ ΠΘΗΕίί: CpSQBHHT & HBHb KOKUeHTpHpOBaHHOi neppeHHeBQfiLKHCJITH, 0_ EHCOKOŽ JCTeUSHiβΗΜΘΗΘΗΗHHOTOTH3ΠHHOTOTH3PHHPOTHhP THHPOTHhPHHHPOTHhPHHHPOTHpP cmoji. Oho oTJiinaeTCH τθμ, ητο ποκοοόΜβΗ προΒΟβΗτ b bw khcjioth chjibho khcjihx KaTHOHHTOB HPH TeMnepaTypax npeuMyinecTβθηηο 90-100 ° C npjHeM Hanan .npeBpaiwT cycneH3Hio neppeHaTa b MexaHHnecKH nepeMeiuaHHoii nepBoft 30He pearcuroi, nocjie ήθγο npeBpameHHe · bo BTopofi 3οηθ Ha TBepno pacnoJioseHHoii hohoΟόΜβΗΗΟδ CMOJTe KOHHaeTCH.

Předmět vynálezuObject of the invention

Claims (1)

Způsob přípravy kyseliny rhenisté s vyšší koncentrací z těžce rozpustných rhenistanů, vyznačený tím, že se suspenze těžce rozpustného rhenistanů, s výhodou rhenistanů draselného, při zvýšené teplotě, s výhodou při teplotě 90 až 100 °C, uvede do styku se silně kyselým katexem v kyselém cyklu zpočátku v mechanicky míchaném loži v prvním pásmu reakce a potom se vznikající roztok uvede ve styk v druhém pásmu reakce s pevným ložem uvedeného ionexu.A process for the preparation of a higher concentration of rhenistic acid from sparingly soluble rhenates, characterized in that a suspension of sparingly soluble rhenates, preferably potassium perrhenates, at elevated temperature, preferably at 90 to 100 ° C, is contacted with a strongly acidic cation exchanger in acidic. cycle in the mechanically stirred bed in the first reaction zone and then the resulting solution is contacted in the second reaction zone with the fixed bed of said ion exchanger. Uznáno vynálezem na základě výsledků expertizy, provedené Úřadem pro vynálezectví a patentnictví, Berlín, (DD)Recognized by the invention based on the results of the expertise carried out by the Office of Invention and Patent, Berlin, (DD)
CS559478A 1977-09-27 1978-08-25 Process for preparing rhenic acid CS233302B1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DD20122077A DD143360A3 (en) 1977-09-27 1977-09-27 PROCESS FOR PREPARING OVERRENEIUM ACID

Publications (1)

Publication Number Publication Date
CS233302B1 true CS233302B1 (en) 1985-02-14

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Family Applications (1)

Application Number Title Priority Date Filing Date
CS559478A CS233302B1 (en) 1977-09-27 1978-08-25 Process for preparing rhenic acid

Country Status (4)

Country Link
BG (1) BG36533A1 (en)
CS (1) CS233302B1 (en)
DD (1) DD143360A3 (en)
SU (1) SU958323A1 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116768276A (en) * 2023-06-27 2023-09-19 矿冶科技集团有限公司 Method for removing silicon from ammonium rhenate

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DD143360A3 (en) 1980-08-20
BG36533A1 (en) 1984-12-16
SU958323A1 (en) 1982-09-15

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