CS218885B1 - Nitrodyes containing the silicon - Google Patents
Nitrodyes containing the silicon Download PDFInfo
- Publication number
- CS218885B1 CS218885B1 CS791665A CS166579A CS218885B1 CS 218885 B1 CS218885 B1 CS 218885B1 CS 791665 A CS791665 A CS 791665A CS 166579 A CS166579 A CS 166579A CS 218885 B1 CS218885 B1 CS 218885B1
- Authority
- CS
- Czechoslovakia
- Prior art keywords
- radical
- silicon
- nitro
- dyes
- natural
- Prior art date
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- 239000001005 nitro dye Substances 0.000 title claims 3
- 229910052710 silicon Inorganic materials 0.000 title claims 3
- 239000010703 silicon Substances 0.000 title claims 3
- 238000000034 method Methods 0.000 claims 3
- 125000004432 carbon atom Chemical group C* 0.000 claims 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- 125000003710 aryl alkyl group Chemical group 0.000 claims 1
- 125000003118 aryl group Chemical group 0.000 claims 1
- 238000004043 dyeing Methods 0.000 claims 1
- 239000000835 fiber Substances 0.000 claims 1
- 229910052736 halogen Inorganic materials 0.000 claims 1
- 150000002367 halogens Chemical class 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 1
- 229910010272 inorganic material Inorganic materials 0.000 claims 1
- 239000011147 inorganic material Substances 0.000 claims 1
- 150000002828 nitro derivatives Chemical class 0.000 claims 1
- 125000005375 organosiloxane group Chemical group 0.000 claims 1
- 239000000985 reactive dye Substances 0.000 claims 1
- 150000004756 silanes Chemical class 0.000 claims 1
- -1 siloxanes Chemical class 0.000 claims 1
- 239000002904 solvent Substances 0.000 claims 1
- 239000012209 synthetic fiber Substances 0.000 claims 1
- 229920002994 synthetic fiber Polymers 0.000 claims 1
- 241000191291 Abies alba Species 0.000 description 1
- 241001553014 Myrsine salicina Species 0.000 description 1
- 229910018540 Si C Inorganic materials 0.000 description 1
- 241000579875 Upupa Species 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B69/00—Dyes not provided for by a single group of this subclass
- C09B69/008—Dyes containing a substituent, which contains a silicium atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
- C07F7/1804—Compounds having Si-O-C linkages
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
Description
- 1 - 218 885
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UejIL Η3θύρθΤΘΗΗΗ
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ΠΡΗΜΘΡΗ OCymeCTBJíeHHH H3OdpeTOHHH
ΠρΗΜΘΡ I B XEMiraecKOM CTanaHe πρΗ λθγκομ βοτρηχηβηηηη ομθιπηβηιοτ 20,3 βθοοβόμnacTH 2,4-#HHHTpoxjiopdeH3OJia h 23 βθοοβηχηηοτη aMHHonporauiTpH3TOKCHoiPiana. Πρπ θτομ ομθοβ dncTpopa3orpeBaeTCH h 2,4-£HHHTpoxjiopdeH3OJi pacTBopaeTca b GHJia-ηθ c βη$θλόηηθμ ra.3a. Πο oxjiasAeHKH #o κομηβτηοΚ TeMnepa-
218 88S - 6 -
Typu nojiy^aeTCH sejpraS, jke®khS KpacHTejiB cjiejxyioineS οτργκ-W11 (C2H5O)3 Si - (GH2)3 - NH - C6H3(KO2)2 K chjiekohoboíí KayqyiaiaoTe, cocToamefi H3 100 βθοοβηχ nac-τθ® nojnmHMeTancHJioKcaHa c riyipoKcioLHHMií rpynnaMH h c bh3-KOOTBK) 5000 CCT, H3 50 ΒΘ00ΒΗΧ HaCTeS ΗΜΟρφΗΟίί EByOKHCHΚρβΜΗΗΗ Η I BecOBOS HaCTH ΒΟΛΗ, XOdaBJUBOT 2 ΒβΟΟΒΗΧ nacTHonucaHHoro KpacHTejiH. JLhh cihhbkh KayqyKiiacTti ^odanzunoT3 βθοοβηθ naoTH cm sen H3 flHdyT&ziflHJiaypaTa cwioBa h TeTpa-OKCHCHJiajaa. B peeyjiBTaTe noJiynaeTca chhhkohobhS KaynyK,ΗΗΤβΗΟΗΒΗΟ OKpaUjeHHHÍí Β 3ΚΘΛΤΗ0 ΙξΒΘΤ. 9τοτ chjhíkohobkě KaynyK no^Bepra/ní nporpeBy npn 180 °C bΤβΗΘΗΗΘ 24 Hac. , UpsreeM Ηβ nOHBJIHJIOCL ΗΗΚΒΚΟΓΟ Η3ΜΘΗΘΗΗΗoKpacKH.
Ecjbi οηληκοηοββη KaynyKnaoTa des .nodaBKH einHBaiomero arén-Ta tojibko ^aoTHHHO KOHfteHcupyeTCH c KpacHTejieM, to bo3mok-HO Η0Π0ΛΒ30Β8ΗΗΘ HpOflyKTa Β ΚΗΗΘΟΤΒΘ ΟΤΤΘΗΟΗΗΟΗ IiaCTH fiRSlCMecefi chjihkohobhx KayqyKOB. ΠρΗΜθΡ 2 20,3 B6G0B0M nacTH 2,4-AHHHTpoxjiopdeH3OJia pacTBopmoT πρκHarpeBaHHH β θτθήολθ b KpyrJioftOHHOH Kojide. K QTowy pacTBO-py flodawifnoT 26,6 βθοοβοη nacTH ομηηοθτηηθμηηοιιροιιιοτρη-MeTOKCHCHJiaHa. PacTBop cpaný se oKpainHBaeTCH β rjiydoKHHsejiTUH ΐξΒθτ. Πο οτγοηκθ 3Tanojia ocTaeTca τθμηο^θλτθη sh#~KOCTB. 5 r nojiyneHHoro KpacHTe&a pacTBopniOT β 95 r boah η β 3τοτpacTBop norpysaioT Kasfloe Ha 5 mhh. 5 r *xJioiraaTodyMasHoroBOJioKHa, 5 r mepcTH, 5 r ποληθμηληογο BojioKHa, 5 r nojiHaKpjm-HHTpmiLHoro BOJioKHa, 5 r ποΛΗθφπρΗΟΓο inejiKa, a Taicse 5 rU.eJUIKVIO3HHX BOJIOKOH. IÍOCJie IiponOJiaCKHBaHHH Η ΜΗΟΓΟΚΡΒΤΗΟΗ ΠρΟΜΗΒΚΗ b μηλβηομpacTBope θτη BOJioKHa coxpamiioT πολριθηηηκ ot sejiToro Kpa-ΟΗΤΘΛΗ SeJITHÉ ηβθτ.
218 88S - 7 - Πρημθρ 3 20,3 ΒΘΟΟΒΟΗ HaCTH 2,4-SHHHTpOXJIOpdeH3OJia paCTBOpíHOT πρκHarpeBaHHH b sTaHOJie b KpyiuiojioHHoft κωιόθ. K stomy pacTBO-py ^OÓaBJIHIOT 10,4 ΒΘΟΟΒΟϋ HaCTuJ aMHHO3THJiaMHHOIipOIIHJI-(Me-TiM-)flHMeTOKCHCHJiaHa h nojiynaiOT χηλκοοτβ rjiydoKoro μ&ητογοypeTa. 100 BecoBux nacTefi npo3paaHoS ΜθτιυιφβΗϋυιοίϋΐΗκοΗΟΒΟΗcmojih cMeniHBaroT c 0,2 βθοοβοΚ, jsaGTMo \ βηπιθηθββθηηογο Kpa-GHTejia h 3aTeM OTBepamaioT npH 200°C β TeaeHHe 2 aac. Τηκημodpa3OM nojiyqařOT TBepxyro, npospaHHyo cHjmKOHOByro CMOJiyatejiToro upeTa. Ecjih ηηοτηηκη KpaoHTejiH tojilko aacTHHHO koh-fleHCHpyioTca c HacTHHKaMH chjehkohoboh cmojih, T.e. de3 OTBep»ΑθΗΗΗ, TO 3Τ0Τ IipOEyKT MQ5K6T dHTL· HCnOJIB3OBaH ΚΘΚ ΟΤΤΘΗΟΉ-Haa nacTa jw chjihkohobhx cmoji. ΠρΗΜθΡ 4 82 ΒΘΟΟΒΗΧ aaCTH nOJIHMeTHJICHJIOKCaHa, ΚΟΤΟρΗΗ ΗΜΘ6Τ MOJieKy-jmpHHM Beč 820 η oftHy awEHorpyímy Ha MOJieKyjiy, cMeniHBaioTHedOJZLfflHMH ΠΟρίί&ΗΜΗ O 20,2 BCCOBOM HaCTBIO 2,4-AHHHTpO-XJiopdeH3Ojia, irpiraeM οηληκοηοβθη jkh£koctb OKpainHBaeTca bOKejiTuíi ιιβθτ c BunejienneM Teiuia. 50 r nojiHMeTHJiciuiOKcaHa c κοηη,θβημη γη^οκοηζιβηημη rpyn-·ΠθΜΗ H C BH3KOCTLK) HpHdjIH3HTeJII>HO 5000 CCT CMOIUHBaDT C0,05 r sejiTofi ckokohoboh mhjxkocth h c 3 r cmnBajomero arénTa, nojiyaeHHoro ομθιπηβηηηθμ 80 βθοοβηχ aacTeĚ TCTpaaTOKCH—cmíana h 20 βθοοβηχ aacTefi jHídyTiwtoaypaTa ojioBa. IlocjieBUflepOTBamía β τθηθηηθ 24 aac. πρκ KOMHaTHoS TeMnepaTypenojiynaioT npo3paaHHH jkcjithS chjihkohobhíí KayayK. - 8 - ΦΟΡΜΑ Η30ΕΡΕΤΕΗΗΗ
218 88S I. KpeMHHco^epjRainHe HHTpoKpacETejra λτιη οκρβιηκβηηηη oprarro-cmíoKcaHOB, peaKTHBHHe KpacHTejra rjíx HaTypajiBHtix η οηητθτηηθο-khx opraHEraecKHX bojiokoh mra jyra HeopraraiHecKHX MaTepnajiOB, OTjranaioiitHecH oóiqeíí $opMyjioft x-Si-Z-N- Ar(NOp)aR^ - b R* ΠρΗΗΘΜ KpaCHmuS ΚΟΜΠΟΗΘHT O ΠΟΜΟΙΙξΒΜ ΓΟΜΘΟΠΟΛΗρΗΗΧ 0ΒΗ3ΘΗ ΟΟΘ/ζΗ—ΗΘΗ C Si-aTOMOM H CHMBOJIH osHanaioT:x = oflHHaKOBue mm pa3JiHHHuc nmpojra3yeMHe rpyrnin mh
CmíHKOHOBHH pSJEEKaH; 2 = anKHJieHOBHfi panuKan c I-IO C-ητομθμη, oKaHHiroaMiiraScH bflaHHOM cjiynae - nr» - rpynnaMH; r = ojíHOBaJieHTHHE opraHiraecKHH pa^imaji; rjc ΒΟβοροΛ, ajrami c I-IO C—βτομημκ, apmi, apajmmi ra,τβκηθ 3aMemeHHtie pa^HKajni; 3aMeiiíeHHitíi mra He3aMemeHHufi apoMaTHHecKira pajíHKaJi; a = ΙίθΛΗΘ HHCJia ot I £0 3
Hb 2. Cnocoó ε3γοτοβλθηεη HETpoKpacHTejies no nyHKTy I, OTjranaio-
IIíHHCn ΤΘΜ, HTO CHJiaHH Mí CHJIOKCaHH Ο0ΙΙξθΗ gÓOpMyjIH x _ Si - Z - NHR*
R K3-b c ηητροοοοληηθηηημη oómefí φοριν^ΛΗ
Hal - Ar(N02)a πριτίβΜ R, R’, x, Z , a h b ημθιοτ BtmienpEBefleHHEie 3ηηηθηηη nHal 03HanaeT aTOM rajioreHa, pearupyioT npn HopMajr&HOH mra ne-μηογο ποβηιπθηηοη TeMnepaType b οτθχηομθτρεηθοκομ οοοτηοπιθηηη. 3. Cnocoó no nyHKTy 2, oTjnraawracn τθμ, hto peaKiran ocyiye-CTBJIHOTCH B paCTBOpETejie. 4. Cnocoó no nyHKTy 3, οτηκηοιοιιτηκοη τθμ, hto peaKiB-ra ocyiue-CTBJLHCTCH C HaTypaJIBHHMH EJIH ΟΗΗΤΘΤΗΗΘΟΚΗΜΗ ΒΟΛΟΚΗΗΜΗ H HTOBO3HHKaioirae peaKTHBHHe KpacHTejra cpa3y οβη3ηββίοτοη g bojiokhom. - 9 -
218 88S AHHOTaUHfl
KpeMHHifcojiepxaiitfíe HHTpoKpacHTejm odqeá $opMyjm X. - S± - Z - N - Ar(NO)b f , * a
R j-b roflHTCH, b jxáHHOM cjiyiae τβκκβ b we οττβΗοπίοκ nacT,jyia oKpainHBaHHH nojiHMepmax coejmHeHnfi opramraecKofi mmHeopraHBraeoKoS upupo^u h ocodeHHO chjihkohobhx npoAyKTOB,a TaKxe κηκ ρθθκτηβηηθ KpacHTejna jyia HaTypajiLHux h chh-τθτΗΉθοκΗΧ bojiokoh. Hx ocodoe npeHMyniecTBO 3aKJHHaeTCHB B03M0XH0CTH BCTpHHBaHHH KpaCJBUerO ΚΟΜΠΟΗΘΗΤΗ B HOJIH-MepHyx» MOJieKyjiy nocpe^CTBOM roMeonojiapHofi CBH3H. Hx no-jiy^eHne JierKO peanH3yeTca aepe3 peaiawo omiaHOB m ch- xoKcaHOB odmeSi φορΜγτΐΉ x - si - z - nhr* b · R3-b
0 HHTpodeH3OXBHHMH ΟΟββΗΗθΗΗΗΜΗ Odlij θϊί <£opMyjEH
Hal - Ar(N02)a rse x osBa^aeT οληηθκοβηθ mm paajimiHhie rmjpojui3yeMHerpynHH mm cHJioKcaHOBiiS pa#HKazi h n»1 03HaaaeT aTOMrajioreHa.
Claims (4)
10 218 885 PŘEDMĚT VYNÁLEZU
1. Nitrobarviva obsahující křemík pro barvení organosiloxanů,pro přírodní a syntetická organická vlákna nebo pro anorga-nické materiály, obecného vzorce xb - Si - z - tj - δγ/νο3/ε R3-b Rkde znamená : X stejné nebo rozdílné hydrolyzovatelné skupiny nebo sili-konový radikál ; Z alkylenový radikál s 2 až 10 atomy uhlíku ; R jednovazebný organický radikál ; Rz vodík, alkyl s 1 až 10 atomy uhlíku, aryl, aralkyl nebopodobné substituované radikály ; A substituovaný nebo nesubstituovaný aromatický radikál ;a,b celá čísla od 1 do 3.
2. Způsob přípravy nitrobarviv podle bodu 1, vyznačující setím, že silany nebo siloxany obecného vzorce X, - Si - Z - NHRZb |. E3-b se nechávají reagovat s nitrosloučeninami obecného vzorceHal - Ar/N02/a kde R, R,z X, Z, a,b mají shora uvedený význam a Hal značíatom halogenu ve stechiometrickém -poměru.
3. Způsob podle bodu 2, vyznačující se tím,že se reakce prová-dí v rozpouštědle.
4. Způsob podle bodu 3, vyznačující se tím,že se reakce prová-dí v přítomnosti přírodních nebo syntetických vláken a vznikající reaktivní barviva se ihned vážou a vláknem. Uznáno vynálezem na základě výsledků expertizy, provedenéÚřadem pro vynálezectví a patentnictví, Berlín, DD.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DD78204590A DD145021A3 (de) | 1978-04-05 | 1978-04-05 | Verfahren zur herstellung neuer si iziumorganischer azofarbstoffe |
Publications (1)
Publication Number | Publication Date |
---|---|
CS218885B1 true CS218885B1 (en) | 1983-02-25 |
Family
ID=5512077
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CS791665A CS218885B1 (en) | 1978-04-05 | 1979-03-12 | Nitrodyes containing the silicon |
Country Status (7)
Country | Link |
---|---|
JP (1) | JPS54148820A (cs) |
CS (1) | CS218885B1 (cs) |
DD (1) | DD145021A3 (cs) |
DE (1) | DE2908207A1 (cs) |
FR (1) | FR2421932A1 (cs) |
GB (1) | GB2018798B (cs) |
SU (1) | SU973578A1 (cs) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4189429A (en) * | 1978-05-08 | 1980-02-19 | Minnesota Mining And Manufacturing Company | Hydrolyzable silyl-substituted dyestuffs for transfer printing |
JPS59157653A (ja) * | 1983-02-28 | 1984-09-07 | Mita Ind Co Ltd | 静電写真記録用トナ− |
FR2830188B1 (fr) | 2001-09-28 | 2005-01-28 | Oreal | Composition tinctoriale contenant un compose para-aminophenol ou para-phenylene diamine substitue par un radical silanique |
-
1978
- 1978-04-05 DD DD78204590A patent/DD145021A3/de not_active IP Right Cessation
-
1979
- 1979-03-02 DE DE19792908207 patent/DE2908207A1/de not_active Withdrawn
- 1979-03-07 SU SU797770490A patent/SU973578A1/ru active
- 1979-03-12 CS CS791665A patent/CS218885B1/cs unknown
- 1979-03-23 GB GB7910306A patent/GB2018798B/en not_active Expired
- 1979-04-04 FR FR7908523A patent/FR2421932A1/fr not_active Withdrawn
- 1979-04-05 JP JP4152879A patent/JPS54148820A/ja active Pending
Also Published As
Publication number | Publication date |
---|---|
GB2018798A (en) | 1979-10-24 |
FR2421932A1 (fr) | 1979-11-02 |
DE2908207A1 (de) | 1979-10-11 |
SU973578A1 (ru) | 1982-11-15 |
GB2018798B (en) | 1982-08-25 |
DD145021A3 (de) | 1980-11-19 |
JPS54148820A (en) | 1979-11-21 |
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