CS218864B1

CS218864B1 - Method of controlled rafination of the hydrocarbon oils by the sulphuric acid

Info

Publication number: CS218864B1
Application number: CS774078A
Authority: CS
Inventors: Hermann Butof; Helmut Gorke; Horst Heinicke; Herbert Martens; Gerhard Schroder
Original assignee: Hermann Butof; Helmut Gorke; Horst Heinicke; Herbert Martens; Gerhard Schroder
Priority date: 1977-12-14
Filing date: 1978-11-24
Publication date: 1983-02-25
Also published as: DD138020A3; BG37143A1; SU943266A1; HU181474B

Abstract

Vynález se týká způsobu řízené rafinace kyselinou 3Írovou, dýmavou kyselinou sírovou a/nebo kyselými pryskyřicemi s velkým obsahem kyseliny sírové za účelem získání speciálních olejů a regenerace použitých starých olejů. Cílem vynálezu je vypracování takové metody řízené rafinace kyselinou sírovou, kterou je možno uskutečniti podle jednoduché technologie, při stávajících zařízeních a při využití levných pomocných materiálu. Úkol spočívá v tom, aby pomocí vhodných příměsí se proces rafinace kyselinou sírovou řídil tak, aby na konci rafinace se vytvořily jednotlivé fáze rafinovaného oleje a kyseliny, aby se rychlost usazování fází z reakční směsi zvýšila a odpadlo nové zpracovávání pryskyřice a kyseliny. Úkol byl rozřešen díky tomu, se po přidání rafinačních činidel k reakční směsi se přidává fenolový dehet a voda. Po ustání se kyselina sírová a pryskyřice usazují rychlostí 2 až 3krát větší a reakční směs se rozděluje na fázi kyseliny sírové,pryskyřici a olej. Rafinovaný olej v případě potřeby může být po alkalickém promytí zpracován metylalkoholem nebo směsí metylalkoholu a vody.The invention relates to a process for controlled refining sulfuric acid, fuming sulfuric acid and / or large acidic resins sulfuric acid for recovery special oils and regeneration used old oils. The object of the invention is to develop such a method controlled sulfuric acid refining, which can be realized by simple technology, with existing facilities and using cheap auxiliary materials. The challenge is to help with suitable admixtures, the acid refining process sulfuric drove it to the end of refining individual refined phases were created oil and acid make up the speed phase settling from the reaction mixture increased the new resin processing has disappeared and acid. The task was resolved because of the addition refining agents to the reaction mixture phenol tar and water are added. Stopping sulfuric acid and resins settle at a rate of 2-3 times greater and the reaction mixture is divided into a sulfuric acid phase, a resin and oil. Refined oil in case may be required after alkaline washing treated with methanol or a mixture of methanol and water.

Description

t - r n w a a í í í í í í í í í í í í Uf

AíL o

Xs C; what

O

O 03 «r ·

O it · 'rV'AP? í pře

ΗΑ3ΒΑΕΪΕ E30EPETEW

Cnocod ynpaBJíHewoíí cepHOKXCJioíi paňxHarwc - I - OÓJiaCTL ΠρπΜΘΗΘΗΜ Π3Ο0ρθΤΘΒΗΗ ΗβοόρβτθΗπθ xacaeTca cnocoda ynpaBJíaeMofí partaaiwi cepHoftKHCJiOTOft, oJieyMOM h / c itjiií khcjiothhmií cMOjrazvnr dojiBniHM cojxep-and-ΚΗβΜ cepnoři KHCJIOTH £ SOUTH HOJiyHeHHH cnewíajiBHHX Mace h pefe-KepnpoEaHHH OTpaÓoTaHHHX Mace.

XapaKTepncTHxa η3ΒΘοτηηχ τθχηηήθοκηχ pememetry

PteBecTHo nojiyqerae cnemiaJiBHHX Mace π-otPA pereHepnpoBaHHe doTaHHHX Mace nocpe ^ cTBOM paŤHHanxH cepHOíí khcjiotoíí, ojieyMOMh / hJIH KHCJIOTHHMH CMOJiaMH C dOJIBUIHM ΟΟΚβρΤΚΒΗΗβΜ CepHOÍí KHCJIOTH.JIjw κοοτπ.κθηηη TpedyeMHX KaaecTB Heoóxojwio ποοτθπθηηοθ UPOS-jiemie okho- hjih MHorocTyneHaaToíí: belong) HHamr &. IlocJie Kajxnoft cTyne-htc paitxHanxx b ocasoK BananajoT κχολοτηκθ cmojih, κοτορκβ βη, ιι, θ-jmot H3 pa ^ xHxpoBaHHoro Macjia. OcaxjieHHe khcjiothhx cmoji H3peaKUHOHHoft ομθοη TpedyeT dojiBniHX 3aTpaT βρθμθηη .. Tax, bpsmhOCaajíeHHH KHCJIOTHHX CMOJI H3 peaKUHOHHOH CMeCH ΟόΒΘΜΟΜ 25 m3 npnnojiyaeHHH dejioro opraHHaecKoro Macjia cocTaBJíaeT b 33βιιοημοοτηot cTyneHH paíiHKaiw, rt 18 0 8 £ aacoB. the BOCCTaHOBJe xeOTpaOtaHHHX waceji cepnoft khcjiotoíi, and the Tarcse khcjiothhmh CMOJia-MH C dojilnTHM KHCJIOTH irpHXCWTCH CHHTaTBCHc eiqe djHHH. B o c t o c a c o t o b c a p e rt rt 14 £ 0 40 aacoB. Πρττ nojiyaeHHH τρπκοφορΜΟτοριίΗΧMaceší patfHHaiiHeíi rrapeKcnapatf> HHOB h napeKcnpoTOHBHX Mace BPE-MH ocaxneHKH n3-3a dojiee hh3koíí bh3Kocth odpadaTHBaeworo wacjiacocTaBJLaeT tojibko rt 14 8 No aacoB, onHaKO, π b of one hundred meters cjiyaae-pa3yeTca dojiBmoe κοληήθοτβο khcjiothhx cmoji. 0dpa3ywieca ripn3T0M HJIH BpyTOM nOJCOdHOM cnocode KHCJIOTHHe CMOJIH AOJIKHH dHTL · nepepadoTaHH b cneimajiBHHX ycTanoBKax hjih nenoHHposaHH de3Bpena jvlh oKpyisaiomeíí cpenn hjih odpadoTaiin πομοκφε c) οοοτηβτοτ-Byjomnx HečTpajrn3amíOHHHx ancopdnHOHHHX cpencTB h.

ÁJ

Crrocod patfraHamra cepHoíí khcjiotoíí, oJieyMOM h / hjih khcjiothkmhCMOJiaMír c óojr & inHM cojxep ^ AHNE cspHofi khcjioth c hcjibío noJiyHeHHHcnercíaiLHHX Wace h pereHepHpoBaHHH oTpadoTaHHHX Mace ημθθτtot HenocTaTOK, HTO ckopocth oca ^ ehhh ichcjiothhx cmoji h3 peax-iihohhom CMecn οηθηβ MajiH chromatography K3-3a dojimioro ΒρθΜΘΗΗ ocaxneHHHΠρΟΒθπθΗΗβ 3Τ0Γ0 npOHeCCa HenpepHBHHM CnOCOÓOM HJIH COBCeM He-B03M0HH0, HJIH CBH3aH0 C ΠΟΒΗΠΙΘΗΗΗΜΗ 3aTpaTaMH. JIpyTHM HesocTaTKOM hbjihctch CAMA odpasyrotqaHCH KHCJiOTHan cMOJia.nojiyqanuajTCH npn paftHHamiH CMOJia μομθτ tojibko no3HHee c TPY-20M π NPTII dojiBnmx 3aTpaTax dHTB nepepadoTaHa c HeynoBJíSTBopuTQ-jibhhmh pe3yjiBTaTa.wH, ujih ήθγο TpedyroTca cnemiaJiBHHe ycTpoiícTBa, jlonojiHiiTejiBHaH 3HepniH padonan cnjia h. Xoth npoMHBaHHe khcjiot-HHX CMOJI 03 B03M0ZHO, OUHaKO ΓΐρΐΙ 3TOM HapOHHOe X03HÍÍCTBO ΤβρΗΘΤTaKoe neHHoe βτορηηηοθ chpbb, khk cepHyro KiicjiOTy, cmojih h wac-jia.

Eme ohhkm ηθβ: οοτβτκομ pad5nHaixnn cepHoS khcjiotoíi yrJieBonopouHHXwaceji aBJíHeTCH dojiLman noTepa Máčejí - no 25 Bec .-%.

UejiL H3odpeTeHHH

Usjib o ii3odpeT6HHH HBJíHeTCH pa3padoTKa cnocoda ynpaBJíaeMofi pa- (fcHHamiH CepHOÍi KHCJIOTOÍI, OJieyMOM h / hJIH KHCJIOTHHMH CMOJiaMH cdojr & Imimi coHepatamieM cepHofí khcjioth c nejiBio noJiyaeHHa cneiiHajiB-πηχ Mace h pereHepnpoBaHHa OTpadoTaHHHX Mace Rip HcnojiB3o-EaHiiii npocToft TexBOJiorroi b HMefomnxca ycTaHOBKax π Rip ncnojiB-3OBaHiin neraeBHX BcnoMoraTOJiBHHX MaTepnazroB.

H3JionteHne cyiUHOcra H3odpeTeHHH B οοηοβθ H3odp6TOHiíH JiersHT 3a £ aaa pa3padoTaTB TaKoft criocod, KOTopuft no3BOJBíT ynpaBJíHTB Pat & HHamieíí cepHofí khcjiotoíi hjwnojiyaeHHH cnerpiajiBHHX Mace h pereHepupoBaHna OTpadoTaHHHX Ma-Cejl C nOMOqLJD COOTBeTCTByWIX HOdaBOK ΤΒΚΗΜ Odpa3OM, ΗΤΟ B KOHIiepeaKUHH padfoiHauzH odpa3yroTcn τρπ orrpeneJieHHHe $ and3H MacJia, cmo-south II KHCJIOTH, CKOpOCTB OCaKJieHHH $ a3 H3 peaKIBIOHHOft CM6CH no- - 3 - bhciitch, and nepepadoTza cmoohj from kzcoioth OTnazeT.

Coroiacno H3odpeTemno, κ peaKixzoHHofi CMecz Z3 yrzesozopoznoroMacoia of khcoioth b 3ββζοζμοοτζ ot ycTaHOBJíennoro iisbsct YSE-HHM cnocodOM KoonmecTBa pacczHzpy®íiíero cpezcTBa I nocjie from óaBJíemaH κοτοροΓΟ-Zzz is nocze oKOHzanzH cooTBeTCTByn ^ eronocJiepeaKixiiOHHoro nepzoza nepeiweniZBaHzz mlz NPZ NPZ-noKazzna HZZ HPZ ΠΟΜΟΖΖ ΠΗβΒΜΒΤΖΗΘΟΚΟΓΟ yCTpOÍICTBa ΠΖΖΒΤΘΘTTTTΘTTTTTTTTTToraTTTTTTTTTTTTTTTTTTTTTTT 0,01 0,01 0,01 0,01 0,01 0,01 0,01 0,01 0,01 0,01 0,01 0,01 0,01 0,01 0,01 0,01 0,01 0,01 0,01 £ £ £ £ £ £ £ £ £ £ £ £ £ £ £ £ £ £ £ 0,1 1,5 1,5ezezezez,..... cmocb nanpaB-'jiaeTCH b aimapaT — otctorhhk, b κοτοροΜ nocze κοροτζοΓΟ BpeMezzOTCTazBaHzz pa ^ zHzpoBaHHoe waczo odpa3yeT Bepxnzz czofi, cmo-za - cpezhzz czoz, and cepHaz zzczoTa - hzshzz czoz, κοτορζεmosho HenpepzBHO yzazHTB. Odpasyrozazcz 40 - 70% -it- cepnazKzczoTa z cMoza, dzarozapz zx xopomzM KazecTBaw, zbzhiotch zenβήμ cupBeM zzh μηογζχ τβχζζζβοκζχ npozeccoB. JIodaBzenze čpenozoBoro ζθΓΤΗ of Bozhich Moshe npoz3BozzTB paszezn-zzz it BMEC nocze npezBapzTezBHoro cMezzBanzH B zazecTBepacTBopzTezefl ocodenno ποζχοζητ čýeHozoEHe ζθγτζ, κοτοόηθ πο-zyzaioTCH πρζ sKCTpaxTZBHoz of zzctzzzhtzbhoz nepepadoTxe cnpo-ro čDenoza iuiothoctlk c) HPH OT 20 ° C 1.10 0 £ 1 25 γ / cm ac L L L 230 230 230 230 230 230 ° ° ° ° ° ° ° ° ° ° ° a a a a a a a a a a a a a

CooTHoineHze KOzzzecTB roenozoBoro aογτη z bozh 3aBnCZT ot pa-ípHHzpyeMHx yrzeBozopozHzx wacez, yczoBZH. papznazzz, CTenenznozzMepz3azzz, CTenezz ocMozemin of CTenemi KOKCOBanzn of βητθ-Kaxxiíero Z3 stopo odpasyromerocH πρζ θτομ cocTana BeiqecTB za-nezez kzczothoS cmozh. Zz ζ oda oda oda zz zz zz zz zz zz zz zz zz zz par par par par par par par par par par par par par par par par par par par ne ne ne ne B Mznezzax KanezBzzcepHofí kzczoth by BozazzBaxiTCH nacTZZKaMZ cmozh from cvzbc) o kzczo-th. B 3aBzczM0CTZ ot BemecTBeHHoro cocTaBa of gjz3zzecKzx cboz- - 4 - ctb oópa3ywcccH KanejreK khcjiothoS cmojih pa3JnreHLiM εβληθτοηποβθλθηηθ peaxnnoHHHx cweceS b npoixecce ocao3Hiia π paccjice-EHH.

Bhjio HaiineHo, ητο ποβθλθηηθμ peaKimoHHHx CMeceii b npoueccsxpaccjioeHHH h OTCTaHBaraiH mojkho yrrpaBJíHTL nyTeM EodaBKH toseo-ΛΟΒΟΓΟ «ΣζΘΓΤίΙ Η ΒΟβΗ. ΟΟΟΤΗΟΙΠΘΗΙΤθ MejKJOy pamHHHpyiOUHH BeiqeCTBOMφθ ΑθΓΤΘΜ Π BO £ OI COCTaBJLHST ΠρθΗΜγΕΘΟΤΒβΗΗΟ OT I: 0,0: 0,5 λο I: 1,5: 1,2. Ejiaro ^ apa ^ odaBJíeinw pacTBopiiTejia no-cjie jíodaBJíeHHH pamHHHpyraqero BeinecTBa iuih ποοεθ οκοηηβηηηcooTBeTCT ^ goiíero nocjiepeaKUHOHHoro nepno ^ a, odpasoBanne Kane-jieKVCMOJiu npezíOTBpamaeTCH hjih the προιιοχοβΗτ pacmeruieKHe evaporating 3OBaBinHXCH KaneJISK KHCJIOTHOÉ CMOJIH, iipH 3T0M CMOJia ΠΟΓΕΟΙΙ ^ ΘΤ-chloro φβΗΟ ^ ΟΒΗΜ βΘΓΤβΜ , and cepHaH KHCJiOTa pacTBopaeTCH b βολθ.HeKOTopaa ηβοτβ Φθηολοβογο λθγτη b 3aBHCHM0CTii ot TeMnepaTy-pa MoseT Óhtl Taxse pacTBopeHa b payóiiHHpoBaHHOM wacjie. It is not possible to change the temperature to 60 ° C. -JIOBHH ΛΘΓΟΤΒ B paCTBOp Ηβ ΒΗΛΘΛΗΘΤΟΗ HJIH ΒΗ £ β.ΊΗΌΤΟΗ OHeiIL Ma-JIO. OCTaTKH 3 ΗΟ H H ΓΤΗ H H H H H 3 3 3 3 3 3 3 3 3 3 ef ef ef ef ef ef ef ΛΒΗΟ ΛΒΗΟ h h...................

He y Bcex peaKmioHHax cMecež npn stux οτηοοητθλβηο hh3khxTewnepaTypax ot 20 ° C 60 ° C nponcxojjHT OT ^ enemie khcjiothot cmojm. Il3-3a bhcokoíí bh3kocth cmojih cepnan KiicnoTa οοταοτ-ch b CMOJie b φορΜθ xanejiL. Ojmaao χχχ τογο, HTOda H3desaTLποβηπιθκηη TeMnepaTypa ajih ποηεκθηιιη bh3kocth cmojih, MO-BO Heotíxojm ΒρθΜίϊ npouecca OTCTaHBaHHH ΠρίΙΒΟβΗΤΒ ΒΒΗίΧβΗΗΘ KHCJIOT B-H Hyio CMOJIHHyro fta3H, NPN 3T0M KaneJEbKH khcjioth οηθηβ xopomoOT ^ ejimoTCH cmojih rpm.

EacTpoe ocasjíeHne cepnon khcjioth h cmojih h3 peaicmiOHHOH CMO-cii.ocotíeHHO xopomee pa3j; ejieHne Ha τρη meat nponcxojniT BCJieji; -CTBiie H3tíHpaTejn> Hoa pacTBOOHMOCTH OTjjejrtHax BemecŤB MesnyCOdOH, dOJIBinOrO pa3JIKHILH IIJIOTHOCTH paCTBOpei B-B £ IHNX JjpyT PV- re BemecTB π dojiBinoi! pa3daBJieHHOCTH padbHHHpoBaHHoro Macjia.

30 30 30 30 í 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30. ΠρΠΜθΌ I. ,0 25.0 τ p p p p H H H H H H H H H H H H H 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 ITocjie oko Driven nightJiepeaKHHOHHoro nepiioiza, paBHoro15 MZHyTaM, succesTCH CMecB, cocToamaa H3 1.0 τ $ eHdJioBorojxerTH π 1,75 τ bojzh. j η η j ec ec ec ec ec ec ec ec ec ec ec ec ec ec ec ec ec ec ec OJ OJ OJ OJ OJ OJ OJ OJ OJ OJ OJ OJ OJ OJ OJ OJ OJ OJ OJ OJ OJ OJ BH BH BH B ^ ηη ηθμ cjioe BHmejiHJiocB τOKpameHHO # 3,2-b cjiado KpacHHfl γζβθτ 51 ^ -ofí cepHoii khcjioth b cpejz-ηθμ cJioe - 2.4 τ cmojih HB BepxBew cjioe - pazSnHHpoBaHHoe Macjio.OHHTueHHoe Macjio well TpajiHiiHOHHoft TexHOJiornn nepepadaTHBaeTca cnoMonzBD meJionHoro npoMHBa , EHCTUJUiHmieft h ocBeTJieHHeM. IlocJiemejioHHoro npoMHBamia npoH3BojzHTCH BTopoe προμηβηηηθ 7 Bec. % -mpacTBopoM H3 MeTHJiOBoro crrapTa h bohu b οοοτηοιιιθηηη I: I hjihΤΟΓΟ, HTOdH BHMHTB ΒΟΘ OCTaTKH ČĎeHOJIOBOrO ΖΖβΓΤΗ. ΠρΚΜβρ 2. 25,0 τ NpejiBapnTejiBHo OHHmeHHoft CMecn H3 HHizycTpHajiLHoro OTpa-doTaHHoro Macjia η ^ H T oro oro j j j 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5. IlocjieOKOHHaroiH nocjiepeaKiiHOHHoro irepnozia, rrpx nepeMemzBaHHH zzodaB-jiaeTca CMecB H3 1,2 τ cbeHOJioBoro 2,2θγτη η 2,2 t βοκη. 3aTe.MpeaKmioHHyro ομθοβ ocTaBJínioT OTCTanBaTBoa npz TeMnepaType 35 ° Cyne nepe3 6 nacoB peaKrmoHHaH cwecB pa3jzejweTca Hacjioh cepHoft khcjioth, cmojih h pacHiHHpoPaHHoro wacjia. <T'a3H CepHOi KHCJIOTH H CMOJIH HpHBOZCIJIHCB B ΖΒΗΗβΗΗβ MetHaJlKOIi.

3T0M 0dpa3OBaji0CL 3.9 T 52% -o3 cepHOĚ khcjioth h 3.1 T - 6 - cmojih. PapHHzpoBaHHoe Macjio nepepadaTmaeTca no TpajuaxuoHHcfiΤΘΧΗΟΖΟΓΗΗ.

25.0 τ HpHMep third ochobhopo Macjia, κοτοροθ dmio nojiyueHo E3 Ηθφτιι nyreMneperoHKH, ropopa ^ uHaunH, hobtophoh neperoHKH from jjenapafeHii-3aiW BHSKOCfBIO ΠΏΕ C 20 ° C 100 H CCT CpejJHHM MOXeKyjIHpiiiíMβθοομ 340 -MOJiL.r, κοτοροΘ jjojdkho read nepepadOTauo b de-jioe MHHepaJEBHoe Macjio MHorocTynemiaToS WasteOtKoS oxeyMOM, WasteFEBaeTca b uepBoz CTynsHH pa $ HHnpoBamiH npz noMonpi 4,4τ ojieywa. lipu ^ ajiLHe & neM nepeMemuBaHHH κ peaKUuoHHi cMecnflodaBJímoTCH 6,0 τ peacToRoRoRoY ή γ ή ή t t t t t ríepe3 3 nacapeaKimoHHaH ομθοβ pa3jjejiaeTCH on τρζ $ a3E - papiiHHPBaHHoeMacno, cMOJY from KHCJioTy. Πρζ stom odpasyioTCH 12,2 τ cmojie ii3,46 t OKpameHKofi b czado-KpacHuS ηβθτ 51,6% -ofi cepnoii kkcjio-th.

HpHMep 4.HaHPBaHHOMy Macy CTβτΒθρτοδ: CTajuni pa $ uHEpoBamiH ii3npuMepa 3 jjodaBjmeTca Ha uhtoh CTynenz pacjpnjupoBaHini 3.8 τojieyMa, Tyjja from npzeMeunBaHEH jxodaBJíaiOT ομθοέ, cocToamyx) H3 1.0 τ φΘΗΟ ^ ΟΒΟΓΟ ίξθΓΤΗ η 2.5 τ fight. Hepe3 5 uacoB peax-uzoHHaji CMecL pa3ja; ejiHeTCH Ha τρζ $ a3H - pa $ HHzpoBanHoe Maczo, CMOJiy from cepHyio KiiCJiOTy. Πρζ stom odpa3yeTCH 2.4 τ cmojih ii5.1 τ fight oii 62% -oft cepnoS kecjioth.

UpzMep 5 27.0 τ COMHOHHTHOTHOPHOTHOTTOPHOR $ opMaTopHoro Macjra paňiuni-pyioT c 2,2 τ cepnoS khcjioth. 5ρH555ímeímeímeímeeueueuUUUUUUUUUUU5555555555555555555555555555555555555555555555555 1,9 1,9 1,9 1,9 1,9 1,9 1,9 1,9 1,9 1,9 1,9 1,9 1,9 1,9 1,9 1,9 1,9 1,9 1,9 1,9 1,9 1,9 1,9 1,9 1,9 1,9 1,9 1,9 1,9 1,9 1,9 1,9 1,9 1,9 1,9ec 1,9 1,9ececececececececececececececececececececececececececececececec b cjrado-Kpaciimi ubot51.6% -cephoi khcjioth.

Corjiaciio H3odpeTefiiro npemiymecTBO cnocoda ynpaBJTHOMc? pacpnio-uhh cepHoft kecjiotoh nejiBK c) nojryueHHH cneimajiBHiJX Macex n pe ~ - 7 - reHepiipoBaHHH OTpatíoTaHHHx Mace οοηοβηββθτοη Ha that HTO on? .HOCTiiaeHHH seaaeMoro 3 $ cpeKTa npmvieHaioTca λβθ ήθεθεηθ η Bcerncaerxo nocTaBJíaeMHX noóaBKn - $ enoaoBoro λθγτη h fear htonpe £ OTBpainaeTCH oópa3OBai-IHE kiicjiothhx cmoji b ceopoctl ocaj-Y-HHH HeBCn0JrB30BaHH0fi CepHOfl KBCaOTH Η ΠΟΛρΐΗΒΙΠθ3θΒ CMOBH ΠΟ BtnnaeTca b-2-3 pa3a well OTHomeHiw κ οκοροοτπ ocaaaeffiia KSC-JIOTHHX CMOJI.npPT 3TOM CílOCOÓC He B03HHKaeT HHKaKIIX Ιϊροτς / ΚΤΟΒOTXOUOB, UpOHCXOJÍHT ΠΟΛΗΟΘ ΒΘΠ ^ ΘΟΤΒΘΗΗΟΘ Π0Π0ΒΒ30Β0ΗΗΘ BCeXhcxouhux npo # yKTOB, daarojíapa aewy He rcponcxo ^ HT 3arpa3HeiiHaOKpyaaucqefí h3-3a jienoHupoBaHna ra nepepadoTKH kbqjiot-hhx cmoji. Kpowe pačóHHpoBaHHoro Macaa noayaaioTca npo3paaHaa, OKpameHHaa b caado-KpacHOBaTídí πβθτ 40-70 ^ -aa cepnaa KiicaoTaη πθηηηη κομποηθητ - φθΗοχοΒΗΗ jjeroTL-CMoaa. Rmi xaj & Keii & eBoηοποχββοβηηηη KHcaoT no TpeóyeTca HHKaiwfi λοιιοβηιιτθββηοηOHHCTKH, O HeOÓXOJÍHMOCTH TaJEGKe Η ΟΗΘΗΤΠΟΗΘΗΤ φθΗΟΒΟΕΗΗ JJS -roTB-CMoaa pa3jíeaaTL c πομοήβε neperoHKK. .HaaLHenuiee npenMymecTBO coctoht b tom, ητο noTepir Macaa, nocpaBiieHino what CTapoit TexHoaorneft, CHuaaioTca jio 50% hb cbh3hC 3ΤΠΜ COXpaHHBTCH ΠΘΗΗΗΘ γΓΒΘΒΟΤζΟρΟΤζΗΗΘ Macaa.

Eaarojíapa ποβηιηθηηκ οκοροοτπ ocaKjjeHHa pa3jíeaeHHH peaKmiOH π-HOB cMecH CTAA bo3mo & HHM npoBejjeHHe cnocoóa pamxHainiH ο πο?.: Ο · H & E cepHoĚ KncaoTH n / c nan κηοβοτηηχ cMoa óoaLinHM cojíepaaini-ΘΜ CepHOlí KHCaOTH HenpepHBHHM CnOCOÓOM. 6. ΠρΕΜΘρ 25.0 τ npeTCBapzTeaLHo οηηπιθηηογο HHjjycTpiiaaLHoro OTpadoTan-ηογο Macau πρπ ηητθηοηβηομ πθρθμθιιιηββηηη noóaBaaioTCH 2.5 τKHcaoTHoS cmojih, NAV [epaaiiíe2: doatmoe κοχηηθοτβο cepnoíí icncno-th, KOTopaa oópa3OBaaacL πρπ paioHHamní cepnoři κηοποτη OC-IOB ηογο TpaHCtpopMaTopiíoro Macau. Oth KHcaOTHaa CMoaa HBaaeTcaMaaoBH3Kofl h conepaiiT 80 Bec.% CepHOM KncaoTH. Ilocae OKonaa-hhh nocaepeaKUnoHHoro nepHOjxa, paBHoro 30 MHHyTaM, jioóaBaaeT-ca ομθοβ, cocToamaa H3 1,3 τ οθηοποβογο πογτβ η 1,8 τ bojih. - 8 -

PeaKmiOHHSJi cwecB nepe3 5 nacoB pa3 £ ejiHeTCH npz TeunepaTypeOTCTaiEBaHHH, paBHoíi 38 ° c. B ιπβκηθη cnoeBimanaeT 3,6 τ OKpaineHHOii b cnado-KpacHHi ηβθτ 50 ^ -ofi cepnoiikhchoth, b cpejtHeM cnoe- 3,1 τ cmohh η b BepxHew οηοθ - pann-HiipoBaHHoe Macjio. «Hanin ííman nepepadoTKa pa $ iiHHpoBaHHoro mation ιιροζββολητοηοοοτΒθτοτΒθΗΐιο npHMepy I. ΠρΗΜθρ 7th 25.0 τ οοηοβηογο mation, nonyneHHoro KaK onzcano npiaiepe b 3 c βη3κοοτβκ paBHoS npn TeMnepaType 20 ° C for 410 h CCT cpenmc.'MOJieKyjiapHHM βθοομ 460 μοηβ.γ- 1 WasteYTHBaeTcn Ha nepBofíCTyneHH patpHHamni c 4,5 τ cepnoíi khchoth. P p p p p τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ OC H $ a3a - H3 7.8 τ cmohh h Bepxnnn wa-3a H3 pacpiHHpoBaHHoro Macna. Ha Βτοροίί CTOT pa $ HHamiH pa- (jEtHHpoBaHHoe mation odpadaTHBaeTca C for 2.5 h, τ oneyMa nočněοκοηηθηηη nocjiepeaKHHOHHoro nepzoAa, paBHoro 15 μηηυτβμ, λο daBJíHeTca 2,5-τ Φθηοποβογο λθγτη η 1.6 τ βολή. Ποοηθ otgtsji-BaHZH MOJSHO ΟΤΛΘΗΒΗΟ ΥΛθΗΗΤΒ $ a3H KHCHOTH, CMOH H pa $ HHHpO-ββηηογο Macna ΠρΗ 3tom odpa3yeTcn 3,3 τ 52 ^ -oii cepnoii khcho-th, 5,1 τ οΜΟΛΗΗοδ <pa3H η KHcnoe Macno b KanecTBe pamiIHHpO-BaHHoro Macna. b cnemiani, -Hoe Macno 3KCTpampoBaHneM cyni ^ oKncnoT η οτ0θληβοηηθμ ΠρΗΜβρ 8.-

25,0 το οοηοβηογο Macna, KaK onncaHO b npwepe 3, waste and THBa-et 5 τ cepHoS khchoth h 5 τ oneyMa. «HodaBneHne cepHoíl khcho-TH H OJieywa ΠρθΗ3ΒΟΛΗΤΟΗ ΠΟΟΗΘΛΟΒΘΤΘΗΒΗΟ ΟΛΗΟ 3a ΛργΤΕΜ. 30ρΘ3 30 30-ζ / Τ HOdaBHHETCH 12 Θ φΘ-30ΠΟΒΟΓΟ Η Η 4 Τ P- PeaKnHOHHaH ΟΜΘΟΒ ρΗ3ΛΘΠΗΘΤΟΗ ΠΟΟ-ΗΘ 1,5 - nacoBoro OTCTanBaimH. Ec KanecTBe ηππηοπ ónsn yna.; RnicT - 9 - 52 ^ -ofi cepHoS kzcjioth, cpejziež <£ a3u - 25,5 τ cmojzi z Bepxzeííffla3H - Kiicjioe Macjio. Kzczoe mbcjio zepepadaTHBaioT b cnezzazB-ηοθ wacjio, bzpzMepe 7. -YE & .r "^ ·, WasteAtBaeTCH zoBeBeBBoNpz no-μοπζζ 5.5 τzjjnjjjjjnnnnnnnnnnnnnnnnnnnnnnnnnnnnnnn τ τ τ τ τ τ τ τ τ. KzcJiOTHaa CMOJia cozepszT 88 Bec .-% cepHOíi KKCJiOTH of odpa3yeTCH npz paSimanira οοηοβηογο Tpancmop-MaTopHoro Macza c cepnoz zzczotoz. Ilocze ozoHnazzH nocjiepeaz-Ζηοηηογο nepzojia, paBHoro 45 MZHyTaM npz sa ^ & HezmeM nepeMenni-Bazzz zodasjímtCH 12,8 τ Φθηολοβογο οθγτη z 4,0 τ bozn. Peaic-ηοηηηη CMeGB pa3zejineTcz nocze 1.5 zacos OTCTazBaiizz for hzk-hjok) á> a3y, what ^ epsamyro 8.2 τ 52 ^ -o2 zzczoth, cpe / zzoio (oa-sy, what ^ epsamyio 26,3 τ cmozh from Bepxmoio $ a3y, what ^ epsamyio paoz-HaT b BE # e zzcjioro Macza. Kzczoe mhcjio nepepadaTmaioT b cne-zzaJiLzoe, zazzhoho b npzMepe 7.

α cc σ Ο Ο Γ "Ο ί

CC Ο 'I.Cnocod ynpaBJíHeMofi cepHOKZCJioS pagóznanzn yrneEo ^ OPOS-HHX Wace cepHoii kzcjioto2, ozeyMOM of / ^ iz zjiz kzcjiotk cmojis-mz c £ donLinzM what epsaHzeM cepHoíí kzcjioth c uejiLío nonynerniHcneííHajiLHHX Mace of perenepupoBaiiH OTpadoTaHřrax Wace, otjiz-naBonracH τθμ, ητο κ peaKiizoHHoÉ CMecz b 3aBHczM0CTZ rpm ycTa-HOBJT6HHoro y & e K3 ^ CTHHM cnocodoM KOJiznecTBa paoinrapyioinerocpejxcTBa I nocjie .nodaBJíenzH κοτοροΓΟ MRA nocne OKomianzncooTBeTCTByioinero nocjiepeaKiraoHHoro nepzojxa HPH nepeMemzBaHzzh TeMnepaType rpm 20 ° C but 60 ° C npennonTZTejiLHo - οτ 20 ° C No40 C , jiodaBJIfUDT φΘΗΟΛΟΒΒώ nichroTL z Bony b cooTHOffiemm papnnz-pynnero cpencTBa κ c £ eH0Ji0B0My λθγτκ, to Bone, paBKoro ot 1: 0,01: 0,3 no I: 2,0: 1,5, npennoHTZTejiBHO οτ I: 0,02 : 0.5 £ 0I: 1.5: 1.2; of CT) and 3H-bo BpeizH OTCTazsa HZH npzBO ZTL ^ b jíBZJseHze and paózHzpoBaHHoe MaCJIO, HPH-neodxo ηζΜΟοτζ, nocjre ynaneHKH kzcjioth of cmojih npoMHBaioT corjiacnoζ3βθοτηο2 menozHoz HeiiTpajiz3anzz μθτζζοβημ οπζότομ zjizcwecBE MeTznoBoro cnzpTa from Bonz. 2. Cnocod ynpaBFromMay cepHOKzcjiofí pa $ ZHamra. cornacHonyHKTy I OTjranawtíícn τθμ, HTO HPH pereHepzpoBairaz OTpadoTan-HHX Mace it cepHofl kzcjiotoS from / zjlz kzcjiothhmz cMOJiakz c óojib-MZM cojjep & aHzeM cepHoií kzcjioth to peaKHzoHHoii cwecz b 3sbz-czmoctz ol YXE ζθβθοτηβμ cnocodoM ycTaHOBJíeHHoro KOJizzecTBapacpzHzpynqero cpencTBa I nocjie nodaBJíeHZH oma τ ρ oma zj, oma η η η η η η η η η η:::::::::::::::::::::::::::: : 1,2. Third Cnocod ynpaBJíHeMO # cepHOKZcjiofít ρΗφζΗπηζζ corjiacno nyHK-Ty I OTjnraawracH τθμ, HTO HPH nojiyneram dejmx Mace Mace nyTezpaJzHanzz ochobhhx oJieyMOM b 3aBzczM0CTZ οτ CTynerai / ZY papzzazzz: κ peaKUzoHHoS cMecz b 3aBZCHM0CTH yCTaHO3JieHiio rt-ro dog η3βθοίήημ cnocoóoM KCunraecTBa pa ^ zHapyromero cpezpTBaI, nocjie EodaBJíeHHH κοτοροΓΟ mm nocjie οκοηηοηζη cootbctctbpcmero nocjiepeaKZzoHHoro nepzo.ua jiodaBJímoT φθΗοηοΒκί'ΐ jzeroTL products unless b οοοτηοπιθηζζ pejMnízpyroii ee ^ CPE CTBO peHOJiOBowy ίζθττιο κ, κ BO £ e Kaz: οτ I 0.05 0.5 IO I : 1.5: 1.2. 4.Cnocod ynpaBJíHeMO # cepzoKZCJioft pa ^ zHazzz corzacno nyinc-Ty I OTJEzraawniCH τθμ, ZTO HPH papzHanzz ochobhhx TpazcóopMatophhx Mace napeKcnapa $ KHOB of napeKcnpoTOHHHx Macez cepHOKZCJIOTOfi from / zJIZ OJieyMOM K peaKIXZOHHOZ CMeCH B 3aBHCHM0CTH OT, yze H3BecTHHM chocoóom ycTaHOBJíoHHoro KOjnraecTBa patazpyiDiiíe -ro cpejíCTBa I nocjie .nodaBJíeHZH κοτοροΓΟ, zjiz nocjie οκοηηβηιιηcooTBeTCTBym; ero nocjiepeazzzoHHoro nepzojía, jjpdaBJíHiOT penojio-BHZ JjprOTL Z BOAy ΟΟΟΤΗΟΗΙΘΗΖΖ B: ρπφΖΗΖρρΟΙΙξθθ ΟρθβΟΤΒΟ Κ φθΙΙΟjiOBOMy λθγτκ κ Βθ £ θ οτ I: 0.02: 0.5 £ 0 I : 0.3: 1.0.

AHHOTAW JJRAD FOR WANTING W6Mvy ρνΤΣ ”1 and TIME.

PŘIL

U-VAR

'] PERSON / POST

About what

O

O ω «o> ro coco,

Rí - r | VYft, -2 1 ii

IfeodpeTeHze Kaca & TCJi cnocodá'ynpaBJLHeMoií ^ -S-p'aážzaiw- piťoíiiuicjiotoií, ojieywoM from / hjiz kzcjiothnmh cMozaMz c doJiBmiíM copep ;; íaηζθμ cepnofí khcjioth not seize nojiyzemia cneiizaJE c & HHX Macez of pereHepzpoBaHZH OTpadOTaHHHx CTapnx Wace.

UejE & ro H3odpeTeHHH ηβληθτοη pa3padoTKa TAKORA Meto-and yupaBJíeHZHcepHOKzcJiofí pa $ ZHanzz, κοτοριώ mchkho ocymecTBJíKTL · no npocToiíTexHOJiorzz, HPH HMewíxcH ycTaHOBKax of HPH zcnoJH> 3OBaHzz .neme-'bhx BcnoMoraTejn> MCC MaTepzajioB. Sahana coctozt b that HTodti cΠΟΜΟΠζ & Κ nO £ XOJUWC £ ΠρΗΜΘΟΘΖ so odpa3OM ynpaBJíHTL nponeccoMcepHOKHCJioíi paíSzHanzz, HTodH b κοηηθ peaKiizz pacTDZHanzz odpa3o-BajmcL · OTnejEBme (£ 3 H pačpzHzpoBaHHoro Macjia of khcjioth, οκοροοτηocasmeHHH $ a3 Z3 peaKZzoHHofi CMecz noBuczjiacL and nepepadoTKacmojeh of khcjioth OTnazra.

Sanana DMRA paspemena dJiaronapn Tomy ητο nocze nodasJíenznpatjzHzpywcx cpencTB κ peaKiizomiofí CMecz nodaBJímor Φθηο; ιοβηΗneroTL of Bony- Ilocjie oTCTazBannH cepHan KHCJiOTa of cwojia Oca? K-naPOTCH what CKopocTLKi b 2-3 pa3a dojmmefí of peaKnzoHHan cwecBpa3 Ha £ ejiHeTCH cepHOKzcjiOTHyio, CMOJiHHyro of MacjinHyio $ a3H. Patos-HzpoBaHHoe Macjio npz HeodxonzMocTZ nocze mejiozHoro npoMHBaHznJIOJIHHO dHTB Waste MeTZJIOBHM CUZpTOM ZJIZ CMSCLH3 MeTZJIOBO-ΓΟ CZZpTa FROM BO £ H.

Claims

F 'S OBJECT OF THE INVENTION

A process for the controlled refining of hydrocarbon oils with sulfuric acid, fuming sulfuric acid and / or high-acidic acid resins for the purpose of obtaining special oils and regenerating processed oils, characterized in that In a known manner, after the addition or pre-reaction time of stirring and at a temperature of 20-60 ° C, preferably 20-40 ° C, phenol tar water is added to the phenol tar to water ratio of 1: 0.01: 0 3 to 1: 2.0: 1.5, preferably 1: 0.02: 0.5 to 1: 1.5: 1.2, whereupon the reaction mixture is separated into the sulfuric acid phase, the resin and the oil and wherein the acidic and the resinous phase of the sedimentation mixes and the refined oil is washed, if necessary, after removing the acid and resin, known to the alkaline neutralization of methyl alcohol or a mixture of methanol and water.

2. A process for the controlled sulfuric acid refining according to claim 1, wherein phenol tar and water relative to phenol tar and water 1: 0.2: 0.5 to 1: 1.2 are added to regenerate worn-out oils. 1.2

3. A process for the controlled sulfuric acid refining process according to claim 1, wherein phenol tar and water are refined to phenol tar to water when the white oils are obtained by refining base oils with fuming sulfuric acid. 1: 0.05: 0.5 to 1: 1.5: 1.2. -fy-

4. A method of controlled sulfuric acid refining according to claim 1, wherein phenol tar and water relative to each other are added to the refining of basic transformer oils, parexparaffins, and parexebuttons: phenol tar refining agent, 1: 0.02: 0.5 to 1: 0.3: 1.0. Recognized by the invention on the basis of the results of an expert review by the Office of Invention and Patenting, Berlin, DD. ,