CO6400214A2 - Método de preparación del alcohol a partir de ácido carboxílico mediante un proceso de un solo paso - Google Patents

Método de preparación del alcohol a partir de ácido carboxílico mediante un proceso de un solo paso

Info

Publication number
CO6400214A2
CO6400214A2 CO11086433A CO11086433A CO6400214A2 CO 6400214 A2 CO6400214 A2 CO 6400214A2 CO 11086433 A CO11086433 A CO 11086433A CO 11086433 A CO11086433 A CO 11086433A CO 6400214 A2 CO6400214 A2 CO 6400214A2
Authority
CO
Colombia
Prior art keywords
alcohol
step process
hydrogenation
esterification
carboxylic acid
Prior art date
Application number
CO11086433A
Other languages
English (en)
Inventor
Seong Ho Lee
Seung Hoon Oh
Young Seek Yoon
In Ho Cho
Sin Young Kang
Gi Ho Goh
Cher Hee Park
Hee Soo Kim
Original Assignee
Sk Innovation Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sk Innovation Co Ltd filed Critical Sk Innovation Co Ltd
Publication of CO6400214A2 publication Critical patent/CO6400214A2/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/02—Monohydroxylic acyclic alcohols
    • C07C31/125—Monohydroxylic acyclic alcohols containing five to twenty-two carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P3/00—Preparation of elements or inorganic compounds except carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C12P7/02—Preparation of oxygen-containing organic compounds containing a hydroxy group
    • C12P7/04—Preparation of oxygen-containing organic compounds containing a hydroxy group acyclic
    • C12P7/06—Ethanol, i.e. non-beverage
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C12P7/02—Preparation of oxygen-containing organic compounds containing a hydroxy group
    • C12P7/04—Preparation of oxygen-containing organic compounds containing a hydroxy group acyclic
    • C12P7/16—Butanols
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C12P7/40—Preparation of oxygen-containing organic compounds containing a carboxyl group including Peroxycarboxylic acids
    • C12P7/52—Propionic acid; Butyric acids
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C12P7/40—Preparation of oxygen-containing organic compounds containing a carboxyl group including Peroxycarboxylic acids
    • C12P7/54—Acetic acid
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Zoology (AREA)
  • Biotechnology (AREA)
  • Microbiology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Biochemistry (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • General Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Genetics & Genomics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

La presente invención se refiere a un método de preparación para alcohol haciendo reaccionar ácido carboxílico, alcohol, e hidrógeno empleando catalizadores de hidrogenación. Más específicamente, la invención se refiere a un método para preparar alcohol realizando esterificación e hidrocraqueo en un proceso de un solo paso, empleando catalizadores de hidrogenación, en lugar de un proceso de dos pasos. De acuerdo con la invención, se prepara alcohol a partir de ácido carboxílico mediante la esterificación e hidrogenación en un proceso de un solo paso empleando catalizadores de hidrogenación. Por consiguiente, pueden reducirse los costos de producción y los costos de tratamiento de los subproductos, en comparación con un proceso de dos pasos. Además, la invención es efectiva y económica puesto que puede producir alcohol con un rendimiento relativamente alto mediante un proceso sencillo. Más aún, la invención permite un rendimiento elevado con una presión relativamente más baja, cuando se compara con la producción de alcohol a partir de ácido carboxílico mediante hidrogenación sin esterificación, y resuelve los problemas de lixiviación por los catalizadores.
CO11086433A 2008-12-12 2011-07-11 Método de preparación del alcohol a partir de ácido carboxílico mediante un proceso de un solo paso CO6400214A2 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR20080126542 2008-12-12
KR1020090121930A KR101140545B1 (ko) 2008-12-12 2009-12-09 카르복시산으로부터 단일 공정을 통해 알코올을 제조하는 방법

Publications (1)

Publication Number Publication Date
CO6400214A2 true CO6400214A2 (es) 2012-03-15

Family

ID=42366676

Family Applications (1)

Application Number Title Priority Date Filing Date
CO11086433A CO6400214A2 (es) 2008-12-12 2011-07-11 Método de preparación del alcohol a partir de ácido carboxílico mediante un proceso de un solo paso

Country Status (5)

Country Link
US (1) US20110300596A1 (es)
KR (1) KR101140545B1 (es)
CN (1) CN102300837B (es)
BR (1) BRPI0917759A2 (es)
CO (1) CO6400214A2 (es)

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KR20000063418A (ko) * 2000-07-07 2000-11-06 심상협 담배 줄기와 뿌리를 이용한 농약 제조
KR101694545B1 (ko) * 2010-07-27 2017-01-10 에스케이이노베이션 주식회사 카르복시산의 직접수소화를 통한 알코올 제조방법
KR20120025998A (ko) 2010-09-08 2012-03-16 에스케이이노베이션 주식회사 미생물 발효액으로부터의 알킬부틸레이트 제조방법
SG11201408356VA (en) * 2012-06-15 2015-03-30 Microvi Biotech Inc Novel biocatalyst compositions and processes for use
US9212375B2 (en) * 2012-07-11 2015-12-15 Coskata, Llc Method for producing C2 oxygenates by fermentation using high oxidation state sulfur
TWI494433B (zh) * 2012-10-15 2015-08-01 Green Cellulosity Corp 製造羧酸及／或醇的方法
DE102013003329A1 (de) * 2013-02-25 2014-08-28 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Silane, Hybridpolymere und Photolack mit Positiv-Resist Verhalten sowie Verfahren zur Herstellung
NZ743055A (en) * 2013-03-08 2020-03-27 Xyleco Inc Equipment protecting enclosures
CN103896818A (zh) * 2013-10-16 2014-07-02 江苏恒祥化工有限责任公司 一种由l-脯氨酸高压加氢制备l-脯氨醇的方法
CN104829512A (zh) * 2015-04-02 2015-08-12 吴志明 由l-脯氨酸高压加氢制备l-脯氨醇的方法
CN108569950B (zh) * 2018-05-18 2021-11-30 东莞理工学院 一种聚3-羟基丁酸酯工业粗品一锅法制备正丁醇的方法
KR102272012B1 (ko) * 2019-11-06 2021-07-01 세종대학교산학협력단 혐기성소화조의 중간생성물을 이용한 바이오알코올의 제조방법
CN115417748B (zh) * 2021-06-01 2024-05-14 青岛俪徕精细化工有限公司 一种环保型多碳正构二元醇的连续制备方法

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US4398039A (en) * 1981-05-18 1983-08-09 The Standard Oil Company Hydrogenation of carboxylic acids
GB8509530D0 (en) * 1985-04-13 1985-05-15 Bp Chem Int Ltd Hydrogenation of carboxylic acids
GB8707595D0 (en) * 1987-03-31 1987-05-07 British Petroleum Co Plc Chemical process
ZA938109B (en) * 1992-10-29 1994-06-06 Davy Mckee London Process for the production of fatty alcohols
MXPA01009153A (es) * 1999-03-11 2003-07-14 Verser Dan Proceso para producir etanol.
KR101163807B1 (ko) * 2004-06-16 2012-07-09 더 텍사스 에이 & 엠 유니버시티 시스템 카르복실산 및 알콜로의 생체물질 전환용 방법 및 시스템
EP2261365A3 (en) * 2004-06-16 2012-02-29 The Texas A&M University System Methods and systems for biomass conversion to carboxylic acids and alcohols
JP2007083197A (ja) * 2005-09-26 2007-04-05 Mitsubishi Gas Chem Co Inc 銅−亜鉛−アルミニウム系触媒の製造方法
US20080248540A1 (en) * 2007-04-03 2008-10-09 The Ohio State University Methods of producing butanol
KR101588052B1 (ko) * 2008-03-28 2016-01-25 에스케이이노베이션 주식회사 발효액으로부터 부티르산을 추출하고 부티르산을 바이오연료로 화학적으로 전환하는 방법
EP2447237A3 (en) * 2008-12-02 2012-06-27 The Texas A&M University System Alternative paths to alcohols and hydrocarbons from biomass

Also Published As

Publication number Publication date
CN102300837B (zh) 2014-10-29
US20110300596A1 (en) 2011-12-08
BRPI0917759A2 (pt) 2016-02-23
KR101140545B1 (ko) 2012-05-02
CN102300837A (zh) 2011-12-28
KR20100068198A (ko) 2010-06-22

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