CN87100726A - The frit that decorative material of ceramic relief is used - Google Patents
The frit that decorative material of ceramic relief is used Download PDFInfo
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- CN87100726A CN87100726A CN 87100726 CN87100726A CN87100726A CN 87100726 A CN87100726 A CN 87100726A CN 87100726 CN87100726 CN 87100726 CN 87100726 A CN87100726 A CN 87100726A CN 87100726 A CN87100726 A CN 87100726A
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- frit
- ceramic
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Abstract
The invention discloses the frit that a kind of decorative material of ceramic relief is used, and the method for making this frit.
This frit is by PbO, Na
2O, K
2O, CaO, ZnO, TiO
2, Ai
2O
3, B
2, O
3, SiO
2Form, its raw material mixed, at high temperature become molten state, the cooling back frit.With this frit is the embossing material of main ingredient, by printing method, can form various concavo-convex, coloury sculptured decorative patterns on Ceramic glaze, has stereoscopic sensation.Its grain pattern is regular, the specification unanimity, and cost is lower, is a kind of novel material in the building ceramic decoration.
Description
The invention belongs to the ceramic decoration material field.
Existing ceramic decoration material generally is to use various metal oxides, comprise that rare-earth oxide is mixed with various beramic colors, the user produces needs according to it, beramic color is modulated into ceramic stamp or the coloured drawing pigment that is fit to various differing tempss, its decorative effect is a plane decoration, the stereoeffect of no concave-convex.Utilizing beramic color to adopt screen printing on the mechanize glaze, is state-of-the-art trailing in the current architectural pottery wall floor tile production, and its design pattern is changeable, colored abundant, can adapt to the big production of mechanize.But stamp on the current glaze, its decorative effect has only plane effect, the stereoeffect of no concave-convex.
The frit that will provide a kind of novel ceramic decoration material to use is provided, it and stamp condiment mix and adds an amount of selected beramic color forms ceramic decoration material, its seal or be drawn on the ceramic body after the glazing after burning till, just can form various concavo-convex decorative patterns, have the bossage effect, its figure colour can utilize the variable color of the color of various colored glazes itself or this material and various colored glazes or this material is modulated into shades of colour.
Content of the present invention is the frit that a kind of decorative material of ceramic relief is used, and the method for making this frit.Frit has stronger corrosive nature and penetrating power to glaze in sintering process, according to this specific character of frit, can modulate the embossing material that meets mechanize printing technology performance.
This frit is by PbO, Na
2O, K
2O, CaO, ZnO, TiO
2, Al
2O
3, B
2O
3, SiO
2Form.
The composition scope of this frit is (weight percent):
PbO 40-94%
K
2O 0-5%
Na
2O 0-15%
CaO 0-3%
ZnO 0-15%
TiO
20-12%
Al
2O
30-2%
B
2O
30-25%
SiO
24-30%
The each component summation is a 100%(weight)
The manufacture method of this frit is:
1, the batching stirring of above-mentioned component is evenly mixed, make a kind of mixture;
2, be that 750-1050 ℃, heating-up time are that 1.5-2 hour, soaking time are under 30-60 minute the condition in temperature, make mixture all become molten state;
3, then the mixture of molten state is flowed in the cold water chilling frit.
Frit provided by the present invention can satisfy ceramic body in sintering process, and ceramic glaze is had stronger corrosive nature and penetrating power, adapts to simultaneously the needs of various processing performances such as mechanize stamp again.With this frit is the embossing material of main component, only needs by method for printing, just can make to form various concavo-convex, sculptured decorative patterns on the ceramic glaze, has stereoscopic sensation.Can also allocate some beramic color in this material as required, make the grain pattern that prints off form multicolour, grain pattern is regular, the specification unanimity, and cost is lower, is a kind of novel material in the building ceramic decoration.
Non-limiting examples of the present invention:
Example 1
Frit component (weight percent) is:
PbO 80%
K
2O 1.5%
ZnO 5.0%
TiO
25.0%
SiO
28.5%
The summation of each component is a 100%(weight)
The manufacture method of this frit is:
1, the batching with above-mentioned component stirs mixed a kind of mixture that evenly makes;
2, be that 775 ℃ ± 25 ℃, heating-up time are that 1.5-2 hour, soaking time are under 30-60 minute the condition in temperature, make mixture all become molten state;
3, then the mixture of molten state is flowed in the cold water chilling frit.
Example 2
Frit component (weight percent) is:
PbO 65.4%
K
2O 2.37%
Na
2O 8.4%
B
2O
318.87%
SiO
24.95%
The summation of each component is a 100%(weight)
The manufacture method of this frit is:
1, the batching stirring of above-mentioned component is evenly mixed, make a kind of mixture;
2, be that 825 ℃ ± 25 ℃, heating-up time are that 1.5-2 hour, soaking time are under 30-60 minute the condition in temperature, make mixture all become molten state;
3, then the mixture of molten state is flowed in the cold water chilling frit.
Example 3
Frit component (weight percent) is:
PbO 58.04%
Na
2O 7.8%
CaO 1.4%
Al
2O
31.0%
B
2O
317.56%
SiO
214.20%
The summation of each component is a 100%(weight)
The manufacture method of this frit is:
1, the batching stirring of above-mentioned component is evenly mixed, make a kind of mixture;
2, be that 975 ℃ ± 25 ℃, heating-up time are that 1.5-2 hour, soaking time are under 30-60 minute the condition in temperature, make mixture all become molten state;
3, then the mixture of molten state is flowed in the cold water chilling frit.
Be the preparation method of embossing material of main component and the embodiment of effect thereof with this frit:
1, tails over 0.03-0.05% to 10000-hole sieve with frit is levigate;
2, then with frit and levigated stamp condiment by 1: the weight ratio of 0.7-1 is mixed and add an amount of selected levigate beramic color, carry out fully evenly mixed, the embossing material;
3, with the silk screen of various patterns, the embossing material is imprinted on the glazed body, calcination in temperature is 1050-1250 ℃ of scope just can form the anaglyph of various different-styles.
4,, when modulation stamp material, need suitably to adjust the maturing temperature and the tone of stamp material according to different glazes and different firing temperatures.
Claims (3)
1, the frit used of a kind of decorative material of ceramic relief is characterized in that it is by PbO, SiO
2, K
2O, Na
2O, B
2O
3, CaO, ZnO, TiO
2, Al
2O
3Form, its weight percent is:
40-94% PbO
4-30% SiO
2
0-5% K
2O
0-15% Na
2O
0-25% B
2O
3
0-3% CaO
0-15% ZnO
0-12% TiO
2
0-2% Al
2O
3
The each component summation is 100% (weight)
2, make the method for the described frit of claim 1, it is characterized in that the batching stirring of its component is mixed evenly, make a kind of mixture, is 750-1050 ℃ in temperature, heating-up time is that 1.5-2 hour, soaking time are under 30-60 minute the condition, to make mixture all become molten state.
3,, it is characterized in that the material inflow cold water chilling of molten state is formed frit according to the method for claim 2.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 87100726 CN87100726A (en) | 1987-02-14 | 1987-02-14 | The frit that decorative material of ceramic relief is used |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 87100726 CN87100726A (en) | 1987-02-14 | 1987-02-14 | The frit that decorative material of ceramic relief is used |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN87100726A true CN87100726A (en) | 1988-05-25 |
Family
ID=4812996
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 87100726 Pending CN87100726A (en) | 1987-02-14 | 1987-02-14 | The frit that decorative material of ceramic relief is used |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN87100726A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102249736A (en) * | 2011-05-20 | 2011-11-23 | 醴陵陶润实业发展有限公司 | Decoration manufacturing method for forming crystal relief on ceramic plate product |
| CN102718559A (en) * | 2012-06-11 | 2012-10-10 | 卡罗比亚釉料（昆山）有限公司 | Colored leaded frit |
| CN105564121A (en) * | 2014-10-13 | 2016-05-11 | 林金东 | Process for preparing image under ceramic glaze |
| CN109369015A (en) * | 2018-12-10 | 2019-02-22 | 九牧厨卫股份有限公司 | A kind of high relief glaze compound powder, the preparation method of high relief powdered frit and the preparation method of sanitary ceramics high relief |
| CN114276166A (en) * | 2021-11-30 | 2022-04-05 | 卡罗比亚(中国)高新材料有限公司 | Processing technology of fast-fired colorful-luster metal-effect decorative glaze |
-
1987
- 1987-02-14 CN CN 87100726 patent/CN87100726A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102249736A (en) * | 2011-05-20 | 2011-11-23 | 醴陵陶润实业发展有限公司 | Decoration manufacturing method for forming crystal relief on ceramic plate product |
| CN102718559A (en) * | 2012-06-11 | 2012-10-10 | 卡罗比亚釉料（昆山）有限公司 | Colored leaded frit |
| CN105564121A (en) * | 2014-10-13 | 2016-05-11 | 林金东 | Process for preparing image under ceramic glaze |
| CN109369015A (en) * | 2018-12-10 | 2019-02-22 | 九牧厨卫股份有限公司 | A kind of high relief glaze compound powder, the preparation method of high relief powdered frit and the preparation method of sanitary ceramics high relief |
| CN109369015B (en) * | 2018-12-10 | 2022-03-25 | 九牧厨卫股份有限公司 | Preparation method of sanitary ceramic high relief |
| CN114276166A (en) * | 2021-11-30 | 2022-04-05 | 卡罗比亚(中国)高新材料有限公司 | Processing technology of fast-fired colorful-luster metal-effect decorative glaze |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C01 | Deemed withdrawal of patent application (patent law 1993) | ||
| WD01 | Invention patent application deemed withdrawn after publication |