CN217869114U - Electrode slice unit and ozone generator - Google Patents

Electrode slice unit and ozone generator Download PDF

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Publication number
CN217869114U
CN217869114U CN202021742272.6U CN202021742272U CN217869114U CN 217869114 U CN217869114 U CN 217869114U CN 202021742272 U CN202021742272 U CN 202021742272U CN 217869114 U CN217869114 U CN 217869114U
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Prior art keywords
electrode
electrode sheet
sheet
electrode slice
electrode plate
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CN202021742272.6U
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Chinese (zh)
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杨静
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Hangzhou Yingou Technology Co ltd
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Aikeyi Technology Shanghai Co ltd
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Priority to CN202021742272.6U priority Critical patent/CN217869114U/en
Priority to PCT/CN2021/112500 priority patent/WO2022037493A1/en
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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00Electrolytic production of inorganic compounds or non-metals
    • C25B1/01Products
    • C25B1/13Ozone
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/02Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Oxygen, Ozone, And Oxides In General (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Electrodes For Compound Or Non-Metal Manufacture (AREA)

Abstract

The utility model discloses an electrode slice unit and ozone generator, this electrode slice unit includes first electrode slice, second electrode slice and clamp locate the ion exchange membrane between first electrode slice and the second electrode slice, first electrode slice and second electrode slice are formed by the electrode plate cutting, first electrode slice and second electrode slice all include protruding tooth and open slot, the shape and the size homogeneous phase of protruding tooth and open slot, so that first electrode slice and second electrode slice can complementary form concatenation, and when making first electrode slice, ion exchange membrane and second electrode slice superpose, the open slot of first electrode slice and second electrode slice is aimed at each other. The electrode plate unit improves the utilization rate of the electrode plate, reduces waste materials and saves cost. In addition, the ozone generator comprises the electrode sheet unit, and the material cost is low.

Description

Electrode slice unit and ozone generator
Technical Field
The utility model relates to an electrode subassembly technical field, more specifically say, relate to an electrode slice unit. In addition, the utility model discloses still relate to an ozone generator including above-mentioned electrode piece unit.
Background
In the ozone generator, it is necessary to apply to an electrode sheet unit to generate ozone by electrolytic reaction.
The electrode plate unit comprises an anode, a cathode and an ion exchange membrane, the ion exchange membrane is clamped between the anode and the cathode, and oxidation-reduction reactions respectively occur on the anode and the cathode when the ion exchange membrane is electrified, wherein the anode generates an oxidation reaction to oxidize water into oxygen and ozone; the cathode undergoes a reduction reaction to reduce water to hydrogen.
In the prior art, the cathode and the anode are generally flat electrode plates, and a circular through hole or a rectangular through hole is formed in the middle of the electrode plates so that ions after electrolysis can pass through the through hole.
However, since the anode and cathode electrode plates are formed by diamond electrode surface plating, the electrode plates are expensive. The existing electrode plate needs to remove materials in the middle of a flat plate so as to process a round through hole or a rectangular through hole, more waste materials are generated, and the cost of the electrode plate is increased.
In summary, it is an urgent need to solve the problem of providing an electrode sheet unit capable of reducing waste and saving cost.
SUMMERY OF THE UTILITY MODEL
In view of this, the present invention provides an electrode plate unit to reduce waste and save cost.
Another object of the present invention is to provide an ozone generator comprising the above electrode sheet unit, which has low material cost.
In order to achieve the above object, the present invention provides the following technical solutions:
an electrode slice unit comprises a first electrode slice, a second electrode slice and an ion exchange membrane clamped between the first electrode slice and the second electrode slice, wherein the first electrode slice and the second electrode slice are formed by cutting electrode plates, the first electrode slice and the second electrode slice respectively comprise a protruding tooth and an open slot, and the protruding tooth is identical to the open slot in shape and size, so that the first electrode slice and the second electrode slice can be spliced in a complementary mode, and the first electrode slice, the ion exchange membrane and the second electrode slice are superposed, and the open slots of the first electrode slice and the second electrode slice are aligned with each other.
Preferably, at least one of the first and second electrode pads is a boron-doped diamond electrode pad.
Preferably, the boron-doped diamond electrode sheet comprises a base material and a boron-doped diamond film arranged on the surface of the base material.
Preferably, the whole boron-doped diamond electrode sheet is made of naturally-grown boron-doped diamond.
Preferably, the thickness ranges of the first electrode sheet and the second electrode sheet both include 0.2mm to 2mm.
Preferably, the thickness ranges of the first electrode plate and the second electrode plate are both 0.3 mm-0.8 mm.
Preferably, the first electrode plate and the second electrode plate each include a comb-shaped electrode plate, a fishbone-shaped electrode plate, a C-shaped electrode plate, an E-shaped electrode plate, or an L-shaped electrode plate.
Preferably, the convex teeth and corners of the open grooves have a predetermined curvature.
Preferably, the ion exchange membrane further comprises a first conductive sheet and a second conductive sheet which are correspondingly attached and overlapped with one sides of the first electrode sheet and the second electrode sheet, which are far away from the ion exchange membrane respectively.
An ozone generator comprises an electrode sheet unit, wherein the electrode sheet unit is any one of the electrode sheet units.
The utility model provides an electrode plate unit, because the shape and the size homogeneous phase of protruding tooth and open slot are the same, also, protruding tooth and open slot can gomphosis each other, consequently, can be in the same place first electrode slice and second electrode slice concatenation through complementary form, and like this, the protruding tooth of first electrode slice just can compensate the vacancy of the open slot department of second electrode slice, and the protruding tooth of second electrode slice just can compensate the vacancy of the open slot department of first electrode slice, also promptly, can form a flat board after first electrode slice and the concatenation of second electrode slice.
Therefore, when the first electrode plate and the second electrode plate are formed, the flat plate-shaped electrode plates can be used for cutting, one electrode plate is continuously cut according to a preset path, and two electrode plates with the same shape can be formed through one cutting process.
Therefore, only few materials on two sides of the flat plate need to be removed, so that the protruding teeth on the outermost sides of the two electrode plates and the open grooves are identical in shape, waste of materials in the middle of the electrode plates is avoided, more waste materials can be avoided, the materials of the whole electrode plates are utilized to the maximum, the utilization rate of the electrode plates is improved, the waste materials are reduced, and the cost is saved.
The utility model provides an ozone generator, including the electrode plate unit, its material cost is low.
Drawings
In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the drawings required to be used in the description of the embodiments or the prior art will be briefly described below, it is obvious that the drawings in the following description are only embodiments of the present invention, and for those skilled in the art, other drawings can be obtained according to the provided drawings without creative efforts.
Fig. 1 is a schematic structural diagram of an electrode sheet unit according to an embodiment of the present invention;
fig. 2 is a schematic structural diagram of a first electrode sheet and a second electrode sheet provided in the first embodiment;
fig. 3 is a schematic structural view of the first electrode sheet and the second electrode sheet shown in fig. 2 after being spliced;
fig. 4 is a schematic structural diagram of a first electrode sheet and a second electrode sheet provided in the second embodiment;
fig. 5 is a schematic structural view of the first electrode sheet and the second electrode sheet shown in fig. 4 after being spliced;
fig. 6 is a schematic structural diagram of a first electrode sheet and a second electrode sheet provided in the third embodiment;
fig. 7 is a schematic structural view of the first electrode sheet and the second electrode sheet shown in fig. 6 after being spliced;
fig. 8 is a schematic structural diagram of a first electrode sheet and a second electrode sheet provided in the fourth embodiment;
fig. 9 is a schematic structural view of the first electrode sheet and the second electrode sheet shown in fig. 8 after being spliced;
fig. 10 is an exploded view of an ozone generator according to an embodiment of the present invention;
FIG. 11 is a cross-sectional view of the ozone generator of FIG. 10 assembled;
fig. 12 is a partial enlarged view of a in fig. 11.
The reference numerals in fig. 1 to 12 are as follows:
1 is a first electrode plate, 11 is a convex tooth, 12 is an open slot, 2 is a second electrode plate, 3 is an ion exchange membrane, 4 is a first conductive sheet, 5 is a second conductive sheet, 6 is a first shell, and 7 is a second shell.
Detailed Description
The technical solutions in the embodiments of the present invention will be described clearly and completely with reference to the accompanying drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only some embodiments of the present invention, not all embodiments. Based on the embodiments in the present invention, all other embodiments obtained by a person skilled in the art without creative efforts belong to the protection scope of the present invention.
The core of the utility model is to provide an electrode plate unit to reduce the waste material, practice thrift the cost. The other core of the utility model is to provide an ozone generator comprising the electrode plate unit, which has low material cost.
Please refer to fig. 1-12, which are drawings illustrating the present invention.
The utility model provides an electrode slice unit mainly includes first electrode slice 1, second electrode slice 2 and ion exchange membrane 3 etc. and ion exchange membrane 3 presss from both sides and locates between first electrode slice 1 and second electrode slice 2.
Specifically, the first electrode plate 1 and the second electrode plate 2 are formed by cutting the electrode plates, the first electrode plate 1 and the second electrode plate 2 both include the protruding teeth 11 and the open grooves 12, the shapes and the sizes of the protruding teeth 11 and the open grooves 12 are the same, so that the first electrode plate 1 and the second electrode plate 2 can be spliced together in a complementary manner, and meanwhile, when the first electrode plate 1, the ion exchange membrane 3 and the second electrode plate 2 are stacked, the open grooves 12 of the first electrode plate 1 and the second electrode plate 2 are aligned with each other.
That is to say, the protruding teeth 11 and the open slot 12 can be mutually embedded, so, the first electrode plate 1 and the second electrode plate 2 can be spliced together in a complementary manner, so that the protruding teeth 11 of the first electrode plate 1 can just make up for the vacancy at the open slot 12 of the second electrode plate 2, and the protruding teeth 11 of the second electrode plate 2 can just make up for the vacancy at the open slot 12 of the first electrode plate 1, that is, the first electrode plate 1 and the second electrode plate 2 can form a flat plate after being spliced.
Therefore, when the first electrode sheet 1 and the second electrode sheet 2 are formed, the flat plate-shaped electrode sheets may be used for cutting, one electrode sheet is continuously cut according to a preset path, and two electrode sheets having the same shape may be formed through one cutting process.
Therefore, as shown in fig. 3, 5, 7 and 9, only a small amount of material on both sides of the flat plate needs to be removed, so as to ensure that the shapes of the protruding teeth 11 and the open grooves 12 on the outermost sides of the two electrode plates are the same, thereby avoiding the waste of the material in the middle of the electrode plates, i.e., avoiding the generation of more waste materials, maximizing the utilization of the material of the whole electrode plates, improving the utilization rate of the electrode plates, reducing the waste materials and saving the cost.
The first electrode sheet 1 and the second electrode sheet 2 may be cut from the same electrode plate, or may be cut from different electrode plates.
When the first electrode plate 1 and the second electrode plate 2 are cut and formed by the same electrode plate, the first electrode plate 1 and the second electrode plate 2 are made of the same material; when the first electrode sheet 1 and the second electrode sheet 2 are cut and formed by different electrode plates, the combination of the electrode sheets of different materials can be realized.
It can be understood that, in actual production, for mass production, electrode plates of different materials can be selected according to actual needs to be cut to form the first electrode sheet 1 and the second electrode sheet 2 of different materials, so that various combination modes of the first electrode sheet 1 and the second electrode sheet 2 can be realized.
In addition, as known to those skilled in the art, in use, that is, when the electrode sheet unit is formed, the first electrode sheet 1, the ion exchange membrane 3 and the second electrode sheet 2 are closely overlapped, at this time, it is required to ensure that the protruding teeth 11 of the first electrode sheet 1 and the second electrode sheet 2 are oppositely arranged, and the open grooves 12 of the first electrode sheet 1 and the second electrode sheet 2 are oppositely arranged, so that the open grooves 12 of the first electrode sheet 1 and the second electrode sheet 2 can form a channel for ions to pass through.
Preferably, when the first electrode sheet 1, the ion exchange membrane 3 and the second electrode sheet 2 are stacked, the opening directions of the open grooves 12 of the first electrode sheet 1 and the second electrode sheet 2 are opposite.
During the electrolytic reaction, the protruding teeth 11 electrolyze water and perform oxidation-reduction reaction with ions, and the open grooves 12 allow hydrogen ions to pass through and pass through the ion exchange membrane 3.
It is understood that the ion exchange membrane 3 has a function of allowing hydrogen ions to pass therethrough, and other ions and substances such as water cannot pass therethrough. Therefore, after the power is supplied, the anode is electrolyzed to generate oxygen ions and hydrogen ions, the hydrogen ions are attracted by the cathode, pass through the ion exchange membrane 3 from the open groove 12, reach the cathode, and are oxidized into hydrogen gas, and meanwhile, the oxygen ions at the anode are reduced into ozone.
Obviously, the larger the number of the open grooves 12, the larger the open area of the single open groove 12, the more the hydrogen ions generated by electrolysis under a certain current flow pass through the ion exchange membrane 3 during the reaction, so that a more sufficient electrolysis reaction can occur and more ozone is generated.
In addition, the protruding teeth 11 and the open grooves 12 are of the same shape and size, so that the electrolysis efficiency is improved, more water can be electrolyzed under the condition of certain voltage and current, and more ozone can be generated.
Simultaneously, open slot 12 can influence the original flow state of rivers, and a plurality of open slots 12 can form certain vortex effect to rivers, have certain scouring action to 11 surperficial adnexed impurity of protruding tooth to be favorable to reducing the adhesion volume of first electrode slice 1 and 2 surperficial impurity of second electrode slice, and then increased the effective life of first electrode slice 1 and second electrode slice 2.
In order to improve the electrolysis efficiency, at least one of the first electrode sheet 1 and the second electrode sheet 2 is a boron-doped diamond electrode sheet on the basis of the above embodiment.
That is, in this embodiment, one of the first electrode tab 1 and the second electrode tab 2 must be a boron-doped diamond electrode tab, and the other electrode tab may be a boron-doped diamond electrode tab or another electrode tab made of an electrically conductive material.
Preferably, the first electrode sheet 1 and the second electrode sheet 2 are both boron-doped diamond electrode sheets.
That is to say, the first electrode plate 1 and the second electrode plate 2 are made of the same material and are both made of boron-doped diamond material.
It can be understood that, as the time of the electrolytic reaction increases, a certain amount of impurities remain on the surface of the negative electrode plate, which leads to the reduction of the efficiency of the electrolytic reaction, and therefore, the ozone concentration is lower than the effective sterilization concentration after accumulating for a certain period of time.
When the first electrode plate 1 and the second electrode plate 2 are both boron-doped diamond electrode plates, the cathode and the anode can be interacted through circuit control, so that the service lives of the first electrode plate 1 and the second electrode plate 2 can be balanced, and the service life of the whole electrode plate unit is maximized.
In view of the specific formation manner of the boron-doped diamond electrode sheet, on the basis of the above embodiment, the boron-doped diamond electrode sheet includes a substrate and a boron-doped diamond film provided on the surface of the substrate.
It should be noted that, in the embodiment, the specific material of the substrate is not limited, and those skilled in the art can select the material according to actual needs.
Alternatively, based on the above embodiment, the boron-doped diamond electrode sheet is a boron-doped diamond which is naturally grown as a whole.
That is, the whole material of the boron-doped diamond electrode plate is uniform.
In order to ensure the structural strength of the first electrode sheet 1 and the second electrode sheet 2 and ensure that the first electrode sheet 1 and the second electrode sheet 2 have smaller sizes, the thickness ranges of the first electrode sheet 1 and the second electrode sheet 2 both include 0.2mm to 2mm on the basis of the above-mentioned embodiments.
Further preferably, in addition to the above embodiment, the thickness ranges of the first electrode sheet 1 and the second electrode sheet 2 are both 0.3mm to 0.8mm.
In the embodiment, the first electrode plate 1 and the second electrode plate 2 are both relatively thin, so that the electrode plate unit is compact in structure.
It should be noted that, the present invention does not limit the specific shape of the first electrode plate 1 and the second electrode plate 2, as long as it is ensured that the first electrode plate 1 and the second electrode plate 2 all have the protruding teeth 11 and the open slot 12, and the shape and the size of the two are the same.
Preferably, the first electrode sheet 1 and the second electrode sheet 2 are all identical in shape and size.
Preferably, the first electrode sheet 1 and the second electrode sheet 2 each include a comb-shaped electrode sheet, a fishbone-shaped electrode sheet, a C-shaped electrode sheet, an E-shaped electrode sheet, an L-shaped electrode sheet, or the like, based on the above-described embodiments.
Obviously, these electrode sheets are all easy to cut, continuous in profile and of regular shape.
Further, as shown in fig. 4 and 5, on the basis of the above-described embodiment, the corners of the protruding teeth 11 and the open grooves 12 have a predetermined curvature.
In addition, on the basis of the above embodiment, the ion exchange membrane electrode assembly further includes a first conductive sheet 4 and a second conductive sheet 5 which are respectively attached and superposed in correspondence with the respective sides of the first electrode sheet 1 and the second electrode sheet 2 which are away from the ion exchange membrane 3.
That is, in the present embodiment, the first conductive sheet 4, the first electrode sheet 1, the ion exchange membrane 3, the second electrode sheet 2, and the second conductive sheet 5 are closely laminated in this order and stacked together to form one electrode sheet unit.
In addition to the electrode sheet unit, the present invention further provides an ozone generator including the electrode sheet unit disclosed in the above embodiments, and the structure of other parts of the ozone generator refers to the prior art, which is not described herein again.
For example, as shown in fig. 11, the ozone generator further includes a first housing 6 and a second housing 7, and the electrode sheet unit described above is installed between the first housing 6 and the second housing 7.
When the ozone generator is used, a voltage of between 5 and 30V is preferably applied to the two ends of the electrodes, and after water enters the ozone generator, a reaction occurs at the electrode unit, and ozone, water and hydrogen are generated through the electrolysis of the water.
The embodiments are described in a progressive manner in the specification, each embodiment focuses on differences from other embodiments, and the same and similar parts among the embodiments are referred to each other.
The electrode sheet unit and the ozone generator provided by the utility model are introduced in detail. The principles and embodiments of the present invention have been explained herein using specific examples, and the above descriptions of the embodiments are only used to help understand the method and its core ideas of the present invention. It should be noted that, for those skilled in the art, without departing from the principle of the present invention, the present invention can be further modified and modified, and such modifications and modifications also fall within the protection scope of the appended claims.

Claims (10)

1. An electrode plate unit comprises a first electrode plate (1), a second electrode plate (2) and an ion exchange membrane (3) clamped between the first electrode plate (1) and the second electrode plate (2), and is characterized in that the first electrode plate (1) and the second electrode plate (2) are formed by cutting electrode plates, the first electrode plate (1) and the second electrode plate (2) respectively comprise a protruding tooth (11) and an open slot (12), the protruding tooth (11) and the open slot (12) are identical in shape and size, so that the first electrode plate (1) and the second electrode plate (2) can be spliced in a complementary mode, and the first electrode plate (1), the ion exchange membrane (3) and the second electrode plate (2) are overlapped, and the open slots (12) of the first electrode plate (1) and the second electrode plate (2) are aligned with each other.
2. An electrode sheet unit according to claim 1, wherein at least one of the first electrode sheet (1) and the second electrode sheet (2) is a boron-doped diamond electrode sheet.
3. The electrode sheet unit according to claim 2, wherein the boron-doped diamond electrode sheet comprises a substrate and a boron-doped diamond film provided on a surface of the substrate.
4. An electrode sheet unit according to claim 2, wherein the boron-doped diamond electrode sheet is entirely of naturally-grown boron-doped diamond.
5. The electrode sheet unit according to any one of claims 1 to 4, wherein the thickness ranges of the first electrode sheet (1) and the second electrode sheet (2) each comprise 0.2mm to 2mm.
6. The electrode sheet unit according to claim 5, wherein the thickness of the first electrode sheet (1) and the second electrode sheet (2) each ranges from 0.3mm to 0.8mm.
7. The electrode tab unit according to any one of claims 1-4, wherein the first electrode tab (1) and the second electrode tab (2) each comprise a comb-shaped electrode tab, a fishbone-shaped electrode tab, a C-shaped electrode tab, an E-shaped electrode tab, or an L-shaped electrode tab.
8. The electrode tab unit according to claim 7, wherein corners of the protruding teeth (11) and the open grooves (12) have a predetermined curvature.
9. The electrode sheet unit according to claim 1, further comprising a first conductive sheet (4) and a second conductive sheet (5) respectively laminated and superposed in correspondence with respective sides of the first electrode sheet (1) and the second electrode sheet (2) remote from the ion exchange membrane (3).
10. An ozone generator comprising an electrode sheet unit, wherein the electrode sheet unit is an electrode sheet unit according to any one of claims 1 to 9.
CN202021742272.6U 2020-08-19 2020-08-19 Electrode slice unit and ozone generator Active CN217869114U (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN202021742272.6U CN217869114U (en) 2020-08-19 2020-08-19 Electrode slice unit and ozone generator
PCT/CN2021/112500 WO2022037493A1 (en) 2020-08-19 2021-08-13 Electrode plate unit and ozone generator

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202021742272.6U CN217869114U (en) 2020-08-19 2020-08-19 Electrode slice unit and ozone generator

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WO (1) WO2022037493A1 (en)

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5069383B1 (en) * 2012-04-27 2012-11-07 日科ミクロン株式会社 Ozone water generator
CN103413954B (en) * 2013-08-26 2016-03-02 中国东方电气集团有限公司 The preparation method of membrane electrode assembly, flow battery and electrode
WO2017221866A1 (en) * 2016-06-23 2017-12-28 富士フイルム株式会社 Artificial photosynthesis module and artificial photosynthesis device
GB2559111A (en) * 2016-11-29 2018-08-01 Roseland Holdings Ltd Electrode and electrochemical cell comprising the same
GB2557181B (en) * 2016-11-29 2020-02-12 Roseland Holdings Ltd Electrode and electrochemical cell comprising the same
GB2557182B (en) * 2016-11-29 2020-02-12 Roseland Holdings Ltd Electrode and electrochemical cell comprising the same
JP6712420B1 (en) * 2019-09-13 2020-06-24 高光産業株式会社 Electrolytic cell, ozone water generator including the same, conductive diamond electrode, and method for manufacturing the same

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Effective date of registration: 20231215

Address after: Room 1309, 13/F, East Building, Building 6, No. 735, Jianghong Road, Changhe Street, Binjiang District, Hangzhou City, Zhejiang Province, 310052

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Patentee before: Aikeyi Technology (Shanghai) Co.,Ltd.

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