CN212369180U - Water absorption core body capable of realizing glue-free reverse absorption - Google Patents

Water absorption core body capable of realizing glue-free reverse absorption Download PDF

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CN212369180U
CN212369180U CN202020229864.1U CN202020229864U CN212369180U CN 212369180 U CN212369180 U CN 212369180U CN 202020229864 U CN202020229864 U CN 202020229864U CN 212369180 U CN212369180 U CN 212369180U
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chemical fiber
layer
water
absorbent resin
wood pulp
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王振宇
王伟成
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Zhejiang Zhenyu water absorbing material technology Co.,Ltd.
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Zhejiang Zhenyu Water Absorbing Material Co ltd
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Abstract

The utility model relates to a no gluey reverse absorption's absorbent core, it includes upper ES chemical fiber layer, middle polymer absorbent resin layer and lower floor's wood pulp ES chemical fiber mixed layer, upper ES chemical fiber layer and lower floor's wood pulp ES chemical fiber mixed layer wrap up middle polymer absorbent resin layer in the centre, upper ES chemical fiber layer and lower floor's wood pulp ES chemical fiber mixed layer between through thermal treatment shaping formula structure as an organic whole. The utility model provides a through heat treatment alright form the formed body without the adhesive between ES chemical fiber layer and the thick liquid ES chemical fiber mixing layer, compare in the condition that adopts the binder to bond, liquid infiltration is fast down to furthest has guaranteed the dry and comfortable on upper strata, makes environmental protection health more simultaneously.

Description

Water absorption core body capable of realizing glue-free reverse absorption
Technical Field
The utility model belongs to the technical field of health supplies, especially, relate to a no reverse absorptive absorbent core that absorbs of glue.
Background
The water absorption core body has wide application, at present, the sanitary articles sold on the market, such as the water absorption core body of a sanitary towel or a paper diaper, are usually composed of fluff pulp or non-woven fabrics, in order to improve the absorption performance of the water absorption core body, people develop and add a high polymer water absorption layer in the water absorption core body, because the water absorption core body is very compact, the absorption of liquid and the diffusion of liquid are very slow, if the liquid can not be absorbed in a short time, discomfort and trouble can be brought to a user, and the requirement that the user needs the water absorption core body to absorb a large amount of liquid in a short time can not be met.
Chinese patent CN209392255U discloses a water-absorbing core body of a sanitary product, which comprises an upper layer non-woven fabric, a middle layer non-woven fabric and a lower layer dust-free paper, wherein the upper layer non-woven fabric is bonded with the middle layer non-woven fabric through a bonding agent, and the middle layer non-woven fabric is bonded with the lower layer dust-free paper through the bonding agent; the upper part of the middle-layer non-woven fabric is permeated with first macromolecular water-absorbent resin, the lower part of the middle-layer non-woven fabric is permeated with second macromolecular water-absorbent resin, the particle size of the first macromolecular water-absorbent resin is larger than that of the second macromolecular water-absorbent resin, and the water absorption performance of the first macromolecular water-absorbent resin is weaker than that of the second macromolecular water-absorbent resin.
In the above-mentioned public health supplies absorbent core body, the binder bonds between upper non-woven fabrics, intermediate level non-woven fabrics and the dustless paper of lower floor, can form a rete after the binder is dried to block that moisture from infiltrating down, lead to the infiltration speed slow, moisture stays on upper non-woven fabrics surface, and the influence skin is healthy.
SUMMERY OF THE UTILITY MODEL
In order to solve the defects of the prior art, the utility model provides a glueless reverse absorption's core that absorbs water, infiltration effect is good, it is efficient to absorb water, makes the skin surface keep dry and comfortable, reduces red butt by a wide margin, and anaphylaxis and microorganism breed scheduling problem.
In order to achieve the purpose, the utility model provides a technical scheme does:
the utility model relates to a no gluey reverse absorption's absorbent core, it includes upper ES chemical fiber layer, middle polymer absorbent resin layer and lower floor's wood pulp ES chemical fiber mixed layer, upper ES chemical fiber layer and lower floor's wood pulp ES chemical fiber mixed layer wrap up middle polymer absorbent resin layer in the centre, upper ES chemical fiber layer and lower floor's wood pulp ES chemical fiber mixed layer between through thermal treatment shaping formula structure as an organic whole.
Preferably, the particle size of the high molecular water-absorbing resin in the middle high molecular water-absorbing resin layer is 100-300 mesh.
Preferably, the gram weight of the upper ES chemical fiber layer is 20-60 g/m2The gram weight of the lower wood pulp ES chemical fiber mixed layer is 50-200 g/m2The amount of the polymeric water-absorbing resin in the intermediate polymeric water-absorbing resin layer is 100-400 g/m2
Preferably, the thickness of the lower wood pulp ES chemical fiber mixed layer is larger than that of the upper ES chemical fiber layer.
Preferably, the high-molecular water-absorbent resin layer comprises first high-molecular water-absorbent resin and second high-molecular water-absorbent resin, the first high-molecular water-absorbent resin permeates the lower surface of the upper ES chemical fiber layer, and the second high-molecular water-absorbent resin permeates the upper surface of the lower wood pulp ES chemical fiber mixed layer.
Preferably, the particle size of the first high-molecular water-absorbent resin is 120-300 mesh, and the particle size of the second high-molecular water-absorbent resin is 100-120 mesh; the water absorption multiplying power of the first high-molecular water-absorbent resin is 50-180 times, and the water absorption multiplying power of the second high-molecular water-absorbent resin is 110-260 times; the dosage of the first high-molecular water-absorbing resin is 50-200 g/m2The dosage of the second high polymer water-absorbing resin is 50-200 g/m2
A preparation process of a glue-free reverse-absorption water-absorption core body comprises the following steps:
(1) laying the wood pulp ES chemical fiber mixing layer on a workbench, wherein an exhaust fan and a vibrator are arranged below the wood pulp ES chemical fiber mixing layer, and macromolecular water-absorbent resin is uniformly sprayed on the upper side surface of the wood pulp ES chemical fiber mixing layer;
(2) under the action of an exhaust fan and a vibrator, the high-molecular water-absorbent resin permeates into the wood pulp ES chemical fiber mixed layer;
(3) under the action of an exhaust fan, laying the ES chemical fiber layer above the wood pulp ES chemical fiber mixing layer;
(4) heating to make the ES fibers on the ES chemical fiber layer and the wood pulp ES chemical fiber mixed layer mutually connected to form a forming body, cooling, rolling and cutting to obtain the glue-free reverse absorption water absorption core body.
Preferably, in the step (4), the temperature of the heating treatment is 100 to 150 ℃.
Adopt the technical scheme provided by the utility model, compare with prior art, have following beneficial effect:
1. the utility model provides a through heat treatment alright form the formed body without the adhesive between ES chemical fiber layer and the thick liquid ES chemical fiber mixing layer, compare in the condition that adopts the binder to bond, liquid infiltration is fast down to furthest has guaranteed the dry and comfortable on upper strata, makes environmental protection health more simultaneously.
2. The utility model can make liquid quickly seep from the ES chemical fiber layer to the lower wood pulp ES chemical fiber mixed layer because no binder is adopted in the middle, and the liquid is absorbed by the middle polymer water-absorbing resin layer in the seeping process; the diffusion effect always exists in the liquid permeation process, the liquid completely diffuses after reaching the wood pulp ES chemical fiber mixing layer at the lower layer, and the liquid permeating into the wood pulp ES chemical fiber mixing layer can reversely permeate into the middle high polymer water absorption resin layer from the two ends of the water absorption core body, so that the water can be quickly absorbed, and the absorption efficiency of the water absorption core body is improved.
3. The utility model discloses a polymer water absorbent resin that the particle size is different, the polymer water absorbent resin particle size of upside is big, and the polymer water absorbent resin particle size of downside is little, so the clearance between the polymer water absorbent resin of upside is big, and liquid can infiltrate rapidly. Meanwhile, as the macromolecular water-absorbent resin on the upper side is relatively weak, when liquid seeps downwards, the macromolecular water-absorbent resin on the upper part of the macromolecular water-absorbent resin is unlikely to expand rapidly to seal gaps among particles, so that the liquid seeps downwards conveniently, the ES chemical fiber layer on the upper layer is kept in a dry and comfortable state, and a human body can feel more comfortable when the ES chemical fiber layer is worn.
Drawings
Fig. 1 is a schematic structural diagram of the present invention;
FIG. 2 is a schematic structural view in example 2;
FIG. 3 is a schematic view of water osmotic diffusion in the present invention;
fig. 4 is a schematic view showing the diffusion of the test solution on the surface of the water-absorbent core in the comparative example.
Description of the labels in the schematic:
1-ES chemical fiber layer; 2-a high-molecular water-absorbent resin layer; 3-wood pulp ES chemical fiber mixed layer; 21-first high molecular water-absorbent resin; 22-second high molecular water absorption resin.
Detailed Description
For further understanding of the present invention, the present invention will be described in detail with reference to the following examples, which are provided for illustration of the present invention but are not intended to limit the scope of the present invention.
Example 1
As shown in fig. 1, the present embodiment relates to a non-glue reverse absorption absorbent core, which comprises an upper ES chemical fiber layer 1, a middle polymer absorbent resin layer 2 and a lower wood pulp ES chemical fiber mixed layer 3, wherein the upper ES chemical fiber layer 1 and the lower wood pulp ES chemical fiber mixed layer 3 wrap the middle polymer absorbent resin layer 2 in the middle, and the upper ES chemical fiber layer 1 and the lower wood pulp ES chemical fiber mixed layer 3 are formed into an integrated structure through heat treatment.
The thickness of the lower wood pulp ES chemical fiber mixed layer 3 is larger than that of the upper ES chemical fiber layer 1. The particle size of the high polymer water-absorbing resin in the middle high polymer water-absorbing resin layer 2 is 100 mesh. The gram weight of the upper ES chemical fiber layer 1 is 30g/m2The gram weight of the lower wood pulp ES chemical fiber mixed layer 3 is 90g/m2The amount of the high-molecular water-absorbent resin in the intermediate high-molecular water-absorbent resin layer 2 is 250g/m2
The preparation process of the glue-free reverse-absorption water-absorption core body comprises the following steps:
(1) laying the wood pulp ES chemical fiber mixing layer on a workbench, wherein an exhaust fan and a vibrator are arranged below the wood pulp ES chemical fiber mixing layer, and macromolecular water-absorbent resin is uniformly sprayed on the upper side surface of the wood pulp ES chemical fiber mixing layer;
(2) under the action of an exhaust fan and a vibrator, the high-molecular water-absorbent resin permeates into the wood pulp ES chemical fiber mixed layer;
(3) under the action of an exhaust fan, laying the ES chemical fiber layer above the wood pulp ES chemical fiber mixing layer;
(4) heating to make the ES fibers on the ES chemical fiber layer and the wood pulp ES chemical fiber mixed layer mutually connected to form a forming body, cooling, rolling and cutting to obtain the glue-free reverse absorption water absorption core body.
In the step (4), the temperature of the heat treatment was 120 ℃.
As shown in fig. 3, 80ml of test solution is poured over the middle of the upper ES chemical fiber layer 1 of the water-absorbent core with no gel reverse absorption, the test solution can rapidly permeate downwards and diffuse around, most of the upper ES chemical fiber layer 1 can be kept dry, the test solution is absorbed by the middle high polymer water-absorbent resin layer 2, and the test solution permeating into the lower wood pulp ES chemical fiber mixed layer 3 starts to reversely permeate into the middle high polymer water-absorbent resin layer 2 to be absorbed.
According to the method for measuring the slip amount in the paper diaper (sheet and pad) of the national standard GB/T28004-2011 of the people's republic of China, the adhesive-free reverse absorption water absorption core is made into the paper diaper for babies as a sample, the sample is placed on an inclined plate with the inclination of (30 +/-2) DEG, the using surface is upward, 100mm is respectively taken from two ends of the central point of the adhesive-free reverse absorption water absorption core in the sample as a test area, 50ml of test solution is measured, the test solution is made to flow along the inclined plane, and the slip amount is finally measured to be 11.6ml and is lower than 20ml of the national standard through a plurality of experiments.
According to the method for measuring the back seepage amount in the paper diaper (sheet or pad) of the national standard GB/T28004-2011 of the people's republic of China, the glue-free reverse absorption water absorption core is made into a medium-sized baby diaper as a sample, 60ml of test solution freely flows to the surface of the center of the sample through a funnel, the same amount of test solution is injected again through the funnel after 5 minutes, a plurality of layers of filter paper with the diameter of 100mm are placed on the surface of the sample after 10 minutes, meanwhile, a standard pressing block is pressed on the filter paper, the standard pressing block is removed after 1 minute of pressing, the test is carried out for a plurality of times in the measuring mode, and finally, the average back seepage amount of the sample is measured to be 5.7g and is 10g lower than the national standard.
According to the method for measuring the leakage amount in the paper diaper (sheet or pad) of the national standard GB/T28004-2011 of the people's republic of China, the adhesive-free reversely-absorbed water absorbent core is prepared into the adult paper diaper as a sample, the sample is flatly laid on a horizontal table, 80ml of test solution is measured by a separating funnel, the test solution is poured into the center of the sample at a constant speed within 30 seconds, and after 5 minutes, no liquid leakage around the sample is observed.
Example 2
As shown in fig. 2, the present embodiment relates to a non-glue reverse absorption absorbent core, which comprises an upper ES chemical fiber layer 1, a middle polymer absorbent resin layer 2 and a lower wood pulp ES chemical fiber mixed layer 3, wherein the upper ES chemical fiber layer 1 and the lower wood pulp ES chemical fiber mixed layer 3 wrap the middle polymer absorbent resin layer 2 in the middle, and the upper ES chemical fiber layer 1 and the lower wood pulp ES chemical fiber mixed layer 3 are formed into an integrated structure through heat treatment.
The thickness of the lower wood pulp ES chemical fiber mixed layer 3 is larger than that of the upper ES chemical fiber layer 1. The gram weight of the upper ES chemical fiber layer 1 is 30g/m2The gram weight of the lower wood pulp ES chemical fiber mixed layer 3 is 90g/m2
The high-molecular water-absorbent resin layer 2 comprises first high-molecular water-absorbent resin 21 and second high-molecular water-absorbent resin 22, the first high-molecular water-absorbent resin 21 permeates the lower surface of the upper ES chemical fiber layer 1, and the second high-molecular water-absorbent resin 22 permeates the upper surface of the lower wood pulp ES chemical fiber mixed layer 3.
The particle size of the first high-molecular water-absorbent resin 21 is 200mesh, and the particle size of the second high-molecular water-absorbent resin is 100 mesh; the water absorption multiplying power of the first high-molecular water-absorbent resin is 100 times, and the water absorption multiplying power of the second high-molecular water-absorbent resin is 200 times; the dosage of the first high molecular water-absorbing resin is 100g/m2The dosage of the second high molecular water-absorbing resin is 100g/m2
The preparation process of the non-glue reverse absorption water absorption core body comprises the following steps:
(1) laying an ES chemical fiber layer and a wood pulp ES chemical fiber mixing layer on a workbench, wherein an exhaust fan and a vibrator are arranged below the ES chemical fiber layer and the wood pulp ES chemical fiber mixing layer, first high-molecular water-absorbent resin is uniformly sprayed on the upper side surface of the ES chemical fiber layer, and second high-molecular water-absorbent resin is uniformly sprayed on the upper side surface of the wood pulp ES chemical fiber mixing layer;
(2) under the action of an exhaust fan and a vibrator, the first high-molecular water-absorbent resin permeates into the ES chemical fiber layer, and the second high-molecular water-absorbent resin permeates into the wood pulp ES chemical fiber mixed layer;
(3) turning the upper side of the ES chemical fiber layer downwards, and paving the ES chemical fiber layer above the wood pulp ES chemical fiber mixing layer under the action of an exhaust fan;
(4) heating to make the ES fibers on the ES chemical fiber layer and the wood pulp ES chemical fiber mixed layer mutually connected to form a forming body, cooling, rolling and cutting to obtain the glue-free reverse absorption water absorption core body.
In the step (4), the temperature of the heat treatment was 120 ℃.
As shown in fig. 3, 80ml of test solution is poured over the middle of the upper ES chemical fiber layer 1 of the water-absorbent core with no gel reverse absorption, the test solution can rapidly permeate downwards and diffuse around, most of the upper ES chemical fiber layer 1 can be kept dry, the test solution is absorbed by the middle high polymer water-absorbent resin layer 2, and the test solution permeating into the lower wood pulp ES chemical fiber mixed layer 3 starts to reversely permeate into the middle high polymer water-absorbent resin layer 2 to be absorbed.
According to the method for measuring the slip amount in the paper diaper (sheet and pad) of the national standard GB/T28004-2011 of the people's republic of China, the adhesive-free reverse absorption water absorption core is made into the paper diaper for babies as a sample, the sample is placed on an inclined plate with the inclination of (30 +/-2) DEG, the using surface is upward, 100mm is respectively taken from two ends of the central point of the adhesive-free reverse absorption water absorption core in the sample as a test area, 50ml of test solution is measured, the test solution is made to flow along the inclined plane, and the slip amount is finally measured to be 9.7ml and is lower than 20ml of the national standard through a plurality of experiments.
According to the method for measuring the back seepage amount in the paper diaper (sheet or pad) of the national standard GB/T28004-2011 of the people's republic of China, the glue-free reverse absorption water absorption core is made into a medium-sized baby diaper as a sample, 60ml of test solution freely flows to the surface of the center of the sample through a funnel, the same amount of test solution is injected again through the funnel after 5 minutes, a plurality of layers of filter paper with the diameter of 100mm are placed on the surface of the sample after 10 minutes, meanwhile, a standard pressing block is pressed on the filter paper, the standard pressing block is removed after 1 minute of pressing, the test is carried out for a plurality of times in the measuring mode, and finally, the average back seepage amount of the sample is measured to be 4.9g and is 10g lower than the national standard.
According to the method for measuring the leakage amount in the paper diaper (sheet or pad) of the national standard GB/T28004-2011 of the people's republic of China, the adhesive-free reversely-absorbed water absorbent core is prepared into the adult paper diaper as a sample, the sample is flatly laid on a horizontal table, 80ml of test solution is measured by a separating funnel, the test solution is poured into the center of the sample at a constant speed within 30 seconds, and after 5 minutes, no liquid leakage around the sample is observed.
Comparative example 1
In the comparative example 1, the upper ES chemical fiber layer in the example 1 is replaced by a wood pulp fiber layer, and the wood pulp fiber layer, the middle high polymer water-absorbent resin layer and the lower ES chemical fiber mixed layer are bonded together through hot melt adhesive to form the water-absorbent core body in the comparative example 1, wherein the thickness of the water-absorbent core body is the same as that of the water-absorbent core body in the example 1.
The water-absorbent cores of comparative example 1 and the non-gel reverse-absorbent cores of example 1, both having dimensions of 16 x 16cm, were used as test objects. As shown in fig. 4, 80ml of the test solution was poured at an even rate over 30 seconds under the same conditions above the center points of the water-absorbent core of comparative example 1 and the non-gel reverse-absorbent core placed horizontally, and the spreading of the test solution on the upper surface (i.e., upper layer) of the water-absorbent core of comparative example 1 and the non-gel reverse-absorbent core was observed. In the absorbent core of comparative example 1, the liquid was slowly drained after pouring the test solution, and most of the liquid was diffused outward, and the test solution was not poured yet at 15 th, i.e., completely diffused to a position 8cm from the center point of the upper surface (i.e., the edge of the core). In the water-absorbing core body without the adhesive reverse absorption, after the test solution is poured, the liquid quickly seeps downwards, the liquid at the upper layer is only diffused to the position of 3.6cm away from the central point of the upper surface at the 30 th s and basically keeps not to be diffused outwards, other positions on the upper surface of the core body keep dry, and the liquid is basically absorbed by the middle layer and the lower layer.
Comparative example 2
In the comparative example 2, the water-absorbing core material with the same structure in the example 1, the upper ES chemical fiber layer, the middle high polymer water-absorbing resin layer and the lower wood pulp ES chemical fiber mixed layer are bonded by hot melt adhesive to form the water-absorbing core with the same thickness as that in the example 1.
The water-absorbent cores of comparative example 2 and the non-gel reverse-absorbent cores of example 1, both having dimensions of 16 x 16cm, were used as test objects. As shown in FIG. 4, 80ml of the test solution was poured at an even rate over 30 seconds under the same conditions above the center points of the horizontally disposed absorbent core of example 2 and the non-gel reverse-absorbent core, and the spreading of the test solution on the upper surface (i.e., upper layer) of the absorbent core of comparative example 2 and the non-gel reverse-absorbent core was observed. In the absorbent core of comparative example 2, the liquid was slowly drained after pouring the test solution, and most of the liquid was diffused outward, and the test solution was not poured yet at 15 th, i.e., the liquid was completely diffused to a position 8cm from the center point of the upper surface (i.e., the edge of the core). In the water-absorbing core body without the adhesive reverse absorption, after the test solution is poured, the liquid quickly seeps downwards, only diffuses to the position 3.6cm away from the central point of the upper surface at the 30 th s, the liquid basically keeps on the upper surface and does not diffuse outwards, other positions on the upper surface of the core body keep dry, and the liquid is basically absorbed by the middle layer and the lower layer.
Synthesize comparative example 1 and comparative example 2, show that the test solution in the absorbent core of the non-glue reverse absorption of the utility model has fast infiltration speed and slow surface diffusion speed under the absorbent core body. Indicating that the ES chemical fiber layer had a faster infiltration effect than the wood pulp fiber layer, and also that the binder used for bonding had a greater effect on the infiltration of the test solution.
The present invention and its embodiments have been described above schematically, without limitation, and what is shown in the drawings is merely an embodiment of the present invention, and the actual structure is not limited thereto. Therefore, those skilled in the art should understand that they can easily and effectively implement the present invention without departing from the spirit and scope of the present invention.

Claims (6)

1. The utility model provides a no gluey reverse absorption's absorbent core body, its characterized in that, it includes upper ES chemical fiber layer, middle polymer absorbent resin layer and lower floor's wood pulp ES chemical fiber mixed layer, upper ES chemical fiber layer and lower floor's wood pulp ES chemical fiber mixed layer wrap up middle polymer absorbent resin layer in the centre, through the thermal treatment shaping formula structure as an organic whole between upper ES chemical fiber layer and the lower floor's wood pulp ES chemical fiber mixed layer.
2. The non-glue reverse absorption water absorption core body as claimed in claim 1, wherein the particle size of the high molecular water absorption resin in the middle high molecular water absorption resin layer is 100-300 mesh.
3. The non-glue reverse absorption water absorbent core body according to claim 1, wherein the gram weight of the upper ES chemical fiber layer is 20-60 g/m2The gram weight of the lower wood pulp ES chemical fiber mixed layer is 50-200 g/m2The amount of the polymeric water-absorbing resin in the intermediate polymeric water-absorbing resin layer is 100-400 g/m2
4. The glue-free reverse absorbent core as claimed in claim 1, wherein the thickness of said lower mixed ES chemical fiber layer is greater than that of said upper mixed ES chemical fiber layer.
5. The absorbent core of claim 1, wherein the polymeric absorbent resin layer comprises a first polymeric absorbent resin and a second polymeric absorbent resin, the first polymeric absorbent resin is impregnated into the lower surface of the upper ES chemical fiber layer, and the second polymeric absorbent resin is impregnated into the upper surface of the lower wood pulp ES chemical fiber mixed layer.
6. The non-adhesive reverse-absorbent core body as claimed in claim 5, wherein said first superabsorbent polymer particlesThe diameter is 120-300 mesh, and the particle size of the second high polymer water-absorbent resin is 100-120 mesh; the water absorption multiplying power of the first high-molecular water-absorbent resin is 50-180 times, and the water absorption multiplying power of the second high-molecular water-absorbent resin is 110-260 times; the dosage of the first high-molecular water-absorbing resin is 50-200 g/m2The dosage of the second high polymer water-absorbing resin is 50-200 g/m2
CN202020229864.1U 2020-02-29 2020-02-29 Water absorption core body capable of realizing glue-free reverse absorption Active CN212369180U (en)

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Address after: 311311 Yi Yi village, Yu Qian Town, Ling'an District, Hangzhou, Zhejiang

Patentee after: Zhejiang Zhenyu water absorbing material technology Co.,Ltd.

Address before: 311311 Yi Yi village, Yu Qian Town, Ling'an District, Hangzhou, Zhejiang

Patentee before: Zhejiang Zhenyu water absorbing material Co.,Ltd.

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Denomination of utility model: A non adhesive reverse absorption water absorbing core body

Granted publication date: 20210119

Pledgee: Zhejiang Lin'an Rural Commercial Bank Co.,Ltd. Yuqian Branch

Pledgor: Zhejiang Zhenyu water absorbing material technology Co.,Ltd.

Registration number: Y2024330000483

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Granted publication date: 20210119

Pledgee: Zhejiang Lin'an Rural Commercial Bank Co.,Ltd. Yuqian Branch

Pledgor: Zhejiang Zhenyu water absorbing material technology Co.,Ltd.

Registration number: Y2024330000483