CN211513969U - Industrial waste gas treatment equipment system - Google Patents
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- CN211513969U CN211513969U CN201922380276.8U CN201922380276U CN211513969U CN 211513969 U CN211513969 U CN 211513969U CN 201922380276 U CN201922380276 U CN 201922380276U CN 211513969 U CN211513969 U CN 211513969U
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Abstract
本实用新型涉及一种工业废气处理设备系统,包括进气风机、一级吸收塔、第一加药桶、二级吸收塔和第二加药桶,两个吸收塔上均设有多层交替设置的吸附填料和喷淋管,进气管与一级吸收塔接通,且进气管上设有过滤网,废气经过滤网进入一级吸收塔内,该过程过滤网除去废气中的大颗粒和絮绒物,喷淋管上接通有针对性的药剂溶液,废气经过吸收塔时,通过喷淋药剂溶液以及吸附填料对废气进行吸收处理,处理后的废气再通过除雾器除湿最后经排气筒排出,除雾器在除湿的过程中收集的水经过排水管排入集水池内,集水池内收集的水通过冲洗泵增压定期对过滤网进行冲洗,冲洗掉的垃圾流入收集池内,最后经排污管排出,本实用新型结构合理、废气处理效果好。
The utility model relates to an industrial waste gas treatment equipment system, comprising an air intake fan, a primary absorption tower, a first dosing barrel, a secondary absorption tower and a second dosing barrel. The set adsorption packing and spray pipe, the intake pipe is connected with the first-level absorption tower, and the intake pipe is provided with a filter screen, the exhaust gas enters the first-level absorption tower through the filter screen, and the filter screen in the process removes large particles in the exhaust gas and The flock is connected to the targeted chemical solution on the spray pipe. When the waste gas passes through the absorption tower, the waste gas is absorbed and treated by spraying the chemical solution and adsorption packing, and the treated waste gas is dehumidified by the demister and finally discharged. The air cylinder is discharged, and the water collected by the demister in the process of dehumidification is discharged into the collection tank through the drain pipe. The water collected in the collection tank is pressurized by the flushing pump to regularly flush the filter screen, and the washed garbage flows into the collection tank. Finally, it is discharged through the sewage pipe, and the utility model has reasonable structure and good waste gas treatment effect.
Description
技术领域technical field
本实用新型涉及废气处理设备的技术领域,特别涉及一种工业废气处理设备系统。The utility model relates to the technical field of waste gas treatment equipment, in particular to an industrial waste gas treatment equipment system.
背景技术Background technique
废气是指人类在生产和生活过程中排出的有毒有害的气体。特别是化工厂、钢铁厂、制药厂,以及炼焦厂和炼油厂等,排放的废气气味大,严重污染环境和影响人体健康。大气是由一定比例的氮、氧、二氧化碳、水蒸气和固体杂质微粒组成的混和物。就干洁空气而言,按体积计算,在标准状态下,氮气占78.08%,氧气占20.94%,氩气占0.93%,二氧化碳占0.03%,而其他气体的体积则是微乎其微的。随着现代工业和交通运输的发展,向大气中持续排放的物质数量越来越多,种类越来越复杂,引起大气成分发生急剧的变化。当大气正常成分之外的物质达到对人类健康、动植物生长以及气象气候产生危害的时候,我们就说大气受了污染。在工业或化工生产中产生大量的含尘废气,并且排放的废气气味大,废气中含有一定的油烟及有害物质,直接排放对环境造成极大的污染,严重影响人体健康。而现有的废气处理装置功能较为单一,这样对于废气的处理不够充分、彻底,排放到大气中仍会污染环境和危害人体健康,因此,现亟需一种成熟高效的工业废气处理设备。Exhaust gas refers to the toxic and harmful gases emitted by human beings in the process of production and life. Especially chemical plants, steel plants, pharmaceutical plants, as well as coking plants and oil refineries, etc., the exhaust gas emitted has a strong odor, which seriously pollutes the environment and affects human health. The atmosphere is a mixture of certain proportions of nitrogen, oxygen, carbon dioxide, water vapor and solid impurity particles. As far as dry and clean air is concerned, calculated by volume, under standard conditions, nitrogen accounts for 78.08%, oxygen accounts for 20.94%, argon accounts for 0.93%, carbon dioxide accounts for 0.03%, and the volume of other gases is negligible. With the development of modern industry and transportation, more and more substances are continuously emitted into the atmosphere, and the types are more and more complex, causing drastic changes in the composition of the atmosphere. When substances other than the normal composition of the atmosphere are harmful to human health, the growth of animals and plants, and the weather and climate, we say that the atmosphere is polluted. In industrial or chemical production, a large amount of dusty exhaust gas is generated, and the exhaust gas has a strong odor. The exhaust gas contains a certain amount of oil fume and harmful substances. The direct emission causes great pollution to the environment and seriously affects human health. However, the functions of the existing waste gas treatment device are relatively single, so the treatment of waste gas is not sufficient and thorough, and the discharge into the atmosphere will still pollute the environment and endanger human health. Therefore, a mature and efficient industrial waste gas treatment equipment is urgently needed.
实用新型内容Utility model content
为了解决上述问题,本实用新型提出一种工业废气处理设备系统。In order to solve the above problems, the utility model proposes an industrial waste gas treatment equipment system.
具体内容如下:工业废气处理设备系统,包括进气风机、一级吸收塔、第一加药桶、二级吸收塔和第二加药桶,其特征是:The specific contents are as follows: The industrial waste gas treatment equipment system includes an air intake fan, a primary absorption tower, a first dosing barrel, a secondary absorption tower and a second dosing barrel, and is characterized by:
所述的一级吸收塔的底部接通有进气管,该进气管上串联接通有进气风机和过滤网,且进气风机位于过滤网与一级吸收塔之间,在进气管外设有与其内部连通的收集池,该收集池位于过滤网的正下方且过滤网向下伸入收集池内,在一级吸收塔内沿竖直方向设有至少三层间隔开的第一吸附填料,相邻两层第一吸附填料之间的空间内均有向下喷淋的第一喷淋管,每根第一喷淋管均与第一循环管接通,第一循环管的下端接通在一级吸收塔的底部,且在第一循环管上串联接通有第一循环泵;The bottom of the first-stage absorption tower is connected with an intake pipe, and the intake pipe is connected in series with an intake fan and a filter screen, and the intake fan is located between the filter screen and the first-stage absorption tower, and is arranged outside the intake pipe. There is a collection tank communicated with its interior, the collection tank is located directly below the filter screen and the filter screen extends downward into the collection tank, and at least three layers of spaced first adsorption fillers are arranged in the first-level absorption tower along the vertical direction. , the space between the adjacent two layers of the first adsorption packing has a first spray pipe that sprays downward, and each first spray pipe is connected to the first circulation pipe, and the lower end of the first circulation pipe is connected to It is connected to the bottom of the first-stage absorption tower, and a first circulating pump is connected in series on the first circulating pipe;
所述的二级吸收塔的底部通过废气管道与一级吸收塔的顶部接通,在二级吸收塔内沿竖直方向设有至少三层间隔开的第二吸附填料,相邻两层第二吸附填料之间的空间内均有向下喷淋的第二喷淋管,每根第二喷淋管均与第二循环管接通,第二循环管的下端接通在二级吸收塔的底部,且在第二循环管上串联接通有第二循环泵,在二级吸收塔的顶部设有排气筒,在二级吸收塔的内部且位于排气筒的下方设有除雾器,该除雾器位于最顶层的第二吸附填料的上方,且除雾器上接通有排水管,该排水管与二级吸收塔外部的集水池接通。The bottom of the secondary absorption tower is connected to the top of the primary absorption tower through the waste gas pipeline, and the secondary absorption tower is provided with at least three layers of second adsorption packings spaced apart along the vertical direction, and two adjacent layers are arranged. In the space between the second adsorption fillers, there are second spray pipes that spray downward, each second spray pipe is connected to the second circulation pipe, and the lower end of the second circulation pipe is connected to the secondary absorption pipe At the bottom of the tower, a second circulating pump is connected in series on the second circulating pipe, an exhaust cylinder is arranged at the top of the secondary absorption tower, and a degasser is arranged inside the secondary absorption tower and below the exhaust cylinder. The mist eliminator is located above the second adsorption packing on the topmost layer, and a drain pipe is connected to the mist eliminator, and the drain pipe is connected to the water collecting tank outside the secondary absorption tower.
优选的,所述的一级吸收塔上设有伸入其底部的第一pH计。Preferably, the first-stage absorption tower is provided with a first pH meter extending into its bottom.
优选的,所述的一级吸收塔上还连通有第一加药装置,该第一加药装置包括第一加药桶、第一加药泵和第一加药管,第一加药桶与一级吸收塔之间通过第一加药管接通,所述的第一加药泵串联接通在第一加药管上。Preferably, the first-stage absorption tower is also connected with a first dosing device, and the first dosing device includes a first dosing barrel, a first dosing pump and a first dosing pipe. The first dosing barrel It is connected with the first-stage absorption tower through a first dosing pipe, and the first dosing pump is connected in series on the first dosing pipe.
优选的,所述的二级吸收塔上设有伸入其底部的第二pH计。Preferably, the secondary absorption tower is provided with a second pH meter extending into its bottom.
优选的,所述的二级吸收塔上还连通有第二加药装置,该第二加药装置包括第二加药桶、第二加药泵和第二加药管,第二加药桶与二级吸收塔之间通过第二加药管接通,所述的第二加药泵串联接通在第二加药管上。Preferably, the secondary absorption tower is also connected with a second dosing device, the second dosing device includes a second dosing barrel, a second dosing pump and a second dosing pipe, and the second dosing barrel It is connected with the secondary absorption tower through a second dosing pipe, and the second dosing pump is connected in series on the second dosing pipe.
优选的,所述的集水池的底部与进气管通过冲洗管接通,该冲洗管上串联接通有冲洗泵和控制阀门,且冲洗管与进气管的连接处位于过滤网的正上方。Preferably, the bottom of the sump is connected to the intake pipe through a flushing pipe, the flushing pipe is connected in series with a flushing pump and a control valve, and the connection between the flushing pipe and the intake pipe is located just above the filter screen.
优选的,所述的收集池的底部接通有排污管。Preferably, a sewage pipe is connected to the bottom of the collection tank.
本实用新型的有益技术效果:Beneficial technical effects of the present utility model:
本实用新型是一种工业废气处理设备系统,两个吸收塔上均设有多层交替设置的吸附填料和喷淋管,进气管与一级吸收塔接通,且进气管上设有过滤网,废气经过滤网进入一级吸收塔内,该过程过滤网除去废气中的大颗粒和絮绒物,吸收塔内通过加药泵添加针对性的药剂溶液,药剂溶液通过循环泵加注到喷淋管上进行喷淋,使其与废气接触进而吸收有害气体,药剂溶液能够通过循环泵使其在吸收塔内连续使用,提高药剂溶液的使用率,节省成本,废气经过吸收塔,通过喷淋药剂溶液以及吸附填料对废气进行吸收处理,处理后的废气再通过除雾器除湿最后经排气筒排出,除雾器在除湿的过程中收集的水经过排水管排入集水池内,集水池内收集的水通过冲洗泵增压定期对过滤网进行冲洗,提高过滤网的过滤效果,提高废气的处理效果,减少过滤网的损坏率以及更换频率,降低成本,冲洗掉的垃圾流入收集池内,最后经排污管排出,利用除雾器收集的水定期对过滤网进行冲洗,无需另设水源,结构更合理,资源利用率更高;本实用新型结构合理、运行稳定,废气处理效果好。The utility model is an industrial waste gas treatment equipment system. Two absorption towers are provided with multiple layers of alternately arranged adsorption fillers and spray pipes, the air inlet pipe is connected with the first-stage absorption tower, and the air inlet pipe is provided with a filter screen , the exhaust gas enters the first-stage absorption tower through the filter screen. In this process, the filter screen removes the large particles and flocs in the exhaust gas. The absorption tower is added with the targeted chemical solution through the dosing pump, and the chemical solution is added to the spray through the circulating pump. Spray on the shower pipe to make it contact with the waste gas and absorb harmful gases. The chemical solution can be continuously used in the absorption tower through the circulating pump, which improves the utilization rate of the chemical solution and saves costs. The waste gas passes through the absorption tower and sprays The waste gas is absorbed and treated by the chemical solution and the adsorption filler, and the treated waste gas is dehumidified by the demister and finally discharged through the exhaust pipe. The water collected inside is pressurized by the flushing pump to regularly flush the filter screen, improve the filtering effect of the filter screen, improve the treatment effect of exhaust gas, reduce the damage rate of the filter screen and the replacement frequency, reduce the cost, and the washed garbage flows into the collection tank, Finally, it is discharged through the sewage pipe, and the filter screen is regularly washed with the water collected by the mist eliminator, no need to set up another water source, the structure is more reasonable, and the resource utilization rate is higher; the utility model has reasonable structure, stable operation and good waste gas treatment effect.
附图说明Description of drawings
图1为工业废气处理设备系统的连接关系图;Fig. 1 is the connection diagram of the industrial waste gas treatment equipment system;
图2为二级吸收塔的主视图;Fig. 2 is the front view of secondary absorption tower;
图3为图1中A的放大示意图;Fig. 3 is the enlarged schematic diagram of A in Fig. 1;
图中:22.进气风机、21.一级吸收塔、17.第一加药桶、14.二级吸收塔、11.第二加药桶、26.进气管、24.过滤网、23.收集池、28.第一吸附填料、29.第一喷淋管、30.第一循环管、19.第一循环泵、32.废气管道、38.第二吸附填料、39.第二喷淋管、41.第二循环管、13.第二循环泵、36.排气筒、37.除雾器、35.排水管、15.集水池、20.第一pH计、18.第一加药泵、31.第一加药管、40.第二pH计、12.第二加药泵、42.第二加药管、33.冲洗管、25.冲洗泵、44.控制阀门、43.排污管。In the picture: 22. Air intake fan, 21. Primary absorption tower, 17. First dosing barrel, 14. Secondary absorption tower, 11. Second dosing barrel, 26. Air intake pipe, 24. Filter screen, 23 . Collection tank, 28. First adsorption packing, 29. First spray pipe, 30. First circulation pipe, 19. First circulation pump, 32. Exhaust gas pipeline, 38. Second adsorption packing, 39. Second spray Shower pipe, 41. Second circulation pipe, 13. Second circulation pump, 36. Exhaust cylinder, 37. Mist eliminator, 35. Drain pipe, 15. Water collection tank, 20. First pH meter, 18. First Dosing pump, 31. The first dosing pipe, 40. The second pH meter, 12. The second dosing pump, 42. The second dosing pipe, 33. The flushing pipe, 25. The flushing pump, 44. The control valve, 43. Sewage pipes.
具体实施方式Detailed ways
实施例一,参见图1-3,工业废气处理设备系统,包括进气风机、一级吸收塔、第一加药桶、二级吸收塔和第二加药桶;Embodiment 1, referring to Figures 1-3, an industrial waste gas treatment equipment system, including an air intake fan, a primary absorption tower, a first dosing barrel, a secondary absorption tower, and a second dosing barrel;
所述的一级吸收塔的底部接通有进气管,该进气管上串联接通有进气风机和过滤网,且进气风机位于过滤网与一级吸收塔之间,在进气管外设有与其内部连通的收集池,收集池的底部接通有排污管,冲洗过滤网时产生的垃圾流入收集池内,最终由排污管排出,该收集池位于过滤网的正下方且过滤网向下伸入收集池内,在一级吸收塔内沿竖直方向设有至少三层间隔开的第一吸附填料,相邻两层第一吸附填料之间的空间内均有向下喷淋的第一喷淋管,每根第一喷淋管均与第一循环管接通,第一循环管的下端接通在一级吸收塔的底部,且在第一循环管上串联接通有第一循环泵;The bottom of the first-stage absorption tower is connected with an intake pipe, and the intake pipe is connected in series with an intake fan and a filter screen, and the intake fan is located between the filter screen and the first-stage absorption tower, and is arranged outside the intake pipe. There is a collection tank connected to the inside of the collection tank. The bottom of the collection tank is connected with a sewage pipe. The garbage generated when washing the filter screen flows into the collection tank and is finally discharged by the sewage pipe. The collection tank is located directly below the filter screen and the filter screen extends downward. into the collection tank, in the first-stage absorption tower, there are at least three layers of first adsorption packing spaced apart along the vertical direction, and the space between the adjacent two layers of the first adsorption packing has a downward spraying first adsorption packing. Spray pipes, each first spray pipe is connected to the first circulation pipe, the lower end of the first circulation pipe is connected to the bottom of the first-stage absorption tower, and the first circulation pipe is connected in series with the first circulation pipe Pump;
所述的二级吸收塔的底部通过废气管道与一级吸收塔的顶部接通,在二级吸收塔内沿竖直方向设有至少三层间隔开的第二吸附填料,相邻两层第二吸附填料之间的空间内均有向下喷淋的第二喷淋管,每根第二喷淋管均与第二循环管接通,第二循环管的下端接通在二级吸收塔的底部,且在第二循环管上串联接通有第二循环泵,在二级吸收塔的顶部设有排气筒,在二级吸收塔的内部且位于排气筒的下方设有除雾器,该除雾器位于最顶层的第二吸附填料的上方,且除雾器上接通有排水管,该排水管与二级吸收塔外部的集水池接通。设置多级吸收塔能够对一种烟气进行多次处理,也可对多种混合烟气进行多级处理。The bottom of the secondary absorption tower is connected to the top of the primary absorption tower through the waste gas pipeline, and the secondary absorption tower is provided with at least three layers of second adsorption packings spaced apart along the vertical direction, and two adjacent layers are arranged. In the space between the second adsorption fillers, there are second spray pipes that spray downward, each second spray pipe is connected to the second circulation pipe, and the lower end of the second circulation pipe is connected to the secondary absorption pipe At the bottom of the tower, a second circulating pump is connected in series on the second circulating pipe, an exhaust cylinder is arranged at the top of the secondary absorption tower, and a degasser is arranged inside the secondary absorption tower and below the exhaust cylinder. The mist eliminator is located above the second adsorption packing on the topmost layer, and a drain pipe is connected to the mist eliminator, and the drain pipe is connected to the sump outside the secondary absorption tower. Setting up a multi-stage absorption tower can perform multiple treatments on one type of flue gas, and can also perform multi-stage processing on multiple mixed flue gases.
所述的一级吸收塔上设有伸入其底部的第一pH计,用于监测一级吸收塔内药剂溶液的pH值,从而判断药剂溶液的使用率。The first-stage absorption tower is provided with a first pH meter extending into the bottom of the first-stage absorption tower, which is used to monitor the pH value of the pharmaceutical solution in the first-stage absorption tower, thereby judging the utilization rate of the pharmaceutical solution.
所述的一级吸收塔上还连通有第一加药装置,该第一加药装置包括第一加药桶、第一加药泵和第一加药管,第一加药桶与一级吸收塔之间通过第一加药管接通,所述的第一加药泵串联接通在第一加药管上,加药桶内添加针对性药剂溶液,药剂溶液通过加药泵添加至对应的吸收塔内。The first-stage absorption tower is also connected with a first dosing device. The first dosing device includes a first dosing barrel, a first dosing pump and a first dosing pipe. The first dosing barrel is connected to the first dosing barrel. The absorption towers are connected through the first dosing pipe, the first dosing pump is connected in series on the first dosing pipe, the targeted pharmaceutical solution is added in the dosing barrel, and the pharmaceutical solution is added to the dosing pump through the dosing pump. in the corresponding absorption tower.
所述的二级吸收塔上设有伸入其底部的第二pH计,用于监测二级吸收塔内药剂溶液的pH值,从而判断药剂溶液的使用率。The secondary absorption tower is provided with a second pH meter extending into the bottom thereof for monitoring the pH value of the pharmaceutical solution in the secondary absorption tower, thereby judging the utilization rate of the pharmaceutical solution.
所述的二级吸收塔上还连通有第二加药装置,该第二加药装置包括第二加药桶、第二加药泵和第二加药管,第二加药桶与二级吸收塔之间通过第二加药管接通,所述的第二加药泵串联接通在第二加药管上。The secondary absorption tower is also connected with a second dosing device. The second dosing device includes a second dosing barrel, a second dosing pump and a second dosing pipe. The second dosing barrel is connected to the secondary dosing barrel. The absorption towers are connected through a second dosing pipe, and the second dosing pump is connected in series on the second dosing pipe.
所述的集水池的底部与进气管通过冲洗管接通,该冲洗管上串联接通有冲洗泵和控制阀门,且冲洗管与进气管的连接处位于过滤网的正上方,利用除雾器收集的水定期对过滤网进行冲洗,无需另设水源,结构更合理,资源利用率更高。The bottom of the sump is connected with the intake pipe through a flushing pipe, the flushing pipe is connected in series with a flushing pump and a control valve, and the connection between the flushing pipe and the intake pipe is located directly above the filter screen, and a mist eliminator is used. The collected water regularly rinses the filter screen, no need to set up another water source, the structure is more reasonable, and the resource utilization rate is higher.
本实用新型的工作过程及原理:The working process and principle of the present utility model:
废气经进气管进入一级吸收塔,进气管上设有过滤网,废气经过滤网进入一级吸收塔内,该过程过滤网除去废气中的大颗粒和絮绒物,吸收塔内通过加药泵添加针对性的药剂溶液,加药桶内的药剂溶液通过循环泵加注到喷淋管上进行喷淋,使其与废气接触进而吸收有害气体,药剂溶液能够通过循环泵使其在吸收塔内连续使用,提高药剂溶液的使用率,节省成本,废气经过吸收塔,通过喷淋药剂溶液以及吸附填料对废气进行吸收处理,处理后的废气再通过除雾器除湿最后经排气筒排出,除雾器在除湿的过程中收集的水经过排水管排入集水池内,集水池内收集的水通过冲洗泵增压定期对过滤网进行冲洗,提高过滤网的过滤效果,提高废气的处理效果,减少过滤网的损坏率以及更换频率,降低成本,冲洗掉的垃圾流入收集池内,最后经排污管排出,利用除雾器收集的水定期对过滤网进行冲洗,无需另设水源,结构更合理,资源利用率更高;本实用新型结构合理、运行稳定,废气处理效果好。The exhaust gas enters the first-level absorption tower through the intake pipe, and there is a filter screen on the intake pipe, and the exhaust gas enters the first-level absorption tower through the filter screen. The pump adds targeted pharmaceutical solution, and the pharmaceutical solution in the dosing barrel is injected into the spray pipe through the circulating pump for spraying, making it contact with the exhaust gas to absorb harmful gases, and the pharmaceutical solution can pass through the circulating pump to make it in the absorption tower. It can be used continuously in the interior to improve the utilization rate of the chemical solution and save the cost. The waste gas passes through the absorption tower, and the waste gas is absorbed and treated by spraying the chemical solution and the adsorption packing. The treated waste gas is dehumidified by the demister and finally discharged through the exhaust pipe. The water collected by the demister in the process of dehumidification is discharged into the sump through the drain pipe, and the water collected in the sump is pressurized by the flushing pump to regularly flush the filter screen to improve the filtering effect of the filter screen and improve the treatment effect of waste gas , reduce the damage rate and replacement frequency of the filter screen, reduce the cost, the washed garbage flows into the collection tank, and finally is discharged through the sewage pipe, and the filter screen is regularly washed with the water collected by the mist eliminator, no need to set up another water source, and the structure is more reasonable , the utilization rate of resources is higher; the utility model has reasonable structure, stable operation and good waste gas treatment effect.
Claims (7)
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113041736A (en) * | 2021-04-21 | 2021-06-29 | 广东柏然环保科技有限公司 | A exhaust treatment system for catalyst regeneration is calcined |
| CN116440680A (en) * | 2023-06-01 | 2023-07-18 | 福建凯美特气体有限公司 | Adsorption tower for carbon dioxide production |
| CN119951281A (en) * | 2025-03-27 | 2025-05-09 | 绵阳艾萨斯电子材料有限公司 | A method for recovering waste gas from copper-clad laminate |
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2019
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113041736A (en) * | 2021-04-21 | 2021-06-29 | 广东柏然环保科技有限公司 | A exhaust treatment system for catalyst regeneration is calcined |
| CN116440680A (en) * | 2023-06-01 | 2023-07-18 | 福建凯美特气体有限公司 | Adsorption tower for carbon dioxide production |
| CN119951281A (en) * | 2025-03-27 | 2025-05-09 | 绵阳艾萨斯电子材料有限公司 | A method for recovering waste gas from copper-clad laminate |
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Address after: 450000 west house, floor 5, unit 6, block B, fengyasong Tianjiao University South District, Sanquan Road, Jinshui District, Zhengzhou City, Henan Province Patentee after: Zhengkai Group Co.,Ltd. Address before: 450000 west house, floor 5, unit 6, block B, fengyasong Tianjiao University South District, Sanquan Road, Jinshui District, Zhengzhou City, Henan Province Patentee before: Henan Zhengkai Environmental Protection Engineering Co.,Ltd. |
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