CN208753333U - A kind of solar power generation watt substrate and solar power generation watt - Google Patents

A kind of solar power generation watt substrate and solar power generation watt Download PDF

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Publication number
CN208753333U
CN208753333U CN201821257800.1U CN201821257800U CN208753333U CN 208753333 U CN208753333 U CN 208753333U CN 201821257800 U CN201821257800 U CN 201821257800U CN 208753333 U CN208753333 U CN 208753333U
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layer
substrate
power generation
solar power
film
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朱伟
张继凯
程晓龙
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Hanergy Mobile Energy Holdings Group Co Ltd
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Hanergy Mobile Energy Holdings Group Co Ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/042PV modules or arrays of single PV cells
    • H01L31/048Encapsulation of modules
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04DROOF COVERINGS; SKY-LIGHTS; GUTTERS; ROOF-WORKING TOOLS
    • E04D13/00Special arrangements or devices in connection with roof coverings; Protection against birds; Roof drainage ; Sky-lights
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/02Details
    • H01L31/0216Coatings
    • H01L31/02161Coatings for devices characterised by at least one potential jump barrier or surface barrier
    • H01L31/02167Coatings for devices characterised by at least one potential jump barrier or surface barrier for solar cells
    • H01L31/02168Coatings for devices characterised by at least one potential jump barrier or surface barrier for solar cells the coatings being antireflective or having enhancing optical properties for the solar cells
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/042PV modules or arrays of single PV cells
    • H01L31/048Encapsulation of modules
    • H01L31/049Protective back sheets
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/18Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02BCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
    • Y02B10/00Integration of renewable energy sources in buildings
    • Y02B10/10Photovoltaic [PV]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Electromagnetism (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Architecture (AREA)
  • Sustainable Energy (AREA)
  • Laminated Bodies (AREA)

Abstract

A kind of solar power generation watt substrate, comprising: substrate, the substrate are curved;And color layer, the color layer are covered at least one surface in opposite two surfaces of the substrate, the color layer light-permeable.The solar power generation watt of the utility model embodiment substrate can be used in making colored solar power generation tile, the light-receiving surface of solar power generation watt can be made to present colored, so as to meet customer need, make building have more aesthetic feeling in application.

Description

A kind of solar power generation watt substrate and solar power generation watt
Technical field
The utility model relates to but be not limited to technical field of photovoltaic power generation, be particularly, but not limited to a kind of solar power generation Watt with substrate and solar power generation watt.
Background technique
From the point of view of the differentiation of energy pattern, novel clean energy resource replaces traditional energy to be trend of the times, and the one of energy development A track and rule are to move towards cleaning from unclean.Society can be promoted with effective protection ecological environment by greatly developing clean energy resource Good and steady economic growth.In this context, the solar power generation watt for having both building decoration and generating function comes into being.
Solar power generation watt is the thin film solar electrification component based on copper indium gallium selenide technology.In general, solar power generation watt Front panel be transparent substrate, appearance color present be solar panel color.
However, China has a vast territory, various regions are due to historical tradition or folkways and customs etc., watt can incline on pitched roof To in different colors, this requires solar power generations watt to have different colors for client's selection.
Utility model content
It is the general introduction to the theme being described in detail herein below.This general introduction is not the protection model in order to limit claim It encloses.
The utility model provides a kind of solar power generation watt substrate and solar power generation watt, the solar power generation watt with It is colored that substrate can be such that the light-receiving surface of solar power generation watt presents, and so as to meet customer need, to build in application More aesthetic feeling.
The utility model embodiment provides a kind of solar power generation watt substrate, and the substrate includes:
Substrate, the substrate are curved;And
Color layer, the color layer is covered at least one surface in opposite two surfaces of the substrate, described Color layer light-permeable.
Illustratively, the color layer may include: a colour developing sublayer or multiple be stacked and present mutually homochromy The colour developing sublayer of tune.
Illustratively, each colour developing sublayer may include multiple first film layers, and the multiple first film layer stacking is set It sets, each first film layer is made of homogenous material, and the material of multiple first film layers is different.
Illustratively, the refractive index of the multiple first film layer in each colour developing sublayer is different and presses same sequence It is cascading.
Illustratively, each colour developing sublayer may include two the first film layers, and one of them described first film The refractive index of layer is higher than the refractive index of the first film layer described in another by least 0.5, and in described two first film layers, refractive index is high First film layer is nearest from the substrate surface or first film layer that refractive index is low most from the substrate surface Closely.
Illustratively, first film layer can be selected from silicon dioxide layer, titanium pentoxide layer, magnesium fluoride layer, zinc sulphide Layer, aluminum oxide layer, titanium dioxide layer, titanium sesquioxide layer, chrome green layer, titanium dioxide zirconium layer.
Illustratively, each colour developing sublayer may include two the first film layers, and described two first film layers can divide It Wei not titanium pentoxide layer and silicon dioxide layer.
Illustratively, each colour developing sublayer may include two the first film layers, and described two first film layers can divide It Wei not magnesium fluoride layer and zinc sulfide layer.
Illustratively, each colour developing sublayer may include three the first film layers, and three first film layers can divide It Wei not titanium pentoxide layer, silicon dioxide layer and lanthanum sulfate layer.
Illustratively, a colour developing sublayer may include: second film layer, and second film layer is by a variety of differences Material mixed according to predetermined ratio.
Illustratively, the thickness of first film layer can include between 80-230nm, and in the color layer The number of first film layer can be between 6-12, for example, between 8-12.
Illustratively, the light transmittance of the solar power generation watt substrate can be between 50-91.5%.
Illustratively, the substrate can be tempering ultra-clear glasses.
The utility model embodiment additionally provides a kind of solar power generation watt, and the power generation tile includes: solar panel; And backboard and solar power generation watt substrate as described above positioned at the solar panel opposite sides.
The utility model embodiment provides a kind of solar power generation watt substrate and solar power generation watt, too due to this Positive energy power generation tile substrate includes curved substrate, and at least one of opposite two surface for being covered on the substrate Therefore the solar power generation watt is being used substrate as setting in solar energy by the color layer on surface, and the color layer light-permeable When the foreboard of the light-receiving surface of power generation tile, on the one hand, can guarantee there is solar irradiation to be mapped on solar panel, be solar-electricity Pond plate provides illumination;On the other hand, additionally it is possible to make the light-receiving surface of solar power generation watt present it is colored (can for it is red, orange, yellow, green, Any one color in blue, indigo and purple), so as to meet customer need, make building have more aesthetic feeling in application.
Other features and advantages of the utility model will illustrate in the following description, also, partly from specification In become more fully apparent, or understood and implementing the utility model.The purpose of this utility model and other advantages can pass through Specifically noted structure is achieved and obtained in the specification, claims and drawings.
Detailed description of the invention
In order to illustrate the embodiment of the utility model or the technical proposal in the existing technology more clearly, below will be to embodiment Or attached drawing needed to be used in the description of the prior art is briefly described, it should be apparent that, the accompanying drawings in the following description is only It is some embodiments of the utility model, for those of ordinary skill in the art, in the premise not made the creative labor Under, it is also possible to obtain other drawings based on these drawings.
Fig. 1 is a kind of structural schematic diagram of solar power generation watt substrate provided by the embodiment of the utility model;
Fig. 2 is the structural schematic diagram of another solar power generation watt substrate provided by the embodiment of the utility model;
Fig. 3 is the structure chart of another solar power generation watt substrate provided by the embodiment of the utility model;
Fig. 4 is the structure chart of another solar power generation watt substrate provided by the embodiment of the utility model;
Fig. 5 is the structure chart of another solar power generation watt substrate provided by the embodiment of the utility model;
Fig. 6 is a kind of structural schematic diagram of solar power generation watt provided by the embodiment of the utility model.
Specific embodiment
The following will be combined with the drawings in the embodiments of the present invention, carries out the technical scheme in the embodiment of the utility model Clearly and completely describe, it is clear that the described embodiments are only a part of the embodiments of the utility model, rather than whole Embodiment.Based on the embodiments of the present invention, those of ordinary skill in the art are without making creative work Every other embodiment obtained, fall within the protection scope of the utility model.
In the description of the present invention, it should be understood that term " center ", "upper", "lower", "front", "rear", The orientation or positional relationship of the instructions such as "left", "right", "vertical", "horizontal", "top", "bottom", "inner", "outside" is based on attached drawing institute The orientation or positional relationship shown, is merely for convenience of describing the present invention and simplifying the description, rather than indication or suggestion is signified Device or element must have a particular orientation, be constructed and operated in a specific orientation, therefore should not be understood as to this is practical Novel limitation.In the description of the present invention, unless otherwise indicated, the meaning of " plurality " is two or more.
The utility model embodiment provides a kind of solar power generation watt substrate, referring to Fig. 1 and Fig. 2, the substrate packet Include: substrate 1, the substrate 1 are curved;And color layer 2, the color layer 2 are covered in opposite two surfaces of the substrate 1 On at least one surface, 2 light-permeable of color layer.
Wherein, which is transparent substrate, for penetrating light.
Color is by the way that, to the visual experience of light, we arrive finding of naked eye caused by eye, brain and our experience of life Light, be to be generated by the electromagnetic wave of narrow wavelength range, the electromagnetic wave of different wave length shows as different colors.
When front panel of the substrate 1 as solar power generation watt, the substrate 1 include towards solar panel one side and Backwards to the one side of solar panel, as shown in Figure 1, the color layer 2 can be covered on the substrate 1 towards solar panel One side on, can also be covered on the substrate 1 backwards to solar panel one side on, as shown in Fig. 2, can also both cover In the one side towards solar panel of the substrate 1, it is also covered on the one side backwards to solar panel of the substrate 1 On.The color layer 2 being covered in the one side towards solar panel of substrate 1 is due to being encapsulated in substrate 1 and solar-electricity It between the plate of pond, is not exposed in external environment, avoids wind, solarization and drenches with rain, therefore the service life is longer, is covered on base The service life of the color layer 2 in the one side of solar panel of plate 1 is then relatively short.In the utility model embodiment In, since the solar power generation watt substrate includes curved substrate 1, and it is covered on opposite two table of the substrate 1 The color layer 2 at least one surface in face, and 2 light-permeable of color layer, therefore, by the solar power generation watt of the light transmission When using foreboard of the substrate as the light-receiving surface that solar power generation watt is arranged in, on the one hand, can guarantee there is solar irradiation to be mapped to too On positive energy solar panel, solar panel is enable to absorb sunlight;On the other hand, additionally it is possible to make the light of solar power generation watt Colored (for example, can be any one color in red, orange, yellow, green, blue, indigo and purple) be presented in face, so as to meet client Demand makes building have more aesthetic feeling in application.
In one embodiment of the utility model, referring to Fig. 3, which may include: a colour developing sublayer 21.Alternatively, As shown in figure 4, the color layer 2 can also include multiple colour developing sublayers 21 for being stacked and same hue being presented.
Tone is to be determined in the light by object reflection with which kind of wavelength dominance, and different wave length generates different colours Feeling, tone is the important feature of color, it determines the basic feature of color essence.As red tone refers to color layer 2 The color presented based on feux rouges (wavelength is by 620-780nm) spectrum in the light of reflection.
Illustratively, when the color layer 2 is displayed in red, which can be red shown by a colour developing sublayer 21 Color, or shown red out after the colour developing sublayer 21 of multiple display light reds is superimposed.
To it is described colour developing sublayer 21 specific structure without limitation, the colour developing sublayer 21 can be a film layer, can also Think multiple film layers.In the possible implementation of the first of the utility model, a colour developing sublayer 21 may include multiple layers First film layer 211 of folded setting, each first film layer 211 is made of homogenous material, and the material of multiple first film layers 211 It is different.Homogenous material refers to that the material removed other than impurity is one kind.
Illustratively, the refractive index of multiple first film layers in each colour developing sublayer is different and presses same sequence It is cascading, so that in entire color layer, low first film layer of refractive index and high first film of refractive index Layer is in be arranged alternately.According to the difference for the color that desired power generation tile is presented, first film layer nearest from the substrate can be folding Low first film layer of rate is penetrated, high first film layer of refractive index is also possible to.
In one example, the color layer may include 2 colour developing sublayers, and each colour developing sublayer includes 2 the first film layers: A film layer and B film layer.2 first film layers in each colour developing sublayer are stacked gradually according to one of following two sequence Setting: A film layer-B film layer, B film layer-A film layer;In the example, in both the above sequence, first the first film layer is this 2 First film layer nearest from substrate surface in first film layer.Second the first film layer is covered on the separate base of first the first film layer The side of plate surface is the first film layer farthest from substrate surface in 2 first film layers.
In one example, the color layer may include 3 colour developing sublayers, and each colour developing sublayer includes 3 the first film layers: A film layer, B film layer and C film layer.3 first film layers in each colour developing sublayer according to one of following 6 kinds of sequences successively It is stacked:
A film layer-B film layer-C film layer;
A film layer-C film layer-B film layer;
B film layer-A film layer-C film layer;
B film layer-C film layer-A film layer;
C film layer-A film layer-B film layer;
C film layer-B film layer-A film layer;
In the example, in above 6 kinds of sequences, first the first film layer is nearest from substrate surface in 3 first film layers The first film layer.Second the first film layer is covered on first side of first film layer far from substrate surface, the first film of third Layer is covered on second side of first film layer far from substrate surface, is farthest from substrate surface in 3 first film layers First film layer.According to the difference for the color that desired power generation tile is presented, first the first film layer can be rolls in 3 first film layers The first minimum film layer of rate is penetrated, highest first film layer of refractive index in 3 first film layers is also possible to.
Illustratively, first film layer can be selected from silicon dioxide layer, titanium pentoxide layer, magnesium fluoride layer, zinc sulphide Any one in layer, aluminum oxide layer, titanium dioxide layer, titanium sesquioxide layer, chrome green layer, titanium dioxide zirconium layer.
Illustratively, each colour developing sublayer may include two the first film layers being stacked, and one of them The refractive index of first film layer is higher than the refractive index of another first film layer.
Theoretically, the refractive index of the first adjacent film layer is the bigger the better.Illustratively, each colour developing sublayer can To include two the first film layers being stacked, and the refractive index of one of them first film layer is than described in another first The refractive index height at least 0.5 of film layer, in described two first film layers, high first film layer of refractive index is from the substrate table First film layer that face is nearest or refractive index is low is nearest from the substrate surface.
Illustratively, each colour developing sublayer may include two the first film layers being stacked, and described two first Film layer can be respectively titanium pentoxide layer and silicon dioxide layer.
Illustratively, each colour developing sublayer may include two the first film layers being stacked, and described two first Film layer can be respectively magnesium fluoride layer (refractive index is about 1.38) and zinc sulfide layer (refractive index is about 2.4).
Illustratively, each colour developing sublayer may include three the first film layers being stacked, and described three first Film layer can be respectively titanium pentoxide layer, silicon dioxide layer and lanthanum sulfate layer.
Illustratively, as shown in Figure 3 and Figure 4, color layer 2 may include a colour developing sublayer 21 (as shown in Figure 3) or packet Two colour developing sublayers 21 (as shown in Figure 4) for being stacked and presenting same hue are included, colour developing sublayer 21 may include two layers First film layer 211 of folded setting, two first film layers 211 can be respectively titanium pentoxide layer and silicon dioxide layer.In Fig. 4 Color layer 2 in, titanium pentoxide layer and silicon dioxide layer are in being arranged alternately.
In the possible implementation of second of the utility model, referring to Fig. 5, a colour developing sublayer 21 includes: one A second film layer 212, second film layer 212 can be mixed by a variety of different materials according to predetermined ratio.Here not Each material of same material kind is also considered as homogenous material, and the material that homogenous material also refers to other than removing impurity is One.
Illustratively, which can be mixed by titanium pentoxide and silica with predetermined ratio.
In practical applications, the shade of color layer 2 is determined by the thickness of the color layer 2.When color layer 2 includes one When the sublayer 21 that develops the color, the thickness of the colour developing sublayer 21 is the thickness of the color layer 2, and when color layer includes multiple is stacked And when the colour developing sublayer 21 of same hue is presented, the thickness and number of the colour developing sublayer 21 codetermine the thickness of the color layer 2.
In order to preferably improve the transmitance of light when showing deeper color, illustratively, first film layer Thickness can between 80-230nm, the number of the first film layer for including in the color layer can between 6-12, such as Between between 8-12.Light transmittance is the ability for indicating light and penetrating medium, be through transparent or semitransparent body light it is logical The percentage of amount and its incident flux.
In the another embodiment of the utility model, the light transmittance of the solar power generation watt substrate between 50-91.5% it Between.The solar power generation watt can reach higher light transmittance with substrate while display color.
Wherein, without limitation to the material of the substrate 1, which can be glass material, or plastic material.
Illustratively, which can be ultra-clear glasses, for example, tempering ultra-clear glasses.Ultra-clear glasses are a kind of super Bright low iron glass is provided simultaneously with all processability possessed by high-quality float glass, has superior physics, machinery and light Performance is learned, various deep processings can be carried out as other high-quality float glasses, light transmittance is up to 91.5% or more.
The utility model embodiment additionally provides a kind of solar power generation watt, and referring to Fig. 6, the power generation tile includes: the sun It can solar panel 01;Positioned at the backboard 02 and solar power generation watt base as described above of 01 opposite sides of solar panel Bottom 03.
Solar power generation watt provided by the embodiment of the utility model, using the solar power generation watt substrate 03 of above-mentioned light transmission Foreboard as the light-receiving surface that solar power generation watt is arranged in, on the one hand, can guarantee there is solar irradiation to be mapped to solar battery On plate 01, solar panel 01 is enable to absorb sunlight;On the other hand, additionally it is possible to which the light-receiving surface for making solar power generation watt is in Existing colored (can be any one color in red, orange, yellow, green, blue, indigo and purple), so as to meet customer need, answering Used time makes building have more aesthetic feeling.
The solar panel 01 and the backboard 02 and solar power generation watt are with can pass through packaging adhesive film between substrate 03 04 realizes encapsulation.
The packaging adhesive film 04 can for ethylene-octene copolymer (Polyolefin Elastomer, POE) glue film or Ethylene-vinyl acetate copolymer (Polyethylene Vinylacetate, EVA) glue film.Wherein, POE glue film or EVA glue Film realizes the bonding to solar panel 01, backboard 02 and solar power generation watt substrate 03 in lamination process.
The solar power generation watt is with being also provided with waterproof glue film 05 between substrate 03 and solar panel 01.
The waterproof glue film 05 can be formed by butyl rubber.
In order to realize the series connection of sub- solar panel, remittance can also be set between the backboard 02 and solar panel 01 Flow item 06.
The utility model embodiment provides a kind of preparation method of solar power generation watt substrate as described above, packet It includes: preparing curved substrate;And color layer is formed at least one surface in opposite two surfaces of the substrate.
The utility model embodiment provides a kind of preparation method of solar power generation watt substrate, prepares the sun obtained It is colored that energy power generation tile substrate can be such that the light-receiving surface of solar power generation watt presents, and so as to meet customer need, is applying When make building have more aesthetic feeling.
It is such as bent since solar power generation watt usually makes various moulding by imitative conventional sintering watt, roof clay tile, glazed tiles Face watt, semicircular tile, S type watt etc..Therefore, plated film is carried out usually in flat-shaped substrate to prepare colored substrate, according to processing technology It is broadly divided into on-line coating and two kinds off-line coated, on-line coating refers to that the technical process of plated film is in float glass processes Middle progress, sprays film layer by magnetron sputtering.Off-line coated is then to carry out plated film processing after flat-shaped substrate factory.Compared with The firmness of on-line coating, off-line coated obtained film layer will necessarily be affected.
Magnetron sputtering plating is exactly so that the particle deposition pounded is existed using lotus energy particle bombardment target surface in a vacuum Technology on substrate.
Solar power generation watt needs to carry out hot bending, cooling (can be annealing or tempering), if the sun because of modeling requirement Energy power generation tile uses on-line coating or off-line coated tabular coated basal plate obtained, and in the process of hot bending, heating furnace will To molten condition, (when the coated basal plate is glass, the heating temperature of molten condition is 690~730 to coated basal plate continuous heating DEG C), curved substrate is obtained subsequently into mold extrusion forming.
Regardless of coated glass, under this substrate melting temperature, film layer can melt and cause to demould.Demoulding refers to What caused by the film layer on substrate is cracked, melted due to various external force, temperature etc. etc. and substrate was detached from, peels off etc. shows As.If temperature when being lowered into mold to film layer melt temperature hereinafter, if bad molding, yields is low.Even increase Cost is to improve the melt temperature of film layer, in a mold when brake forming, film layer still can due to the curvature of substrate extruding or Person stretches and cracks.Equally it is not applied for the beautiful requirement of solar power generation watt.
And in the utility model embodiment, by the way that substrate is first prepared into curved, then the plated film on curved substrate Method formed film layer (color layer i.e. in the utility model embodiment), avoid first plated film, after by substrate manufacture at curved surface The extruding or stretching of the curvature of substrate when shape and occur demould phenomenon.
Wherein it is possible to prepare curved substrate by various methods such as hot bending method, clod wash methods, it is not limited here.
In the embodiments of the present invention, preparing curved substrate may include: that flat-shaped substrate is carried out hot bending, cold But (can be annealing process, or steel process) obtains the curved substrate.
Hot bending, which refers to, to be heated and softened flat-shaped substrate and forms in a mold, the technique that curved surface is made, cooling after hot bending Complete tempering.Wherein, annealing refers to that glass is transformed into brittleness by typical liquid when by transition temperature region (Tf-Tg) State, and glass molecule still is able to migrate within the scope of Tg point suitable temperature below, the heat that can be eliminated in glass is answered The inhomogeneities of power and configuration state, this section of temperature region are the annealing region of glass, i.e. annealing region has with glass viscosity It closes.Tempering then refer to glass is heated to softening temperature hereinafter, carry out above 50-60 DEG C of Tg point quickly, it is uniformly cooling obtain, Hardness can be increased.In practical applications, substrate can be heated to molten condition, design is squeezed by upper and lower mold Shape, then annealed or tempering and obtain substrate.
Illustratively, substrate can be tempering substrate.Tempering substrate hardness is higher.
The specific method that color layer is formed at least one surface in opposite two surfaces of the substrate is not limited It is fixed, as long as at least one surface that color layer can be formed in opposite two surfaces of the substrate.For example, can be with Color layer is formed at least one surface in opposite two surfaces of substrate using electron beam evaporation deposition method.
In the another embodiment of the utility model, target can be heated using beam bombardment, so that target It evaporates and is deposited at least one surface in opposite two surfaces of the substrate, form color layer.
When passing through magnetic control sputtering plating embrane method depositional coating, the speed that film layer deposits on the surface of the substrate is fast, due to solar energy Power generation tile is usually curved surface, and with the progress of deposition, the thickness difference of the film layer of the Wave crest and wave trough of curved surface is pushed away with plated film time Move increasing, the bad control of the uniformity of film layer, therefore, magnetron sputtering plating is more applied to facet coatings.And electronics Beam evaporation plated film refers to using target in beam bombardment crucible, evaporates so that target melts and is deposited on the plated film on substrate Method, this method can realize vapor deposition more accurately, can plate out the high-precision film of high-purity.Using electron beam evaporation plating When embrane method carries out plated film, film layer is slow in the speed that substrate surface deposits, and with the progress of vapor deposition, is deposited on the film layer of Wave crest and wave trough Thickness difference is unobvious, and uniformity controls well, is suitable for curved surface plated film.It therefore, can be preferably by electron beam evaporation deposition The thickness of film layer is adjusted.
Film layer is formed by using electron beam evaporation deposition and is resistant to 300 DEG C of high temperature, much higher than the envelope to solar power generation watt The heating temperature (usually 160 DEG C) in lamination process is filled, can prevent film layer from cracking, demoulding etc. occurring in lamination process existing As.
Illustratively, the temperature on the target material deposition to substrate can be 60-80 DEG C.That is, target film-forming temperature ( It is exactly adiabatic condensation temperature of the target on substrate) it can be 60-80 DEG C.
Illustratively, vacuum degree when electron beam evaporation deposition method being used to form color layer can be with≤10-2Pa, for example, can Think 5 × 10-3-7×10-3Pa。
In the another embodiment of the utility model, which can also include: to be formed after color layer, aobvious to this Chromatograph and substrate are heated, for improving the bond strength of color layer and substrate.
Formed after color layer, the temperature that the color layer and the substrate are heated can according to the color layer and The material of the substrate is rationally arranged.Illustratively, the temperature of the heating can be 200-400 DEG C.For example, the temperature of heating It can be any one temperature in 200 DEG C, 250 DEG C, 300 DEG C, 350 DEG C and 400 DEG C.The temperature of the heating is higher, color layer It is better with the bond strength of substrate, and color layer will not melt at 400 DEG C, therefore will not occur to demould phenomenon.
In the another embodiment of the utility model, the preparation method can also include: using beam bombardment to target Material is heated, so that using before target is evaporated and is deposited at least one surface in opposite two surfaces of substrate Ion beam bombardment film surface to be plated (surface of the color layer to be formed of the i.e. described substrate), with treat coated surface carry out cleaning and Roughening treatment.The processing can treat coated surface burr, it is dirty be removed, can also be improved by roughening treatment Adhesive force of the film layer on substrate.Ion beam bombardment film surface to be plated can make film surface to be plated form recess or protrusion, improve The roughness of film surface to be plated.
In an embodiment of the utility model, formed at least one surface in opposite two surfaces of substrate aobvious Chromatograph may include: formed at least one surface in opposite two surfaces of substrate one or more be stacked and The colour developing sublayer of same hue is presented.
Formed at least one surface in opposite two surfaces of substrate a colour developing sublayer can use two kinds can The implementation of energy.
In the first possible implementation, a variety of different materials can be carried out while is steamed according to predetermined ratio Plating, to obtain colour developing sublayer.For example, different materials can be respectively placed in different crucibles according to predetermined ratio, lead to Cross the boiling point for controlling the temperature of each crucible to placed material, vapor deposition while realizing different materials.
Illustratively, which can be mixed by titanium pentoxide and silica with predetermined ratio.
In the second possible implementation, a variety of different materials can successively be steamed according to predetermined ratio Plating, to obtain colour developing sublayer.For example, the first material can be deposited on substrate and then by second of material be deposited to On the film surface that the first material is formed, and so on, until being deposited multiple material to substrate.Using electron beam evaporation Coating method is conducive to carry out well the thickness of a variety of different materials in colour developing sublayer compared with magnetron sputtering embrane method Control, is formed by stacking the color layer of same thickness by relatively thin material layer, so, using electron beam evaporation plating The number of plies of embrane method film layer obtained can be more, to keep the depth variation range of the color of color layer also wider, and then make It is fuller, gorgeous to obtain color.
Illustratively, a colour developing sublayer may include two the first film layers, and two the first film layers can be respectively Titanium pentoxide layer and silicon dioxide layer.For example, when the tone that colour developing sublayer is presented is blue, two first film layers The thickness ratio of (titanium pentoxide layer and silicon dioxide layer) can be 40:70-50:70, when the tone that colour developing sublayer is presented is When yellow, the thickness ratio of two first film layers (titanium pentoxide layer and silicon dioxide layer) can be a:b, wherein the value of a It may range from 65-70, the value range of b can be 90-100, and when the tone that colour developing sublayer is presented is red, two should The thickness ratio of first film layer (titanium pentoxide layer and silicon dioxide layer) can be 80:130-95:130.
Illustratively, when the tone that colour developing sublayer is presented is blue, the thickness of titanium pentoxide layer and silicon dioxide layer The arbitrary value that the ratio between degree can be 40:70-50:70 within the scope of this, such as can be 40:70, exemplary, titanium pentoxide layer It can be 40nm, silicon dioxide layer can be 70nm, such as can also be 45:70 or 50:70, it is all the same with the example, five The thickness unit for aoxidizing three titanium layers and silicon dioxide layer can be nanoscale.When the tone that colour developing sublayer is presented is yellow, The arbitrary value that the ratio between titanium pentoxide layer and the thickness of silicon dioxide layer can be 60:100-70:90 within the scope of this, such as can Think 65:90, exemplary, titanium pentoxide layer can be 65nm, and silicon dioxide layer can be 90nm, such as can also be 70: 100,70:90 or 70:100, all the same with the example, the thickness unit of titanium pentoxide layer and silicon dioxide layer, which can be, to be received Meter level.When the tone that colour developing sublayer is presented is red, the ratio between thickness of titanium pentoxide layer and silicon dioxide layer can be Arbitrary value of the 80:130-95:130 within the scope of this, such as can be 80:130, exemplary, titanium pentoxide layer can be 80nm, silicon dioxide layer can be 130nm, such as can also be 90:130 or 95:130, five oxidations all the same with the example The thickness unit of three titanium layers and silicon dioxide layer can be nanoscale.
Illustratively, a colour developing sublayer may include two the first film layers, and two the first film layers can be respectively Titanium pentoxide layer and silicon dioxide layer.For example, when the tone that colour developing sublayer is presented is blue, the thickness of silicon dioxide layer It can be 40-50nm, the thickness of titanium pentoxide layer can be 70nm;When the tone that colour developing sublayer is presented is yellow, two The thickness of silicon oxide layer can be 60-70nm, and the thickness of titanium pentoxide layer can be 90-100nm;When colour developing sublayer is presented Tone when being red, the thickness of silicon dioxide layer can be 80-95nm, and the thickness of titanium pentoxide layer can be 130nm.
The light transmittance for the solar power generation watt substrate being prepared using method provided by the embodiment of the utility model is situated between Between 50-91.5%, the light transmittance of the solar power generation watt substrate for the blue that develops the color is not less than 85%;And the color of substrate Consistency is good, without part demoulding phenomenon.
The utility model embodiment additionally provides a kind of preparation method of solar power generation watt, and the preparation method can wrap It includes: in the solar power generation watt that solar power generation watt as described above substrate or preparation method as described above prepare With successively laying solar panel and backboard in substrate, and encapsulation process is carried out, obtains the solar power generation watt.
The preparation method of solar power generation watt provided by the embodiment of the utility model, can obtain appearance is the colored sun Energy power generation tile makes building have more aesthetic feeling so as to meet customer need in application.
In solar power generation watt, the solar panel and backboard can be laid in the solar power generation watt in substrate Any one color layer side.
Illustratively, which can be provided with a color layer, the solar-electricity in side in substrate Pond plate and backboard can successively be laid in the side with color layer.
Present disclosure is the example of the principle of the utility model embodiment, not makes any form to the utility model Upper or substantial restriction, or the utility model is limited to specific embodiment.To those skilled in the art, very The element, the method and system of technical solution etc. of obvious the utility model embodiment, can be changed, are changed, changed, be drilled Become, without departing from the embodiments of the present invention as described above, technical solution, as defined in the claims principle, Spirit and scope.These change, change, changing, the embodiment of differentiation is included in the equivalent integers of the utility model, These equivalent integers are included in the range of being defined by the claims of the utility model.Although can be in many different forms Embody the utility model embodiment, but be described in detail herein be the utility model some embodiments.In addition, this The embodiment of utility model includes some or all of any possible combination of various embodiments described herein, also includes In the utility model in the range of being defined by the claims.In the present invention or any one reference patent, reference Patent application or other references data in Anywhere mentioned all patents, patent application and other citations evidences This is integrally incorporated by reference with it.
Above disclosure is defined as illustrative rather than exhaustive.To those skilled in the art, this theory The bright gathering of calligraphers implies many variations and optional scheme.All these optional schemes and variation are intended to be included in present claims In the range of, wherein term " includes " means " including, but are not limited to ".
The description to the selectable embodiment of the utility model is completed herein.One skilled in the art will recognize that this Locate other equivalent transformations of the embodiment, these equivalent transformations are also as investing included by the claims herein.

Claims (10)

1. a kind of solar power generation watt substrate, the substrate include:
Substrate, the substrate are curved;And
Color layer, the color layer are covered at least one surface in opposite two surfaces of the substrate, the colour developing Layer light-permeable.
2. solar power generation watt substrate according to claim 1, wherein the color layer includes: a colour developing sublayer, Or multiple colour developing sublayers for being stacked and same hue being presented.
3. solar power generation watt substrate according to claim 2, wherein each colour developing sublayer includes multiple first Film layer, the multiple first film layer are stacked, and each first film layer is made of homogenous material, and multiple first films The material of layer is different.
4. solar power generation watt substrate according to claim 3, wherein the multiple in each colour developing sublayer The refractive index of first film layer is different and is cascading by same sequence.
5. solar power generation watt substrate according to claim 3, wherein each colour developing sublayer includes two first Film layer, and the refractive index of one of them first film layer is higher than the refractive index of the first film layer described in another by least 0.5, In described two first film layers, high first film layer of refractive index is nearest from the substrate surface or refractive index is low institute It is nearest from the substrate surface to state the first film layer.
6. solar power generation watt substrate according to claim 4, wherein first film layer be selected from silicon dioxide layer, Titanium pentoxide layer, magnesium fluoride layer, zinc sulfide layer, aluminum oxide layer, titanium dioxide layer, titanium sesquioxide layer, three oxidations two Layers of chrome, titanium dioxide zirconium layer.
7. solar power generation watt substrate according to claim 4, wherein each colour developing sublayer includes two first Film layer, described two first film layers are respectively titanium pentoxide layer and silicon dioxide layer;Or
Each colour developing sublayer includes two the first film layers, and described two first film layers are respectively magnesium fluoride layer and zinc sulphide Layer;Or
Each colour developing sublayer includes three the first film layers, and three first film layers are respectively titanium pentoxide layer, dioxy SiClx layer and lanthanum sulfate layer.
8. the solar power generation watt substrate according to any one of claim 3-7, wherein the thickness of first film layer Between 80-230nm, and the number for first film layer for including in the color layer is between 6-12.
9. solar power generation watt substrate according to claim 1, wherein the light transmission of the solar power generation watt substrate Rate is between 50-91.5%.
10. a kind of solar power generation watt, the power generation tile include:
Solar panel;And
Positioned at the backboard and solar power generation as claimed in any one of claims 1-9 wherein of the solar panel opposite sides Watt with substrate.
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CN112151479B (en) * 2020-11-24 2021-02-12 度亘激光技术(苏州)有限公司 Heat sink for device, semiconductor device and preparation method of heat sink for device
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