CN208234593U - Portable super dense hydrogen-rich microbubble drinking device - Google Patents

Portable super dense hydrogen-rich microbubble drinking device Download PDF

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Publication number
CN208234593U
CN208234593U CN201820241281.3U CN201820241281U CN208234593U CN 208234593 U CN208234593 U CN 208234593U CN 201820241281 U CN201820241281 U CN 201820241281U CN 208234593 U CN208234593 U CN 208234593U
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water
hydrogen
microbubble
rich
tank house
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王建真
肖志邦
徐磊
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Dalian Shuangdi New Technology Research Institute Co Ltd
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Dalian Shuangdi New Technology Research Institute Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/20Mixing gases with liquids
    • B01F23/23Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/20Mixing gases with liquids
    • B01F23/23Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
    • B01F23/235Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids for making foam
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/20Mixing gases with liquids
    • B01F23/23Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
    • B01F23/2366Parts; Accessories
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/40Static mixers
    • B01F25/45Mixers in which the materials to be mixed are pressed together through orifices or interstitial spaces, e.g. between beads
    • B01F25/452Mixers in which the materials to be mixed are pressed together through orifices or interstitial spaces, e.g. between beads characterised by elements provided with orifices or interstitial spaces
    • B01F25/4522Mixers in which the materials to be mixed are pressed together through orifices or interstitial spaces, e.g. between beads characterised by elements provided with orifices or interstitial spaces the components being pressed through porous bodies, e.g. flat plates, blocks or cylinders, which obstruct the whole diameter of the tube
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/50Circulation mixers, e.g. wherein at least part of the mixture is discharged from and reintroduced into a receptacle
    • B01F25/51Circulation mixers, e.g. wherein at least part of the mixture is discharged from and reintroduced into a receptacle in which the mixture is circulated through a set of tubes, e.g. with gradual introduction of a component into the circulating flow
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F35/00Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
    • B01F35/20Measuring; Control or regulation
    • B01F35/21Measuring
    • B01F35/211Measuring of the operational parameters
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F35/00Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
    • B01F35/20Measuring; Control or regulation
    • B01F35/22Control or regulation
    • B01F35/221Control or regulation of operational parameters, e.g. level of material in the mixer, temperature or pressure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F35/00Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
    • B01F35/20Measuring; Control or regulation
    • B01F35/22Control or regulation
    • B01F35/221Control or regulation of operational parameters, e.g. level of material in the mixer, temperature or pressure
    • B01F35/2211Amount of delivered fluid during a period
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F35/00Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
    • B01F35/20Measuring; Control or regulation
    • B01F35/22Control or regulation
    • B01F35/221Control or regulation of operational parameters, e.g. level of material in the mixer, temperature or pressure
    • B01F35/2213Pressure
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • C02F1/46109Electrodes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/68Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00Electrolytic production of inorganic compounds or non-metals
    • C25B1/01Products
    • C25B1/02Hydrogen or oxygen
    • C25B1/04Hydrogen or oxygen by electrolysis of water
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B15/00Operating or servicing cells
    • C25B15/08Supplying or removing reactants or electrolytes; Regeneration of electrolytes
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/17Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
    • C25B9/19Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/70Assemblies comprising two or more cells
    • C25B9/73Assemblies comprising two or more cells of the filter-press type
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    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • C02F1/46109Electrodes
    • C02F2001/46133Electrodes characterised by the material
    • C02F2001/46138Electrodes comprising a substrate and a coating
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/36Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

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  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
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Abstract

The utility model relates to a kind of portable super dense hydrogen-rich microbubble drinking devices, belong to the technical field of mixed operation of general method or apparatus physically or chemically.The device includes source water tank, circulating pump and electrolytic cell, electrolytic cell includes cation membrane, negative tank house and positive tank house, cation membrane two sides are equipped with yin, yang electrode, the entery and delivery port of negative tank house is successively serially connected to and is formed circulation loop by pipeline with the entery and delivery port of circulating pump, and positive tank house is equipped with anode-side inlet pipeline and anode-side outlet pipeline;When in use, the water mixing in hydrogen and the tank house that electrode generates in the negative tank house on circulation loop generates bubble hydrogen and flows in circulation loop high speed.The device can keep that the concentration of ordinary dissolution of the super dense hydrogen-rich microbubble in water is unattenuated, the ultra micro bubble hydrogen in water maintains have enough quantity is not broken to disappear for a long time.

Description

Portable super dense hydrogen-rich microbubble drinking device
Technical field
The utility model relates to a kind of portable super dense hydrogen-rich microbubble drinking device, belong to it is general physically or chemically The technical field of mixed operation of method or apparatus.
Background technique
Hydrogen is the molecule that content is most in the smallest molecule of nature and universe, is the important component of water, to life Contribution is huge.Early in the 80's of 20th century, just having scholar to publish thesis, hydrogen can be with hydroxyl freedom in the solution for proposition Base directly reacts.In July, 2007, Japanese Ohta Shigeo of medical university professor report, animal breath in " nature-medicine " 2% hydrogen just can effectively clear free radical, significantly improve cerebral ischemia re-pouring injured, and basis is the selection of hydrogen in vivo Property antioxidation.The paper attracts extensive attention rapidly, starts the upsurge of research hydrogen treating disease.Meanwhile health care Industry welcomes development new opportunities because of the rise of hydrogen molecule medicine, and the product of various leading " hydrogen " concepts lists fast sale one after another.
Using hydrogen treating disease, the most frequently used and basic method is breathing hydrogen and drinks two kinds of hydrogen water.Research has shown that, Hydrogen water is a kind of ideal method using hydrogen treating disease.
In order to improve the medical effect of hydrogen water, it is desirable to which the molten degree of depositing of hydrogen in water is as high as possible.But hydrogen is difficult to dissolve Yu Shui, the only about 1.6ppm of saturation solubility in water.Existing electrolytic hydrogen production method either without film or has film (two Room/tri- Room) directly to water electrolysis or be SPE Electrowinning hydrogen water, hydrogen solubility is difficult to reach saturation or even super full in water With, it is necessary to it is auxiliary otherwise, realized generally by the mixing wastewater with air method of nanometer bubble hydrogen.
The bubble being present in water, if partial size > 50mm, normally referred to as air pocket;Partial size < 5mm, referred to as minute bubbles; 1 μm of partial size >, referred to as micron bubble or microbubble;When in water there are when about 50 μm of a large amount of average grain diameters or so of bubble, Due to light refraction action we can observe that aqueous solution be creamy white, be commonly called as milk water.Partial size is less than 200 μm, habit Referred to as nano bubble;And micro-nano bubble, then refer to the bubble between micron bubble and nano bubble.
Nanometer and micro-nano bubble show some special characteristics, such as large specific surface area, in water deposit since size is small In the phase boundary potential ζ high that the time is long, itself pressurization is dissolved, mass-transfer efficiency is high, surface charge is formed and it can release free radical Etc. characteristics.Nano bubble technology is introduced, the water-soluble degree of depositing of hydrogen in hydrogen water can be made to reach saturation or even over-saturation.Moreover, because receiving The presence of rice and micro-nano bubble hydrogen, the hydrogen concentration rate of decay can slow down significantly in hydrogen water.
It generates nanometer or there are many micro-nano bubble methods, such as dispersion air method, molten gas outgassing method, ultrasonic cavitation method etc., But the soaked preparation technique of existing nanometer hydrogen and device are sufficiently complex, product price is also expensive therewith, it more difficult to small in accomplishing Type portability, the general common people are public can not to consume at all.If high-quality, efficient, easy, cheap nanometer hydrogen water technology can be developed And product, the fast development of hydrogen molecule medical health industry is pushed, benefits the common people and society, this is in environmental pollution acceleration, the common people Health meets with the today seriously threatened, is boundless beneficence thing.
In addition, how to maintain bubble to be stabilized in a liquid is a problem.Bubble itself is unstables ystem, in liquid In always to be risen by buoyancy, finally pass through the double membrane interfaces of gas-liquid and flee.Although reducing bubble size can effectively extend There is the time in bubble, but to keep bubble not vanish for a long time in a liquid, number of bubbles remains close enough in a liquid Degree, gas solubility is unattenuated, this does not accomplish in constant vessel.
To sum up, how to keep the concentration of ordinary dissolution of the super dense hydrogen-rich microbubble in water is unattenuated, the ultramicro air bubble in water always Maintenance have enough quantity it is not broken disappear (solubility of super dense hydrogen-rich microbubble in water reach saturation or over-saturation and it is long when Between keep), be urgent problem in reality.
Utility model content
The technical issues of the utility model solves is, in view of the shortcomings of the prior art, proposing a kind of super dense richness kept in water The concentration of ordinary dissolution of hydrogen microbubble is unattenuated, the ultra micro bubble hydrogen in water maintain to have for a long time enough quantity it is not broken disappear it is portable The super dense hydrogen-rich microbubble drinking device of formula.
In order to solve the above-mentioned technical problem, the inventor of the utility model proposes following technology on the basis of above-mentioned cognition Scheme is: a kind of portable super dense hydrogen-rich microbubble drinking device, including source water tank, circulating pump and electrolytic cell, the electrolytic cell Including water-permeable cation membrane and the yin, yang tank house being separated out by cation membrane, the cation membrane two sides Being equipped with for being symmetrically close to is located at the indoor yin, yang electrode of yin, yang electrolysis, the entery and delivery port and circulation of the yin tank house The entery and delivery port of pump is successively serially connected to and is formed circulation loop by pipeline, and the sun tank house is equipped with anode-side water inlet pipe Road and anode-side outlet pipeline are communicated with main water inlet tube between the source water tank and the pipeline of close circulating pump water inlet, institute It states pipeline and is further connected with the primary flow pipe outside connection in the water outlet close to negative tank house, the source water tank is equipped with and the master The return pipe of outlet pipe connection;When in use, the hydrogen and be somebody's turn to do that electrode generates in the negative tank house on the circulation loop Water mixing in tank house generates bubble hydrogen and flows in the circulation loop high speed.
The working mechanism of above-mentioned portable super dense hydrogen-rich microbubble drinking device technical solution disclosed by the utility model and Beneficial effect is presented below.
Utility model device structure feature is, referring to Fig. 1, source water is sent from source water tank to pump entry, when main water outlet When pipe is closed, under circulating pump driving, source water constitutes a circulation through circulating pump water outlet → yin tank house → circulating pump water inlet Circuit carries out closed cycle flow, the water resistance very little of entire circulation loop, and pressure-drop in pipeline goes to zero, therefore the very little pump of circulating pump Pressure can generate very high rate of circulating flow, and water flow aggregate performance is laminar condition.
The utility model hydrogen that first electrode generates in negative tank house, since the flow rate of water flow in circulation loop is very high, Hydrogen molecule is dissolved into water flow rapidly, with the water mixing in the tank house, generates a considerable amount of bubbles in water.
In inactive liquid, most important power is lift between bubble hydrogen and liquid, and bubble hydrogen is continuous under lift effect It floats and escapes.And bubble hydrogen, because of differences such as gas-liquid two-phase density, viscositys, causes fast between bubble hydrogen and fluid in field of flow There is some difference for degree.And the relative speed difference of gas-liquid two-phase, generate the drag force between gas-liquid two-phase.In inactive liquid, hydrogen Most important power is lift between bubble and liquid, and in working fluid is then mainly drag force.The presence of drag force, limits bubble It floats, bubble is moved with fluid in the same direction and kept relative stability.
Flow velocity is higher, and the probability for occurring mutually to collide between synchronized, homodromous bubble is with regard to smaller.Bubble hydrogen enters flowing water When being moved afterwards with flow direction, must be squeezed by water flow and attenuate elongated → being continuously extended → break into minute bubbles → stingy Bubble further reduces ... or even bubble diameter can achieve 100 nanometers or less.Utility model device is exactly based on holding envelope The high flow rate of water body in closed loop pipeline, to ensure to generate minute bubbles.
Of particular note is that: it is largely stabilized for bubble hydrogen in water to be made, it is also desirable to which bubble hydrogen is uniform Distribution suspends in water, and does not collide between each other, while solving the defect that bubble hydrogen can not be stabilized in stationary water.This reality It is with new device that bubble hydrogen is molten there are in the circulation loop of a closing rotation, form a dynamic water tank.By hydrodynamics Common sense knows that for same pipeline sectional area, flow velocity is higher, and flow is bigger, it is meant that dynamic volume increases, and can contain more Bubble enters.It is continued into water along with bubble in tank house, the gas concentration of ordinary dissolution and number of bubbles in circulation loop are steady Step uniformly increases, and quickly reaches saturation or even over-saturation.
The beneficial effect for summarizing the portable super dense hydrogen-rich microbubble drinking device technical solution of above-mentioned the utility model is:
1) the utility model passes through the hydrogen that electrode generates in negative tank house, incorporates in water, carries out from water body inside three-dimensional Molten gas is discharged there are a large amount of bubble hydrogens especially ultra micro bubble hydrogen in water along with the shattered to pieces gas of bubble hydrogen in water, so that it may It can occur to become over-saturation hydrogen water, hydrogen is in water with the dissolution of the excess of unimolecule or polymolecular state in hydrogen water Diffusion can not be limited by water surface solubility, can achieve the state of over-saturation degree, and after entering flowing water with It when flow direction moves, is squeezed by water flow, it might even be possible to be continuously extended, break into and reach 100 nanometers or less partial sizes, together When, by the high flow rate in circulation loop, so that the hydrogen concentration of ordinary dissolution in circulation loop is unattenuated, in water, bubble hydrogen is always Maintenance has enough quantity.
2) the utility model can be intake by cathode side enters anode-side inlet pipeline and anode through diaphragm for electrolytic cell Side outlet pipeline is discharged, at this point, anode-side inlet pipeline and anode-side outlet pipeline can form open circuit, it is not only positive in this way The product that pole side reaction generates can be discharged by the pipeline that positive tank house connects, and also open humidification to diaphragm simultaneously, more Faradaic current is effectively controlled well.
The improvement of the utility model on that basis of the above technical scheme is: when in use, the circulation in the circulation loop Both water flow Lc of water flow Lx and primary flow pipe keep quantitative relationship are as follows: Lx:Lc≤5.
Specific practical function is: if the flow of water intaking output is excessive from circulation waterway (dynamic water tank), will destroy The stabilization of air-water two phase flow type in circulation loop, therefore utility model device limits Lx:Lc≤5.
The utility model on that basis of the above technical scheme perfect first is that: the anode-side inlet pipeline is connected to source water Case and positive tank house, the anode-side outlet pipeline are connected to positive tank house and ultrasonic humidifying port.
Specific practical function is: the pipeline that the product that anode reaction generates can be connected by positive tank house, from ultrasound Wave humidifies port discharge, not only only humidifies to air, but also the product that can use anode-side is carried out in air Sterilization.
The utility model on that basis of the above technical scheme perfect second is that: the electrolytic cell is externally provided with compensation tank, The anode-side inlet pipeline and anode-side outlet pipeline are respectively communicated with positive tank house and compensation tank and form primary Ioops.
Specific practical function is: by anode-side inlet pipeline and anode-side outlet pipeline be respectively communicated with positive tank house and Compensation tank simultaneously forms primary Ioops, can exclude the by-product of anode, while opening humidification to diaphragm, preferably effectively Control Faradaic current.
The three perfect improvement of the utility model on that basis of the above technical scheme is: being serially connected on the circulation loop Comb grate unit, the comb grate unit include being equipped with to pass through and comb for mixing wastewater with air solution to separate the porous of bubble Material.
Specific practical function is: comb grate unit carries out combing separation to the bubble population of suspended motion in water, prevents gas It is mutually built up between bubble, maintains foam flow pattern, can also stop bubble floating at high temperature.
The utility model on that basis of the above technical scheme perfect fourth is that: the device further include set on circulating pump into The water management list out of water inlet control unit at the mouth of a river and the water outlet set on the negative tank house being located on the circulation loop Member, the inlet/outlet control unit are switch valve, check valve or pressure maintaining valve.
The utility model on that basis of the above technical scheme perfect fifth is that: the circulation loop is equipped with loop control Unit, the loop control unit include circulation check valve, flow control valve, pressure maintaining valve or combinations thereof.
Specific practical function is: can be run by loop control unit to flow, flow velocity, pressure of gas water circulation etc. Operating condition is debugged or is adjusted.
The six perfect improvement of the utility model on that basis of the above technical scheme is: the yin, yang electrode is titanium Base and the metal electrode for spraying platinum family inert metal oxides, the yin, yang electrode are evenly distributed with aperture.
The seven perfect improvement of the utility model on that basis of the above technical scheme is: the circulating pump is diaphragm pump, The exit of the primary flow pipe is equipped with instantaneous heater.
Specific practical function is: by being equipped with instantaneous heater in the exit of primary flow pipe, being more suitable for most people Demand to drinking-water.
Detailed description of the invention
The portable super dense hydrogen-rich microbubble drinking device of the utility model is described further with reference to the accompanying drawing.
Fig. 1 is the connection structure signal of the portable super dense hydrogen-rich microbubble drinking device of the utility model embodiment one Figure.
Fig. 2 is the connection structure signal of the portable super dense hydrogen-rich microbubble drinking device of the utility model embodiment two Figure.
Fig. 3 is the connection structure signal of the portable super dense hydrogen-rich microbubble drinking device of the utility model embodiment three Figure.
Specific embodiment
Embodiment one
The portable super dense hydrogen-rich microbubble drinking device of the present embodiment, referring to Fig. 1, including source water tank 1, circulating pump and electricity Solve slot 2.Electrolytic cell 2 includes water-permeable cation membrane 21 and the negative tank house 22 and positive electricity that are separated out by cation membrane Room 23 is solved, what 21 two sides of cation membrane were symmetrically close to, which be equipped with, is located at yin, yang and is electrolysed indoor negative electrode 24 and positive electrode 25。
In order to improve the efficiency of preparing hydrogen water, electrolytic cell 2 can use multiple cascade modes.When expectation acquisition is higher When dissolved hydrogen, the water route of each electrolytic cell 2 can be connected;If it is expected that increase water flow, can be by each 2 water route of electrolytic cell simultaneously Connection.As for the electrode supply voltage of each electrolytic cell 2, it is preferred to use the positive and negative mode being connected in series, to keep identical Faradaic current. If design is rationally, can be powered with circulating pump using unified voltage class, so that system more simplifies.
The entery and delivery port of negative tank house 22 is successively serially connected to and is formed by pipeline with the entery and delivery port of circulating pump and followed Loop back path 3, positive tank house 23 are equipped with anode-side inlet pipeline 26 and anode-side outlet pipeline 27.
The circulating pump of the present embodiment is diaphragm pump, and negative electrode 24 and positive electrode 25 are titanium-based and spraying platinum family inert metal The metal electrode of oxide, yin, yang electrode are evenly distributed with aperture.
Main water inlet tube 4 is communicated between source water tank 1 and the pipeline of close circulating pump water inlet, pipeline is close to negative electricity solution The water outlet of room 22 is further connected with the primary flow pipe 5 outside connection, and source water tank 1 is equipped with the return pipe being connected to primary flow pipe 5.It is main The exit of outlet pipe 5 is equipped with instantaneous heater.
The device further includes set on the water inlet control unit of the water inlet of circulating pump and set on circulation loop 3 The water outlet of negative tank house 22 goes out water control unit.Inlet/outlet control unit can be switch valve, check valve or pressure stabilizing Valve, etc..
When in use, the water in the hydrogen and the tank house that electrode in the negative tank house 22 on circulation loop 3 generates Body mixing generates bubble hydrogen and flows in circulation loop high speed.Meanwhile circulating water flow Lx and main water outlet in circulation loop 3 Both water flow Lc of pipe 5 keep quantitative relationship are as follows: Lx:Lc≤5.
In order to which the volume for the dynamic water tank for serving as closed circulation water route is sufficiently large, while from air-water two phase flow morphological research It is found that make bubble group energy is uniform and stable to be distributed in fluid (corresponding air-water two phase flow type bubble flow or foam Stream), pipeline diameter should be far longer than bubble diameter;Conversely, water circulation power loss will increase if caliber is too big.It is comprehensive flat After weighing apparatus, the pipeline of the circulation loop 3 of utility model device is using tool hydrophobic property, section inside diameter ranges 100mm≤D≤2mm Inner wall of the pipe material.
The pipe section product phase of the sectional area of the negative tank house being located on circulation loop 3 of the present embodiment and circulation loop 3 Together.Minimum flow velocity Umin=ɑ of mixing wastewater with air solution in circulation loop 3 × water flow ÷ circulation loop 3 pipe section product S, wherein ɑ is setting numerical value, takes 5 >=ɑ >=2.
In actual tests test, the hydrogen water produced is mixed with hydrogen and water, using the micro- electricity of Denmark's Unisense high precision hydrogen Pole detection, dissolution hydrogen concentration can be stably maintained at 3.0ppm or more.Bubble density is 1500~3100/ml.
When in use, 3 groundwork of circulation loop is in≤0.01MPa low pressure range for utility model device.Circulating pump begins It is in light load conditions eventually, therefore not only energy saving, but also reliable operation, failure rate are extremely low.Meanwhile it is each in utility model device Assembly of elements be substantially on the market technology maturation, easily purchase easy component, therefore the cost performance of utility model device is high, fits It closes and produces in enormous quantities, popularized suitable for various occasions.The gas bubble degree for the air-bubble that utility model device generates reaches It can be kept for a long time in water body (no less than 300s) to saturation or over-saturation, bubble, high temperature resistant, it can continuous big flow output Air-bubble.
Embodiment two
The portable super dense hydrogen-rich microbubble drinking device of the present embodiment is improvement on the basis of embodiment one, with implementation Example one the difference is that: referring to fig. 2, the anode-side inlet pipeline 26 of the present embodiment is connected to source water tank 1 and positive tank house 23, anode-side outlet pipeline 27 is connected to positive tank house 23 and ultrasonic humidifying port 28.
Embodiment three
The portable super dense hydrogen-rich microbubble drinking device of the present embodiment is improvement on the basis of embodiment one, with implementation Example one the difference is that: referring to Fig. 3, the electrolytic cell 2 of the present embodiment is externally provided with compensation tank 29, anode-side inlet pipeline 26 Positive tank house 23 and compensation tank 29 are respectively communicated with anode-side outlet pipeline 27 and form primary Ioops.
Example IV
The portable super dense hydrogen-rich microbubble drinking device of the present embodiment is improvement on that basi of the above embodiments, and upper State embodiment the difference is that: comb grate unit, comb grate unit packet are serially connected on the circulation loop 3 of the present embodiment Include the porous material for being equipped with and passing through and comb for mixing wastewater with air solution and separating bubble.
Porous material is active carbon particle, sintering activity charcoal or zeolite.Porous material can also use microfiltration membranes or ultrafiltration Film.The effects of a large amount of random micropores of porous material play blocking, segmentation to water flow is allowed to tend to become unordered turbulent flow, can So that gas dissolves more abundant in water, the nano bubble of generation is more, bubble diameter is smaller.This hydrogen for being insoluble in water Gas, effect are especially pronounced.
Due to being based on same reason, negative 22 internal watercourses of tank house can be designed to be easily formed the structure of turbulent flow, example Such as form of zigzag, spiral shape.The preferred channel section of circulation loop 3 is in tapered sudden expansion shape, and flow section gradually contracts Sudden enlargement after small, water flow sharp impacts in channel form vortex, cut to bubble, when flow section is shunk again, Fluidised form drastic change, turbulent fluctuation is more violent, and bubble further becomes smaller, and finally generates hyperfine nanometer bubble hydrogen.
The circulation loop 3 of the present embodiment is equipped with loop control unit, and loop control unit includes circulation check valve, flow Control valve, pressure maintaining valve or combinations thereof.
Utility model device is drawn water from source water tank 1, when utility model device circulatory system pressure flow adjusts After having got well, hydraulic pressure, the flow of system each point have been in relatively fixed, even if the removal of each circulation check valve is not had at this time, System remains to steady operation.Also that is, circulation check valve is not to be necessary.
Further, suitable porous material and interstitital texture are selected, successively decreases distribution with suitable hydraulic pressure, then presses Force regulating valve can also save, and this only reduces absolutely not cost, it should however be clear that under the premise of guaranteeing required function, one more smart The system of letter is also more reliable and more stable.
The specific technical solution that the utility model is not limited to the above embodiment, such as: on the circulation loop 3 of the present embodiment Equipped with bubble diameter measurement sensor.By the diopter of gas in detection recirculated water, to judge that air water solution two-phase operates feelings Condition realizes the control to system conditions, and pump is made to be in the state of cyclic operation, etc. of low speed holding;The utility model The technical solution of above-mentioned each embodiment can form new technical solution each other with combined crosswise.It is all using equivalent replacement formed Technical solution is the protection scope of the requires of the utility model.

Claims (9)

1. a kind of portable super dense hydrogen-rich microbubble drinking device, it is characterised in that: including source water tank, circulating pump and electrolytic cell, The electrolytic cell includes water-permeable cation membrane and the yin, yang tank house that is separated out by cation membrane, the sun from What sub- diaphragm two sides were symmetrically close to, which be equipped with, is located at yin, yang and is electrolysed indoor yin, yang electrode, the yin tank house into and out of The mouth of a river is successively serially connected to and is formed circulation loop by pipeline with the entery and delivery port of circulating pump, and the sun tank house is equipped with sun Pole side inlet pipeline and anode-side outlet pipeline are communicated with master between the source water tank and the pipeline of close circulating pump water inlet Water inlet pipe, the pipeline are further connected with the primary flow pipe outside connection in the water outlet close to negative tank house, and the source water tank is set There is the return pipe being connected to the primary flow pipe;When in use, electrode generates in the negative tank house on the circulation loop Hydrogen and the tank house in water mixing generate bubble hydrogen and the circulation loop high speed flow.
2. portable super dense hydrogen-rich microbubble drinking device according to claim 1, it is characterised in that: when in use, described Both water flow Lc of circulating water flow Lx and primary flow pipe in circulation loop keep quantitative relationship are as follows: Lx:Lc≤5.
3. portable super dense hydrogen-rich microbubble drinking device according to claim 1 or claim 2, it is characterised in that: the anode-side Inlet pipeline is connected to source water tank and positive tank house, and the anode-side outlet pipeline is connected to positive tank house and ultrasonic humidifying port.
4. portable super dense hydrogen-rich microbubble drinking device according to claim 1 or claim 2, it is characterised in that: the electrolytic cell It is externally provided with compensation tank, the anode-side inlet pipeline and anode-side outlet pipeline are respectively communicated with positive tank house and compensation tank And form primary Ioops.
5. portable super dense hydrogen-rich microbubble drinking device according to claim 1 or claim 2, it is characterised in that: described to be recycled back to Road is serially connected with comb grate unit, and the comb grate unit includes being equipped with to pass through for mixing wastewater with air solution and comb separation The porous material of bubble.
6. portable super dense hydrogen-rich microbubble drinking device according to claim 1 or claim 2, it is characterised in that: the device also wraps Include the water inlet control unit set on the water inlet of circulating pump and the water outlet set on the negative tank house being located on the circulation loop Go out water control unit at mouthful, the inlet/outlet control unit is switch valve, check valve or pressure maintaining valve.
7. portable super dense hydrogen-rich microbubble drinking device according to claim 1 or claim 2, it is characterised in that: described to be recycled back to Road is equipped with loop control unit, and the loop control unit includes circulation check valve, flow control valve, pressure maintaining valve or its group It closes.
8. portable super dense hydrogen-rich microbubble drinking device according to claim 1 or claim 2, it is characterised in that: the yin, yang electricity Pole is titanium-based and the metal electrode for spraying platinum family inert metal oxides, and the yin, yang electrode is evenly distributed with aperture.
9. portable super dense hydrogen-rich microbubble drinking device according to claim 1 or claim 2, it is characterised in that: the circulating pump Exit for diaphragm pump, the primary flow pipe is equipped with instantaneous heater.
CN201820241281.3U 2017-06-12 2018-02-11 Portable super dense hydrogen-rich microbubble drinking device Withdrawn - After Issue CN208234593U (en)

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CN201820241212.2U Withdrawn - After Issue CN208234592U (en) 2017-06-12 2018-02-11 Over-saturation hydrogen-rich water dispenser
CN201820241281.3U Withdrawn - After Issue CN208234593U (en) 2017-06-12 2018-02-11 Portable super dense hydrogen-rich microbubble drinking device
CN201810139298.2A Active CN108236851B (en) 2017-06-12 2018-02-11 Supersaturated stable bubble liquid generating device
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CN108238666B (en) 2023-10-27

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