A kind of Dali stone ceramic tile of degradable formaldehyde
Technical field
The utility model is related to a kind of ceramic tile, especially a kind of Dali stone ceramic tile of degradable formaldehyde.
Background technology
With the extensive use of ornament materials of all kinds, Formaldehyde Pollution of Indoor Air is also more serious, has investigation to show, and 98%
New house finishing rear chamber in formaldehyde, the ceramic tile ornament materials most wide as application surface, if assign its removal formaldehyde function,
To very there be application value, currently, most of patented technology all rests on ceramic tile surface coating, such as utility model patent " one
Photocatalyst layer, is covered in the upper table of ceramic tile ontology by method disclosed in ceramic tile of the kind containing photocatalyst layer " (CN202152318U)
Face, to pollutants such as degradation of formaldehyde.Although this technology can achieve the purpose that the pollutants such as degradation of formaldehyde, light in the short time
Catalyst layer is easily worn consumption, and use value is little.Therefore, a kind of not only degradable formaldehyde is developed, but also continuous and effective can be kept
Method, have very important significance.
Utility model content
It is a kind of degradable the purpose of the utility model is to overcome being provided in place of above-mentioned the deficiencies in the prior art based on this
The Dali stone ceramic tile of formaldehyde.
To achieve the above object, technical solution adopted in the utility model is:A kind of marble porcelain of degradable formaldehyde
Brick, successively include marble tile base layer, be solidificated in marble tile base layer upper surface intermediate adhesion layer and with it is described in
Between the function of removing formaldehyde layer that is combined of adhesion layer upper surface.
The utility model function of removing formaldehyde layer is connect by intermediate adhesion layer with ceramic substrate, and function of removing formaldehyde layer is increased
The fastness of attachment.
Preferably, marble tile base layer upper surface is uneven or marble tile base layer upper surface
Equipped with micropore.
The utility model function of removing formaldehyde layer not only has the firm attachment of pasting material to act on, and also has roughening to be formed
The small pore space structure in surface so that function of removing formaldehyde layer is not easy to be worn, improve service life.
Preferably, the intermediate adhesion layer is at least one of stain-proofing layer, adhesive layer.
Preferably, the material of the intermediate adhesion layer is at least one of organic material, inorganic material.
Preferably, the function of removing formaldehyde layer is at least one in photocatalyst layer, formaldehyde removing oxidant layer, formaldehyde dissolving enzyme layer
Kind.
Preferably, the marble tile base layer is the marble tile base layer of surface polishing.
It is highly preferred that the marble tile base layer is the polishing marble ceramic tile that surface is porcelain, surface is enamel
One kind in polishing marble ceramic tile.
Meanwhile a kind of preparation method of the Dali stone ceramic tile of the degradable formaldehyde is also disclosed in the utility model, including
Following steps:
(1) stick one layer of pasting material in the upper surface of marble tile base layer, obtain being attached with the big of intermediate adhesion layer
Reason stone ceramic tile;
(2) adhere to one layer of function of removing formaldehyde layer in the upper surface of the Dali stone ceramic tile for being attached with intermediate adhesion layer, obtain
To the Dali stone ceramic tile of degradable formaldehyde described in the utility model.
Preferably, in the step (1), if marble tile base layer upper surface is smooth, first in marble tile base layer
Surface is roughened, then sticks one layer of pasting material in the upper surface of marble tile base layer, obtains being attached with centre
The Dali stone ceramic tile of adhesion layer.Roughening treatment described in the utility model can be selected according to the surface properties of product, if
Product surface is coarse, then need not be roughened again, if product surface is smooth, then is carried out at roughening to product surface
Reason.
It is highly preferred that the roughening treatment is at least one of surface corrosion, surface sand-blasting.
It is highly preferred that before being roughened, first marble tile base layer is polished, edging processing.
Preferably, in the step (2), the attachment technique of function of removing formaldehyde layer is in smearing, showering, injection, polishing
It is at least one.
Compared with the existing technology, the beneficial effects of the utility model are:
The Dali stone ceramic tile of degradable formaldehyde described in the utility model, function of removing formaldehyde layer not only have the secured of pasting material
Adhewsive action, and the small pore space structure in surface for also having roughening to be formed so that function of removing formaldehyde layer is not easy to be worn, significantly
Service life is improved, the defect that function of removing formaldehyde layer is easily worn is solved, improves the service life of functional layer, and not
Influence all technicals such as the original glossiness of Dali stone ceramic tile, color and luster.Meanwhile the technique is simple and direct, it can be in former marble
It is operated on ceramic tile production line, easily realizes industrial applications.
Description of the drawings
Fig. 1 is a kind of structural schematic diagram of the Dali stone ceramic tile of degradable formaldehyde described in the utility model;
Fig. 2 is a kind of flow chart of the preparation method of the Dali stone ceramic tile of degradable formaldehyde described in the utility model;
Fig. 3 is the efficiency chart that the Dali stone ceramic tile of degradable formaldehyde described in the utility model cleans front and back degradation of formaldehyde;
Wherein, 1, marble tile base layer;2, intermediate adhesion layer;3, function of removing formaldehyde layer.
Specific implementation mode
To better illustrate the purpose of this utility model, technical solution and advantage, below in conjunction with attached drawing and specific implementation
The utility model is described in further detail for example.
Embodiment 1
A kind of embodiment of the Dali stone ceramic tile of degradable formaldehyde described in the utility model, degradable first described in the present embodiment
The structural schematic diagram of the Dali stone ceramic tile of aldehyde is as shown in Fig. 1:
Successively include marble tile base layer 1, be solidificated in 1 upper surface of marble tile base layer intermediate adhesion layer 2 and
With the function of removing formaldehyde layer 3 that 2 upper surface of intermediate adhesion layer is combined, 1 upper surface of marble tile base layer is uneven, marble
Tile base layer 1 is the marble tile base layer (surface is the polishing marble ceramic tile of porcelain) of surface polishing, and intermediate adhesion layer 2 is
The material of stain-proofing layer, intermediate adhesion layer 2 is inorganic material, and function of removing formaldehyde layer 3 is photocatalyst layer.
The preparation method of the Dali stone ceramic tile of degradable formaldehyde described in the present embodiment, includes the following steps (preparation flow
As shown in Fig. 2):
(1) stick one layer of pasting material in the upper surface of coarse marble tile base layer, obtain being attached with centre and stick
The Dali stone ceramic tile of layer;
(2) the super clean bright equipment on production line is used, in the upper table of the Dali stone ceramic tile for being attached with intermediate adhesion layer
Photocatalyst particle is firmly combined by technique for grinding and forms function of removing formaldehyde layer on pasting material by face, obtain it is described can
The Dali stone ceramic tile of degradation of formaldehyde.
Embodiment 2
A kind of embodiment of the Dali stone ceramic tile of degradable formaldehyde described in the utility model, degradable first described in the present embodiment
The structural schematic diagram of the Dali stone ceramic tile of aldehyde is as shown in Fig. 1:
Successively include marble tile base layer 1, be solidificated in 1 upper surface of marble tile base layer intermediate adhesion layer 2 and
With the function of removing formaldehyde layer 3 that 2 upper surface of intermediate adhesion layer is combined, 1 upper surface of marble tile base layer is equipped with micropore, marble
Tile base layer 1 is the marble tile base layer (surface is the polishing marble ceramic tile of enamel) of surface polishing, and intermediate adhesion layer 2 is
The material of adhesive layer, intermediate adhesion layer 2 is organic material, and function of removing formaldehyde layer 3 is formaldehyde removing oxidant layer.
The preparation method of the Dali stone ceramic tile of degradable formaldehyde described in the present embodiment, includes the following steps (preparation flow
As shown in Fig. 2):
(1) first marble tile base layer is polished, edging processing, then by hydrofluoric acid surface corrosion to ceramic base
Layer surface is roughened;
(2) the super clean bright equipment on production line is used, sticking one layer in the upper surface of coarse marble tile base layer sticks
Enclosure material obtains the Dali stone ceramic tile for being attached with intermediate adhesion layer;
(3) in the upper surface of the Dali stone ceramic tile for being attached with intermediate adhesion layer, one layer of first is adhered to by spray technology
Aldehyde removes oxidant layer, obtains the Dali stone ceramic tile of the degradable formaldehyde.
Embodiment 3
A kind of embodiment of the Dali stone ceramic tile of degradable formaldehyde described in the utility model, degradable first described in the present embodiment
The structural schematic diagram of the Dali stone ceramic tile of aldehyde is as shown in Fig. 1:
Successively include marble tile base layer 1, be solidificated in 1 upper surface of marble tile base layer intermediate adhesion layer 2 and
With the function of removing formaldehyde layer 3 that 2 upper surface of intermediate adhesion layer is combined, 1 upper surface of marble tile base layer is equipped with micropore, marble
Tile base layer 1 is the marble tile base layer (surface is the polishing marble ceramic tile of enamel) of surface polishing, and intermediate adhesion layer 2 wraps
Stain-proofing layer, adhesive layer are included, the material of intermediate adhesion layer 2 is the mixture of organic material and inorganic material, function of removing formaldehyde layer 3
Enzyme layer is dissolved for formaldehyde.
The preparation method of the Dali stone ceramic tile of degradable formaldehyde described in the present embodiment, includes the following steps (preparation flow
As shown in Fig. 2):
(1) first marble tile base layer is polished, edging processing, then by surface sand-blasting to ceramic substrate surface
It is roughened;
(2) the super clean bright equipment on production line is used, sticking one layer in the upper surface of coarse marble tile base layer sticks
Enclosure material obtains the Dali stone ceramic tile for being attached with intermediate adhesion layer;
(3) in the upper surface of the Dali stone ceramic tile for being attached with intermediate adhesion layer, one layer of first is adhered to by leaching coating process
Aldehyde dissolves enzyme layer, obtains the Dali stone ceramic tile of the degradable formaldehyde.
Embodiment 4
It is 400*400mm that Dali stone ceramic tile prepared by the utility model, which is cut into size, is subsequently placed in closed transparent
Its degradation of formaldehyde performance is detected in glass container, chooses the energy-saving lamp of a 15W as light source, 5mL is injected into glass container
Formaldehyde gas, the catabolite CO of formaldehyde is detected with carbon dioxide tester2, with CO2Speed and concentration are generated to characterize this
The performance of Dali stone ceramic tile degradation of formaldehyde;Then Dali stone ceramic tile is continuously cleaned with wet rag to mop floor with analog family for 1000 times
Journey, then detect by aforementioned test method degradation of formaldehyde after Dali stone ceramic tile is cleaned performance it is performance lasting to assess its,
The efficiency chart of the degradation of formaldehyde of Dali stone ceramic tile is as shown in Fig. 3 before scouring, after cleaning, from attached drawing 3 as can be seen that before cleaning
Afterwards, how formaldehyde reduced efficiency does not almost change, this illustrates that the Dali stone ceramic tile of the degradable formaldehyde of the utility model can not only have
Degradation of formaldehyde is imitated, and can keep permanent effective, function of removing formaldehyde layer service life is long.
Finally, it should be noted that above example is only to illustrate the technical solution of the utility model rather than to this reality
With the limitation of novel protected range, although being explained in detail to the utility model with reference to preferred embodiment, this field it is common
It will be appreciated by the skilled person that can be modified or replaced equivalently to the technical solution of the utility model, without departing from this reality
With the spirit and scope of new technique scheme.