CN107675850A - A kind of Dali stone ceramic tile of degradable formaldehyde and preparation method thereof - Google Patents
A kind of Dali stone ceramic tile of degradable formaldehyde and preparation method thereof Download PDFInfo
- Publication number
- CN107675850A CN107675850A CN201711084186.3A CN201711084186A CN107675850A CN 107675850 A CN107675850 A CN 107675850A CN 201711084186 A CN201711084186 A CN 201711084186A CN 107675850 A CN107675850 A CN 107675850A
- Authority
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- China
- Prior art keywords
- layer
- ceramic tile
- formaldehyde
- stone ceramic
- dali stone
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/07—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
- E04F13/08—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
- E04F13/0866—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements composed of several layers, e.g. sandwich panels or layered panels
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B11/00—Apparatus or processes for treating or working the shaped or preshaped articles
- B28B11/04—Apparatus or processes for treating or working the shaped or preshaped articles for coating or applying engobing layers
- B28B11/048—Apparatus or processes for treating or working the shaped or preshaped articles for coating or applying engobing layers by spraying or projecting
Abstract
The invention discloses a kind of Dali stone ceramic tile of degradable formaldehyde, successively including marble tile base layer, the function of removing formaldehyde layer that is solidificated in the middle adhesion layer of marble tile base layer upper surface and is combined with the middle adhesion layer upper surface.The Dali stone ceramic tile of degradable formaldehyde of the present invention, the firm attachment that function of removing formaldehyde layer not only has pasting material acts on, and the small pore space structure in surface for also having roughening to be formed, so that function of removing formaldehyde layer is not easy to be worn, service life is greatly improved, and does not influence all technicals such as the original glossiness of Dali stone ceramic tile, color and luster.Meanwhile invention additionally discloses a kind of preparation method of the Dali stone ceramic tile, the technique is simple and direct, can be operated on former marble ceramic tile production line, easily realize industrial applications.
Description
Technical field
The present invention relates to a kind of ceramic tile and preparation method thereof, the Dali stone ceramic tile and its system of especially a kind of degradable formaldehyde
Preparation Method.
Background technology
With the extensive use of ornament materials of all kinds, Formaldehyde Pollution of Indoor Air is also serious all the more, has investigation to show, and 98%
New house finishing rear chamber in formaldehyde, the ceramic tile ornament materials most wide as application surface, if assign its removal formaldehyde function,
To very there is application value, at present, most of patented technology all rests on ceramic tile surface coating, such as utility model patent " one
Ceramic tile of the kind containing photocatalyst layer " method disclosed in (CN202152318U), photocatalyst layer is covered in the upper table of ceramic tile body
Face, so as to pollutants such as degradation of formaldehyde.Although this technology can reach the purpose of the pollutants such as degradation of formaldehyde, light in the short time
Catalyst layer is easily worn consumption, and use value is little.Therefore, a kind of both degradable formaldehyde is developed, and can keeps continuous and effective
Method, have very important significance.
The content of the invention
Based on this, a kind of degradable formaldehyde is provided it is an object of the invention to overcome above-mentioned the deficiencies in the prior art part
Dali stone ceramic tile.
To achieve the above object, the technical solution used in the present invention is：A kind of Dali stone ceramic tile of degradable formaldehyde, according to
It is secondary including marble tile base layer, be solidificated in the middle adhesion layer of marble tile base layer upper surface and sticked with the centre
The function of removing formaldehyde layer that attached layer upper surface is combined.
Function of removing formaldehyde layer of the present invention is connected by middle adhesion layer with ceramic substrate, adds the attachment of function of removing formaldehyde layer
Fastness.
Preferably, the marble tile base layer upper surface is uneven, or the marble tile base layer upper surface
Provided with micropore.
The firm attachment that function of removing formaldehyde layer of the present invention not only has pasting material acts on, and the table for also having roughening to be formed
The small pore space structure in face so that function of removing formaldehyde layer is not easy to be worn, and improves service life.
Preferably, the middle adhesion layer is at least one of stain-proofing layer, adhesive layer.Some stain-proofing layers can also fill
When adhesive use, there is adhesion；Meanwhile some adhesive layers can also serve as anti-fouling agent use, have antifouling effect.
Preferably, the material of the middle adhesion layer is at least one of organic material, inorganic material.
Preferably, the function of removing formaldehyde layer is at least one in photocatalyst layer, formaldehyde removing oxidant layer, formaldehyde dissolving enzyme layer
Kind.
Preferably, the marble tile base layer is the marble tile base layer of surface polishing.
It is highly preferred that the marble tile base layer including surface is the polishing marble ceramic tile of porcelain, surface is enamel
Polishing marble ceramic tile in one kind.
Meanwhile invention additionally discloses a kind of preparation method of the Dali stone ceramic tile of described degradable formaldehyde, including it is as follows
Step:
(1) stick one layer of pasting material in the upper surface of marble tile base layer, obtain being attached with the big of middle adhesion layer
Reason stone ceramic tile；
(2) adhere to one layer of function of removing formaldehyde layer in the upper surface of the Dali stone ceramic tile for being attached with middle adhesion layer, obtain
To the Dali stone ceramic tile of degradable formaldehyde of the present invention.
Preferably, in the step (1), if marble tile base layer upper surface is smooth, first in marble tile base layer
Surface is roughened, then sticks one layer of pasting material in the upper surface of marble tile base layer, obtains being attached with centre
The Dali stone ceramic tile of adhesion layer.Roughening processing of the present invention can be selected according to the surface properties of product, if product
It rough surface, then need not again be roughened, if product surface is smooth, then product surface is roughened.
It is highly preferred that the roughening processing is at least one of surface corrosion, surface sand-blasting.
It is highly preferred that before being roughened, first marble tile base layer is polished, edging processing.
Preferably, in the step (2), the attachment technique of function of removing formaldehyde layer is in smearing, showering, injection, polishing
It is at least one.
Relative to prior art, beneficial effects of the present invention are：
The Dali stone ceramic tile of degradable formaldehyde of the present invention, function of removing formaldehyde layer not only have the firm attachment of pasting material
Effect, and the small pore space structure in surface for also having roughening to be formed so that function of removing formaldehyde layer is not easy to be worn, and greatly improves
Service life, solve the defects of function of removing formaldehyde layer is easily worn, improve the service life of functional layer, and do not influence
The all technicals such as the original glossiness of Dali stone ceramic tile, color and luster., can be in former Dali stone ceramic tile meanwhile the technique is simple and direct
Operated on production line, easily realize industrial applications.
Brief description of the drawings
Fig. 1 is a kind of structural representation of the Dali stone ceramic tile of degradable formaldehyde of the present invention；
Fig. 2 is a kind of flow chart of the preparation method of the Dali stone ceramic tile of degradable formaldehyde of the present invention；
Fig. 3 is the efficiency chart of degradation of formaldehyde before and after the Dali stone ceramic tile of degradable formaldehyde of the present invention is cleaned；
Wherein, 1, marble tile base layer；2nd, middle adhesion layer；3rd, function of removing formaldehyde layer.
Embodiment
To better illustrate the object, technical solutions and advantages of the present invention, below in conjunction with the drawings and specific embodiments pair
The present invention is described further.
Embodiment 1
A kind of embodiment of the Dali stone ceramic tile of degradable formaldehyde of the present invention, degradable formaldehyde described in the present embodiment
The structural representation of Dali stone ceramic tile is as shown in Figure 1：
Successively include marble tile base layer 1, be solidificated in the upper surface of marble tile base layer 1 middle adhesion layer 2 and
With the function of removing formaldehyde layer 3 that the middle upper surface of adhesion layer 2 is combined, the upper surface of marble tile base layer 1 is uneven, marble
Tile base layer 1 is the marble tile base layer (surface is the polishing marble ceramic tile of porcelain) of surface polishing, and middle adhesion layer 2 is
Stain-proofing layer, the material of middle adhesion layer 2 is inorganic material, and function of removing formaldehyde layer 3 is photocatalyst layer.
The preparation method of the Dali stone ceramic tile of degradable formaldehyde described in the present embodiment, comprises the following steps (preparation flow
As shown in Figure 2):
(1) stick one layer of pasting material in the upper surface of coarse marble tile base layer, obtain being attached with centre and stick
The Dali stone ceramic tile of layer；
(2) with the super clean bright equipment on production line, in the upper table of the Dali stone ceramic tile for being attached with middle adhesion layer
Face, photocatalyst particle is firmly incorporated on pasting material by formation function of removing formaldehyde layer by technique for grinding, obtain it is described can
The Dali stone ceramic tile of degradation of formaldehyde.
Embodiment 2
A kind of embodiment of the Dali stone ceramic tile of degradable formaldehyde of the present invention, degradable formaldehyde described in the present embodiment
The structural representation of Dali stone ceramic tile is as shown in Figure 1：
Successively include marble tile base layer 1, be solidificated in the upper surface of marble tile base layer 1 middle adhesion layer 2 and
With the function of removing formaldehyde layer 3 that the middle upper surface of adhesion layer 2 is combined, the upper surface of marble tile base layer 1 is provided with micropore, marble
Tile base layer 1 is the marble tile base layer (surface is the polishing marble ceramic tile of enamel) of surface polishing, and middle adhesion layer 2 is
Adhesive layer, the material of middle adhesion layer 2 is organic material, and function of removing formaldehyde layer 3 is formaldehyde removing oxidant layer.
The preparation method of the Dali stone ceramic tile of degradable formaldehyde described in the present embodiment, comprises the following steps (preparation flow
As shown in Figure 2):
(1) first marble tile base layer is polished, edging processing, then by hydrofluoric acid surface corrosion to ceramic base
Layer surface is roughened；
(2) with the super clean bright equipment on production line, one layer is sticked in the upper surface of coarse marble tile base layer and is sticked
Enclosure material, obtain being attached with the Dali stone ceramic tile of middle adhesion layer；
(3) in the upper surface of the Dali stone ceramic tile for being attached with middle adhesion layer, one layer of first is adhered to by spray technology
Aldehyde removes oxidant layer, obtains the Dali stone ceramic tile of the degradable formaldehyde.
Embodiment 3
A kind of embodiment of the Dali stone ceramic tile of degradable formaldehyde of the present invention, degradable formaldehyde described in the present embodiment
The structural representation of Dali stone ceramic tile is as shown in Figure 1：
Successively include marble tile base layer 1, be solidificated in the upper surface of marble tile base layer 1 middle adhesion layer 2 and
With the function of removing formaldehyde layer 3 that the middle upper surface of adhesion layer 2 is combined, the upper surface of marble tile base layer 1 is provided with micropore, marble
Tile base layer 1 is the marble tile base layer (surface is the polishing marble ceramic tile of enamel) of surface polishing, and middle adhesion layer 2 wraps
Include stain-proofing layer, adhesive layer, the material of middle adhesion layer 2 is organic material and the mixture of inorganic material, function of removing formaldehyde layer 3
Enzyme layer is dissolved for formaldehyde.
The preparation method of the Dali stone ceramic tile of degradable formaldehyde described in the present embodiment, comprises the following steps (preparation flow
As shown in Figure 2):
(1) first marble tile base layer is polished, edging processing, then by surface sand-blasting to ceramic substrate surface
It is roughened；
(2) with the super clean bright equipment on production line, one layer is sticked in the upper surface of coarse marble tile base layer and is sticked
Enclosure material, obtain being attached with the Dali stone ceramic tile of middle adhesion layer；
(3) in the upper surface of the Dali stone ceramic tile for being attached with middle adhesion layer, one layer of first is adhered to by leaching coating process
Aldehyde dissolves enzyme layer, obtains the Dali stone ceramic tile of the degradable formaldehyde.
Embodiment 4
It is 400*400mm that Dali stone ceramic tile prepared by the present invention is cut into size, is subsequently placed in closed transparent glass
Its degradation of formaldehyde performance is detected in container, chooses 15W electricity-saving lamp as light source, the injection 5mL first into glass container
Aldehyde gas, the catabolite CO of formaldehyde is detected with carbon dioxide tester2, with CO2Speed and concentration are produced to characterize this Dali
The performance of stone ceramic tile degradation of formaldehyde；Then Dali stone ceramic tile is continuously cleaned 1000 times with wet rag to mop floor process with analog family,
It is performance lasting to assess its that the performance of degradation of formaldehyde after the Dali stone ceramic tile is cleaned is detected by aforementioned test method again, is cleaned
Before, clean after Dali stone ceramic tile degradation of formaldehyde efficiency chart as shown in Figure 3, from accompanying drawing 3 as can be seen that clean before and after, drop
How the efficiency of formaldehyde does not almost change, and the Dali stone ceramic tile of the degradable formaldehyde of this explanation present invention not only can effectively degrade first
Aldehyde, and can keep permanent effective, function of removing formaldehyde layer service life length.
Finally, it should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention rather than the present invention is protected
The limitation of scope is protected, although being explained in detail with reference to preferred embodiment to the present invention, one of ordinary skill in the art should
Understand, technical scheme can be modified or equivalent substitution, without departing from the essence of technical solution of the present invention
And scope.
Claims (9)
- A kind of 1. Dali stone ceramic tile of degradable formaldehyde, it is characterised in that successively including marble tile base layer, be solidificated in Dali The middle adhesion layer of stone ceramic tile basic unit upper surface and the function of removing formaldehyde layer being combined with the middle adhesion layer upper surface.
- 2. the Dali stone ceramic tile of degradable formaldehyde as claimed in claim 1, it is characterised in that in the marble tile base layer Surface irregularity, or the marble tile base layer upper surface are provided with micropore.
- 3. the Dali stone ceramic tile of degradable formaldehyde as claimed in claim 1, it is characterised in that the middle adhesion layer is antifouling At least one of layer, adhesive layer.
- 4. the Dali stone ceramic tile of degradable formaldehyde as claimed in claim 1, it is characterised in that the function of removing formaldehyde layer is light At least one of catalyst layer, formaldehyde removing oxidant layer, formaldehyde dissolving enzyme layer.
- 5. the Dali stone ceramic tile of degradable formaldehyde as claimed in claim 1, it is characterised in that the marble tile base layer is The marble tile base layer of surface polishing.
- 6. a kind of preparation method of the Dali stone ceramic tile of degradable formaldehyde as described in any one of Claims 1 to 5, its feature exist In comprising the following steps:(1) stick one layer of pasting material in the upper surface of marble tile base layer, obtain being attached with the marble of middle adhesion layer Ceramic tile；(2) adhere to one layer of function of removing formaldehyde layer in the upper surface of the Dali stone ceramic tile for being attached with middle adhesion layer, obtain this Invent the Dali stone ceramic tile of the degradable formaldehyde.
- 7. the preparation method of the Dali stone ceramic tile of degradable formaldehyde as claimed in claim 6, it is characterised in that the step (1) in, if marble tile base layer upper surface is smooth, first marble tile base layer upper surface is roughened, then One layer of pasting material is sticked in the upper surface of marble tile base layer, obtains being attached with the Dali stone ceramic tile of middle adhesion layer.
- 8. the preparation method of the Dali stone ceramic tile of degradable formaldehyde as claimed in claim 7, it is characterised in that the roughening Handle as at least one of surface corrosion, surface sand-blasting.
- 9. the preparation method of the Dali stone ceramic tile of degradable formaldehyde as claimed in claim 6, it is characterised in that the step (2) in, the attachment technique of function of removing formaldehyde layer is at least one of smearing, showering, injection, polishing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711084186.3A CN107675850A (en) | 2017-11-06 | 2017-11-06 | A kind of Dali stone ceramic tile of degradable formaldehyde and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711084186.3A CN107675850A (en) | 2017-11-06 | 2017-11-06 | A kind of Dali stone ceramic tile of degradable formaldehyde and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107675850A true CN107675850A (en) | 2018-02-09 |
Family
ID=61145784
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711084186.3A Pending CN107675850A (en) | 2017-11-06 | 2017-11-06 | A kind of Dali stone ceramic tile of degradable formaldehyde and preparation method thereof |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108756117A (en) * | 2018-04-28 | 2018-11-06 | 南安市创培电子科技有限公司 | A kind of ceramic tile and its production technology of imitative dark fund sand marbling effect |
| CN108837697A (en) * | 2018-06-08 | 2018-11-20 | 佛山市简陶瓷有限公司 | A kind of durability photocatalysis is except formaldehyde ceramic tile and preparation method thereof |
| CN109016098A (en) * | 2018-06-27 | 2018-12-18 | 清远市简陶瓷有限公司 | A kind of antibiotic ceramic tile and preparation method thereof |
| CN110372356A (en) * | 2019-08-17 | 2019-10-25 | 山东华宇国际控股有限公司 | A kind of photocatalyst cleaning ceramic tile |
| CN111267209A (en) * | 2020-03-05 | 2020-06-12 | 杭州诺贝尔陶瓷有限公司 | Full-digital decorative ceramic polished tile with formaldehyde degradation function and production method thereof |
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| US6294247B1 (en) * | 1993-10-12 | 2001-09-25 | Toto Ltd. | Multi-functional material with photocatalytic functions and method of manufacturing same |
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| JP2007190543A (en) * | 2005-12-22 | 2007-08-02 | Kiichiro Sumi | Method for manufacturing titanium dioxide coating-formed material and titanium dioxide coating-formed material manufactured thereby |
| CN102561627A (en) * | 2010-12-30 | 2012-07-11 | 佐贺光触媒环保科技(大连)有限公司 | Tile with photocatalyst antibacterium effects |
| CN204475760U (en) * | 2015-03-11 | 2015-07-15 | 吴锦芳 | A kind of sepiolite ceramic tile |
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Patent Citations (5)
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| US6294247B1 (en) * | 1993-10-12 | 2001-09-25 | Toto Ltd. | Multi-functional material with photocatalytic functions and method of manufacturing same |
| CN2658149Y (en) * | 2003-08-22 | 2004-11-24 | 王明正 | Workpiece with protection film layer |
| JP2007190543A (en) * | 2005-12-22 | 2007-08-02 | Kiichiro Sumi | Method for manufacturing titanium dioxide coating-formed material and titanium dioxide coating-formed material manufactured thereby |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108756117A (en) * | 2018-04-28 | 2018-11-06 | 南安市创培电子科技有限公司 | A kind of ceramic tile and its production technology of imitative dark fund sand marbling effect |
| CN108837697A (en) * | 2018-06-08 | 2018-11-20 | 佛山市简陶瓷有限公司 | A kind of durability photocatalysis is except formaldehyde ceramic tile and preparation method thereof |
| CN109016098A (en) * | 2018-06-27 | 2018-12-18 | 清远市简陶瓷有限公司 | A kind of antibiotic ceramic tile and preparation method thereof |
| CN110372356A (en) * | 2019-08-17 | 2019-10-25 | 山东华宇国际控股有限公司 | A kind of photocatalyst cleaning ceramic tile |
| CN111267209A (en) * | 2020-03-05 | 2020-06-12 | 杭州诺贝尔陶瓷有限公司 | Full-digital decorative ceramic polished tile with formaldehyde degradation function and production method thereof |
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Application publication date: 20180209 |
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