CN207581635U - A kind of sludge freezes prilling granulator - Google Patents

A kind of sludge freezes prilling granulator Download PDF

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Publication number
CN207581635U
CN207581635U CN201721594616.1U CN201721594616U CN207581635U CN 207581635 U CN207581635 U CN 207581635U CN 201721594616 U CN201721594616 U CN 201721594616U CN 207581635 U CN207581635 U CN 207581635U
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China
Prior art keywords
serrated knife
sludge
roll squeezer
granulating machine
machine
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Expired - Fee Related
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CN201721594616.1U
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Chinese (zh)
Inventor
李志鹏
石玉
温继瀚
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SHENGHUO TECHNOLOGY (HENAN) Co Ltd
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SHENGHUO TECHNOLOGY (HENAN) Co Ltd
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  • Drying Of Solid Materials (AREA)

Abstract

The utility model patent discloses a kind of sludge freezing prilling granulator, belongs to field of solid waste disposal, from top to bottom includes roll squeezer, serrated knife granulating machine and stirring type dryer successively;It will be transported by feeder by simple air-dried and precipitation process sludge to roll squeezer and freeze and be rolled into thin mud cake; thin mud cake is continued to freeze and be cut into inch strips by serrated knife granulating machine; and there is gravity to be fractured into particle; mud granule enters the stirring type dryer of closing by heating for multiple times and stirs; the moisture of mud granule is reduced to specified range by distillation vaporization; designated position is transported to by discharging machine, is completed sludge freeze-drying and is granulated.The utility model is by the way of using rolling granulating and stepwise disposal so that the energy utilization rate and desiccation effect of the utility model are more preferable.

Description

A kind of sludge freezes prilling granulator
Technical field
The utility model belongs to field of solid waste disposal, and in particular to a kind of sludge freezes prilling granulator.
Background technology
With Chinese society economy and the development of urbanization, the generation of municipal sewage and quantity are constantly increasing.According to having Prediction is closed, China's municipal sewage amount can also increase by a fairly big margin for 20 years in future.At present, China produces the nearly 3 × 106t of dewatered sludge per year, with The development of domestic sewage disposal cause, the total process water yield of sewage treatment plant and the continuous of degree for the treatment of expand and improve, institute The sludge quantity of generation also will increasingly increase.A large amount of sludge fails to obtain timely, rational processing and sink as sewage treatment plant The burden of weight.Also containing a large amount of N, P, K, Ca and organic matter in sludge, and N, P can have based on organic with slow release There is long-term effect.Sludge is useful living resources, as can rationally utilizing can not only then turn waste into wealth, moreover it is possible to increase economic benefit, So disposition is effectively treated and is had important practical significance using the technology of sludge.
Treatment of Sludge method is filled for desiccation and then again at this stage, but with the development of modern city, is gone special It is unrealistic to be filled to take out a piece of vacant lot, in addition directly fills the recycling that can not also realize to resource.Also A kind of method is exactly to carry out desiccation, pyrolysis, gasification to sludge, realizes the recycling of resource.Drying sludge technology is a kind of Common can effectively reduce moisture percentage in sewage sludge in order to which it continues the technology of subsequent processing, and specific is specially to design Sludge is heated in equipment, the process of evaporation wherein moisture can be not only effectively realized for " free in sludge The removal effect of water ", while also " Interstitial Water " therein, " surface-bonded water " or even " internal junction Heshui " can all be played quickly Evaporate purpose;Since the technology can be according to the requirement of subsequent processing process, by sludge drying to specified moisture content, therefore its quilt It is widely used in existing drying sludge.
Drying sludge usually using dedicated sludge drier, with steam, high-temperature flue gas or just like heat conduction oil or even Solar energy using direct or indirect mode of heating, is aided with mixing and stirring, and then reach its drying purpose as heat source.Its In, direct heat transfer formula sludge drier, this is applying artificial Suzhou Zili Chemical Equipment Co., Ltd. on June 22nd, 2010 The utility model patent of application《Sludge drying process and equipment》It waits and is described in texts, most of them are with boiler high temperature cigarette Gas etc. is used as heat source, is in direct contact after making it into drying machine with wet mud, by thermal convection directly to take wet mud out of Interior moisture;This kind of mode dehumidification efficiency is high, but being in direct contact and being precipitated due to a large amount of flue gases and wet mud, and flying dust is caused to give up Hanker that dust content is huge, and because without appropriate follow-up dust separation measure, being prone to generate the security risks such as dust explosion. In indirect heat transmission type sludge drier, sludge and heat source are not directly contacted with, but heat transfer is carried out by way of heat transfer, Such as apply for utility model patent filed in artificial 19 days April in 2012 of Zhejiang University《Sludge anhydration burning integrated processing system And its technique》A kind of indirect heat transmission type drying sludge mode is just given, since sludge and heat source are separated by artificial, It is good to heat flue gas cleannes, without related dust hidden danger, therefore using more;However, due to current indirect heat transmission type drying machine Or in a manner that the static training of similar pot and stove is dried, cause to generate sludge settling inside it under the effect of gravity and single side occur and add Thermal phenomenon, heating is not uniform enough, can not uniformly be parched so as to cause pending mud, and dehumidification efficiency is poor, even if as aforementioned special Fixed and moving tooth in sharp text is staggeredly and moving teeth is in a manner of hollow Flue duct design, and mode also not only causes its complicated numerous Superfluous, it is extremely inconvenient to safeguard, at the same its interior sludge can also be caused largely to deposit in fixed tooth lower chamber and occur not drying with The phenomenon that direct sintering sets further, since its moving teeth flank of tooth is its vertical rotor shaft direction, how to ensure sludge after the drying Discharge purpose, and being clearly for its mechanism can not conclusive realization;In addition, current sludge drier, since its sludge holds Chamber of receiving needs frequently to contact dry or wet sludge always, and the accommodating chamber wear rate after severe friction is high, service life Often influence the efficiency of actual of complete machine.How a kind of rational in infrastructure sludge drier is developed, so as to make it really Real plays convenient and efficient drying sludge purpose, to be compeled technical barrier to be solved nearly ten years both at home and abroad.
Chinese patent publication No. CN103693829A discloses a kind of sludge treatment device and technique, and equipment includes sludge Conveyer, sludge crushing molding machine and sludge drying machine, be provided with from top to bottom in the sludge hopper of sludge crushing molding machine by The broken mud roller of a pair and a pair of of mud compression moulding roller of variable-frequency motor driving;The desiccation storehouse inner cavity of sludge drying machine is divided into desiccation Room is heated in room with circulated air, if being provided with dried layer stainless (steel) wire belt transfer station, the sludge of sludge crushing molding machine in desiccation room The discharge port of hopper is located at the surface at the transmission beginning of the stainless (steel) wire belt transfer station of top in desiccation storehouse.At the sludge Equipment and technique are managed during being handled for municipal sludge, has that processivity is strong, period short efficient, place Manage the remarkable advantages such as good effect, non-secondary pollution, environmental protection, stable equipment operation safety, low energy consumption, the degree of automation height.
However, the equipment is during processing sludge compacting mud item, since water content and the big sludge of stickiness are easily bonded, Therefore the present apparatus is made to be only capable of processing water content is small and the little sludge of stickiness, use scope is significantly smaller;On the other hand, due to sludge Stickiness be insufficient to allow its keep strip, be easily broken off accumulating in switching process so that the drying efficiency of the device is lower, no Conducive to energy saving, which keeps the molding effect of sludge item grain using using by the way of additive, and increase desiccation into This, is also unfavorable for green processing;It follows that the effect of sludge granulating is most important to drying and other treatment.
Utility model content
For the problems of the prior art, the purpose of this utility model is to provide for a kind of sludge freezing prilling process and dress Put, granulating rolled using Refrigeration Technique, and using drying and other treatment step by step by the way of so that the energy utilization rate of the utility model with Desiccation effect is more preferable.
In order to achieve the above object, the technical solution of the utility model is:
A kind of sludge freezes prilling process, including that will pass through the simple dirt air-dried with precipitation process by feeder first Mud is transported to feeding of roll squeezer funnel;Then, loading hopper will freeze into roll squeezer after material collection and be rolled into thin mud cake; Again, serrated knife granulating machine cuts into inch strips thin mud cake, and freezing further reduces its moisture, and strip sludge is broken by gravity It splits to form the particle for being not fixed length;Meanwhile 0.01 DEG C of cold air is sucked by exhaust fan and air admission hole, and make roll squeezer and The negative pressure of about 610.75Pa is formed inside the equipment of serrated knife granulating machine so that the moist part distillation in the sludge after freezing;Most Afterwards, the mud granule after freezing enters the stirring type dryer of closing by heating for multiple times and stirs, by the moisture of mud granule By distilling or vaporizing, specified range is reduced to, designated position is transported to by discharging machine, completes sludge drying processing.
A kind of sludge freezes prilling granulator, from top to bottom includes roll squeezer, serrated knife granulating machine and stirring type dryer successively;
The feeding of roll squeezer mouth sets loading hopper, and the roll squeezer is included to rotating drum, described to discharge to rotating drum Mouth setting is adjacent to the material scraping plate to rotating drum surface;
The serrated knife granulating machine inlet docks the discharge port of the roll squeezer, and the serrated knife granulating machine is included to revolving tooth Knife, described pair of rotation serrated knife surface set groove along direction of rotation, and the serrated knife granulating machine discharge port setting is close to revolving serrated knife table The clear frid in face;
The main shaft of the roll squeezer and serrated knife granulating machine is hollow shaft, the hollow shaft setting approach section and discharge section, institute It states approach section and discharge section is separated by partition or solid core, the partition or solid core both ends are set into hole and portal respectively;It is described The inside of roll squeezer and serrated knife granulating machine sets cavity, and the cavity is connect respectively with entering hole and portalling;The serrated knife granulating machine With the roll squeezer by the way that together with cage connection, air inlet is set in serrated knife granulating machine lower part, the row of setting at the top of roll squeezer Air port, the exhaust outlet set exhaust fan;
If the stirring type dryer is divided into dried layer by multiple partition boards, the partition board be divided into outer circle opening large baffle and The small baffle of inner circle opening, the diaphragm internal set cavity, and the partition board top sets scraper plate, and the scraper plate is by presetting not The material of partition board is transported to different positions by same angle in same direction of rotation;The feed inlet of the stirring type dryer and Discharge gate is respectively provided with sealing conveyer.
Further, the roll squeezer is single-stage or multistage, and the series of the roll squeezer is the natural number no more than 10, institute The spacing to rotating drum for stating multistage roll squeezer is sequentially reduced.
Further, the spacing to rotating drum can adjust.
Further, the serrated knife granulating machine is single-stage or multistage, and the series of the serrated knife granulating machine is no more than 10 Natural number, the multistage serrated knife granulating machine are sequentially reduced the spacing for revolving serrated knife.
Further, the spacing of described pair of rotation serrated knife can adjust.
Further, the quantity of the partition board is the positive integer no more than 20.
The beneficial effects of the utility model are:
The utility model is passed through refrigerant in the operation of rolling in roller is rolled, during sludge is rolled into mud cake, Make the hydrogenesis in mud cake, make mud cake more easily molded, convenient for the processing of next step;
During sludge cake cuts granulating, add refrigerant further makes hydrogenesis in mud cake as early as possible, ensures Granulating effect;
Meanwhile the cold air that 0.01 DEG C is formed using external environment or equipment enters equipment, and passes through exhaust fan and make roll-in The negative pressure of about 610.75Pa is formed inside the equipment of machine and serrated knife granulating machine, reaches the three phase point that ice is considered to be worth doing in mud granule, not Make ice bits distillation in the case of destroying mud granule form, while decrease the generation of peculiar smell;
After the sludge of basic granulating enters the stirring type dryer of closing, the sludge of particle is transported to multistage partition board by scraper plate It heat drying and stirs, the environment of high temperature and pressure is formed in drying machine so that ice water distillation or/and vaporization in sludge make Desiccation granulating is more thorough.
Description of the drawings
It in order to illustrate the embodiment of the utility model or the technical proposal in the existing technology more clearly, below will be to embodiment Or attached drawing needed to be used in the description of the prior art is briefly described, it should be apparent that, the accompanying drawings in the following description is only It is some embodiments of the utility model, for those of ordinary skill in the art, in the premise not made the creative labor Under, it can also be obtained according to these attached drawings other attached drawings.
Fig. 1 is the main structure diagram of the utility model.
Fig. 2 is the present invention looks up structural representation of the utility model roll squeezer.
Fig. 3 is the A-A cross-sectional views of the utility model roll squeezer.
Fig. 4 is the present invention looks up structural representation of the utility model serrated knife granulating machine.
Fig. 5 is the B-B cross-sectional views of the utility model serrated knife granulating machine.
Fig. 6 is the main structure diagram of the utility model stirring type dryer.
Fig. 7 is the C-C cross-sectional views of the utility model stirring type dryer.
Fig. 8 is the D-D cross-sectional views of the utility model stirring type dryer.
In figure:1- feeders, 2- roll squeezers, 21- roll squeezer refrigerant exits, 22- loading hoppers, 23- exhaust outlets, 24- rollers Press refrigerant inlet, 25- is to rotating drum, and 26- material scraping plates, 27- is to rotating drum main shaft;3- serrated knife molding machines, 31- serrated knife granulating machines Refrigerant inlet, 32- serrated knife granulating machine refrigerant exits, 33- air inlets, 34- is to rotary roll serrated knife, and the clear frids of 35-, 36- is to rotary roll tooth Knife main shaft;4- stirring type dryers, 41- hot wind inlets, 42- drying machines heating agent inlet and outlet, 43- power plants, 44- speed reducers, 45- drying machine discharge gates, 46- drying machine inlets, 47- moisture exhausting ports, 48a- forward direction scraper plates, 48b- back scrapers, 49a- septulums Plate, 49b- large baffles;5- discharging machines, 6- exhaust fans.
Specific embodiment
The utility model is further described with reference to the accompanying drawings and examples.
As shown in Figure 1, a kind of sludge freezing prilling granulator, from top to bottom includes roll squeezer 2,3 and of serrated knife granulating machine successively Stirring type dryer 4.
As shown in Figures 2 and 3,2 feed inlet of the roll squeezer setting loading hopper 22, the roll squeezer 2 are included to rotating drum 25, the spacing to rotating drum 25 can adjust, and the device of the spacing adjustment includes the silk for being separately positioned on roller both ends Thick stick, cylinder or/and oil cylinder;Pass through the adjustment of spacing so that the thickness of sludge cake is in appropriate range, in order to next step Slitting.The material scraping plate 26 being adjacent to the setting of 25 discharge port of rotating drum to 25 surface of rotating drum, material scraping plate 26 can prevent dirt Mud cake is bonded in cylinder surface due to stickiness so that the ratio of briquetting and speed of production of sludge cake reduce.
As shown in Figures 4 and 5,3 feed inlet of serrated knife granulating machine docks the discharge port of the roll squeezer 2, the serrated knife into Grain machine 3 is included to revolving serrated knife 34, and described pair of 34 surface of rotation serrated knife sets groove, the spacing of described pair of rotation serrated knife 34 along direction of rotation It can adjust, the device of the spacing adjustment includes the leading screw, cylinder or/and oil cylinder that are separately positioned on roller both ends;By Away from adjustment so that the shape of sludge item is in suitable range so that is more easy to fragment into smaller particle.The serrated knife granulating The clear frid 35 to 34 surface of rotation serrated knife, the notch geometry of clear frid 35 and the slot to revolving serrated knife 34 are close in the setting of 3 discharge port of machine The shape of bottom and groove face is coincide, and clear frid 35 removes the mud granule being bonded in rotation 34 slot bottom of serrated knife and groove face in time, increases The operational efficiency of equipment.
The roll squeezer 2 is hollow to rotation serrated knife main shaft 36 to rotating drum main shaft 27 and the serrated knife granulating machine 3 Axis, the hollow shaft setting air inlet section and exhaust section, roll squeezer is connected to the air inlet section and exhaust section of rotating drum main shaft 27 respectively Refrigerant exit 21 and roll squeezer refrigerant inlet 24, the air inlet section and exhaust section of described pair of rotation serrated knife main shaft 36 connect serrated knife respectively Granulating machine refrigerant inlet 31 and serrated knife granulating machine refrigerant exit 32.
The air inlet section and exhaust section are separated by partition or solid core, the partition or solid core both ends be set into respectively hole and Portal;The inside of the roll squeezer 2 and serrated knife granulating machine 3 sets cavity, and the cavity is connect respectively with entering hole and portalling;It is described Refrigerant 5 enters hole into the roll squeezer 2 and the internal cavities of serrated knife granulating machine 3 by air inlet section, reduces in equipment and equipment Sludge temperature, freeze it, by portalling and the designated position outside exhaust section device for transferring, the refrigerant be external equipment The cryogen of offer;The roll squeezer 2 and serrated knife granulating machine 3 constantly accelerate dirt during sludge is handled, by freezing The rolling of mud is freezed so that the better protrusion of final granulating.
Together with the serrated knife granulating machine 3 and 2 external connection of roll squeezer, by being arranged on serrated knife in the operation of rolling 33 air inlet of air inlet of 3 lower part of granulating machine is vented by the exhaust fan 6 for being arranged on 2 top exhaust outlet 23 of roll squeezer.
As shown in Fig. 6,7 and 8, the stirring type dryer 4 is cylindrical with end cap up and down, upper end cover setting drying machine Feed inlet 46 and moisture exhausting port 47, bottom end cover setting drying machine discharge gate 45, drying machine Heating medium 41 and the outlet of drying machine heating agent 42;If the dryer inner is divided into dried layer by multiple partition boards, the partition board is divided into the large baffle 49b and inner circle of outer circle opening The small baffle 49a of opening, the diaphragm internal set heating chamber, the heating chamber by pipeline respectively with drying machine Heating medium 41 and 42 connection of drying machine heating agent outlet, by heated barrier, indirectly heat mud granule makes to form high temperature in drying machine high The environment of pressure so that moisture or ice bits vaporization distillation in mud granule achieve the purpose that dry mud granule;The moisture exhausting port 47 externally discharge high-temperature steam by valve not timing, while ensureing internal environment, exclude the steam in sludge;The heating agent Including the high temperature fluid provided by external equipment.
The partition board top sets scraper plate, and the scraper plate presets different angles, drying machine main shaft is fixed on by skeleton On, the drying machine main shaft at same direction of rotation, by forward direction arrangement positive scraper plate 48a or reversed arrangement it is anti- To scraper plate 48b to the material of partition board is transported to different positions, fall lower floor outer circle opening large baffle 49b or inner circle opening it is small Partition board 49a, until dropping out drying machine discharge gate 45;The main shaft lower part setting power plant 43 and speed reducer 44, revolve for main shaft Turn to provide power, the power plant 43 includes motor and fuel oil or gas engine, and the speed reducer 44 includes bevel gear Speed reducer, parallel gears speed reducer and planet-gear speed reducer.
The feed inlet 46 and discharge gate 45 of the stirring type dryer are respectively provided with sealing conveyer, the sealed conveying Machine includes sealed Shaftless screw conveyor, and the helical blade setting partition board of the sealed Shaftless screw conveyor makes sealing The O-shaped shell of formula Shaftless screw conveyor and multiple sealing cavities are formed with partition board helical blade, ensureing material in work While conveying, the leakproofness of equipment is kept.
The water vapour that the roll squeezer 2 and the evaporation of serrated knife granulating machine 3 generate is discharged from exhaust outlet 23, stirring type dryer 4 The water vapour that evaporation generates is discharged from the moisture exhausting port 47 being located on head cover, if any peculiar smell, what exhaust outlet 23 and moisture exhausting port 47 were discharged Gas empties after can be collected into spray column processing deodorization.
A kind of sludge freezes prilling process, including that will pass through the simple dirt air-dried with precipitation process by feeder 1 first Mud is transported to 2 loading hopper 22 of roll squeezer;Then, loading hopper 22 will be freezed and be rolled into roll squeezer 2 after material collection Thin mud cake;Again, serrated knife granulating machine 3 cuts into inch strips thin mud cake, and freezing further reduces its moisture, and strip sludge is by weight Power effect fragmentation formation is not fixed the particle of length;Meanwhile cold air is sucked by exhaust fan 6 and air inlet 33 so that freezing Moist part distillation in sludge afterwards;Finally, the mud granule after freezing enters the stirring type dryer 4 of closing by multiple It heats and stirs, by the moisture of mud granule by distilling or vaporizing, be reduced to specified range, transported to by discharging machine 5 specified Sludge drying processing is completed in position.
Embodiment 2
The present embodiment and the primary structure of embodiment one are substantially the same, difference lies in:2 series of roll squeezer is little In 10 natural number, preferably 3 grades, the spacing to rotating drum 25 of the roll squeezer 2 is sequentially reduced;3 grades of the serrated knife granulating machine Number is the natural number no more than 10, and preferably 2 grades, the serrated knife granulating machine 3 is sequentially reduced the spacing for revolving serrated knife 34.It sets in this way The purpose of meter is while ratio of briquetting is ensured, the utilization of the energy is more efficient.
It is understood that above with respect to the specific descriptions of the utility model, it is merely to illustrate the utility model and is not The described technical solution of the utility model embodiment is limited to, it will be understood by those of ordinary skill in the art that, it still can be with It modifies to the utility model or equivalent replacement, to reach identical technique effect;As long as meet using needs, all in this reality Within novel protection domain.

Claims (6)

1. a kind of sludge freezes prilling granulator, it is characterised in that:From top to bottom include roll squeezer (2), serrated knife granulating machine (3) successively With stirring type dryer (4);
Roll squeezer (2) feed inlet setting loading hopper (22), the roll squeezer (2) are described right including to rotating drum (25) The setting of rotating drum (25) discharge port is adjacent to the material scraping plate (26) to rotating drum (25) surface;
Serrated knife granulating machine (3) feed inlet docks the discharge port of the roll squeezer (2), the serrated knife granulating machine (3) including pair Serrated knife (34) is revolved, described pair of rotation serrated knife (34) surface sets groove, serrated knife granulating machine (3) the discharge port setting along direction of rotation It is close to the clear frid (35) to revolving serrated knife (34) surface;
The main shaft of the roll squeezer (2) and serrated knife granulating machine (3) is hollow shaft, the hollow shaft setting approach section and discharge section, The approach section and discharge section are separated by partition or solid core, and the partition or solid core both ends are set into hole and portal respectively;Institute The inside setting cavity of roll squeezer (2) and serrated knife granulating machine (3) is stated, the cavity is connect respectively with entering hole and portalling;
The serrated knife granulating machine (3) and the roll squeezer (2) together, are set by cage connection in serrated knife granulating machine (3) lower part Air inlet (33) is put, the setting exhaust outlet (23) at the top of roll squeezer (2), the exhaust outlet setting exhaust fan (6);
For the stirring type dryer (4) if being divided into dried layer by multiple partition boards, the partition board is divided into the large baffle of outer circle opening The small baffle (49a) of (49b) and inner circle opening, the diaphragm internal set cavity, and the partition board top sets scraper plate, described to scrape The material of partition board is transported to different positions by plate by presetting different angles in same direction of rotation;The stirring-type drying The feed inlet and discharge gate of machine are respectively provided with sealing conveyer.
2. a kind of sludge freezing prilling granulator as described in claim 1, it is characterised in that:The roll squeezer (2) for single-stage or Multistage, the series of the roll squeezer (2) are the natural number no more than 10, the multistage roll squeezer (2) to rotating drum (25) Spacing is sequentially reduced.
3. a kind of sludge freezing prilling granulator as claimed in claim 1 or 2, it is characterised in that:It is described to rotating drum (25) Spacing can adjust.
4. a kind of sludge freezing prilling granulator as described in claim 1, it is characterised in that:The serrated knife granulating machine (3) is single Grade is multistage, and the series of the serrated knife granulating machine (3) is the natural number no more than 10, pair of the multistage serrated knife granulating machine (3) The spacing of rotation serrated knife (34) is sequentially reduced.
5. a kind of sludge freezing prilling granulator as described in claim 1 or 4, it is characterised in that:Described pair of rotation serrated knife (34) Spacing can adjust.
6. a kind of sludge freezing prilling granulator as described in claim 1, it is characterised in that:The quantity of the partition board be no more than 20 positive integer.
CN201721594616.1U 2017-11-25 2017-11-25 A kind of sludge freezes prilling granulator Expired - Fee Related CN207581635U (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107777858A (en) * 2017-11-25 2018-03-09 圣火科技(河南)有限责任公司 A kind of sludge freezing prilling process and device

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107777858A (en) * 2017-11-25 2018-03-09 圣火科技(河南)有限责任公司 A kind of sludge freezing prilling process and device
CN107777858B (en) * 2017-11-25 2023-09-08 圣火科技(河南)有限责任公司 Sludge freezing granulation method and device

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