CN207391302U - A kind of methane/hydrogen coproduction organic fertilizer integration installation for fermenting - Google Patents

A kind of methane/hydrogen coproduction organic fertilizer integration installation for fermenting Download PDF

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Publication number
CN207391302U
CN207391302U CN201721088292.4U CN201721088292U CN207391302U CN 207391302 U CN207391302 U CN 207391302U CN 201721088292 U CN201721088292 U CN 201721088292U CN 207391302 U CN207391302 U CN 207391302U
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fermentation reactor
reactor
methane
fermentation
organic fertilizer
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马力通
赵悦
王亚雄
李珺
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Inner Mongolia University of Science and Technology
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Inner Mongolia University of Science and Technology
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/40Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse

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Abstract

The utility model discloses a kind of methane/hydrogen coproduction organic fertilizer integration installation for fermentings, are arranged at including aerobic fermentation reactor, anaerobic fermentation reactor, flexible screw conveyor and supply air system, anaerobic fermentation reactor inside aerobic fermentation reactor;The device realizes the gas fertilizer integration production of lignite, the low-order coals such as peat, and the heat that microorganism decomposition organic matter in fermentation process discharges is made full use of, and solves the China such as the Inner Mongol, Heilungkiang and trembles with fear the aerogenesis of the low-order coals such as area's microorganism conversion lignite, peat(Biological methane, hydrogen), production organic fertilizer reactor heating and thermal insulation problem, realize in a low temperature of the Inner Mongol long winter season microbial fermentation system of the low-order coals such as lignite, peat inverting biological methane it is artificial maintain, regulation and control and strengthen, have the advantages that simple in structure, solid state fermentation/liquid fermentation be carried out at the same time, the effectively save energy.

Description

A kind of methane/hydrogen coproduction organic fertilizer integration installation for fermenting
Technical field
The utility model belongs to fermentation technical field, and in particular to a kind of methane/hydrogen coproduction organic fertilizer integration fermentation Device, for low-order coal such as lignite, peat fermentation and hydrogen production gas/biological methane and fermentation production high humic acid organic fertilizer.
Background technology
Lignite(Also known as bavin coal, Lignite;Brown coal), it is that degree of coalification is minimum rich in organic matter and humic acid There is coal distribution to concentrate, and bury shallow, the features such as easy exploitation.By taking China as an example:Existing explored lignite resource reserves 130,300,000,000 Ton, accounts for nearly the 13% of national coal resources gross reserves, is mainly distributed on east Inner Mongolia, Yunnan and 3 provinces of Northeast China.Wherein, only Inner Mongol The lignite reserves of ancient east just account for national lignite gross reserves more than 70%, Zhalainuoer coalfield, Ping Zhuanyuan such as east Inner Mongolia Golconda coalfield, huolinhe coalfield, black nit coalfield, Yi Min rivers coalfield, wild goose coalfield, exhale with Nore coalfield and Shengli Coalfield, Lignite reserves are more than 1,000,000,000 tons, suitable for strip mining transformation, so as to significantly reduce the security risk of Lignite Mine and cost.
Lignite moisture is up to 30-50%, and calorific value is low, easy-weathering and spontaneous combustion, combustion power generation are that the main of present lignite utilizes hand Section since lignite usually contains higher moisture, is not easy to long distance transportation, and lignite is mainly used for electric power stations near coal-mines power generation.It is but brown The thermal efficiency is lowly larger to power plant's device loss when the non-upgrading dehydration of coal is directly burnt, and also has seriously polluted the environment, and lignite High water cut causes the transformation dryness dehydration link before burning(Moisture is reduced to less than 10%)Add cost of electricity-generating.If lignite is made For raw material trans-utilization, and it is subject to High water cut, high limitation containing ash.Therefore, the country of petroleum resources abundance, seldom scale exploitation Utilize lignite.So the method for the more clean on-fuel application lignite of development is efficiently to utilize the effective of the low orders coal resources such as lignite Approach.
Microorganism conversion may be the best method of the low-order coals trans-utilization such as lignite, lignite, the peat of High water cut Etc. low-order coals need not be dehydrated or dry, biological methane is converted into the help of microorganism(Also known as biogas, biology are natural Gas, CH4), hydrogen, high humic acid organic fertilizer etc..At present it is known that higher plant coalification is peat, lignite, bituminous coal and nothing The different times of bituminous coal all constantly have coal bed gas(Gas, main CH containing methane4)It generates.Existing research report shows that lignite passes through After microbial degradation, fulvic acid content increases, and humic acid chemism is enhanced, and can improve soil, promotes farming Object is grown, meanwhile, it may additionally facilitate absorption of the plant to nutrients such as nitrogen, phosphorus, potassium, be rare plant growth regulator. The microorganism conversion of lignite is the same as using compared with traditional commercial conversion, having, low energy consumption, conversion condition is mild, transformation efficiency The advantages that high, economic benefit of converted product and application value are high, equipment requirement is simple is to realize that the energy is benign, sustainable development The new way of exhibition.
Microorganism conversion, either hydrogen producing or biological methane, high humic acid organic fertilizer be required for suitable temperature, pH, Suitable carbon-nitrogen ratio, microorganism species.Microbial growth, metabolism, conversion reaction process in, in certain temperature range, Reaction rate during low temperature is low, and reaction rate is high during high temperature, can not outside the colder unfavorable fermentation of northern weather or even winter room Ferment, this be the fermentation of the outdoor progress such as biological methane/hydrogen and organic fertilizer fermentation put into practice industrialization promotion the Inner Mongol, Heilungkiang Deng Han areas urgent problem to be solved.Therefore, bioreactor of the exploitation with efficient heat transfer heat-insulating property is used to keep Fermentation temperature, shortening fermentation period, extension fermenting and producing time limit are just particularly important.
Humic acid plays the role of more, improvement soil physical and chemical property, culture fertility in production.Make punching when humic acid fertilizer to apply Or soil, when applying, it can also improve soil, improve fertilizer efficiency.Because humic acid organic colloid in humic acid fertilizer and the calcium in soil from Son combines to form cotton-shaped gel, and this colloid is good binding material, soil particle cementation can be got up, make water stability in soil Crumb structure increases, so as to improve the water of soil, fertilizer, oxygen, hot situation.Humic acid can provide nutrient for crop simultaneously.It should Fertilizer can absorb the fertilizer point such as ammonium ion, potassium ion, calcium ion, magnesium ion, zinc ion, moreover it is possible to the free iron in acid soil Ion, aluminium ion form iron, aluminium complex, reduce phosphorus fixation, improve utilization rate of fertilizer.And humic acid can promote microorganism Breeding with activity.Humic acid has stimulation to microorganism, improves the mobilities such as fungi, bacterium and nitrogen-fixing bacteria, promotees It is decomposed into organic matter, accelerates farm manure decomposed, promote the release of quick-acting nutrient.Existing solid containing humic acid water-soluble fertilizer Humic acid content is 3.0% or so in product, and humic acid content also has further increase in solid product containing humic acid water-soluble fertilizer Add space, the raising of humic acid content has more important meaning for production activity.
In existing installation for fermenting, all there are certain shortcomings.Patent(200810246603.4)Disclose one The device of kind fiber wastes two-stage fermentation co-producing hydrogen and methane, for producing hydrogen and methane, which needs production hydrogen anti- Answer two reactors of device and methane-producing reactor that could realize co-producing hydrogen and methane, in addition, production hydrogen process accesses thermophilic strain Sub- liquid, temperature control are 55-65 DEG C, and methane phase process access medium temperature methane phase sludge, temperature control is 34-38 DEG C, is not carried And how to realize that the temperature during production hydrogen process and methane phase controls.Patent(200610049907.2)Disclose biomass and The device of solid organic castoff fermentation method co-producing hydrogen and methane, likewise, the device needs hydrolysis and acidification reactor, has Machine acid production hydrogen reactor, the multiple reactors ability co-producing hydrogens of methane-producing reactor and methane, do not refer to how realizing production hydrogen Temperature control during process and methane phase.Patent(201510495698.3)A kind of organic fertilizer fermentation tank is disclosed, including Elevator, agitating device, cylinder transmission device, the elevator include braced frame, elevating hopper, propose out motor, the stirring Device include fermentation tank, roller bearing, agitating paddle, transmission device, the cylinder transmission device include hydraulic cylinder group, brake group, Driven gear, the device solve the problems, such as material lifting in organic fertilizer fermentation, stirring.The device need elevator, agitating device, Cylinder transmission device could realize organic fertilizer fermentation, not refer to that the temperature how provided in fermentation process is kept.In addition more than Patent is provided solely for the production organic fertilizer of device independence or hydrogen producing and methane, is not carried out gas(Hydrogen and methane), fertile coproduction Integration production.
Utility model content
In order to overcome the device for lacking integration production gas fertilizer in existing technology, hydrogen producing or methane phase mistake are not carried out Temperature controlled deficiency in journey, the utility model provide a kind of methane/hydrogen coproduction organic fertilizer integration installation for fermenting, should Device realizes fermentation gas production integrated with fermentation production high humic acid organic fertilizer, the heat generated using Aerobically fermented organic fertilizer Heat source is provided for anaerobic fermentation gas production, keeps fermentation temperature, and the heat that microorganism decomposition organic matter in fermentation process discharges is filled Divide and utilize.
Technical solution is used by the utility model solves its technical problem:
A kind of methane/hydrogen coproduction organic fertilizer integration installation for fermenting, the device include aerobic fermentation reactor, detest Aerobe fermentation reactor, flexible screw conveyor and supply air system;It is anti-that the anaerobic fermentation reactor is arranged at aerobic fermentation It answers inside device;By the way that aerobic fermentation reactor is set to carry out aerobic fermentation to material, by setting anaerobic fermentation reactor to object Material carry out anaerobic fermentation, the device utilize aerobic fermentation reactor fermentation process in microorganism decomposition organic matter discharge heat into Row utilizes, and effectively solves the Inner Mongol, the China such as Heilungkiang tremble with fear the aerogenesis of the low-order coals such as area's microorganism conversion lignite, peat(It is raw Object methane, hydrogen), production organic fertilizer reactor heating and thermal insulation problem, realize lignite, mud in a low temperature of Inner Mongol long winter season The artificial of the microbial fermentation system of the low-order coals inverting biological methane such as charcoal maintains, regulates and controls and strengthens, the effectively save energy.
Temperature detection mouth is provided on the aerobic fermentation reactor side wall, temperature detection mouth may be inserted into temperature detection Device, worker can monitor the temperature of aerobic fermentation reactor by temperature detector in real time, and realizing will be in aerobic fermentation reactor The temperature in portion is controlled within 70 DEG C, is avoided the adverse effect too high or too low for temperature brought, is provided conveniently for aerobic fermentation Yeasting, improve the efficiency of fermentation;The feed inlet of flexible screw conveyor is connected by aerobic fermentation reactor bottom, The discharge port of flexible screw conveyor is connected at the top of aerobic fermentation reactor, by flexible screw conveyor, can be incited somebody to action The material transportation of aerobic fermentation reactor bottom is realized to aerobic fermentation reactor head by aerobic fermentation reactor lower floor material It is transported to material upper strata and carries out turning, ensure that material is sufficiently uniformly mixed and is come into full contact with oxygen and mix, improve aerobic hair The efficiency of ferment reduces the time of aerobic fermentation;The supply air system includes air blower, the air outlet connection air-supply of air blower Pipe, ajutage are connected to inside aerobic fermentation reactor, and aeration is provided on the ajutage inside aerobic fermentation reactor Mouthful, air blast is carried out to aerobic fermentation reactor inside by air blower, realizes material and air inside aerobic fermentation reactor In oxygen sufficiently contact, further improve the fermentation efficiency of aerobic fermentation.
The anaerobic fermentation reactor top is provided with feed inlet and outlet, stirring motor and discharge duct, and anaerobic fermentation is anti- It answers and is connected with agitating vane on stirring motor output shaft inside device, material is added or removed by feed inlet and outlet;By stirring Mixing motor drives agitating vane realization be sufficiently mixed uniformly to the material inside anaerobic fermentation reactor, improves hair The efficiency of ferment;The gas generated inside anaerobic fermentation reactor is discharged by discharge duct.
Preferably, be provided at the top of the aerobic fermentation reactor can Semi-folding sealing cover, sealing cover can be to avoid Influence of the external environment to aerobic fermentation reactor materials inside during the fermentation, if extraneous environment is suitable or reality needs Will, worker can select to open sealing cover.Meanwhile aerobic fermentation reactor surrounding is prepared by thermal insulation material, is ensured aerobic Heat inside fermentation reactor does not scatter and disappear.
Preferably, the anaerobic fermentation reactor is arranged at the central part inside aerobic reactor, ensures as far as possible The heat of release can sufficiently act on the material inside anaerobic fermentation reactor inside aerobic fermentation reactor.
Preferably, the circular anaerobic fermentation reactor side wall setting of the ajutage, further increase material and air Touch opportunity improves the efficiency of aerobic fermentation.
Preferably, the ajutage is vertically arranged on anaerobic fermentation reactor side wall, further increases material and sky The touch opportunity of gas improves the efficiency of aerobic fermentation.
The utility model has the advantages that:
(1)The utility model realizes gas fertilizer integration production, by biological methane/hydrogen and organic fertilizer coproduction, by lignite, The low-order coals such as peat are converted into the green energy resources such as biological methane, hydrogen, and undegradable fermentation residue prepares high humic acid organic fertilizer The products such as material, make the diversification of the low-order coals resource product such as lignite, peat, high-valued conversion, with simple in structure, solid state fermentation/ The advantages of liquid fermentation is carried out at the same time;
(2)The utility model makes full use of the heat that microorganism decomposition organic matter in fermentation process discharges, organic fertilizer hair The heat that ferment generates provides heat for gassy fermentation and keeps temperature, and the solution Inner Mongol, the China such as Heilungkiang are trembled with fear area's microorganism conversion The aerogenesis of the low-order coals such as lignite, peat(Biological methane, hydrogen), production organic fertilizer reactor heating and thermal insulation problem, including realization In a low temperature of Mongolia's very long winter the microbial fermentation system of low-order coals inverting biological methane such as lignite, peat it is artificial maintain, Regulation and control and reinforcing, the effectively save energy.
Description of the drawings
Fig. 1 is the structure diagram of the utility model.
Specific embodiment
The utility model is further described below in conjunction with attached drawing:
As shown in Figure 1, for a kind of methane described in the utility model/hydrogen coproduction organic fertilizer integration installation for fermenting, institute The device stated includes aerobic fermentation reactor 10, anaerobic fermentation reactor 11, flexible screw conveyor 12 and supply air system;Institute The anaerobic fermentation reactor 11 stated is arranged inside aerobic fermentation reactor 10;By setting aerobic fermentation reactor 10 to material Aerobic fermentation is carried out, anaerobic fermentation carries out material by anaerobic fermentation reactor 11, which utilizes aerobic fermentation reactor The heat that microorganism decomposition organic matter discharges in 10 fermentation process is utilized, and effectively solves the China such as the Inner Mongol, Heilungkiang The aerogenesis of the low-order coals such as cold area's microorganism conversion lignite, peat(Biological methane, hydrogen), production organic fertilizer reactor heating and thermal insulation Problem realizes the microbial fermentation system of the low-order coals such as lignite, peat inverting biological methane in a low temperature of Inner Mongol long winter season The artificial of system maintains, regulates and controls and strengthens, the effectively save energy.
This patent in order to realize that the material inside aerobic fermentation reactor 10 is sufficiently contacted with the oxygen in outside air, Facilitate worker control aerobic fermentation reactor 10 inside temperature, while realization to the material inside aerobic fermentation reactor 10 into Row turning realizes that material comes into full contact with the oxygen in air, improves the efficiency of aerobic fermentation, the aerobic fermentation reactor Temperature detection mouth 20 is provided on 10 side walls, 10 bottom of aerobic fermentation reactor connects the charging of flexible screw conveyor 12 Mouthful, the discharge port of flexible screw conveyor 12 is connected to 10 top of aerobic fermentation reactor;The supply air system includes drum Wind turbine 13, the air outlet connection ajutage 14 of air blower 13, ajutage 14 is connected to inside aerobic fermentation reactor 10, positioned at well Aeration opening is provided on ajutage 14 inside aerobe fermentation reactor 10.
This patent excludes anaerobism in time in order to realize that the material inside anaerobic fermentation reactor 11 is sufficiently uniformly mixed The gas that 11 inside of fermentation reactor generates, 11 top of anaerobic fermentation reactor are provided with feed inlet and outlet 15, stirring electricity Machine 16 and discharge duct 17,11 inside of anaerobic fermentation reactor connects is connected with agitating vane on 16 output shaft of stirring motor 18。
This patent is in order to avoid influence of the external environment to 10 materials inside of aerobic fermentation reactor, the aerobic fermentation The top of reactor 10 be provided with can Semi-folding sealing cover 19,10 side wall of aerobic fermentation reactor is prepared by thermal insulation material.
This patent is in order to further improve object of the material inside aerobic fermentation reactor 10 to anaerobic fermentation reactor 11 Material is sufficiently utilized, and the anaerobic fermentation reactor 11 is arranged at the central part inside aerobic reactor 10.
This patent sufficiently contacts in order to further ensure the material inside anaerobic fermentation reactor 11 with extraneous air, The ajutage is set around 11 side wall of anaerobic fermentation reactor.
Fermentation process one is embodied
(1)Grain size is added in aerobic fermentation reactor for 5cm and by air-dried cow dung, 10% low-order coal, corn stalk Stalk and the machine fertilizer fermenting agent for having 1 ‰, are uniformly mixed, and it is 30 to adjust C/N:1, control the temperature of aerobic fermentation material not Higher than 70 DEG C and moisture 45%;
(2)It is micro- that 50 mesh and air-dried cow dung, 1% low-order coal, urea, 50% anaerobism are added in anaerobic fermentation reactor Biology, input concentration control solid content(Ts)Content is uniformly mixed 6% or so, and it is 28 to adjust C/N:1;
(3)Air blower every 1d air blast 3 times, each air blast 8min since the 4d that ferments, until fermentation ends, helical feed Aerobic fermentation reactor lower floor material is transported to material upper strata and carries out turning once by machine 3d, until the organic carbon conversion of fermentation raw material Rate reaches 70%, fulvo acid content 7.34% in organic fertilizer;The biological methane generated in anaerobic fermentation reactor is from exhaust Pipeline is discharged.
Fermentation process two is embodied
(1)Grain size is added in aerobic fermentation reactor for 1cm and by air-dried cow dung, 5% low-order coal, corn stalk Stalk and the machine fertilizer fermenting agent for having 0.5 ‰, are uniformly mixed, and it is 30 to adjust C/N:1, control the temperature of aerobic fermentation material Not higher than 50 DEG C and moisture 40%;
(2)30 mesh are added in anaerobic fermentation reactor and air-dried cow dung, 0.8% low-order coal, urea, 45% are by 60 DEG C heat 30min anaerobic activated sludge, input concentration control solid content(Ts)Content is stirred 6% or so Even, it is 28 to adjust C/N:1;
(3)Air blower every 1d air blast 2 times, each air blast 5min since the 4d that ferments, until fermentation ends, helical feed Aerobic fermentation reactor lower floor material is transported to material upper strata and carries out turning once by machine 2d, until the organic carbon conversion of fermentation raw material Rate reaches 60%, fulvo acid content 7.70% in organic fertilizer, at this time the content of organic matter 50.96% in organic fertilizer;Anaerobic fermentation The biological hydrogen generated in reactor is discharged from discharge duct.
Finally it should be noted that:Obviously, above-described embodiment is only intended to clearly illustrate the utility model example, And it is not intended to limit the embodiments.For those of ordinary skill in the art, may be used also on the basis of the above description To make other variations or changes in different ways.There is no necessity and possibility to exhaust all the enbodiments.And thus Among changes and variations that derived from are still in the scope of protection of the utility model.

Claims (5)

1. a kind of methane/hydrogen coproduction organic fertilizer integration installation for fermenting, which is characterized in that the device includes aerobic fermentation Reactor, anaerobic fermentation reactor, flexible screw conveyor and supply air system;The anaerobic fermentation reactor is arranged at Aerobe fermentation inside reactor;
Temperature detection mouth is provided on the aerobic fermentation reactor side wall, aerobic fermentation reactor bottom connects flexible spiral shell The feed inlet of conveyer is revolved, the discharge port of flexible screw conveyor is connected at the top of aerobic fermentation reactor;The air-supply System includes air blower, and the air outlet connection ajutage of air blower, ajutage is connected to inside aerobic fermentation reactor, positioned at well Aeration opening is provided on the ajutage of aerobe fermentation inside reactor;
The anaerobic fermentation reactor top is provided with feed inlet and outlet, stirring motor and discharge duct, anaerobic fermentation reactor Agitating vane is connected on internal stirring motor output shaft.
2. a kind of methane/hydrogen coproduction organic fertilizer integration installation for fermenting as described in claim 1, which is characterized in that described Aerobic fermentation reactor at the top of be provided with can Semi-folding sealing cover, aerobic fermentation reactor surrounding by thermal insulation material prepare and Into.
3. a kind of methane/hydrogen coproduction organic fertilizer integration installation for fermenting as described in claim 1, which is characterized in that described Anaerobic fermentation reactor be arranged at central part inside aerobic reactor.
4. a kind of methane/hydrogen coproduction organic fertilizer integration installation for fermenting as described in claim 1, which is characterized in that described Ajutage set around anaerobic fermentation reactor side wall.
5. a kind of methane/hydrogen coproduction organic fertilizer integration installation for fermenting as described in claim 1, which is characterized in that described Ajutage be vertically arranged on anaerobic fermentation reactor side wall.
CN201721088292.4U 2017-08-29 2017-08-29 A kind of methane/hydrogen coproduction organic fertilizer integration installation for fermenting Active CN207391302U (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107353069A (en) * 2017-08-29 2017-11-17 内蒙古科技大学 A kind of methane/hydrogen coproduction organic fertilizer integration installation for fermenting and fermentation process
CN114378105A (en) * 2022-01-19 2022-04-22 重庆大学 Kitchen waste and cellulose biomass synergistic multi-stage treatment system and method

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107353069A (en) * 2017-08-29 2017-11-17 内蒙古科技大学 A kind of methane/hydrogen coproduction organic fertilizer integration installation for fermenting and fermentation process
CN114378105A (en) * 2022-01-19 2022-04-22 重庆大学 Kitchen waste and cellulose biomass synergistic multi-stage treatment system and method
CN114378105B (en) * 2022-01-19 2024-04-12 重庆大学 Multistage treatment system and method for kitchen waste and cellulosic biomass in cooperation

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