CN206570410U - A kind of recovery and processing system of acidic etching waste liquid - Google Patents

A kind of recovery and processing system of acidic etching waste liquid Download PDF

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Publication number
CN206570410U
CN206570410U CN201720014515.6U CN201720014515U CN206570410U CN 206570410 U CN206570410 U CN 206570410U CN 201720014515 U CN201720014515 U CN 201720014515U CN 206570410 U CN206570410 U CN 206570410U
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CN
China
Prior art keywords
chlorine
waste liquid
acidic etching
etching waste
recovery
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Expired - Fee Related
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CN201720014515.6U
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Chinese (zh)
Inventor
吴超
查长虹
林得发
罗东军
王懿
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SHENZHEN XINRUISI ENVIRONMENTAL PROTECTION TECHNOLOGY Co Ltd
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SHENZHEN XINRUISI ENVIRONMENTAL PROTECTION TECHNOLOGY Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

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Abstract

The utility model discloses a kind of recovery and processing system of acidic etching waste liquid, by carrying out film electrolytic regeneration PROCESS FOR TREATMENT to acidic etching waste liquid, the chlorine that acidic etching waste liquid is produced in film electrolytic regeneration technique again absorbs through chlorine absorption unit and is directed into dense heat alkali liquid, reaction generation mixed solution, the mixed solution of generation needs the oxidant of addition to use in being produced as former etching solution, realize that pollutant is converted into resource reclaim recycling, it is more environmentally-friendly, and with good economic benefit.

Description

A kind of recovery and processing system of acidic etching waste liquid
Technical field
The utility model is related to the processing regeneration field of acidic etching waste liquid, and more particularly to one kind can be efficient by chlorine The recovery and processing system of the acidic etching waste liquid absorbed.
Background technology
In the electronics industry, the manufacture of printed circuit board not only consumes substantial amounts of water and energy, and produce to environment and The harmful chemical substance of human health, and acidic etching waste liquid is to etch that a kind of copper content produced during copper foil is higher, acid The larger industrial wastewater of degree.The main component of acidic etching waste liquid is copper chloride, hydrogen chloride, sodium chloride etc., severe contamination environment, The existence of microorganism in water is influenceed, soil granular structure, influence crops existence is destroyed.Scientific research personnel be directed to always through Ji, the exploitation and popularization of efficient acidic etching waste liquid recovery and utilization technology.
Existing acidic etching liquid recycling utilization technique is mainly membrane electrolysis, and this method is to be based on electrochemical principle, Copper chlorine complex ion i.e. in acidic etching waste liquid obtains electron reduction for copper in negative electrode, and anode produces chlorine as oxidizing The cuprous ion produced in etching production.But because of etching work procedure production requirement limitation, solution Central Asia content of copper ion is few, in the presence of Between it is short, cause that the chlorine utilization produced is low, the follow-up more chlorine without utilizing enters exhaust treatment system, need to consume a large amount of Piece alkali or reducing agent processing, material waste are serious, and operation cost is high, project commercial application is there is limitation.
Utility model content
Main purpose of the present utility model is to provide a kind of recovery and processing system of acidic etching waste liquid, can be by acid etching The chlorine produced in the film electrolytic regeneration technique of waste liquid carries out efficient absorption recycling, realizes that pollutant is converted into resource reclaim.
The utility model proposes a kind of recovery and processing system of acidic etching waste liquid, including for collecting etching production line Waste collection groove, the membrane electrolysis cells for being electrolysed to acidic etching waste liquid of acidic etching waste liquid, the waste collection groove Connected between the membrane electrolysis cells by woven hose, and it is defeated by the acidic etching waste liquid in the waste collection groove to install water pump Enter in the membrane electrolysis cells;Electrolytic cell is divided into cathode chamber and anode chamber by the membrane electrolysis cells by film, and the membrane electrolysis cells are by acid Property etching waste liquor electrolysis precipitating metal copper and chlorine, obtain acid etching regenerated liquid;
The recovery and processing system also includes being used to store the accumulator tank of acid etching regenerated liquid, the chlorine for absorbing chlorine Aspiration receiving apparatus, the alkaline reaction groove for storing the alkali lye that concentration is 0.5~50% and the oxygen connected with the alkaline reaction groove Agent collecting vessel, is provided with the heater for being heated to alkali lye on the alkaline reaction groove, protects the alkali lye Hold at 30~80 degrees Celsius, the chlorine of precipitation is absorbed and is directed into the alkaline reaction groove by the chlorine absorption unit In alkali lye, the mixed solution that chlorine needs the oxidant of addition to use in being produced with alkaline reaction generation as former etching solution, The mixed solution formed after the completion of reaction is inputted in the oxidant collection bucket.
Preferably, in addition to the chlorine sensor above the membrane electrolysis cells and for controlling the chlorine absorption The control module of device, the control module is electrically connected with the chlorine sensor, the chlorine absorption unit, in the chlorine When gas sensor detects chlorine, the control module controls the chlorine absorption unit to open.
Preferably, the chlorine absorption unit absorbs or spray-absorption device for injection.
Preferably, in addition to the membrane electrolysis cells circulating slot connected, the cathode chamber and anode chamber are respectively by defeated The circulation of liquid pipe and the circulating slot is connected, and is respectively mounted water pump and is made acidic etching waste liquid in the anode chamber and the circulating slot Between and the cathode chamber and the circulating slot between circulate.
Preferably, the alkali lye is sodium hydroxide or potassium hydroxide solution, and the sodium hydroxide solution is given birth to chlorine reaction Into the mixed solution of sodium chlorate, sodium hypochlorite and sodium chloride;It is the potassium hydroxide solution and chlorine reaction generation potassium chlorate, secondary The mixed solution of potassium chlorate and potassium chloride.
The beneficial effects of the utility model are:
The utility model carries out film electrolytic regeneration PROCESS FOR TREATMENT to acidic etching waste liquid, and acidic etching waste liquid is electrolysed in film The chlorine produced in regeneration technology absorbs and is directed into dense heat alkali liquid through chlorine absorption unit, reaction generation mixed solution, raw Into mixed solution can be produced as former etching solution in need the oxidant of addition to use, realize that pollutant is converted into resource reclaim Recycle, it is more environmentally-friendly, and with good economic benefit.
Brief description of the drawings
Fig. 1 is the structured flowchart of the recovery and processing system of acidic etching waste liquid of the present utility model.
Realization, functional characteristics and the advantage of the utility model purpose will be described further referring to the drawings in conjunction with the embodiments.
Embodiment
It should be appreciated that specific embodiment described herein is not used to limit this only to explain the utility model Utility model.
Reference picture 1, proposes a kind of embodiment of the recovery and processing system of acidic etching waste liquid of the present utility model:
A kind of recovery and processing system of acidic etching waste liquid, including for collecting the acidic etching waste liquid of etching production line Waste collection groove, for the membrane electrolysis cells being electrolysed to acidic etching waste liquid, the circulating slot connected with membrane electrolysis cells.Waste liquid is received Connected between collection groove and membrane electrolysis cells by woven hose, and electric pump is installed and the acidic etching waste liquid in waste collection groove is inputted into film In electrolytic cell.Electrolytic cell is divided into cathode chamber and anode chamber by membrane electrolysis cells by film, and cathode chamber and anode chamber pass through woven hose respectively Connected with circulating slot circulation, and be respectively mounted that electric pump makes acidic etching waste liquid between anode chamber and circulating slot and cathode chamber is with following Circulated between annular groove.Acidic etching waste liquid is electrolysed precipitating metal copper and chlorine by membrane electrolysis cells, obtains acid etching regeneration Liquid.Chemical equation is as follows:
Anolyte reaction chamber:
2(CuCl3)2-+2Cl-→2(CuCl4)2-+2e
2Cl-→Cl2↑+2e
Cathode chamber reacts:
(CuCl4)2-+Cu+2Cl-→2(CuCl3)2-
2(CuCl3)2-→2(CuCl2)-+2Cl-
2(CuCl2)-+2e→2Cu↓+4Cl-
2H++2e→H2
Recovery and processing system is also including being used to store the accumulator tank of acid etching regenerated liquid, being inhaled for absorbing the chlorine of chlorine Receiving apparatus, the alkaline reaction groove for storing the alkali lye that concentration is 0.5~50% and the oxidant collection connected with alkaline reaction groove Bucket.The acid etching regenerated liquid isolated is collected into accumulator tank.
Recovery and processing system is also including the chlorine sensor above membrane electrolysis cells and for controlling chlorine absorption to fill The control module put.Control module is electrically connected with chlorine sensor, chlorine absorption unit, and anode is detected in chlorine sensor When there is chlorine precipitation room, control module control chlorine absorption unit starts to start, and absorbs chlorine.
Heater for being heated to alkali lye is installed on alkaline reaction groove, alkali lye is maintained at 30~80 and takes the photograph Family name's degree.Heater is steam heater or electric heater unit.
The chlorine of precipitation is absorbed and is directed into the alkali lye of alkaline reaction groove by chlorine absorption unit.Alkali lye is concentration For 0.5~50%, temperature is 30~80 degrees Celsius of sodium hydroxide or potassium hydroxide solution:Using sodium hydroxide solution, hydrogen-oxygen Change the mixed solution that sodium solution generates sodium chlorate, sodium hypochlorite and sodium chloride with chlorine reaction;Using potassium hydroxide solution, hydrogen Potassium oxide solution generates the mixed solution of potassium chlorate, postassium hypochlorite and potassium chloride with chlorine reaction.
Sodium hydroxide solution and chlorine reaction equation:
2NaOH+CI2=NaCI+NaCIO+H2O
6NaOH+3CI2=5NaCI+NaCIO3+3H2O
The mixed solution that chlorine is generated with alkaline reaction needs the oxidant of addition to use in being produced as former etching solution, In the mixed solution input oxidant collection bucket formed after the completion of reaction.
Wherein, chlorine absorption unit absorbs or spray-absorption device for injection.Chlorine absorption unit can be single-stage or many Level series connection.
The application method of this recovery and processing system comprises the following steps:
1) acidic etching waste liquid for etching production line is collected into waste collection groove, will be pending in waste collection groove Acidic etching waste liquid add membrane electrolysis cells in;Electrolytic cell is divided into cathode chamber and anode chamber, membrane electrolysis cells by membrane electrolysis cells by film Cathode chamber and anode chamber connected respectively with same circulating slot, by electric pump by acidic etching waste liquid membrane electrolysis cells cathode chamber Circulated between anode chamber and circulating slot;Acidic etching waste liquid in the cathode chamber of membrane electrolysis cells and anode chamber be electrolysed instead Should, metallic copper is generated in cathode chamber, chlorine is generated in anode chamber.
2) it is 0.5~50% to absorb and be directed into concentration the chlorine that generation is electrolysed in step 1 by chlorine absorption unit, Temperature is in 30~80 degrees Celsius of sodium hydroxide solution, sodium hydroxide solution generates sodium chlorate, sodium hypochlorite with chlorine reaction And the mixed solution of sodium chloride.
3) mixed solution generated in step 2 is collected in oxidant collection bucket, needs to add in producing as former etching solution Plus oxidant use.
4) after the completion of acidic etching waste liquid is electrolysed in membrane electrolysis cells, acid etching regenerated liquid is obtained, by acid etching again Raw liquid is separated with the metallic copper of generation, and metallic copper is collected into copper collecting tank, and acid etching regenerated liquid is collected into accumulator tank.
The utility model carries out film electrolytic regeneration PROCESS FOR TREATMENT to acidic etching waste liquid, and acidic etching waste liquid is electrolysed in film The chlorine produced in regeneration technology absorbs and is directed into dense heat alkali liquid through chlorine absorption unit, reaction generation mixed solution, raw Into mixed solution can be produced as former etching solution in need the oxidant of addition to use, realize that pollutant is converted into resource reclaim Recycle, it is more environmentally-friendly, and with good economic benefit.
Preferred embodiment of the present utility model is these are only, the scope of the claims of the present utility model is not thereby limited, it is every The equivalent structure transformation made using the utility model specification and accompanying drawing content, or directly or indirectly it is used in other correlations Technical field, is similarly included in scope of patent protection of the present utility model.

Claims (5)

1. a kind of recovery and processing system of acidic etching waste liquid, it is characterised in that including the acidity for collecting etching production line Waste collection groove, the membrane electrolysis cells for being electrolysed to acidic etching waste liquid of etching waste liquor, the waste collection groove and institute State and connected by woven hose between membrane electrolysis cells, and water pump is installed and the acidic etching waste liquid in the waste collection groove is inputted into institute State in membrane electrolysis cells;Electrolytic cell is divided into cathode chamber and anode chamber by the membrane electrolysis cells by film, and the membrane electrolysis cells lose acidity Waste liquid electrolysis precipitating metal copper and chlorine are carved, acid etching regenerated liquid is obtained;
The recovery and processing system is also including being used to store the accumulator tank of acid etching regenerated liquid, being inhaled for absorbing the chlorine of chlorine Receiving apparatus, the alkaline reaction groove for storing the alkali lye that concentration is 0.5~50% and the oxidant connected with the alkaline reaction groove Collecting vessel, the heater for being heated to alkali lye is provided with the alkaline reaction groove, the alkali lye is maintained at 30~80 degrees Celsius, the chlorine of precipitation is absorbed and is directed into the alkali lye of the alkaline reaction groove by the chlorine absorption unit In, chlorine is generated with alkaline reaction can be as the mixed solution for needing the oxidant of addition to use in the production of former etching solution, reaction After the completion of the mixed solution that is formed input in the oxidant collection bucket.
2. the recovery and processing system of acidic etching waste liquid according to claim 1, it is characterised in that also including installed in institute State the chlorine sensor above membrane electrolysis cells and the control module for controlling the chlorine absorption unit, the control module with The chlorine sensor, chlorine absorption unit electrical connection, when the chlorine sensor detects chlorine, the control Module controls the chlorine absorption unit to open.
3. the recovery and processing system of acidic etching waste liquid according to claim 1 or 2, it is characterised in that the chlorine is inhaled Receiving apparatus absorbs or spray-absorption device for injection.
4. the recovery and processing system of acidic etching waste liquid according to claim 1, it is characterised in that also including with the film The circulating slot of electrolytic cell connection, the cathode chamber and anode chamber are connected by woven hose with circulating slot circulation respectively, and point Not An Zhuan water pump make acidic etching waste liquid between the anode chamber and the circulating slot and the cathode chamber and the circulating slot Between circulate.
5. the recovery and processing system of acidic etching waste liquid according to claim 1, it is characterised in that the alkali lye is hydrogen-oxygen Change sodium or potassium hydroxide solution, the sodium hydroxide solution generates sodium chlorate, sodium hypochlorite and sodium chloride with chlorine reaction Mixed solution;The potassium hydroxide solution generates the mixed solution of potassium chlorate, postassium hypochlorite and potassium chloride with chlorine reaction.
CN201720014515.6U 2017-01-06 2017-01-06 A kind of recovery and processing system of acidic etching waste liquid Expired - Fee Related CN206570410U (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106498401A (en) * 2017-01-06 2017-03-15 深圳市新锐思环保科技有限公司 A kind of recoverying and utilizing method of acidic etching waste liquid and recovery and processing system
CN107630220A (en) * 2017-10-27 2018-01-26 深圳市洁驰科技有限公司 Acidic etching liquid regeneration treatment system
CN108425116A (en) * 2018-02-01 2018-08-21 深圳中科欧泰华环保科技有限公司 The processing method and equipment of three-level cyclic absorption are used in acid etching production line
CN109161895A (en) * 2018-08-27 2019-01-08 安徽绿洲危险废物综合利用有限公司 Acid copper chloride etching liquid copper reclaiming system and reclaiming method
CN109292738A (en) * 2018-10-26 2019-02-01 惠州市臻鼎环保科技有限公司 Using the technique and system of acidic etching waste liquid production industrial bleaching water

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106498401A (en) * 2017-01-06 2017-03-15 深圳市新锐思环保科技有限公司 A kind of recoverying and utilizing method of acidic etching waste liquid and recovery and processing system
CN107630220A (en) * 2017-10-27 2018-01-26 深圳市洁驰科技有限公司 Acidic etching liquid regeneration treatment system
CN107630220B (en) * 2017-10-27 2019-09-20 深圳市洁驰科技有限公司 Acidic etching liquid regeneration treatment system
CN108425116A (en) * 2018-02-01 2018-08-21 深圳中科欧泰华环保科技有限公司 The processing method and equipment of three-level cyclic absorption are used in acid etching production line
CN109161895A (en) * 2018-08-27 2019-01-08 安徽绿洲危险废物综合利用有限公司 Acid copper chloride etching liquid copper reclaiming system and reclaiming method
CN109292738A (en) * 2018-10-26 2019-02-01 惠州市臻鼎环保科技有限公司 Using the technique and system of acidic etching waste liquid production industrial bleaching water
CN109292738B (en) * 2018-10-26 2021-10-26 惠州市臻鼎环保科技有限公司 Process and system for preparing industrial bleaching water by using acidic etching waste liquid

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Address after: 518000 4th floor, building B, Hangcheng Industrial Zone, chentian, Taoyuan community, Xixiang street, Bao'an District, Shenzhen City, Guangdong Province

Patentee after: SHENZHEN XINRUISI ENVIRONMENTAL PROTECTION TECHNOLOGY Co.,Ltd.

Address before: 518000 rooms 530-531, building 1, Taoyuanju complex building, Xixiang street, Bao'an District, Shenzhen City, Guangdong Province

Patentee before: SHENZHEN XINRUISI ENVIRONMENTAL PROTECTION TECHNOLOGY Co.,Ltd.

CF01 Termination of patent right due to non-payment of annual fee
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Granted publication date: 20171020