CN206033579U - Nano -ceramics doubling cavity glass - Google Patents

Nano -ceramics doubling cavity glass Download PDF

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Publication number
CN206033579U
CN206033579U CN201620903210.6U CN201620903210U CN206033579U CN 206033579 U CN206033579 U CN 206033579U CN 201620903210 U CN201620903210 U CN 201620903210U CN 206033579 U CN206033579 U CN 206033579U
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layer
cavity
hollow glass
glass layer
nano
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崔明培
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FOSHAN CITY JUSHITAI POWDER METALLURGY Co Ltd
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FOSHAN CITY JUSHITAI POWDER METALLURGY Co Ltd
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Abstract

The utility model discloses a nano -ceramics doubling cavity glass, including first doubling cavity glass layer, second cavity glass layer and cavity space stop bar. First doubling cavity glass layer is passed through the thermal -insulated hot melt adhesive bonding of nano -ceramics by a glass basic unit and the 2nd glass basic unit to be in the same place, and wherein there is the super -hydrophobic thin oily nanometer protecting film of one deck in the outside of a glass basic unit. First doubling cavity glass layer and second cavity glass layer are passed through the butyl rubber and are bondd with the cavity space stop bar and be in the same place, the cavity space stop bar outside, be provided with between first doubling cavity glass layer and the second cavity glass layer sealed gluey, first doubling cavity glass layer, well cavity of second cavity glass layer and the formation of cavity space stop bar, the cavity intracavity is filled with inert gas. The utility model discloses have the function of safe, energy -conserving, syllable -dividing, grease proofing dirt and automatically cleaning, compare traditional low simultaneously E cavity glass avoids the insulating layer oxidation to cause heat -proof quality inefficacy problem completely, and life is longer.

Description

A kind of nano ceramics laminated hollow glass
Technical field
This utility model is related to a kind of novel glass structure field, is specifically a kind of nano ceramics laminated hollow glass.
Background technology
Application of the glass in building industry is more and more extensive in recent years, meanwhile, it is high that China increases construction area every year newly Up to hundred million square metres of 18-20, it is construction market maximum in the world.At present, to have accounted for national energy resource consumption total for building energy consumption The 27.5% of amount, and wherein up to more than 50% is scattered and disappeared by door glass.It is into 21 century, increasingly withered with the energy Exhaust and environment deterioration, requirement more and more higher of the national governments to energy-saving and emission-reduction, the more energy-conserving and environment-protective of people's urgent needss Green product.
At present, with the fast development of China house property ground industry, double glazing as a kind of energy-saving building material in glass curtain wall and It is widely used in glass door and window, but due to product structure member factor itself and the international impact required with regard to basic structure, Cause traditional aluminum groove hollow glass seal durability can be permanent, internal noble gases are easily revealed, especially so that Low-E Inside double glazing, coating is easily aoxidized, and causes product heat-proof quality to reduce, and service life is reduced.At the same time, ordinary hollow The blast of self-destruction phenomenon, particularly 2015 year Binhai New Area in Tianjin warehouse also easily occurs in glass causes glass rain to be hurted sb.'s feelings thing, allows Built-up city becomes crisis-ridden quickly, is considered the skyscraper of Metroplises symbol, becomes citizen's bad dream Root.
105041138 A of Chinese patent CN provide a kind of heat-insulating double glazing, are realized more using Low emissivity film layer Low infrared heat transmittance, but be difficult to ensure that in product service life, meanwhile, the patent is provided with one layer in outer layer glass outer surface Dichloride in anatase type oxidation titanium film, realizes automatically cleaning using photocatalysis with super hydrophilic.203888303 U of Chinese patent CN disclose one Energy-conservation double glazing is planted, the patent can strengthen the sound insulation of double glazing, effect of heat insulation using common PVB intermediate coats, but remain unchanged Or using low-radiation film reinforcing glass radioprotective effect, the patent from glass outer layer arrange ceramic glaze layer be not only able to The wearability of reinforcing glass, also reduce glass and cleaning strength, but the patent does not indicate the main component of ceramic glaze layer And its automatically cleaning reason.
Therefore, for the shortcoming of above-mentioned prior art, this utility model provides a kind of nano ceramics laminated hollow glass, adopts Absorb realization with the spectral selection in the heat-insulated intermediate layer of nano ceramics to shield visible ray high transmission, near-infrared and ultraviolet height, together When also possess suitable mechanical strength to meet the requirement of safety.At the same time, apply on doubling glass on the outside of double glazing One layer of super-hydrophobic oleophobic nano protecting coating is covered, makes glass that there is the performances such as excellent wear-resisting, oil-stain-preventing and automatically cleaning.
Utility model content
This utility model provides a kind of nano ceramics laminated hollow glass, and heat-proof quality is good, compares traditional Low-E hollow Glass, product shelf life are long, can meet safety, energy-conservation, sound insulation, oil-stain-preventing and automatically cleaning simultaneously.
The utility model discloses a kind of nano ceramics laminated hollow glass, including the first laminated hollow glass layer, second Double glazing layer and empty space bar;The first laminated hollow glass layer is led to by the first glass-base and the second glass-base Cross nano ceramics melt viscosity to be combined, on the outside of wherein the first glass-base, have one layer of super-hydrophobic oleophobic nano protecting film; The first laminated hollow glass layer and the second double glazing layer are bonded together with empty space bar by butyl rubber;In described On the outside of the parting bead of space, between the first laminated hollow glass layer and the second double glazing layer, fluid sealant is provided with;First doubling Double glazing layer, the second double glazing layer and empty space bar form a middle cavity, and hollow intracavity is filled with noble gases.
Further, the nano ceramics PUR includes an EVA or PVB or TPU or SGP intermediate layers.
Further, the thickness in the intermediate layer of the nano ceramics PUR is 0.38-1.52mm.
Further, the super-hydrophobic oleophobic nano protecting film is nano silicon ceramic resin, and thickness is 1-3 μm.
Further, the noble gases are dry argon gas or helium.
Further, the first laminated hollow glass layer and the second double glazing thickness degree are all 6-15mm.
By above-mentioned technical proposal, this using new beneficial effect is:Using nano ceramic material spectral selection reality Existing visible ray high transmission, infrared ray and the high shielding of ultraviolet, it is transparent with heat-insulated simultaneous purpose so as to reach.Directly select The heat-insulated PUR of nano ceramics aids in super-hydrophobic oleophobic nano protecting film as doubling layer so as to safety, energy-conservation, sound insulation, Oil-stain-preventing and self-cleaning function, avoid thermal insulation layer oxidation from causing heat-proof quality while comparing traditional Low-E double glazings completely Problem of Failure, service life are longer.
Description of the drawings
Concrete structure of the present utility model is described in detail in detail below in conjunction with the accompanying drawings
Fig. 1 is a kind of structural representation of nano ceramics laminated hollow glass of this utility model, is received including super-hydrophobic oleophobic Rice protecting film 1, the first glass-base 2, nano ceramics PUR 3, the second glass-base 4, empty space article 5, middle cavity 6, the Two double glazing layers 7, fluid sealant 8, butyl rubber 9.
Specific embodiment
Below in conjunction with the accompanying drawing in this utility model embodiment, the technical scheme in this utility model embodiment is carried out Clear, complete description, so that advantages and features of the present utility model can be easier to be readily appreciated by one skilled in the art, but is retouched The embodiment stated only is the part in this utility model embodiment.
With reference to Fig. 1, this utility model provides a kind of nano ceramics laminated hollow glass, including the first laminated hollow glass Layer, the second double glazing layer 7 and empty space bar 5.First laminated hollow glass layer is by the first glass-base 2 and the second glass Basic unit 4 is bonded together by nano ceramics PUR 3, and the outside of wherein the first glass-base 2 has one layer of super-hydrophobic oleophobic to receive Rice protecting film 1.First laminated hollow glass layer and the second double glazing layer 7 are bonded in one by butyl rubber 9 and empty space bar 5 Rise.On the outside of empty space bar 5, between the first laminated hollow glass layer and the second double glazing layer 7, fluid sealant 8 is provided with.First Laminated hollow glass layer, the second double glazing layer 7 and empty space bar 5 form a middle cavity 6, and hollow intracavity 6 is filled with inertia Gas.
Preferably, nano ceramics PUR 3 adopts caesium, the EVA films of antimony codope Tungstic anhydride., the hollow glass of the first doubling Glass layer be by after the first glass-base 2 and the second glass-base 4 and 3 conjunction plate of nano ceramics PUR at 135 DEG C, -0.08Mpa Lower insulation 35min is obtained, and wherein EVA selects Mitsui EVA-260 (VA:28%, MI:6g/10min), caesium, antimony codope three The content of tungsten oxide is 2wt.%, and caesium, the thickness of the EVA films of antimony codope Tungstic anhydride. are 0.76mm.Additionally, nano ceramics PUR can also be nano antimony-doped tin dioxide (ATO) or cerium, antimony codope tin ash (Ce-ATO);Caesium three oxygen of doping Change any one in tungsten.Simply preferably caesium, antimony codope Tungstic anhydride..Meanwhile, melten gel intermediate layer can also be PVB, TPU with And any one in SGP.Simply preferably EVA, and EVA preferred moltens index is 5-15g/10min.And nano ceramics are heated The content of glue is 0.5-3wt.%, preferably 1.5-2wt.%.
Preferably, super-hydrophobic oleophobic nano protecting film 1 is nano silicon ceramic resin, and thickness is 1 μm.
Preferably, noble gases are dry argon gas.
Preferably, the thickness of the first laminated hollow glass layer is 8.76mm, and 7 thickness of the second double glazing layer is 10mm.
The nano ceramics laminated hollow glass of following structure is made according to the present embodiment, white+0.76 caesiums of glass of 4mm, antimony are co-doped with White glass+12A+10mm the safety glass of EVA film+4mm of miscellaneous Tungstic anhydride., can reach following technical specification by detection:First Glass-base surface contact angle is 156 °, and nano ceramics laminated hollow glass visible transmission ratio is 56%, and heat transfer coefficient is 2.3w/ (m2 K), shading coefficient is 0.43, and ultraviolet (uv) transmission ratio is 0.1%.
This utility model simple structure, it is reasonable in design, realize that visible ray is high thoroughly using nano ceramic material spectral selection Cross, the high shielding of infrared ray and ultraviolet, it is transparent with heat-insulated simultaneous purpose so as to reach.It is directly heat-insulated from nano ceramics PUR aids in super-hydrophobic oleophobic nano protecting film as doubling layer so as to safety, energy-conservation, sound insulation, oil-stain-preventing and from clear Clean function, while comparing traditional Low-E double glazings, avoids thermal insulation layer oxidation to cause heat-proof quality Problem of Failure completely, makes It is longer with the life-span, it is to make building doors and windows and glass curtain wall high performance-price ratio construction material, wide market is adapted to promote.
Herein first, second ... only represents the differentiation of its title, does not represent what their significance level and position have It is different.
Herein, up, down, left, right, before and after only represents its relative position and does not indicate that its absolute position.
Embodiment of the present utility model is the foregoing is only, the scope of the claims of the present utility model is not thereby limited, it is every The equivalent structure made using this utility model description and accompanying drawing content or equivalent flow conversion, or be directly or indirectly used in Other related technical fields, are included in scope of patent protection of the present utility model in the same manner.

Claims (6)

1. a kind of nano ceramics laminated hollow glass, it is characterised in that:Including the first laminated hollow glass layer, the second double glazing Layer and empty space bar;
The first laminated hollow glass layer is to pass through nano ceramics melt viscosity by the first glass-base and the second glass-base It is combined, on the outside of wherein the first glass-base, has one layer of super-hydrophobic oleophobic nano protecting film;
The first laminated hollow glass layer and the second double glazing layer are bonded together with empty space bar by butyl rubber;
On the outside of the empty space bar, between the first laminated hollow glass layer and the second double glazing layer, fluid sealant is provided with;
The first laminated hollow glass layer, the second double glazing layer and empty space bar form a middle cavity, hollow intracavity Filled with noble gases.
2. a kind of nano ceramics laminated hollow glass according to claim 1, it is characterised in that:The nano ceramics hot melt Glue includes an EVA or PVB or TPU or SGP intermediate layers.
3. a kind of nano ceramics laminated hollow glass according to claim 2, it is characterised in that:The nano ceramics hot melt The thickness in glue intermediate layer is 0.38-1.52mm.
4. a kind of nano ceramics laminated hollow glass according to claim 3, it is characterised in that:The super-hydrophobic oleophobic is received Rice protecting film is nano silicon ceramic resin, and thickness is 1-3 μm.
5. a kind of nano ceramics laminated hollow glass according to claim 4, it is characterised in that:The noble gases are dry Dry argon or helium.
6. a kind of nano ceramics laminated hollow glass according to claim 5, it is characterised in that:First doubling is hollow Glassy layer and the second double glazing thickness degree are all 6-15mm.
CN201620903210.6U 2016-08-18 2016-08-18 Nano -ceramics doubling cavity glass Active CN206033579U (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108795334A (en) * 2018-05-31 2018-11-13 安徽荣春玻璃科技有限公司 A kind of doubling for doubling glass
CN110133778A (en) * 2019-05-24 2019-08-16 浙江靓鸿新材料有限公司 A kind of reflective membrane with reflective insulation function
CN114704191A (en) * 2022-03-29 2022-07-05 湖南兴龙科技有限公司 Method for manufacturing hollow glass with built-in shutter by using super-thick glass and hollow glass window

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108795334A (en) * 2018-05-31 2018-11-13 安徽荣春玻璃科技有限公司 A kind of doubling for doubling glass
CN110133778A (en) * 2019-05-24 2019-08-16 浙江靓鸿新材料有限公司 A kind of reflective membrane with reflective insulation function
CN114704191A (en) * 2022-03-29 2022-07-05 湖南兴龙科技有限公司 Method for manufacturing hollow glass with built-in shutter by using super-thick glass and hollow glass window

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C14 Grant of patent or utility model
GR01 Patent grant
PE01 Entry into force of the registration of the contract for pledge of patent right
PE01 Entry into force of the registration of the contract for pledge of patent right

Denomination of utility model: Nano -ceramics doubling cavity glass

Effective date of registration: 20190429

Granted publication date: 20170322

Pledgee: Guangdong Nanhai Rural Commercial Bank branch branch of Limited by Share Ltd

Pledgor: Foshan City Jushitai Powder Metallurgy Co., Ltd.

Registration number: 2019440000168