CN108795334A - A kind of doubling for doubling glass - Google Patents

A kind of doubling for doubling glass Download PDF

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Publication number
CN108795334A
CN108795334A CN201810549042.9A CN201810549042A CN108795334A CN 108795334 A CN108795334 A CN 108795334A CN 201810549042 A CN201810549042 A CN 201810549042A CN 108795334 A CN108795334 A CN 108795334A
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Prior art keywords
parts
minutes
doubling
ceramic fiber
glass
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CN201810549042.9A
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Chinese (zh)
Inventor
徐少春
徐善祥
高玉静
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Anhui Rong Chun Glass Technology Co Ltd
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Anhui Rong Chun Glass Technology Co Ltd
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Priority to CN201810549042.9A priority Critical patent/CN108795334A/en
Publication of CN108795334A publication Critical patent/CN108795334A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J129/00Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Adhesives based on hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Adhesives based on derivatives of such polymers
    • C09J129/14Homopolymers or copolymers of acetals or ketals obtained by polymerisation of unsaturated acetals or ketals or by after-treatment of polymers of unsaturated alcohols
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/04Non-macromolecular additives inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/06Non-macromolecular additives organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08Macromolecular additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2227Oxides; Hydroxides of metals of aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The invention discloses a kind of doublings for doubling glass, it is related to hollow glass processing technique field, the present invention is with PVB films, EVA films are combined into major ingredient, compared to single PVB or EVA films, isolation effect is more preferable, association is with modified ceramic fiber simultaneously, polyaminoester emulsion, silica gel, the doubling for doubling glass is made in the multiple auxiliary materials such as molecular sieve micro mist, the doubling has the performance of reinforcing inlay glass heat-insulating, the ceramic fibre in modified ceramic fiber is utilized simultaneously, the characteristic that the reflectivity of mica powder is strong reduces sunlight projection, mitigate ultraviolet radiation, nano aluminium oxide is utilized simultaneously, the porosity of microcrystalline cellulose, adsorptivity, make PVB, EVA, the absorption such as modified ceramic fiber are on it, also enhance the viscous stickiness and adhesiveness of film, enhance the isolation effect of film.

Description

A kind of doubling for doubling glass
Technical field:
The present invention relates to hollow glass processing technique fields, and in particular to a kind of doubling for doubling glass.
Background technology:
Glass is important construction material, and with the continuous improvement required decorating building, glass is in building trade In usage amount also constantly increase.However, people are when selecting the glass door and window of building now, in addition to considering its aesthetics with other than It sees outside feature, more focuses on the problems such as control of its heat, refrigeration cost and internal sunlight project comfortable balance.
Doubling glass be by two panels or divided glass, between pressed from both sides organic polymer doubling, by special high temperature precompressed After the processing of (or vacuumizing) and high-temperature high-pressure craft, so that glass and doubling is bonded the compound glass product being integrated, there is enhancing The heat insulation and preservation effect of laminated glass reduces sunlight projection, mitigates the effect of ultraviolet radiation.
Invention content:
Technical problem to be solved by the present invention lies in provide a kind of doubling for doubling glass.
The technical problems to be solved by the invention are realized using technical solution below:
A kind of doubling for doubling glass, which is characterized in that be prepared from the following raw materials in parts by weight:PVB films 10- 30 parts, 5-15 parts of EVA films, 5-10 parts of modified ceramic fiber, 2-10 parts of polyaminoester emulsion, 5-10 parts of silica gel, molecular sieve micro mist 4-8 parts, 0.5-3 parts of methyl diphenylene diisocyanate, 0.2-2 parts of nano aluminium oxide, 0.5-2 parts of epoxidized soybean oil, crystallite fibre Tie up 0.5-2 parts of element.
The doubling for doubling glass, which is characterized in that the raw material of preferred following parts by weight is made:PVB films 20 parts, 10 parts of EVA films, 8 parts of modified ceramic fiber, 6 parts of polyaminoester emulsion, 8 parts of silica gel, 6 parts of molecular sieve micro mist, diphenylmethyl 1.8 parts of alkane diisocyanate, 1 part of nano aluminium oxide, 1.5 parts of epoxidized soybean oil, 1.2 parts of microcrystalline cellulose.
Further, the modified ceramic fiber is modified by ceramic fibre, mica powder, bamboo charcoal, palm wax, is changed Property method is:Ceramic fibre is mixed with mica powder, bamboo charcoal and is ground 30-50 minutes, then is mixed with palm wax, is stirred evenly It is sent into microwave processing equipment afterwards, microwave treatment is spaced under microwave frequency 2450MHz, power 600W, interval time is 10 points Clock, each microwave treatment 6 minutes are carried out continuously 5 times, and after treatment places into blender and is stirred, and mixing speed is 600-800r/min, mixing time are 5-15 minutes, stand 5 minutes after stirring, mixture is freeze-dried, dry Micro mist is made to get modified ceramic fiber through micronizer in obtained solid.
The ceramic fibre, mica powder, activated carbon, palm wax weight part ratio be 5:3:4:1.
The doubling for doubling glass, preparation method are as follows:
(1) PVB films, EVA films are mixed, is heated to molten condition, is stirred with the speed of 800-1000r/min Mixing 5-15 minutes adds modified ceramic fiber, continues insulated and stirred and mixes 10-20 minutes, obtains material I;
(2) it by silica gel heating to molten condition, is mixed with polyaminoester emulsion, molecular sieve micro mist is added, in microwave frequency Microwave reflow treatment 5-15min under 2450MHz, power 600W stands 5 minutes, adds methyl diphenylene diisocyanate, after Continuous microwave reflow treatment 5-15 minutes, stands 5 minutes, adds microcrystalline cellulose, continues microwave reflux 5-15 after being sufficiently mixed Minute, obtain material II;
(3) after being sufficiently mixed material I, material II, nano aluminium oxide, epoxidized soybean oil is added, after stirring evenly, is sent into In kneading machine, and it is kneaded 10-20 minutes at 130-150 DEG C;
(4) mixture that step 3 is handled well is poured into mold, carries out gradually cooling treatment, demoulding obtains doubling.
Further, the gradually cooling treatment is divided into, and mold is put into 0 to subzero 10 degree 10-20 points of freezings by the first step Clock, then it is reduced to subzero 10 degree to rise to subzero 5 degree to 0 degree to minus 20 degrees freezing 20-40 minutes, then by temperature temperature, it puts It sets 10-20 minutes.
The beneficial effects of the invention are as follows:
1, the present invention is combined into major ingredient with PVB films, EVA films, and compared to single PVB or EVA films, isolation effect is more It is good, while association is made with multiple auxiliary materials such as modified ceramic fiber, polyaminoester emulsion, silica gel, molecular sieve micro mists for doubling glass Doubling, which has a performance of reinforcing inlay glass heat-insulating, at the same using in modified ceramic fiber ceramic fibre, The characteristic that the reflectivity of mica powder is strong reduces sunlight projection, mitigates ultraviolet radiation, while utilizing nano aluminium oxide, microcrystalline cellulose The porosity of element, adsorptivity make the absorption such as PVB, EVA, modified ceramic fiber on it, also enhance the viscous stickiness of film and glue Conjunction property, enhances the isolation effect of film;
2, modified ceramic fiber is used in raw material of the invention, system is modified with ceramic fibre, mica powder, bamboo charcoal, palm wax At by the way that first ceramic fibre, mica powder, bamboo charcoal are ground, then mixed with palm wax, by the method for microwave treatment, utilizing bamboo The porosity of charcoal makes ceramic fibre and mica powder be adsorbed on bamboo charcoal, and ceramic fibre and mica powder is made to play it to greatest extent Emitting performance mitigates ultraviolet radiation, while ceramic fibre can also enhance the toughness of doubling and anti-ageing property.
Specific implementation mode:
In order to make the technical means, the creative features, the aims and the efficiencies achieved by the present invention be easy to understand, tie below Specific embodiment is closed, the present invention is further explained.
Embodiment 1
A kind of doubling for doubling glass, which is characterized in that be prepared from the following raw materials in parts by weight:PVB films 10 Part, 5 parts of EVA films, 5 parts of modified ceramic fiber, 2 parts of polyaminoester emulsion, 5 parts of silica gel, 4 parts of molecular sieve micro mist, diphenyl methane 0.5 part of diisocyanate, 0.2 part of nano aluminium oxide, 0.5 part of epoxidized soybean oil, 0.5 part of microcrystalline cellulose.
Further, the modified ceramic fiber is modified by ceramic fibre, mica powder, bamboo charcoal, palm wax, is changed Property method is:Ceramic fibre is mixed with mica powder, bamboo charcoal and is ground 30 minutes, then is mixed with palm wax, after stirring evenly It is sent into microwave processing equipment, microwave treatment is spaced under microwave frequency 2450MHz, power 600W, interval time is 10 minutes, Each microwave treatment 6 minutes, is carried out continuously 5 times, after treatment places into blender and is stirred, mixing speed 600r/ Min, mixing time are 5 minutes, stand 5 minutes after stirring, mixture is freeze-dried, and dry obtained solid is through super Micro mist is made to get modified ceramic fiber in atomizer.
The ceramic fibre, mica powder, activated carbon, palm wax weight part ratio be 5:3:4:1.
The doubling for doubling glass, preparation method are as follows:
(1) by PVB films, it is heated to molten condition, mixing 5 minutes is stirred with the speed of 800r/min, is added Modified ceramic fiber continues insulated and stirred and mixes 10 minutes, obtains material I;
(2) it by silica gel heating to molten condition, is mixed with polyaminoester emulsion, molecular sieve micro mist is added, in microwave frequency Microwave reflow treatment 5min under 2450MHz, power 600W stands 5 minutes, adds methyl diphenylene diisocyanate, continues Microwave reflow treatment 5 minutes stands 5 minutes, adds microcrystalline cellulose, continues microwave after being sufficiently mixed and flows back 5 minutes, obtains Material II;
(3) after being sufficiently mixed material I, material II, nano aluminium oxide, epoxidized soybean oil is added, after stirring evenly, is sent into In kneading machine, and it is kneaded 10 minutes at 130 DEG C;
(4) mixture that step 3 is handled well is poured into mold, carries out gradually cooling treatment, demoulding obtains doubling.
Further, the gradually cooling treatment is divided into, and mold is put into 0 degree and freezed 10 minutes by the first step, then by temperature It is reduced to subzero 10 degree to freeze 20 minutes, then temperature is risen to subzero 5 degree, place 10 minutes.
Embodiment 2
A kind of doubling for doubling glass, which is characterized in that be prepared from the following raw materials in parts by weight:PVB films 30 Part, 15 parts of EVA films, 10 parts of modified ceramic fiber, 10 parts of polyaminoester emulsion, 10 parts of silica gel, 8 parts of molecular sieve micro mist, diphenyl 3 parts of methane diisocyanate, 2 parts of nano aluminium oxide, 2 parts of epoxidized soybean oil, 2 parts of microcrystalline cellulose.
The doubling for doubling glass, preparation method are as follows:
(1) PVB films, EVA films are mixed, is heated to molten condition, mixing is stirred with the speed of 1000r/min 15 minutes, modified ceramic fiber is added, continues insulated and stirred and mixes 20 minutes, obtain material I;
(2) it by silica gel heating to molten condition, is mixed with polyaminoester emulsion, molecular sieve micro mist is added, in microwave frequency Microwave reflow treatment 15min under 2450MHz, power 600W stands 5 minutes, adds methyl diphenylene diisocyanate, continues Microwave reflow treatment 15 minutes stands 5 minutes, adds microcrystalline cellulose, continues microwave after being sufficiently mixed and flows back 15 minutes, obtains To material II;
(3) after being sufficiently mixed material I, material II, nano aluminium oxide, epoxidized soybean oil is added, after stirring evenly, is sent into In kneading machine, and it is kneaded 20 minutes at 150 DEG C;
(4) mixture that step 3 is handled well is poured into mold, carries out gradually cooling treatment, demoulding obtains doubling.
Further, the gradually cooling treatment is divided into, and mold is put into subzero 10 degree and freezed 20 minutes by the first step, then will Temperature is reduced to minus 20 degrees to freeze 40 minutes, then temperature is risen to 0 degree, places 20 minutes.
Embodiment 3
A kind of doubling for doubling glass, which is characterized in that be prepared from the following raw materials in parts by weight:PVB films 20 Part, 10 parts of EVA films, 8 parts of modified ceramic fiber, 6 parts of polyaminoester emulsion, 8 parts of silica gel, 6 parts of molecular sieve micro mist, diphenyl methane 1.8 parts of diisocyanate, 1 part of nano aluminium oxide, 1.5 parts of epoxidized soybean oil, 1.2 parts of microcrystalline cellulose.
Further, the modified ceramic fiber is modified by ceramic fibre, mica powder, bamboo charcoal, palm wax, is changed Property method is:Ceramic fibre is mixed with mica powder, bamboo charcoal and is ground 40 minutes, then is mixed with palm wax, after stirring evenly It is sent into microwave processing equipment, microwave treatment is spaced under microwave frequency 2450MHz, power 600W, interval time is 10 minutes, Each microwave treatment 6 minutes, is carried out continuously 5 times, after treatment places into blender and is stirred, mixing speed 700r/ Min, mixing time are 10 minutes, stand 5 minutes after stirring, mixture is freeze-dried, dry obtained solid warp Micro mist is made to get modified ceramic fiber in micronizer.
The ceramic fibre, mica powder, activated carbon, palm wax weight part ratio be 5:3:4:1.
The doubling for doubling glass, preparation method are as follows:
(1) PVB films, EVA films are mixed, is heated to molten condition, mixing is stirred with the speed of 900r/min 10 minutes, modified ceramic fiber is added, continues insulated and stirred and mixes 15 minutes, obtain material I;
(2) it by silica gel heating to molten condition, is mixed with polyaminoester emulsion, molecular sieve micro mist is added, in microwave frequency Microwave reflow treatment 10min under 2450MHz, power 600W stands 5 minutes, adds methyl diphenylene diisocyanate, continues Microwave reflow treatment 10 minutes stands 5 minutes, adds microcrystalline cellulose, continues microwave after being sufficiently mixed and flows back 10 minutes, obtains To material II;
(3) after being sufficiently mixed material I, material II, nano aluminium oxide, epoxidized soybean oil is added, after stirring evenly, is sent into In kneading machine, and it is kneaded 15 minutes at 140 DEG C;
(4) mixture that step 3 is handled well is poured into mold, carries out gradually cooling treatment, demoulding obtains doubling.
Further, the gradually cooling treatment is divided into, and mold is put into subzero 5 degree and freezed 15 minutes by the first step, then will Temperature is reduced to subzero 15 degree to freeze 30 minutes, then temperature is risen to subzero 3 degree, places 15 minutes.
Control group 1:
This control group content and 3 content of embodiment are essentially identical, and something in common no longer repeats, the difference is that:Raw material In only with PVB films or the single raw material of EVA films.
Control group 2:
This control group content and 3 content of embodiment are essentially identical, and something in common no longer repeats, the difference is that:Raw material In do not use modified ceramic fiber.
Control group 3 is commercially available common doubling glass.
Respectively to embodiment 1-3, the made insulating glass sealants of control group 1-3 are used for the performance test of hollow glass, knot Fruit is as shown in table 1.
The performance of the made interior road fluid sealant of 1 embodiment of the present invention of table
Embodiment Thermal coefficient (W/ (m2·K)) Decibel/(dB) Light-transmission coefficient
Embodiment 1 2.0 37 0.35
Embodiment 2 1.9 35 0.33
Embodiment 3 1.8 35 0.32
Comparative example 1 3.3 55 0.42
Comparative example 2 2.5 48 0.64
Comparative example 3 2.7 52 0.63
The above shows and describes the basic principles and main features of the present invention and the advantages of the present invention.The technology of the industry Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the above embodiments and description only describe this The principle of invention, without departing from the spirit and scope of the present invention, various changes and improvements may be made to the invention, these changes Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its Equivalent thereof.

Claims (6)

1. a kind of doubling for doubling glass, which is characterized in that be prepared from the following raw materials in parts by weight:PVB films 10-30 Part, 5-15 parts of EVA films, 5-10 parts of modified ceramic fiber, 2-10 parts of polyaminoester emulsion, 5-10 parts of silica gel, molecular sieve micro mist 4-8 Part, 0.5-3 parts of methyl diphenylene diisocyanate, 0.2-2 parts of nano aluminium oxide, 0.5-2 parts of epoxidized soybean oil, microcrystalline cellulose 0.5-2 parts.
2. a kind of doubling for doubling glass, which is characterized in that include the following steps:It is preferred that the raw material system of following parts by weight At:20 parts of PVB films, 10 parts of EVA films, 8 parts of modified ceramic fiber, 6 parts of polyaminoester emulsion, 8 parts of silica gel, molecular sieve micro mist 6 Part, 1.8 parts of methyl diphenylene diisocyanate, 1 part of nano aluminium oxide, 1.5 parts of epoxidized soybean oil, 1.2 parts of microcrystalline cellulose.
3. the doubling according to claim 1 or 2 for doubling glass, it is characterised in that:The modified ceramic fiber is It is modified by ceramic fibre, mica powder, bamboo charcoal, palm wax, method of modifying is:Ceramic fibre and mica powder, bamboo charcoal are mixed Conjunction is ground 30-50 minutes, then is mixed with palm wax, is sent into microwave processing equipment after stirring evenly, in microwave frequency Microwave treatment is spaced under 2450MHz, power 600W, interval time is 10 minutes, and each microwave treatment 6 minutes is carried out continuously 5 Secondary, after treatment places into blender and is stirred, mixing speed 600-800r/min, and mixing time is 5-15 minutes, 5 minutes are stood after stirring, mixture is freeze-dried, micro mist is made through micronizer in dry obtained solid, i.e., Obtain modified ceramic fiber.
4. the doubling according to claim 3 for doubling glass, which is characterized in that the ceramic fibre, mica powder, work Property charcoal, palm wax weight part ratio be 5:3:4:1.
5. the doubling according to claim 1 or 2 for doubling glass, which is characterized in that preparation method is as follows:
(1) PVB films, EVA films are mixed, is heated to molten condition, mixing is stirred with the speed of 800-1000r/min 5-15 minutes, modified ceramic fiber is added, continues insulated and stirred and mixes 10-20 minutes, obtain material I;
(2) it by silica gel heating to molten condition, is mixed with polyaminoester emulsion, molecular sieve micro mist is added, in microwave frequency Microwave reflow treatment 5-15min under 2450MHz, power 600W stands 5 minutes, adds methyl diphenylene diisocyanate, after Continuous microwave reflow treatment 5-15 minutes, stands 5 minutes, adds microcrystalline cellulose, continues microwave reflux 5-15 after being sufficiently mixed Minute, obtain material II;
(3) after being sufficiently mixed material I, material II, nano aluminium oxide, epoxidized soybean oil is added, after stirring evenly, is sent into and is kneaded In machine, and it is kneaded 10-20 minutes at 130-150 DEG C;
(4) mixture that step 3 is handled well is poured into mold, carries out gradually cooling treatment, demoulding obtains doubling.
6. the doubling according to claim 5 for doubling glass, which is characterized in that the gradually cooling treatment is divided into, The first step by mold be put into 0 to subzero 10 degree freeze 10-20 minute, then by temperature be reduced to subzero 10 degree to minus 20 degrees freezing 20-40 minutes, then temperature is risen to subzero 5 degree to 0 degree, it places 10-20 minutes.
CN201810549042.9A 2018-05-31 2018-05-31 A kind of doubling for doubling glass Pending CN108795334A (en)

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CN112265330A (en) * 2020-11-05 2021-01-26 杭州盛得新材料有限公司 Fabric laminate with recycled modified PVB and preparation method thereof

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112265330A (en) * 2020-11-05 2021-01-26 杭州盛得新材料有限公司 Fabric laminate with recycled modified PVB and preparation method thereof
CN112265330B (en) * 2020-11-05 2021-06-25 杭州盛得新材料有限公司 Fabric laminate with recycled modified PVB and preparation method thereof
WO2022095149A1 (en) * 2020-11-05 2022-05-12 杭州盛得新材料有限公司 Fabric laminate of recycled modified pvb and preparation method therefor

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