CN106566439A - Hectorite-cardanol composite hot melt butyl sealant used for hollow glass, and preparation method thereof - Google Patents
Hectorite-cardanol composite hot melt butyl sealant used for hollow glass, and preparation method thereof Download PDFInfo
- Publication number
- CN106566439A CN106566439A CN201610960796.4A CN201610960796A CN106566439A CN 106566439 A CN106566439 A CN 106566439A CN 201610960796 A CN201610960796 A CN 201610960796A CN 106566439 A CN106566439 A CN 106566439A
- Authority
- CN
- China
- Prior art keywords
- hectorite
- cardanol
- parts
- hot melt
- butyl sealant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000565 sealant Substances 0.000 title claims abstract description 27
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 title claims abstract description 23
- 239000011521 glass Substances 0.000 title claims abstract description 18
- 239000012943 hotmelt Substances 0.000 title claims abstract description 17
- 238000002360 preparation method Methods 0.000 title claims description 7
- 239000002131 composite material Substances 0.000 title abstract 4
- XPFVYQJUAUNWIW-UHFFFAOYSA-N furfuryl alcohol Chemical compound OCC1=CC=CO1 XPFVYQJUAUNWIW-UHFFFAOYSA-N 0.000 claims abstract description 15
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229920005549 butyl rubber Polymers 0.000 claims abstract description 9
- JOLVYUIAMRUBRK-UHFFFAOYSA-N 11',12',14',15'-Tetradehydro(Z,Z-)-3-(8-Pentadecenyl)phenol Natural products OC1=CC=CC(CCCCCCCC=CCC=CCC=C)=C1 JOLVYUIAMRUBRK-UHFFFAOYSA-N 0.000 claims abstract description 8
- YLKVIMNNMLKUGJ-UHFFFAOYSA-N 3-Delta8-pentadecenylphenol Natural products CCCCCCC=CCCCCCCCC1=CC=CC(O)=C1 YLKVIMNNMLKUGJ-UHFFFAOYSA-N 0.000 claims abstract description 8
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 8
- JOLVYUIAMRUBRK-UTOQUPLUSA-N Cardanol Chemical compound OC1=CC=CC(CCCCCCC\C=C/C\C=C/CC=C)=C1 JOLVYUIAMRUBRK-UTOQUPLUSA-N 0.000 claims abstract description 8
- FAYVLNWNMNHXGA-UHFFFAOYSA-N Cardanoldiene Natural products CCCC=CCC=CCCCCCCCC1=CC=CC(O)=C1 FAYVLNWNMNHXGA-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229920002367 Polyisobutene Polymers 0.000 claims abstract description 8
- PTFIPECGHSYQNR-UHFFFAOYSA-N cardanol Natural products CCCCCCCCCCCCCCCC1=CC=CC(O)=C1 PTFIPECGHSYQNR-UHFFFAOYSA-N 0.000 claims abstract description 8
- AOBIOSPNXBMOAT-UHFFFAOYSA-N 2-[2-(oxiran-2-ylmethoxy)ethoxymethyl]oxirane Chemical compound C1OC1COCCOCC1CO1 AOBIOSPNXBMOAT-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229920001451 polypropylene glycol Polymers 0.000 claims abstract description 6
- KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 claims abstract description 5
- 229910000271 hectorite Inorganic materials 0.000 claims abstract description 5
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 4
- 239000000835 fiber Substances 0.000 claims abstract description 4
- 230000001070 adhesive effect Effects 0.000 claims description 9
- 239000002994 raw material Substances 0.000 claims description 9
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 7
- 239000000853 adhesive Substances 0.000 claims description 7
- 230000008878 coupling Effects 0.000 claims description 7
- 238000010168 coupling process Methods 0.000 claims description 7
- 238000005859 coupling reaction Methods 0.000 claims description 7
- 229910000077 silane Inorganic materials 0.000 claims description 7
- 238000001816 cooling Methods 0.000 claims description 6
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 claims description 6
- 239000000178 monomer Substances 0.000 claims description 6
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims description 6
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 3
- 238000001125 extrusion Methods 0.000 claims description 3
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 claims description 2
- 238000007493 shaping process Methods 0.000 claims description 2
- 238000000034 method Methods 0.000 claims 1
- 230000008901 benefit Effects 0.000 abstract description 3
- 230000007797 corrosion Effects 0.000 abstract description 2
- 238000005260 corrosion Methods 0.000 abstract description 2
- 239000006087 Silane Coupling Agent Substances 0.000 abstract 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 239000012530 fluid Substances 0.000 description 3
- 238000007789 sealing Methods 0.000 description 3
- 238000013329 compounding Methods 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 230000003373 anti-fouling effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
- C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
- C09J123/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C09J123/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
- C09J123/22—Copolymers of isobutene; Butyl rubber ; Homo- or copolymers of other iso-olefines
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Sealing Material Composition (AREA)
Abstract
The invention discloses a hectorite-cardanol composite hot melt butyl sealant used for hollow glass. The hectorite-cardanol composite hot melt butyl sealant used for hollow glass is prepared from, by weight, 10-20 parts of butyl rubber, 30-40 parts of polyisobutylene, 5-10 parts of hectorite, 5-10 parts of ethylene-propylene methylene copolymer, 1-2 parts of cardanol, 0.5-1 part of polypropylene glycol diglycidyl ether, 0.5-1 part of a silane coupling agent A-151, 5-10 parts of furfuryl alcohol resin, 3-5 parts of dibutyl phthalate, 10-15 parts of heavy calcium carbonate and 1-2 parts of aluminum silicate fibers. The hectorite-cardanol composite hot melt butyl sealant used for hollow glass has the advantages of excellent deformation resistance, high strength, high bonding performance, high wear, pollution and corrosion resistance, excellent durability, good comprehensive performances and high practicality.
Description
Technical field
The present invention relates to fluid sealant technical field, more particularly to a kind of hectorite-Cardanol compound insulating glass hot melt
Butyl sealant and preparation method thereof.
Background technology
Double glazing integrates the good characteristics such as thermal insulation, sound insulation, daylighting, is a kind of efficient energy-conserving product, in glass
The aspects such as curtain wall, automobile, traffic, aircraft are widely used.As double glazing enters novel building field, people in a large number
To the prescription of double glazing also more and more higher.The economic benefit that the double glazing of sealing life length can not only bring,
Also there is the higher market competitiveness.Butyl sealant has its extremely low water vapor transmittance and good sealing effectiveness, by with
Make first double glazing sealant, the comprehensive quality performance of hollow glass products is played a key effect.
Butyl rubber has creep properties, gives butyl sealant pliability, tack and impact resistance, but is easily caused
Cold flow, deforms upon, and affects the using effect of butyl sealant.CN201010283780 discloses a kind of double glazing hot melt
Butyl sealant, improves the high temperature cold flow of butyl sealant so as to can life-time service and it is indeformable.However, the product
Product have a not enough defect of adhesive property, and cannot improve the intensity and combination property of butyl sealant, in actual applications still
Need to improve.
The content of the invention
The object of the invention is exactly for the defect for making up prior art, there is provided one kind has excellent anti-deformation nature and high-strength concurrently
Hectorite-Cardanol compound insulating glass hot melt butyl sealant and preparation method thereof of degree, high-adhesion energy.
The present invention is achieved by the following technical solutions:
A kind of hectorite-Cardanol compound insulating glass hot melt butyl sealant, which is obtained by the raw material of following weight parts:
Butyl rubber 10-20, polyisobutylene 30-40, hectorite 5-10, ethylene propylene monomer 5-10, Cardanol 1-2, poly- the third two
Alcohol diglycidyl ether 0.5-1, -151 0.5-1 of silane coupling A, furfuryl alcohol resin 5-10, dibutyl phthalate 3-5, weight
Matter Calcium Carbonate 10-15, alumina silicate fibre 1-2.
A kind of hectorite-Cardanol compound insulating glass preparation method of hot melt butyl sealant, comprises the following steps:
(1)Raw material is weighed by weight, first by furfuryl alcohol resin, Cardanol, polypropylene glycol diglycidyl ether and phthalic acid two
Butyl ester mixes 0.5-1h in 80-90 DEG C, is subsequently adding silane coupling A -151 and stirs 10-15min in 100-120 DEG C, after cooling
Must be modified furfuryl alcohol resin adhesive;
(2)Butyl rubber, polyisobutylene and ethylene propylene monomer are first blended at a high speed uniform rear and step(1)In obtain it is modified
Furfuryl alcohol resin adhesive puts in kneader jointly and preheats 15-30min in 80-90 DEG C, temperature is risen to 100-120 DEG C then and is pinched
1-2h is closed, remaining raw material is added and is continued to mediate 1-2h, then start evacuation, to reach 0.08-0.09Mpa follow-up when vacuum
Continuous to mediate 2-4h, extrusion, cooling shaping obtain hectorite-Cardanol compound insulating glass hot melt butyl sealant.
It is an advantage of the invention that:
Furfuryl alcohol resin, Cardanol, polypropylene glycol diglycidyl ether and dibutyl phthalate are blended by the present invention, and
It is modified using silane coupling A -151, the modified furfuryl alcohol resin adhesive for obtaining and butyl rubber, polyisobutylene, binary
The sealing gum of EP rubbers compounding has good compatibility, can be effectively improved the stability of system, it is to avoid produce
Raw and cold flow phenomenon, can improve the adhesive property and intensity of fluid sealant again.Meanwhile, by the selection of remaining raw material and compounding so that
To double glazing hot melt butyl sealant have excellent anti-deformation nature and high intensity, high-adhesion energy concurrently, and it is wear-resisting,
Antifouling Corrosion Protection is high, and with excellent durability, good combination property is practical.
Specific embodiment
A kind of hectorite-Cardanol compound insulating glass hot melt butyl sealant, the component by following weight (kg) are former
Material is prepared from:
Butyl rubber 10, polyisobutylene 30, hectorite 5, ethylene propylene monomer 5, Cardanol 1, polypropylene glycol diglycidyl ether
0.5, silane coupling A -151 0.5, furfuryl alcohol resin 5, dibutyl phthalate 3, ground calcium carbonate 10, alumina silicate fibre 1.
A kind of hectorite-Cardanol compound insulating glass preparation method of hot melt butyl sealant, comprises the following steps:
(1)Raw material is weighed by weight, first by furfuryl alcohol resin, Cardanol, polypropylene glycol diglycidyl ether and phthalic acid two
Butyl ester mixes 0.5h in 80 DEG C, is subsequently adding silane coupling A -151 and stirs 10min in 100 DEG C, and must be modified after cooling furfuryl alcohol resin
Fat adhesive;
(2)Butyl rubber, polyisobutylene and ethylene propylene monomer are first blended at a high speed uniform rear and step(1)In obtain it is modified
Furfuryl alcohol resin adhesive puts in kneader jointly and preheats 15min in 80 DEG C, and temperature risen to 100 DEG C of kneading 1h then, then plus
Enter remaining raw material to continue to mediate 1h, then start evacuation, continue to mediate 2h, extrusion, cooling after vacuum reaches 0.08Mpa
Molding obtains hectorite-Cardanol compound insulating glass hot melt butyl sealant.
Fluid sealant the performance test results obtained above are as follows:
Density(g/cm3):1.32;
Shear strength(MPa):0.28;
Moisture-vapor transmission(24h, 1.8mm)/(g/cm2):0.08;
Mist is sent out in ultraviolet irradiation:It is fogless;
Cold flow properties are close to zero.
Claims (2)
1. a kind of hectorite-Cardanol compound insulating glass is used and heats butyl sealant, it is characterised in which is by following weight
The raw material of part is obtained:
Butyl rubber 10-20, polyisobutylene 30-40, hectorite 5-10, ethylene propylene monomer 5-10, Cardanol 1-2, poly- the third two
Alcohol diglycidyl ether 0.5-1, -151 0.5-1 of silane coupling A, furfuryl alcohol resin 5-10, dibutyl phthalate 3-5, weight
Matter Calcium Carbonate 10-15, alumina silicate fibre 1-2.
2. preparation of a kind of hectorite according to claim 1-Cardanol compound insulating glass with hot melt butyl sealant
Method, it is characterised in that comprise the following steps:
(1)Raw material is weighed by weight, first by furfuryl alcohol resin, Cardanol, polypropylene glycol diglycidyl ether and phthalic acid two
Butyl ester mixes 0.5-1h in 80-90 DEG C, is subsequently adding silane coupling A -151 and stirs 10-15min in 100-120 DEG C, after cooling
Must be modified furfuryl alcohol resin adhesive;
(2)Butyl rubber, polyisobutylene and ethylene propylene monomer are first blended at a high speed uniform rear and step(1)In obtain it is modified
Furfuryl alcohol resin adhesive puts in kneader jointly and preheats 15-30min in 80-90 DEG C, temperature is risen to 100-120 DEG C then and is pinched
1-2h is closed, remaining raw material is added and is continued to mediate 1-2h, then start evacuation, to reach 0.08-0.09Mpa follow-up when vacuum
Continuous to mediate 2-4h, extrusion, cooling shaping obtain hectorite-Cardanol compound insulating glass hot melt butyl sealant.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610960796.4A CN106566439A (en) | 2016-10-28 | 2016-10-28 | Hectorite-cardanol composite hot melt butyl sealant used for hollow glass, and preparation method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610960796.4A CN106566439A (en) | 2016-10-28 | 2016-10-28 | Hectorite-cardanol composite hot melt butyl sealant used for hollow glass, and preparation method thereof |
Publications (1)
Publication Number | Publication Date |
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CN106566439A true CN106566439A (en) | 2017-04-19 |
Family
ID=58535750
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CN201610960796.4A Pending CN106566439A (en) | 2016-10-28 | 2016-10-28 | Hectorite-cardanol composite hot melt butyl sealant used for hollow glass, and preparation method thereof |
Country Status (1)
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CN (1) | CN106566439A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110724476A (en) * | 2019-11-12 | 2020-01-24 | 湖南省和祥润新材料有限公司 | Butyl hot melt adhesive and production process thereof |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101805569A (en) * | 2009-10-23 | 2010-08-18 | 郑州中原应用技术研究开发有限公司 | Transparent butyl hot-melt sealant and preparation method thereof |
CN102399521A (en) * | 2010-09-17 | 2012-04-04 | 成都硅宝科技股份有限公司 | Hot melt butyl sealant for hollow glass and manufacture method thereof |
CN102504709A (en) * | 2011-10-24 | 2012-06-20 | 杜德升 | Sealing rubber sheet for cavity of hollow glass and processing method thereof |
CN103666331A (en) * | 2013-11-27 | 2014-03-26 | 常熟市赛蒂镶嵌玻璃制品有限公司 | Preparation process for hot-melt butyl sealant for hollow glass |
-
2016
- 2016-10-28 CN CN201610960796.4A patent/CN106566439A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101805569A (en) * | 2009-10-23 | 2010-08-18 | 郑州中原应用技术研究开发有限公司 | Transparent butyl hot-melt sealant and preparation method thereof |
CN102399521A (en) * | 2010-09-17 | 2012-04-04 | 成都硅宝科技股份有限公司 | Hot melt butyl sealant for hollow glass and manufacture method thereof |
CN102504709A (en) * | 2011-10-24 | 2012-06-20 | 杜德升 | Sealing rubber sheet for cavity of hollow glass and processing method thereof |
CN103666331A (en) * | 2013-11-27 | 2014-03-26 | 常熟市赛蒂镶嵌玻璃制品有限公司 | Preparation process for hot-melt butyl sealant for hollow glass |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110724476A (en) * | 2019-11-12 | 2020-01-24 | 湖南省和祥润新材料有限公司 | Butyl hot melt adhesive and production process thereof |
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Application publication date: 20170419 |
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