CN205973910U - Reduce equipment of aquatic deuterium content - Google Patents

Reduce equipment of aquatic deuterium content Download PDF

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Publication number
CN205973910U
CN205973910U CN201620111978.XU CN201620111978U CN205973910U CN 205973910 U CN205973910 U CN 205973910U CN 201620111978 U CN201620111978 U CN 201620111978U CN 205973910 U CN205973910 U CN 205973910U
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water
deuterium
ion
electrode
electrode unit
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CN201620111978.XU
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罗烈明
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FUJIAN FANGMING ENVIRONMENTAL TECHNOLOGY Co Ltd
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FUJIAN FANGMING ENVIRONMENTAL TECHNOLOGY Co Ltd
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Abstract

The utility model discloses an equipment of deuterium content among the reduction natural water, including the electrochemical reaction device, this electrochemical reaction device includes that electrode unit and electricity meet the electrical unit of electrode unit, and this electrode unit includes positive pole and negative pole, and this electrode unit enables water and takes place electrochemical reaction to can produce the OH free radical at the positive pole, can produce H ion and D ion at the negative pole, the H ion is changeed than D ion and is weighed the essential water with the OH free radical, and it has D ion proper motion composite reaction to generate deuterium gas and break away from the water to make, in order to reduce aquatic deuterium content. It has following advantage: making the deuterium content in the water reduce through appearing deuterium gas, can further reducing to low deuterium -oxide, equipment is simple, easy accuse, and the energy consumption is low, and the water consumption is hanged down, draws with low costsly, has still remain human essential mineral substance and the microelement who carries moreover in the water among the natural water, can prepare out the high -quality drinking water of health.

Description

The equipment of deuterium content in a kind of reduction water
Technical field
The utility model is related to a kind of equipment reducing deuterium content in Natural Water.
Background technology
Deuterium is the isotope of hydrogen, is the core material of thermofusion reaction.Because of the many neutrons of D-atom core internal ratio protium therefore deuterium Atomic molar ratio protium is big, is 2.014.Deuterium-oxide is widely present in natural water, and in neve scenery with hills and waters, amount containing deuterium is 130-135ppm (matter Amount content is 0.013-0.0135%), in the natural water of plains region, amount containing deuterium is 150ppm, and coastal area amount containing deuterium is slightly higher, leans on Nearly equator and region of the equator are 155ppm.The water that amount containing deuterium is less than 135ppm is referred to as low deuterium-oxide DDW or depleted water, according to numerous Medical research proves, low deuterium-oxide has the effect of inhibition cancer cell growth, is a kind of high-quality healthy drinking water, therefore reduces in water Amount containing deuterium in deuterium content, especially drinking water is highly beneficial to human body.
In existing reduction water, the method for deuterium content or the preparation method of low deuterium-oxide mainly have:Freezing method, rectification method, electrolysis Several with exchange process etc..
Freezing method:Using the deuterium-oxide principle different from protium water freezing point, by controlling the freezing point of natural water come from natural water Isolate deuterium-oxide, by isolating the amount containing deuterium in deuterium-oxide reduction water, but affected to lead to freezing point by many factors such as temperature, air pressure Control extremely difficult, water consumption is big, high cost, therefore is difficult to practical application.
Rectification method:Using the deuterium-oxide principle different from protium water boiling point, by controlling evaporating temperature by the protium water in natural water Evaporate, to prepare low deuterium-oxide, this method is universal method in the market to the protium water that then condensation evaporation falls again, but equipment Precision prescribed is high, and equipment is complicated, and power consumption is big, high cost, controls difficulty big, water consumption is big.And this method also there are as follows not Foot:The low deuterium-oxide produced be distillation after low deuterium-oxide although there is the advantage of low deuterium but simultaneously also by the mineral matter in water and people Body necessary trace element rectifying totally, is drunk for a long time and is not had mineral matter and the low deuterium-oxide of trace element that health can be produced Harmful effect.
Electrolysis:It is easier to be enriched with electrode and be electrolyzed to produce the principle of protium gas using protium ion, in electricity price lower ground Area it be widely adopted in produce deuterium-oxide.The method is to be electrolysed Natural Water with output protium gas and oxygen, and collection protium gas and oxygen are simultaneously It is allowed to reaction and produce protium water.This equipment requirement precision is also high, and equipment is complicated, and power consumption is big, controls difficulty big, water consumption is big, becomes This height, does not contain mineral matter and trace element in low deuterium-oxide.
Exchange process:Reacted using the hydrogen in compound and generate the side that hydrogen generates depleted water again with oxygen reaction Method, because accessory substance is extremely many and difficult to reach environmental requirement, therefore the method is only used for industrial circle.
Utility model content
The utility model provides the equipment reducing deuterium content in Natural Water, which overcomes in background technology and contains in reduction water Deficiency existing for deuterium amount.
The utility model solves being employed technical scheme comprise that of its technical problem:
The equipment of deuterium content in a kind of reduction water, including electrochemical reaction appts and body, this electrochemical reaction appts bag Including one can make water that the electrode unit of electrochemical reaction and the power subsystem of an electric receiving electrode unit occur, and this body is provided with for supplying The runner that current flow through, this electrode unit inserts in the runner of body, and this electrode unit includes producing the sun of OH free radical Pole and H ion and D ion can be produced and the reaction of D ion energy self assemble generates deuterium depart from water body to reduce deuterium content in water Negative electrode.
Among one embodiment:This anode adopts the material of catalytic low analysis oxygen;This negative electrode adopts the low liberation of hydrogen of catalytic Material.
Among one embodiment:This anode selects DSA electrode, outer painting precious metal oxide coating electrode, noble metal electrode, conjunction Gold electrode or non-metal electrode;
This negative electrode is selected in titanium, tantalum, niobium, zirconium, the electrode of vanadium, molybdenum or tungsten or titanium, tantalum, niobium, zirconium, vanadium, molybdenum or tungsten at least The alloy electrode of two kinds of mixing.
Among one embodiment:Also include exhaust apparatus, this exhaust apparatus connect runner delivery port, by exhaust apparatus from The gas including deuterium is discharged in water body.
Among one embodiment:Also include water receiver, this water receiver connects the discharge outlet of exhaust apparatus.
Among one embodiment:This anode and negative electrode all adopt platy structure and parallel interval, and this interval pitch is 0.5mm- 5mm.
Compared with background technology, it has the advantage that the technical program:
Electrode unit can make water occur electrochemical reaction, so that OH free radical can be produced in anode, negative electrode can produce H from Son and D ion, H ion ratio D ion is more easy to reassemble into water with OH free radical so that there being D ion self assemble to react generation deuterium Gas simultaneously separates out, and by separating out deuterium gas, the deuterium content in water body is reduced, and can be further reduced to low deuterium-oxide, equipment letter Single, easily-controllable, energy consumption is low, and water consumption is low, and extraction cost is low, and also retains carry in Natural Water needed by human in water body Mineral matter and trace element, can prepare a kind of health drink water.
Brief description
The utility model is described in further detail with reference to the accompanying drawings and examples.
Fig. 1 is the structural representation reducing the equipment of deuterium content in Natural Water.
Specific embodiment
Refer to Fig. 1, the equipment of deuterium content in a kind of reduction Natural Water, including electrochemical reaction appts 10, body 20, row Device of air 30, water receiver 40.
This body 20 is used for flowing through for current, is provided with the runner for flowing through for current, such as electrolytic cell.The present embodiment with As a example electrolytic cell but be not limited to electrolytic cell, as long as other structure can flow through for current or water, and can power pole unit insertion, Electrode unit contact water can be made.This body is such as adopted and is made from an insulative material.
This electrochemical reaction appts 10 includes electrode unit and the power subsystem 11 of electric receiving electrode unit, this electrode unit bag Include anode 12 and negative electrode 13.
This anode 12 adopts the material of high catalytic property low analysis oxygen (having the high characteristic of overpotential for oxygen evolution), this high catalytic property Low analysis oxygen refers to have and generates the ability of elctro-catalyst and be difficult to be reduced into oxygen can capture 1 electronics and make it generate from OH- The OH free radical escaping, therefore electrolysis nature water energy make anode 12 surrounding be enriched with OH free radical.This negative electrode 13 is urged using height The material of the low liberation of hydrogen of the property changed, the low liberation of hydrogen of this high catalytic property refers to that can adsorb or be enriched with H+ in electrolytic process makes it be difficult to reduce Hydrogen is become to escape, therefore electrolysis nature water energy makes negative electrode 13 ambient absorption or enrichment H ion and D ion.
This anode 12 as from DSA electrode, outer painting precious metal oxide coating electrode, noble metal electrode, alloy electrode or Non-metal electrode;This applies outward precious metal oxide coating electrode such as Ti, Ru, Ir, Sn, Pt, Pd oxide coating electrode, specifically such as Titanium-based Pt oxide coating electrode, titanium-based Pd oxide coating electrode etc.;This noble metal electrode noble metal such as such as Pt, Pd, Ir, Ru Electrode;This non-metal electrode such as carbon, graphite electrode.Above-mentioned enumerating is not intended to limit the electrode that anode 12 is adopted, according to As long as needing the electrode with electrocatalysis characteristic (OH- hydroxyl radical free radical can be produced) all can be set to anode.
This negative electrode 13 is as from Ti electrode, tantalum electrode, niobium electrode, zirconium electrode, vanadium electrode, molybdenum electrode or tungsten electrode, this row Lift and be not intended to limit the electrode that negative electrode 13 is adopted, as long as high catalytic property low liberation of hydrogen material is made as needed.
This power subsystem 11 adopts direct-current switch power supply, but is not limited to direct-current switch power supply, other such as pulse dc powers, The dc sources such as all-wave silicon commutating power supply are also applicable in the utility model.
The electrode of this anode 12 and negative electrode 13 all adopts arranged in parallel between panel construction and electrode and electrode, to improve precipitation Deuterium efficiency.This panel construction is such as surface plate, cambered plate, curved slab etc..This anode and the alternately arranged arrangement of negative electrode, make anode It is all positioned opposite with negative electrode, this anode 12 and negative electrode 14 interval pitch are 0.5mm-5mm, preferably with 0.5mm-3mm, but not Be limited to this distance, certain electrode be also not necessarily limited to plane, electrode arrangement be also not necessarily limited to arranged in parallel, as long as natural water current from sun Flow through between pole and negative electrode and electrochemical reaction occurs.
The anode 12 of this electrode unit and negative electrode 13 insert in the current of runner of body 20, as anode 12 and negative electrode 13 Abut against body 20 inwall to face respectively so that current through flowing through between anode and negative electrode and can occur electrochemical reaction opposite to each other, with OH free radical can be produced in anode 12 and be enriched with around anode 12, H ion and D ion can be produced and in negative electrode in negative electrode 13 13 surrounding enrichments.
Because H ion (protium ion) adsorbs and be difficult to be reduced effusion in negative electrode 13 enrichment, OH free radical is rich in anode 12 Collection adsorbs and is difficult to be precipitated oxygen, and therefore this is that the two recombining reaction provides adequate condition so that H ion and OH are free Base can form rapidly light-water.Because D ion (deuterium ion) quality is the twice of protium mass of ion, deuterium ion speed of separating out is made to be slower than protium Elemental release speed, makes the ability of the OH ion of deuterium ion contention be less than protium ion, so that H ion ratio D ion is more easy to and OH Free radical reassembles into water, and because D ion (deuterium ion) is also enriched with absorption in negative electrode 13, therefore the deuterium ion meeting self assemble of enrichment is anti- D2 (deuterium) should be generated and separate out from negative electrode, bubbing departs from water body and constitutes the gas containing deuterium, also can in this gas It is mixed with hydrogen, the oxygen of precipitation, depart from the water body after gas, reduce deuterium content in water, low deuterium-oxide can be prepared.
This exhaust apparatus 30 connector body 20 is used for discharging the gas separating out in water, and its structure is as solid in included shell 31 and It is contained in the filter membrane air-stopper 32 in shell 31, this shell 31 is connected to the delivery port of body 20 by pipeline, this shell 31 top It is provided with exhaust outlet, this shell 31 bottom is provided with discharge outlet.The water that should discharge from the delivery port of body 20 flows through filter membrane air-stopper 32, So that the gas in water is departed from and gas goes out to discharge from exhaust outlet, the water having discharged gas is arranged through discharge outlet Go out, in this water body, reduced deuterium content.Among the present embodiment, this exhaust apparatus 30 adopts filter membrane air-stopper 32 structure, according to need As long as other structures be may also be employed enable aqueous vapor separating.This water receiver 40 connects the discharge outlet of exhaust apparatus 30.This Embodiment is taking arrange water receiver as a example, but also can not set water receiver as needed, such as directly will be located in water route so that this device Constitute the part in water route so that the current flowing through in water route all play the effect reducing containing deuterium amount, this water receiver as needed Also can directly be set to device, electrode unit be inserted in water receiver and realizes reducing deuterium content effect by separating out deuterium.
As needed, may also include timing unit, this timing unit is used for control and is collected from what electrochemical reaction had started Gas in the 1-60 second, such as includes a valve being arranged on the exhaust outlet of extraction element, this timing unit control valve is in electricity It is in open mode, remaining time closes in the 1-60 second that chemical reaction has started.Certainly, this timing unit also can connect power supply by electricity Unit, for controlling power subsystem to close power supply after the 1-60 second that electrochemical reaction has started.Or, as needed, also wrap Include water flow control mechanism, the time that water flow control mechanism is used for controlling current to flow through electrode unit is the 1-60 second.
In the present embodiment, every square metre of current density adopts 3-20 to pacify, but is not limited to this current density, because any electric current Density all can produce deuterium, simply efficiency difference.
The method reducing deuterium content in water, including:
Step 1, electrode unit makes water that electrochemical reaction to occur, and can produce OH free radical in anode, can produce in negative electrode Raw H ion and D ion;
Step 2, H ion ratio D ion is more easy to reassemble into water with OH free radical so that there being D ion self assemble to react life Become deuterium and separate out;
Step 3, makes the gas including deuterium flow through exhaust apparatus so that the gas in water body escapes, the water of emergent gas Body reduces deuterium content in water.
As for filling in the device of water, then collected the gas within the 1-60 second from electrochemical reaction starts that negative electrode separates out Body or control electro-catalysis time are in the 1-60 second.As for flowing through in the device of electrode unit:This step 1 controls current to flow through electrode The time of unit is the 1-60 second.Above-mentioned time optimal is the 5-60 second.
Electrochemical reaction leading portion (in the short time of initial period) both completed separate out deuterium reaction reach as high as 85% with On, just enter analysis (hydrogen) (protium) phase, deuterium and protium gas eutectoid afterwards, but deuterium content ratio tends to 0, when reacting in the present embodiment Between be about 60 seconds within, but not limited to this reaction time.
The above, only the utility model preferred embodiment, therefore the utility model enforcement can not be limited according to this Scope, the equivalence changes made according to the utility model the scope of the claims and description and modification, all should still belong to this practicality new In the range of type covers.

Claims (4)

1. a kind of reduce water in deuterium content equipment it is characterised in that:Including electrochemical reaction appts and body, this electrochemistry is anti- Answering device to include one can make water that the electrode unit of electrochemical reaction and the power subsystem of an electric receiving electrode unit occur, and this body sets There is the runner flowing through for the stream that supplies water, this electrode unit inserts in the runner of body, this electrode unit includes to produce OH certainly By the anode of base with H ion and D ion can be produced and the reaction of D ion energy self assemble generates deuterium depart from water body to reduce water The negative electrode of middle deuterium content.
2. according to claim 1 a kind of reduce water in deuterium content equipment it is characterised in that:This anode adopts catalytic The material of low analysis oxygen;This negative electrode adopts the material of the low liberation of hydrogen of catalytic.
3. according to claim 1 a kind of reduce water in deuterium content equipment it is characterised in that:Also include water receiver, should Water receiver connects the discharge outlet of exhaust apparatus.
4. according to claim 1 a kind of reduce water in deuterium content equipment it is characterised in that:This anode and negative electrode are all adopted With platy structure and parallel interval, this interval pitch is 0.5mm-5mm.
CN201620111978.XU 2016-02-04 2016-02-04 Reduce equipment of aquatic deuterium content Active CN205973910U (en)

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Application Number Priority Date Filing Date Title
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109044047A (en) * 2018-08-20 2018-12-21 安徽国科生物科技有限公司 A kind of low deuterium preserving cup of dechlorination hydrogen-rich richness light electrolysis
CN109171381A (en) * 2018-08-20 2019-01-11 安徽国科生物科技有限公司 A kind of dechlorination hydrogen-rich mineralising is electrolysed low deuterium health water cup

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109044047A (en) * 2018-08-20 2018-12-21 安徽国科生物科技有限公司 A kind of low deuterium preserving cup of dechlorination hydrogen-rich richness light electrolysis
CN109171381A (en) * 2018-08-20 2019-01-11 安徽国科生物科技有限公司 A kind of dechlorination hydrogen-rich mineralising is electrolysed low deuterium health water cup

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