CN109321938A - A kind of ozone generator - Google Patents

A kind of ozone generator Download PDF

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Publication number
CN109321938A
CN109321938A CN201811441052.7A CN201811441052A CN109321938A CN 109321938 A CN109321938 A CN 109321938A CN 201811441052 A CN201811441052 A CN 201811441052A CN 109321938 A CN109321938 A CN 109321938A
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CN
China
Prior art keywords
anode
cathode
frame plate
ozone generator
plate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811441052.7A
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Chinese (zh)
Inventor
王达
牛振兴
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Shenzhen Kangcheng Boxin Technology Co Ltd
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Shenzhen Kangcheng Boxin Technology Co Ltd
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Application filed by Shenzhen Kangcheng Boxin Technology Co Ltd filed Critical Shenzhen Kangcheng Boxin Technology Co Ltd
Priority to CN201811441052.7A priority Critical patent/CN109321938A/en
Publication of CN109321938A publication Critical patent/CN109321938A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00Electrolytic production of inorganic compounds or non-metals
    • C25B1/01Products
    • C25B1/13Ozone
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/17Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
    • C25B9/19Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Abstract

The present invention provides a kind of ozone generator, including anode stream body cavity, anode frame frame plate, membrane electrode assembly, cathode frame plate, the anode side of the membrane electrode assembly is arranged in the anode stream body cavity and the anode frame frame plate, the cathode side of the membrane electrode assembly is arranged in the cathode frame plate, the anode frame frame plate is electrically connected the anode side of the membrane electrode assembly, the cathode frame plate is electrically connected the cathode side of the membrane electrode assembly, the anode stream body cavity has the fluid outlet channels and a fluid inlet channel in lower opening of a upward opening, the cathode frame plate has venthole.When ozone generator of the invention makes electrolysis water produce ozone, cathode no longer generates hydrogen, eliminates security risk, improves safety.

Description

A kind of ozone generator
Technical field
The present invention relates to electrolytic method ozone fields.
Background technique
Ozone is a kind of gas with strong oxidizing property.Ozone is in sterilizing field, sewage treatment field, and tap water is net Change field, air purification field are all widely used.Safety is ensured when how efficiently quickly to produce ozone, is production ozone A problem.
Traditionally, ionized air method can be used by preparing ozone.It enables air flow through the electric arc of electrion, makes in air Oxygen generate ozone because of ionization.The significant drawback of this method is to generate to have virose oxides of nitrogen gas.
It is the ozone preparation method that recent decades developed that electrolysis water method, which prepares ozone,.This method generally uses one A amberplex keeps apart the cathode and anode for electrolysis, is electrolysed pure water under the effect of the catalyst, generates anode Ozone gas, cathode generate hydrogen.Ozone equipment is prepared using the electrolysis water of this technology, there is a membrane electrode assembly, and The anode stream body cavity of the membrane electrode assembly anode side and the cathode fluid chamber of cathode side are set.Anode stream body cavity have to The gas vent of upper opening and downwardly open liquid-inlet form anode stream body cavity and extraneous anode fluid reservoir stable Fluid circulation.Cathode fluid chamber also has the gas vent and downwardly open liquid-inlet of upward opening, makes cathode fluid chamber Stable fluid circulation is formed with extraneous cathode fluid reservoir.Although this method overcomes ionized air method and generates nitrogen oxidation The problem of object, has obtained dense ozone gas in anode, but due to producing hydrogen at cathode, has still deposited to safety In potential risk.
Summary of the invention
To solve the above problems, the present invention provides a kind of ozone generator, it is intended to solve electrolysis water method and prepare ozone to deposit The byproduct hydrogen the problem of.
A kind of ozone generator, including anode stream body cavity, anode frame frame plate, membrane electrode assembly, cathode frame plate, the sun The anode side of the membrane electrode assembly is arranged in pole fluid cavity and the anode frame frame plate, and the cathode frame plate is arranged in institute The cathode side of membrane electrode assembly is stated, the anode frame frame plate is electrically connected the anode side of the membrane electrode assembly, the cathode Frame plate is electrically connected the cathode side of the membrane electrode assembly, and the anode stream body cavity has the fluid outlet of a upward opening Channel and a fluid inlet channel in lower opening, the cathode frame plate have venthole.
Further, the membrane electrode assembly includes the cathode electrode of the anode electrode of sheet, sheet, and is clipped in the sun PEM proton exchange membrane between pole electrode and cathode electrode.
Further, the anode electrode is lead dioxide electrode.
Further, the anode electrode is platinum carbon resistance rod.
Further, the cathode electrode is carbon resistance rod.
Further, the cathode electrode is platinum carbon resistance rod.
Further, anode collector plate is provided between the anode frame frame plate and the anode electrode.
Further, the anode collector plate is POROUS TITANIUM PLATE.
Further, cathode collector plate is provided between the cathode frame plate and the cathode electrode.
Further, the cathode collector plate is POROUS TITANIUM PLATE or porous stainless steel plate.
Detailed description of the invention
Attached drawing 1 is one embodiment schematic diagram of ozone generator of the invention.
Attached drawing 2 is the Structure explosion diagram of one embodiment of ozone generator of the invention.
Attached drawing 3 is second embodiment schematic diagram of ozone generator of the invention.
Attached drawing 4 is the Structure explosion diagram of second embodiment of ozone generator of the invention.
Attached drawing 5 is the third embodiment schematic diagram of ozone generator of the invention.
Attached drawing 6 is the Structure explosion diagram of the third embodiment of ozone generator of the invention.
Specific embodiment
Present invention will be described in further detail below with reference to the accompanying drawings, to enable those skilled in the art referring to specification text Word can be implemented accordingly.
Electrolysis water method prepares ozone gas, and gas generates position and is electrolysis electrode, for increase it is conductive improve yield, two Electrode should be apart from close.In order to which the product of cathode anode is isolated, using PEM proton exchange membrane to anode electrode and cathode electrode It is isolated, fits closely anode electrode, PEM proton exchange membrane, cathode electrode this three together, collectively constitute membrane electrode Component.
The reaction that anode occurs are as follows:
3H2O→O3+ 6e-+ 6H+
2H2O→O2+ 4e-+ 4H+
Anode uses brown lead oxide as electrode material, or using platinum charcoal as electrode material.
In the reaction that anode occurs, hydrone loses hydrogen atom therein, combines between the oxygen atom left and generates ozone And oxygen.In this process, the gas that anode generates should quickly leave electrode, make to be electrolysed the lasting leaching of raw water molecule Steep anode electrode.To collect the gas of anode rationally, the fluid cavity with upper and lower opening is arranged in anode, and reaction generates Gas be discharged upwards, while some water also by gas push move upwards, make anode fluid it is intracavitary formed one lower section into The flow fields environment of water, top water outlet outlet.
The reaction that cathode occurs are as follows:
O2+ 4e-+ 4H+ →2H2O
Cathode uses charcoal as electrode material, or using platinum charcoal as electrode material.
The hydrogen atom lost in anode reaction passes through PEM proton exchange membrane under electric field action and reaches cathode electrode, and outer Oxygen reduction reaction occurs for the oxygen that boundary provides, and regenerates water.Oxygen reduction reaction occurs in cathode, the oxygen needed can be direct It is provided by air.Water a part generated evaporates, and a part collects downwards drippage.Since the aquatic products amount that it is generated is few, no It needs to be arranged special fluid cavity and collects product.
Individual membrane electrode assembly, its own intensity are not sufficient to that self structure is supported to stablize, and other structures is needed to cooperate, Therefore it needs that an anode frame frame plate is arranged in anode, one cathode frame plate, two frame plate shareds is set in cathode Play structural support effect.Anode frame frame plate and cathode frame plate will can be conductive.
To enable the electrode of planar sheet uniformly to obtain electric energy, a collector plate is set between frame plate and electrode. The electric conductivity that this collector plate needs to have outstanding, outstanding ventilation, water flowing performance and outstanding corrosion resistance.Sun Anode collector plate between pole frame plate and anode electrode, is made of POROUS TITANIUM PLATE, and is handled using passivation technology.Cathode frame Cathode collector plate between frame plate and cathode electrode, is made of POROUS TITANIUM PLATE, can also be made of porous stainless steel plate.
Specifically, a preferred embodiment structure of ozone generator of the invention is referring to attached drawing 1 and attached drawing 2.Membrane electrode Component 1 by the anode electrode 101 of sheet, PEM proton exchange membrane 100, sheet cathode electrode 102 be close together combination and At.Membrane electrode assembly 1 is placed vertically.Anode electrode 101 passes through 201 jointed anode frame plate 2 of anode collector plate.Cathode electrode 102 connect cathode frame plate 3 by cathode collector plate 301.One layer of sealing of intermediate folder of anode frame frame plate 2 and membrane electrode assembly 1 The centre of pad 5, cathode frame plate 3 and membrane electrode assembly 1 also presss from both sides one layer of gasket 5, clamps membrane electrode between this two panels gasket 5 Component 1.The outside of anode frame frame plate 2 is also connected with anode stream body cavity 202, and anode stream body cavity 202 has the stream being open upwards Body exit passageway 2021 and fluid inlet channel 2022 in lower section.Cathode frame plate 3 corresponds at 301 position of cathode collector plate With multiple ventholes 302, cathode collector plate 301 is enable directly to contact outside air.In the present embodiment, anode frame frame plate 2 have multiple pore structures, and the fluid in anode stream body cavity 202 is enable to directly contact anode collector plate 201.Entire ozone hair Raw device carries out assembly fixation using four fastening bolts 4.
Another preferred embodiment structure of ozone generator of the invention is referring to attached drawing 3 and attached drawing 4.Membrane electrode assembly 1 It is close together and is composed by the cathode electrode 102 of the anode electrode 101 of sheet, PEM proton exchange membrane 100, sheet.Film electricity Pole component 1 is placed vertically.Anode electrode 101 is by anode collector plate 201 and joins 203 jointed anode frame plate 2 of electric bracket.Cathode Electrode 102 connects cathode frame plate 3 by cathode collector plate 301.In the present embodiment, anode stream body cavity 202 is arranged in anode The inside of frame plate 2, i.e. anode stream body cavity 202 are clipped between anode frame frame plate 2 and membrane electrode assembly 1.In anode stream body cavity 202 It is interior, join electric 203 connection anode collector plate 201 of bracket and anode frame frame plate 2.In the present embodiment, anode frame frame plate 2 is outermost Side, because without multiple open-celled structures.Anode stream body cavity 202 and the intermediate of membrane electrode assembly 1 press from both sides one layer of gasket 5, cathode The centre of frame plate 3 and membrane electrode assembly 1 also presss from both sides one layer of gasket 5, clamps membrane electrode assembly 1 between this two panels gasket 5.? Also there is one layer of gasket 5 in the present embodiment, between anode frame frame plate 2 and anode stream body cavity 202.Anode stream body cavity 202 have to The fluid outlet channels 2021 of upper opening and fluid inlet channel 2022 in lower section.Cathode frame plate 3 corresponds to cathode collection There are multiple ventholes 302 at 301 position of battery plate, cathode collector plate 301 is enable directly to contact outside air.
Another preferred embodiment structure of ozone generator of the invention is referring to attached drawing 5 and attached drawing 6.Membrane electrode assembly 1 It is close together and is composed by the cathode electrode 102 of the anode electrode 101 of sheet, PEM proton exchange membrane 100, sheet.Film electricity Pole component 1 is horizontal positioned, and the upward cathode of anode is downward.Anode electrode 101 passes through 201 jointed anode frame plate 2 of anode collector plate. Cathode electrode 102 connects cathode frame plate 3 by cathode collector plate 301.The intermediate folder of anode frame frame plate 2 and membrane electrode assembly 1 The centre of one layer of gasket 5, cathode frame plate 3 and membrane electrode assembly 1 also presss from both sides one layer of gasket 5, presss from both sides between this two panels gasket 5 Tight membrane electrode assembly 1.The outside of anode frame frame plate 2 is also connected with anode stream body cavity 202, and anode stream body cavity 202 has upwards The fluid outlet channels 2021 of opening and fluid inlet channel 2022 in lower section side.Cathode frame plate 3 corresponds to cathode collection There are multiple ventholes 302 at 301 position of battery plate, cathode collector plate 301 is enable directly to contact outside air.In the present embodiment In, anode frame frame plate 2 has multiple pore structures, and the fluid in anode stream body cavity 202 is enable to directly contact anode collector plate 201.Entire ozone generator carries out assembly fixation using four fastening bolts 4.
Ozone generator of the invention, when use, only need to establish the liquid circulation of anode i.e. with an anode water tank 6 It can.In actual use, cathode is connected to air, and oxygen reduction reaction occurs, and the oxygen in consumed cabin air generates water.Those skilled in the art Member's disclosed information according to the present invention, can make the similar modification of structure, therefore without departing substantially from claim and equivalent Under universal defined by range, the present invention is not limited to specific details and the legend herein shown with description.

Claims (10)

1. a kind of ozone generator, including anode stream body cavity, anode frame frame plate, membrane electrode assembly, cathode frame plate, the anode The anode side of the membrane electrode assembly is arranged in fluid cavity and the anode frame frame plate, and the cathode frame plate is arranged described The cathode side of membrane electrode assembly, the anode frame frame plate are electrically connected the anode side of the membrane electrode assembly, the cathode frame Frame plate is electrically connected the cathode side of the membrane electrode assembly, and the anode stream body cavity has the fluid outlet of a upward opening logical Road and a fluid inlet channel in lower opening, the cathode frame plate have venthole.
2. ozone generator as described in claim 1, which is characterized in that the membrane electrode assembly includes the anode electricity of sheet Pole, sheet cathode electrode, and the PEM proton exchange membrane being clipped between the anode electrode and cathode electrode.
3. ozone generator as described in claim 1, which is characterized in that the anode electrode is lead dioxide electrode.
4. ozone generator as described in claim 1, which is characterized in that the anode electrode is platinum carbon resistance rod.
5. ozone generator as described in claim 1, which is characterized in that the cathode electrode is carbon resistance rod.
6. ozone generator as described in claim 1, which is characterized in that the cathode electrode is platinum carbon resistance rod.
7. ozone generator as described in claim 1, which is characterized in that between the anode frame frame plate and the anode electrode It is provided with anode collector plate.
8. ozone generator as claimed in claim 7, which is characterized in that the anode collector plate is POROUS TITANIUM PLATE.
9. ozone generator as described in claim 1, which is characterized in that between the cathode frame plate and the cathode electrode It is provided with cathode collector plate.
10. ozone generator as claimed in claim 9, which is characterized in that the cathode collector plate is POROUS TITANIUM PLATE or porous Stainless steel plate.
CN201811441052.7A 2018-11-29 2018-11-29 A kind of ozone generator Pending CN109321938A (en)

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Application Number Priority Date Filing Date Title
CN201811441052.7A CN109321938A (en) 2018-11-29 2018-11-29 A kind of ozone generator

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111575734A (en) * 2020-05-07 2020-08-25 浙江高成绿能科技有限公司 Cathode oxygen reduction ozone generator and using method thereof
CN114134525A (en) * 2021-12-30 2022-03-04 深圳康诚博信科技有限公司 Quick assembly disassembly structure of ozone generator
CN114182274A (en) * 2021-12-30 2022-03-15 深圳康诚博信科技有限公司 Ozone generation and transmission device designed without water pipe
WO2022072763A1 (en) * 2020-10-01 2022-04-07 Dentsply Sirona Inc. Manifold compatible electrolytic cell (eo cell) with coplanar fluidic and electrical connection scheme
CN114293211A (en) * 2021-12-30 2022-04-08 深圳康诚博信科技有限公司 Ozone generator with quick-dismounting structure and preparation method of cathode prefabricated film of ozone generator
CN114470289A (en) * 2021-12-30 2022-05-13 深圳康诚博信科技有限公司 Ozone disinfection machine

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01123086A (en) * 1987-11-05 1989-05-16 Japan Storage Battery Co Ltd Electrochemical ozone generator
US20040031761A1 (en) * 2000-09-29 2004-02-19 Maja Wunsche Device for electrolytic water disinfection without cathodic hydrogen evolution
KR20050081865A (en) * 2004-12-22 2005-08-19 박상길 An onside type generating device for hydrogen peroxide and providing device for hydrogen peroxide
US20090008261A1 (en) * 2005-03-03 2009-01-08 Cambridge Enterprise Limited Oxygen Generation Apparatus and Method
CN101967650A (en) * 2010-10-11 2011-02-09 无锡国赢科技有限公司 Self-breathing electrochemical pure oxygen generation assembly
CN209338667U (en) * 2018-11-29 2019-09-03 深圳康诚博信科技有限公司 A kind of ozone generator

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01123086A (en) * 1987-11-05 1989-05-16 Japan Storage Battery Co Ltd Electrochemical ozone generator
US20040031761A1 (en) * 2000-09-29 2004-02-19 Maja Wunsche Device for electrolytic water disinfection without cathodic hydrogen evolution
KR20050081865A (en) * 2004-12-22 2005-08-19 박상길 An onside type generating device for hydrogen peroxide and providing device for hydrogen peroxide
US20090008261A1 (en) * 2005-03-03 2009-01-08 Cambridge Enterprise Limited Oxygen Generation Apparatus and Method
CN101967650A (en) * 2010-10-11 2011-02-09 无锡国赢科技有限公司 Self-breathing electrochemical pure oxygen generation assembly
CN209338667U (en) * 2018-11-29 2019-09-03 深圳康诚博信科技有限公司 A kind of ozone generator

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111575734A (en) * 2020-05-07 2020-08-25 浙江高成绿能科技有限公司 Cathode oxygen reduction ozone generator and using method thereof
WO2022072763A1 (en) * 2020-10-01 2022-04-07 Dentsply Sirona Inc. Manifold compatible electrolytic cell (eo cell) with coplanar fluidic and electrical connection scheme
CN114134525A (en) * 2021-12-30 2022-03-04 深圳康诚博信科技有限公司 Quick assembly disassembly structure of ozone generator
CN114182274A (en) * 2021-12-30 2022-03-15 深圳康诚博信科技有限公司 Ozone generation and transmission device designed without water pipe
CN114293211A (en) * 2021-12-30 2022-04-08 深圳康诚博信科技有限公司 Ozone generator with quick-dismounting structure and preparation method of cathode prefabricated film of ozone generator
CN114470289A (en) * 2021-12-30 2022-05-13 深圳康诚博信科技有限公司 Ozone disinfection machine
CN114293211B (en) * 2021-12-30 2023-09-05 深圳康诚博信科技有限公司 Ozone generator with rapid disassembly and assembly structure and preparation method of cathode prefabricated film of ozone generator
CN114470289B (en) * 2021-12-30 2023-09-26 深圳康诚博信科技有限公司 Ozone sterilizer
CN114134525B (en) * 2021-12-30 2023-10-03 深圳康诚博信科技有限公司 Quick assembly disassembly structure of ozone generator
CN114182274B (en) * 2021-12-30 2023-12-12 深圳康诚博信科技有限公司 Ozone generation and transmission device with design of anhydrous pipe

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