CN205803325U - A kind of gray coated glass - Google Patents

A kind of gray coated glass Download PDF

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Publication number
CN205803325U
CN205803325U CN201620775872.XU CN201620775872U CN205803325U CN 205803325 U CN205803325 U CN 205803325U CN 201620775872 U CN201620775872 U CN 201620775872U CN 205803325 U CN205803325 U CN 205803325U
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China
Prior art keywords
layer
glass
silicon nitride
coated glass
nitride sinx
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Active
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CN201620775872.XU
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Chinese (zh)
Inventor
李勇
黄成龙
李建根
邓军
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chengdu CSG Glass Co Ltd
Sichuan CSG Energy Conservation Glass Co Ltd
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Chengdu CSG Glass Co Ltd
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Priority to CN201620775872.XU priority Critical patent/CN205803325U/en
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Abstract

This utility model relates to coating film on glass technical field, is specifically related to a kind of off-line gray coated glass.This glass film layers structure is followed successively by: glass substrate, ground floor silicon nitride SiNx layer, second layer nichrome NiCr layer, third layer silicon nitride SiNx layer, the 4th layer of nichrome NiCr layer and layer 5 silicon nitride SiNx layer.The transmitance of the gray coated glass that this utility model provides is 43 45%, glass surface reflectance is 5.8 6.7%, visible ray chromaticity coordinates is that a* is between 0.5~0.5, b* is between 0.5~1.0, this gray coated glass is muted color through color, there is comfortable visual effect, for building curtain wall, the daylighting of building, aesthetic, power conservation requirement can be met very well.

Description

A kind of gray coated glass
Technical field
This utility model relates to coating film on glass technical field, particularly a kind of off-line Lycoperdon polymorphum Vitt sunlight controlling coated glass.
Background technology
At present, the production of smoked glass is mainly by introducing coloring components or utilizing float glass process in forming at glass basis On-line coating mode realizes.Float glass process smoked glass has certain decoration functions and energy-saving effect due to it, by extensively For building curtain wall, glass door and window and vehicle glass industry.
Chinese patent application CN101462826A discloses Fe2O3、CoO、Se、Er2O3Lycoperdon polymorphum Vitt glass is prepared as coloring agent Glass, its transmitance is between 62%-67%, and surface reflectivity is less than 6.5%.In order to reinforcing glass is to ultraviolet and ultrared Absorb, glass ingredient adds the ferrum of a large amount of proportion.Consequently, it is possible to glass can present blueness or green and transmitance is low Feature, its application is limited.Otherwise, reducing the introducing of ferrum, glass is difficult to again reach preferable energy-saving effect, does not meets modern architecture Energy-saving and cost-reducing theory.
The coloring agent component that mass colouring introduces is many, and ratio is difficult to control to, and manufacturing cycle is long, and efficiency is low.In such as State patent application CN101300201A, its colorant assortment introduced reaches 12 kinds more than, and preparation section includes being dried, adding Heat, anneal, many loaded down with trivial details processes such as cooling, batch production technique is difficult to simplify.
On-line coating refers to the method directly carrying out plated film in former production process of float glass process, and its plated film mode is high-temperature hot Solve spraying film forming.When the spraying coating process that patent CN101003419A is reported needs the temperature of strict control glass surface, atomization Pressure, the flow of spraying and the distance of spraying.Its technique is complex, and cost is high, and involved smoked glass is saturating Rate of crossing is low, reflectance is high, it is difficult to popularization and application.But, the off-line mode of production for smoked glass but rarely has report.
Utility model content
Goal of the invention of the present utility model is: the problem existed for prior art, it is provided that a kind of tone of gray is for visitor The Low-E energy-saving glass product that family selects.
To achieve these goals, the technical solution adopted in the utility model is:
A kind of gray coated glass, it is characterised in that this glass film layers structure is followed successively by: glass substrate, ground floor nitrogenize Silicon SiNx layer, second layer nichrome NiCr layer, third layer silicon nitride SiNx layer, the 4th layer of nichrome NiCr layer and layer 5 Silicon nitride SiNx layer.
As preferred version of the present utility model, described low radiation coated glass uses off-line magnetron sputtering or atomic deposition Technology plated film is made.
As preferred version of the present utility model, the thickness of described ground floor silicon nitride SiNx layer is between 10-30nm.
As preferred version of the present utility model, the thickness of described second layer nichrome NiCr layer is between 5-15nm.
As preferred version of the present utility model, the thickness of described third layer silicon nitride SiNx layer is between 30-45nm.
As preferred version of the present utility model, the thickness of described 4th layer of nichrome NiCr layer is between 5-15nm.
As preferred version of the present utility model, the thickness of described layer 5 silicon nitride SiNx layer is between 6-20nm.
In sum, owing to have employed technique scheme, the beneficial effects of the utility model are:
1, the transmitance of gray coated glass of the present utility model is at 43-45%, glass surface reflectance at 5.8-6.7%, Visible ray chromaticity coordinates be a* between-0.5~0.5, b* is between-0.5~-1.0.
2, gray coated glass of the present utility model through color be muted color, have comfortable visual effect, relatively low u value and Shading coefficient (SC) increases energy-conserving action.
Accompanying drawing explanation
Fig. 1 is structural representation of the present utility model.
Labelling in figure: 1-ground floor silicon nitride SiNx layer, 2-second layer nichrome NiCr layer, 3-third layer silicon nitride SiNx layer, the 4th layer of nichrome NiCr layer of 4-, 5-layer 5 silicon nitride SiNx layer.
Detailed description of the invention
Below in conjunction with the accompanying drawings, this utility model is described in detail.
In order to make the purpose of this utility model, technical scheme and advantage clearer, below in conjunction with accompanying drawing and enforcement Example, is further elaborated to this utility model.Should be appreciated that specific embodiment described herein is only in order to explain this Utility model, is not used to limit this utility model.
This utility model can realize by following technical solution: from the beginning of common float glass process white glass surface, is coated with successively Silicon nitride SiNx film, nichrome NiCr film, silicon nitride SiNx film, nichrome NiCr film, silicon nitride SiNx film, thus constitute The neutral gray coated glass of 5 film structure.
As it is shown in figure 1, use fine vacuum magnetron sputtering technique, using aluminum silicon target, nichrome target as target, argon and nitrogen Gas as work atmosphere, sputtering sedimentation ground floor silicon nitride SiNx film layer 1 successively on the white glass of common float glass process;Second layer nickel chromium triangle closes Gold NiCr film layer 2;Third layer silicon nitride SiNx film layer 3;4th layer of nichrome NiCr film layer 4;Layer 5 silicon nitride SiNx film Layer 5.
On the white glass of above-mentioned float glass process, the thickness of ground floor silicon nitride SiNx film layer is 10-30nm, second layer nichrome NiCr The thickness of film layer is 5-15nm, and the thickness of third layer silicon nitride SiNx film layer is 30-45nm, the 4th layer of nichrome NiCr film layer Thickness be 5-15nm, the thickness of layer 5 silicon nitride SiNx film layer is 6-20nm.
The color of final gray coated glass controls in the range of such as following table one: (L* represents psychology lightness, and a*, b* are Psychometric chroma ,+a* represents red, and-a* represents green, and+b* represents yellow, and-b* represents blue, a*g: the red green journey of reflection light Degree, b*g: the champac degree of reflection light)
Table one this utility model ash glass and float glass process ash glass color contrast
Product Visible light transmissivity L*g a*g b*g
Float glass process ash glass 45.31 4.85 0.31 -0.47
This utility model 43~45 5.8-6.7 -0.5~0.5 -0.5~-1.0
Gray coated glass provided by the utility model, reflectance and reflected colour are consistent, thoroughly with common float glass process ash glass Cross color ratio float glass process ash glass closer to muted color.This glass be used for building curtain wall, can meet very well building daylighting, aesthetic, Power conservation requirement.
The foregoing is only preferred embodiment of the present utility model, not in order to limit this utility model, all at this Any amendment, equivalent and the improvement etc. made within the spirit of utility model and principle, should be included in this utility model Protection domain within.

Claims (7)

1. a gray coated glass, it is characterised in that this glass film layers structure is followed successively by: glass substrate, ground floor silicon nitride SiNx layer, second layer nichrome NiCr layer, third layer silicon nitride SiNx layer, the 4th layer of nichrome NiCr layer and layer 5 nitrogen SiClx SiNx layer.
Gray coated glass the most according to claim 1, it is characterised in that described gray coated glass uses off-line magnetic control Sputtering or atomic deposition technique plated film are made.
Gray coated glass the most according to claim 1, it is characterised in that the thickness of described ground floor silicon nitride SiNx layer Between 10-30nm.
Gray coated glass the most according to claim 1, it is characterised in that the thickness of described second layer nichrome NiCr layer Degree is between 5-15nm.
Gray coated glass the most according to claim 1, it is characterised in that the thickness of described third layer silicon nitride SiNx layer Between 30-45nm.
Gray coated glass the most according to claim 1, it is characterised in that the thickness of described 4th layer of nichrome NiCr layer Degree is between 5-15nm.
Gray coated glass the most according to claim 1, it is characterised in that the thickness of described layer 5 silicon nitride SiNx layer Between 6-20nm.
CN201620775872.XU 2016-07-21 2016-07-21 A kind of gray coated glass Active CN205803325U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201620775872.XU CN205803325U (en) 2016-07-21 2016-07-21 A kind of gray coated glass

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201620775872.XU CN205803325U (en) 2016-07-21 2016-07-21 A kind of gray coated glass

Publications (1)

Publication Number Publication Date
CN205803325U true CN205803325U (en) 2016-12-14

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CN201620775872.XU Active CN205803325U (en) 2016-07-21 2016-07-21 A kind of gray coated glass

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114391005A (en) * 2019-09-20 2022-04-22 法国圣戈班玻璃厂 Insulating glazing comprising a thin chromium-based layer

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114391005A (en) * 2019-09-20 2022-04-22 法国圣戈班玻璃厂 Insulating glazing comprising a thin chromium-based layer

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