CN205259534U - Modified PVC laminate flooring of microballon foaming silicate - Google Patents

Modified PVC laminate flooring of microballon foaming silicate Download PDF

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Publication number
CN205259534U
CN205259534U CN201520928542.5U CN201520928542U CN205259534U CN 205259534 U CN205259534 U CN 205259534U CN 201520928542 U CN201520928542 U CN 201520928542U CN 205259534 U CN205259534 U CN 205259534U
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CN
China
Prior art keywords
microballon
layer
floor
foaming
modified pvc
Prior art date
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Expired - Fee Related
Application number
CN201520928542.5U
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Chinese (zh)
Inventor
周锡成
李玉荣
赵雅静
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Liangshan Xicheng New Material Co Ltd
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Liangshan Xicheng New Material Co Ltd
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Priority to CN201520928542.5U priority Critical patent/CN205259534U/en
Application granted granted Critical
Publication of CN205259534U publication Critical patent/CN205259534U/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Abstract

The utility model relates to a plastics processing technique field, saying so more specifically relate to a combined type plastic floor that contains microballon foaming PVC, photosphere etc. On its buffer layer, enhancement layer, microballon foam printing basic unit, printing layer, modified PU wearing layer, embossing layer and UV solidification that includes the microballon foaming. Use the utility model discloses floor intensity height, the wearability of producing are good, and thermal insulation performance is good, and no plasticizer spills over, and the solution has the plastic floor on the above -mentioned technical defect that the floor trade exists, the wooden floor of fungible now.

Description

A kind of microballon silicate modified PVC composite floor board that foams
Technical field
This utility model relates to plastics field, relates in particular a kind of foam Combined floor of silicate modified PVC layer of microballon that contains.
Technical background
Current domestic floor annual requirement is greatly about 1,500,000,000 square metres of left and right, mainly taking wood floors and plastic floor as main, wood floors are divided into solid wooden floor board, solid wooden compound floor and reinforced composite floorboard, solid wood and solid wooden compound floor account for more than 40%, reinforced composite floorboard 50%, especially family's installed floor is all to adopt solid wooden compound floor and consolidated floor substantially, the rich talent of small part uses solid wooden floor board, because solid wood and solid wooden compound floor main raw material(s) are wooden boards, content of formaldehyde is less, but price is more expensive. Reinforced composite floorboard is to adopt wood powder, adhesive and glued board to make, and content of formaldehyde is higher. China is a country that timber resources is poorer, China's afforestation rate only has 16.5% at present, only be equivalent to the World Forests coverage rate and be 31.7% 52%, area of woods is only equivalent to 1/8 left and right of world's Per capita area per capita, a large amount of felling timber not only reduces timber resources and has also destroyed ecological environment, has brought great harm to human habitat. Country has carried out to prohibit to the use of natural forest resource and has cut down and limit is cut down policy for this reason, and new policy, " Green Development is forbidden the harvesting of wood and tree grafting growth " are put into effect again in country's 13 planning. Therefore the raw material of producing from now on wood floors can be fewer and feweri, price also can be more and more expensive, can cause great market has openings to Floor Industry very soon, the fitment material for family of therefore researching and developing alternative wood floors is very important, is also material development person's top priority.
Jin Liangnian lot of domestic and international enterprise begins one's study and develops the PVC plastic floor replacement wood floors of various formula different structures for this reason, divide main formula to be divided into foaming floor and the floor of not foaming by technique, current foaming floor mostly is AC foaming, AC foaming floor cell uniformity is poor, intensity is lower, wear no resistance, service life is short, after AC blowing agent decomposes, discharge oxynitrides and carbon monoxide, document announcement has mutagenesis, can produce stimulation toxic, there is corrosion, contact scar air, suck human body or contact raw material and can cause major injury or lethal, for head it off, the present invention proposes to apply microballon blowing agent PVC is foamed, the PVC aperture of microballon blowing agent foaming is even, density is moderate, yield rate is high, also improve intensity and the anti-wear performance of material simultaneously, and nontoxic, environmental protection, improve from structure on the other hand, enhancement layer all add up and down microballon foamed damping layer, increase the elasticity on floor, the casing play on protection floor is injury-free, extends the service life on floor.
Divide and be mainly divided into the common extrusion molding of individual layer ' structure, homogeneous penetrating structure and multi-layer combined structure by structure, in the production process of PVC floor, need to add the heavy metal salt stabilizing agent such as plasticizer and lead, tin of gross weight 50% left and right, in use plasticizer and heavy metal stabilizer can constantly be separated out, slowly be discharged in indoor environment, there are esophagus, respiratory tract, three kinds of approach of skin to enter human body by entering human body, all can cause serious injury to human reproduction's system, internal system and nervous system, even the fetus in pregnant woman's abdomen be damaged. Also have just above-mentioned reason to cause PVC floor also not obtain people's accreditation in house ornamentation field, market consumption is little. The present invention has adopted microballon foaming multi-layer compound structure, do not add plasticizer, be provided with UV cured layer at floor top layer simultaneously, can well stop like this overflowing of low-molecular material and additive in PVC floor, solve the problem of PVC floor wholesomeness from structure, also can save a large amount of costs.
The utility model content
The subject matter that the utility model solves is, the above-mentioned technology and the fault in material that exist for existing Floor Industry provide that a kind of good springiness, mechanical property are good, long service life, the elastomer floor of alternative wood floors.
The invention provides a kind of microballon silicate modified PVC Combined floor that foams, at least comprise the enhancement layer, microballon foaming printed substrate, modification PU wearing layer and the UV cured layer that on microballon foamed damping layer, set gradually;
Between described microballon foaming printed substrate and modification PU wearing layer, can be provided with printed layers.
Between modification PU wearing layer and UV cured layer, can be provided with embossed layers.
Enhancement layer can be to be made by silicate modified PVC;
Microballon foamed damping layer and microballon foaming printed substrate can be to adopt microballon blowing agent that silicate modified PVC is foamed and made, and described microballon refers to: a kind of or several mixing composition of polyurethane granular, polyvinyl chloride microballon, polyacrylic acid microballon, polyolefin microballon, fluororesin microballon, polystyrene microbeads;
Modification PU wearing layer can be to adopt TPU, TPVC, acrylic acid, acrylonitrile, epoxy resin, polysiloxanes, carborundum, silicate, silica, calcium carbonate one or more carry out modification to polyurethane and make, and improves the anti-wear performance of polyurethane;
The foam preparation method of silicate modified PVC Combined floor of a kind of microballon comprises: blending and modifying, coating, foaming, embossing;
Concrete steps are as follows:
(1) will add in PVC through the silicate of surface active, polyvinyl chloride resin is carried out strength modified, improve its intensity, through mixing, extrude, the operation such as calendering, press polish or mold pressing completes the making of enhancement layer;
(2) adopt reverse roll roller cladding process to apply the silicate modified PVC of one deck microballon foaming at enhancement layer upper surface, then through oily heat roller tube heating gel, complete the making of microballon foaming printed substrate;
(3) adopt 12 look continuous intaglio plate, soft version or net roller printing line, print in microballon foaming printed substrate according to different designs scheme, form printed layers;
(4) in order to improve floor wearability and service life, adopt floating scraper cladding process to apply one deck in above-mentioned surface of semi-finished in the PU slurry after modification, form modification PU wearing layer;
(5) application material reversing frame, by 180 ° of above-mentioned semi-finished product reversions, adopts reverse roll cladding process, applies the PVC of one deck microballon foaming at enhancement layer lower surface, through gel baking oven, completes the making of microballon foamed damping layer;
(6) above-mentioned semi-finished product are through being furnished with the gel blowing oven of CTS bottom nozzle, TP top jet nozzle and roll-type transfer system, microballon foamed damping layer, enhancement layer and microballon foaming printed substrate are foamed, complete the foam process of microballon foaming PVC Combined floor, the be controlled at ± 0.15mm of foaming precision of the thickness of microballon foamed damping layer, enhancement layer and microballon foaming printed substrate;
(7) the modification PU wearing layer upper epidermis after foaming is carried out embossing by application knurling rolls, makes the top of modification PU wearing layer become embossed layers, promotes non-skid property and the aesthetic property on floor;
(8) apply the UV glazing layer of one deck maskable plasticizer and protection indoor environment on embossed layers surface, and solidify, form UV cured layer, obtain a kind of microballon silicate modified PVC Combined floor that foams.
(9) the said goods detected, store after cutting edge, rolling, packaging, detection.
Step (4) can be: first adopt the tape casting to make film material on modification PU layer, be compounded in online above printed layers extruding, after printing process.
Brief description of the drawings:
Fig. 1 is structural representation of the present utility model.
Specific embodiment:
In Fig. 1,1, UV cured layer, 2, embossed layers, 3, modification PU wearing layer, 4, printed layers, 5, microballon foaming printed substrate, 6, silicate modified PVC enhancement layer, 7, microballon foamed damping layer.
A kind of microballon silicate modified PVC Combined floor that foams, comprise the enhancement layer, microballon foaming printed substrate, modification PU wearing layer and the UV cured layer that on microballon foamed damping layer, set gradually, microballon foamed damping layer thickness is at 1 ~ 2.5mm, enhancement layer 1 ~ 2.5mm, microballon foaming printed substrate is at 0.8 ~ 1mm, modification PU wearing layer 0.5 ~ 1mm, UV cured layer 0.2 ~ 1mm. Ultraviolet curing layer is to be mixed and made into UV coating by polyurethane, epoxy resin and wherein one or more of methyl acrylate;
Between described microballon foaming printed substrate and modification PU wearing layer, be provided with printed layers.
Between modification PU wearing layer and UV cured layer, be provided with embossed layers.
Enhancement layer is to be made by silicate modified PVC.
Microballon foamed damping layer and microballon foaming printed substrate are to adopt microballon blowing agent that silicate modified PVC is foamed and made, described microballon refers to: a kind of or several mixing composition of polyurethane granular, polyvinyl chloride microballon, polyacrylic acid microballon, polyolefin microballon, fluororesin microballon, polystyrene microbeads, described blowing agent refers to: wherein one or more such as sodium carbonate, sodium acid carbonate, ammonium hydrogencarbonate, citric acid, sodium antimonate, sodium nitrate, potassium nitrate, alkane are mixed composition. The particle diameter of microballon blowing agent is 40 ~ 80 μ m, and consumption is 0.1%;
Modification PU wearing layer is to adopt TPU, TPVC, acrylic acid, acrylonitrile, epoxy resin, polysiloxanes, carborundum, silicate, silica, calcium carbonate mixture polyurethane to be carried out to modification and make;
The foam preparation method of silicate modified PVC Combined floor of a kind of microballon comprises: blending and modifying, coating, foaming, embossing;
Concrete steps are as follows:
(1) by the talcum powder of surface active, wollastonite in powder, kaolin in 2:1:1 ratio, addition is 50%, add in PVC, and carry out blend by mixing up machine, the material mixing is joined in extruder and extruded, the Temperature Setting of extruder in the scope of 155-165 DEG C, then complete enhancement layer through prior art operations such as calendering, press polish or mold pressings and make, now the intensity of material can improve 8% than simple PVC;
(2) adopt reverse roll cladding process to apply the silicate modified PVC of one deck microballon foaming at enhancement layer upper surface, then heat gel through oil heating roller, temperature is 80 DEG C, and the time is 2S, completes the making of microballon foaming printed substrate;
(3) adopt 12 look continuous intaglio plate, soft version or net roller printing line, print in microballon foaming printed substrate according to different designs scheme, form printed layers;
(4) adopt floating scraper cladding process to apply one deck in above-mentioned surface of semi-finished in the PU slurry after modification, form modification PU wearing layer;
(5) application material reversing frame, by 180 ° of above-mentioned semi-finished product reversions, adopts reverse roll roller cladding process, applies the PVC of one deck microballon foaming at enhancement layer lower surface, and through gel baking oven, temperature is 80 DEG C, and the time is 4S, completes the making of microballon foamed damping layer;
(6) above-mentioned semi-finished product are through being furnished with the gel blowing oven of CTS bottom nozzle, TP top jet nozzle and roll-type transfer system, microballon foamed damping layer, enhancement layer and microballon foaming printed substrate are foamed, the temperature of blowing oven is 160 DEG C, the length of baking oven is 15m, complete the foam process of microballon foaming PVC Combined floor, the be controlled at ± 0.15mm of foaming precision of the thickness of microballon foamed damping layer, enhancement layer and microballon foaming printed substrate;
(7) the modification PU wearing layer upper epidermis after foaming is carried out embossing by application knurling rolls, makes the top of modification PU wearing layer become embossed layers;
(8) apply one deck UV glazing layer on embossed layers surface, and solidify, form UV cured layer, obtain a kind of microballon silicate modified PVC Combined floor that foams.
(9) the said goods detected, store after cutting edge, rolling, packaging, detection.

Claims (4)

1. the microballon silicate modified PVC Combined floor that foams, is characterized in that: at least comprise the enhancement layer, microballon foaming printed substrate, modification PU wearing layer and the UV cured layer that on microballon foamed damping layer, set gradually.
2. it is characterized in that according to the silicate modified PVC Combined floor that foams of a kind of microballon described in right 1: between described microballon foaming printed substrate and modification PU wearing layer, be provided with printed layers.
3. it is characterized in that according to the silicate modified PVC Combined floor that foams of a kind of microballon described in right 1: between modification PU wearing layer and UV cured layer, be provided with embossed layers.
4. it is characterized in that according to the silicate modified PVC Combined floor that foams of a kind of microballon described in right 1: in microballon foamed damping layer and microballon foaming printed substrate, described microballon refers to: a kind of or several mixing composition of polyurethane granular, polyvinyl chloride microballon, polyacrylic acid microballon, polyolefin microballon, fluororesin microballon, polystyrene microbeads.
CN201520928542.5U 2015-11-20 2015-11-20 Modified PVC laminate flooring of microballon foaming silicate Expired - Fee Related CN205259534U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201520928542.5U CN205259534U (en) 2015-11-20 2015-11-20 Modified PVC laminate flooring of microballon foaming silicate

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201520928542.5U CN205259534U (en) 2015-11-20 2015-11-20 Modified PVC laminate flooring of microballon foaming silicate

Publications (1)

Publication Number Publication Date
CN205259534U true CN205259534U (en) 2016-05-25

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105317196A (en) * 2015-11-20 2016-02-10 凉山州锡成新材料股份有限公司 Composite floor containing microsphere-foamed silicate-modified PVC and manufacturing method thereof
CN106585027A (en) * 2016-12-15 2017-04-26 苏州富艾姆工业设备有限公司 Anti-ultraviolet cured foam material and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105317196A (en) * 2015-11-20 2016-02-10 凉山州锡成新材料股份有限公司 Composite floor containing microsphere-foamed silicate-modified PVC and manufacturing method thereof
CN105317196B (en) * 2015-11-20 2017-12-05 凉山州锡成新材料股份有限公司 Silicate modified PVC composite floor boards of a kind of microballon foaming and preparation method thereof
CN106585027A (en) * 2016-12-15 2017-04-26 苏州富艾姆工业设备有限公司 Anti-ultraviolet cured foam material and preparation method thereof

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C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20160525

Termination date: 20191120

CF01 Termination of patent right due to non-payment of annual fee