CN204966602U - Fluidization bed electrode carbon fuel cell device - Google Patents

Fluidization bed electrode carbon fuel cell device Download PDF

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Publication number
CN204966602U
CN204966602U CN201520710589.4U CN201520710589U CN204966602U CN 204966602 U CN204966602 U CN 204966602U CN 201520710589 U CN201520710589 U CN 201520710589U CN 204966602 U CN204966602 U CN 204966602U
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China
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anode
cathode
negative electrode
gas
plate storehouse
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CN201520710589.4U
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Chinese (zh)
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许云翔
王亚斌
王世虎
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Beijing Yuxiang Kechuang Investment Co Ltd
Shanxi Yuxiang Information Technology Co Ltd
Beijing Institute of Technology BIT
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Beijing Yuxiang Kechuang Investment Co Ltd
Shanxi Yuxiang Information Technology Co Ltd
Beijing Institute of Technology BIT
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    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

Abstract

The utility model discloses a fluidization bed electrode carbon fuel cell device. The utility model discloses a positive pole air inlet, positive pole gas outlet, fluidized bed positive pole pipeline and positive pole gas circulation device constitute positive pole fluidized bed device, negative pole air inlet, negative pole gas outlet, fluidized bed negative pole pipeline and negative pole gas circulation device constitute negative pole fluidized bed device, the fluidized bed device has increased the electrochemical reaction interface of positive pole and negative pole, has improved the solid triphase reaction frequency of gas -liquid, has strengthened the heat transfer and the mass transfer of electrode, has improved carbon fuel cell's comprehensive properties, the negative pole adopts nickel lanthanum combined material to the three -dimensional shape of multidimension is processed into, the electrochemical reaction in the unit space can be effectively improves, melting alkali electrolyte adopts liOH, KOH and naOH's mixed ratio solution, can follow speed and efficiency that the reinforcing of bigger degree improves electrochemical reaction to reduce carbon fuel cell's reaction temperature, restrained or avoided boudouard reaction's emergence.

Description

A kind of fluid-bed electrode carbon fuel cell device
Technical field
The utility model relates to Direct Carbon Fuel Cells preparation field, is specifically related to a kind of fluid-bed electrode carbon fuel cell device.
Background technology
Along with Chinese national economy continue, fast-developing, the clean efficiency utilization of the energy becomes very urgent problem gradually.Traditional energy utilization patterns are first heat energy by the converts chemical energy of fuel, and then change mechanical energy and electric energy into, due to the restriction by Carnot cycle and material, generating efficiency only has about 30%, and in power generation process, create serious waste water,waste gas and industrial residue, used heat and noise pollution.Fuel cell is the device chemical energy in fuel and oxidant being converted into electric energy, and it is not by the restriction of Carnot cycle, and generating efficiency can reach 50%-70%; Compared with traditional fired power generating unit: NO xand SO 2discharge capacity less, CO 2discharge capacity can reduce 40%-60%, noise is low; Modularized design can be carried out; Variable load rate is high; Both can decentralized power supply can also centrally connected power supply; Floor space is little.Therefore, fuel cell is called the forth generation Blast Furnace Top Gas Recovery Turbine Unit (TRT) after water power, thermoelectricity and nuclear power.
The beginning of this century, develop the fuel cell of fused carbonate with the Lawrence National Laboratory of the U.S. (LawrenceLivermoreNationalLaboratory) of Cooper leader.This battery adopts the fused carbonate of high temperature (800 DEG C) as molten caustic soda electrolyte, and solid carbon is as fuel, and the oxygen in air is as cathodic reduction agent, and under the operating temperature of 800 DEG C, optimizing current density is 120mA/cm 2, power density is 60mW/cm 2.
Be that the research and development group of leading develops alkaline Direct Carbon Fuel Cells in ZARA company of the U.S. with Zecevic, graphite carbon rod is used to fuel, be immersed in the NaOH molten caustic soda electrolyte of melting as plate conductor simultaneously, oxygen is passed into by the dispersion pipe of battery bottom, and reacts with the cathode contacts as chamber wall.
Tsing-Hua University proposes a kind of Direct Carbon Fuel Cells DCFC reaction unit in patent 200810119204.1, and this reaction unit comprises fixed part, water-cooling section, cathode gas supply part, anodic gas supply part, the arrangement of carbon fuel parts, flow concentrating part, seal member, survey temperature-control units and reaction cavity parts.This device can realize sealing to Direct Carbon Fuel Cells, current collector, the supply of anode and cathode gas, measuring and controlling temp, solid carbon fuel supply, anode add water and the function such as heat stepwise, simultaneously for outside gas circuit, battery performance test, reacting gas detect and leave interface, to meet Direct Carbon Fuel Cells reaction condition demand.
But what the carbon fuel cell device mentioned in above-mentioned document adopted is all traditional fixed bed reactors, its version is simple, flow effect factor is few, is convenient to the speed controlling carbon course of reaction, but is unfavorable for the Direct Electrochemistry course of reaction improving heat transfer efficiency and carbon.Heat transfer, fluidized-bed reactor that mass transfer effect is good is adopted by the anode in DCFC and negative electrode, not only can ensure the advantage of fluid bed DCFC, and by the Direct Electrochemistry reaction interface of carbon from 2 D extension to three-dimensional, can improve the Direct Electrochemistry course of reaction of carbon further.
Tokyo Univ Japan Y.MatSuno is relatively little for electrode area in MCFC, gas transport efficiency is lower and the shortcoming such as complex structure, fluid-bed electrode is used to replace porous gas diffusive electrode in MCFC, design fluid-bed electrode anode of fuel cell, anodic half-cell primarily of earthenware, nickel electrode particle, current collector, to electrode, reference electrode, air distribution plate form.Y.Matsuno have studied the impact on the polarization performance of half-cell such as reaction temperature, propellant composition, gas flow rate, current collector area on this device, finds: improve reaction temperature and can increase current density; In fuel, hydrogen content is higher, and half-cell current density is larger; In scope of experiment, the limiting current density of half-cell increases with the increase of gas speed, but the increase of gas speed can increase the internal resistance (Particle Phase and electrolysis liquid phase) of battery, thus adds ohmic polarization.
Fluid-bed electrode combines with soild oxide DCFC by Gur, defines fluid bed electrode direct carbon fuel cell, and battery adopts He to realize the fluidization of carbon granule as medium, to promote that it contacts with anode current collector, thus reduces the concentration polarization of battery.And testing different scales the type battery, the output power density of midget plant is very low, still less than 2mW/cm 2.
Southeast China University Zhong Zhao puts down and propose a kind of fluid-bed electrode directly carbon fuel cell approach and reforming unit in patent 200510041047.3, propose negative electrode and anode micropore metal baffle for separating and form three phase fluidized bed, take carbonate as molten caustic soda electrolyte, with nickel powder or nichrome for catalyst, carbon dioxide is passed into anode, the mist of carbon dioxide, air is passed into negative electrode, bottom is through-flow oxidizing gases, utility model improves current density.This utility model first class gas does not form gas circulation, causes waste, and second is negative electrode fluidizing gas is the mist of carbon dioxide and air, when high temperature, charcoal and CO2 react and generate CO, and the proportional components of CO can reach more than 85%, and the charcoal of consumption cannot produce electronics.
Tsing-Hua University's history assist Xiang proposes a kind of fluid bed electrode direct carbon fuel cell device in patent 201110217478.6, this utility model is on direct carbon fuel cell of solid oxide basis, conductor catalyst is added in solid carbon fuel, make the direct chemical reaction of carbon from 2 D extension for three-dimensional, promote the gasification reaction of carbon, thus raising battery performance, further enhancing the heat transfer in electrode and mass transfer.This utility model is based on soild oxide carbon consuming cell, and molten caustic soda electrolyte have employed fused carbonate, and electron conductivity can be subject to the restriction of temperature, is secondly that in negative electrode mist, mixing of CO2 also can cause Boudouard to react.
In order to improve the operating efficiency of battery, improve ion/electron conductivity, the Direct Electrochemistry reaction of further raising carbon, in the urgent need to design multidimensional reaction interface, power density is high, reaction temperature is low direct carbon fuel cell device, advances progress and the application of correlation technique.
Utility model content
For above problems of the prior art, the utility model provides a kind of can provide multidimensional reaction cross-section, power density is high and reaction temperature is low direct carbon fuel cell device.
The purpose of this utility model is to provide a kind of fluid-bed electrode carbon fuel cell device.
Fluid-bed electrode carbon fuel cell device of the present utility model comprises: reaction unit, positive plate storehouse, minus plate storehouse, anode, negative electrode, anode current collector plate, cathode collector plate, microporosity separator, fluid bed anode pipe, fluid bed cathode pipe, Anodic Recirculation System device, cathode gas circulating device, molten caustic soda electrolyte and carbon fuel; Wherein, in reaction unit, molten caustic soda electrolyte is held; The positive plate storehouse of tubular and minus plate storehouse are separately positioned on the bottom of reaction unit; Anode and negative electrode are placed in positive plate storehouse and minus plate storehouse respectively; The pertusate anode current collector plate of tool and cathode collector plate penetrate from the top of reaction unit respectively and extend into positive plate storehouse and minus plate storehouse; Between positive plate storehouse and minus plate storehouse, microporosity separator is set; Be positioned at positive plate storehouse in the bottom of reaction unit anode inlet is set, at the top of reaction unit and the position relative with anode inlet arranges anode gas outlet, jointed anode air inlet and the anode gas outlet respectively, two ends of fluid bed anode pipe; Fluid bed anode pipe arranges Anodic Recirculation System device; Anode inlet, anode gas outlet, fluid bed anode pipe and Anodic Recirculation System device form anode fluidized bed plant, are connected with anode fluidizing gas in anode fluidized bed plant; Be positioned at minus plate storehouse arrange cathode inlet mouth in the bottom of reaction unit, at the top of reaction unit and the position relative with cathode inlet mouth arranges negative electrode gas outlet, the two ends of fluid bed cathode pipe connect cathode inlet mouth and negative electrode gas outlet respectively; Fluid bed cathode pipe arranges cathode gas circulating device; Cathode inlet mouth, negative electrode gas outlet, fluid bed cathode pipe and cathode gas circulating device form negative electrode fluidized bed plant, are connected with negative electrode fluidizing gas in negative electrode fluidized bed plant; Carbon fuel is placed in positive plate storehouse.
Molten caustic soda electrolyte adopts the mixing match solution of the combination of two or three in LiOH, KOH and NaOH.Molten caustic soda electrolyte requires lower than the electrolytical reaction temperature of fused carbonate molten caustic soda to the reaction temperature of fuel cell, under can effectively avoiding high temperature like this, the Boudouard of (more than 800 DEG C) reacts, and namely avoids charcoal and carbon dioxide that chemical reaction at high temperature occurs and produces CO (carbon monoxide converter) gas.
Negative electrode adopts nickel lanthanide composite material, and comprise bi-material, the first material is nickel, and the second material is lanthanide series metal or lanthana La 2o 3; Lanthanide series metal adopts the one in lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium and lutetium.In negative electrode, lanthanum improves oxygen desorption dissociating power and the reduction catalysts activity of negative electrode, and improves the conductivity of negative electrode oxonium ion, adds electrode reaction three phase boundary.The La adding high oxygen-ion conduction in the cathode can make negative electrode at high temperature become electron-ion mixed conductor; In addition, the La in negative electrode contributes to the electronic conductivity increasing Ni cathode surface oxide-film, cathode surface resistance is reduced, thus DCFC output performance is improved.Ni cathode surface can be oxidized to the very low p-type semiconductor NiO of conductivity in molten caustic soda and fused carbonate electrolyte.
Negative electrode is non-planar multi-C stereo shape, and the section curve of negative electrode is the one in triangular waveform, sawtooth waveform, sinusoidal wave pattern, square waveform and corrugated, and this multi-C stereo shape, adds space availability ratio.
Anodic Recirculation System device or cathode gas circulating device adopt Self-Priming Gas-Liquid Reactor, gas conveying machinery that need not be extra and gas-liquid contact can be carried out by sucting reaction device headspace gases voluntarily, while feed liquid mixing, constantly sucked the reacting gas on liquid level by hollow turbine agitator, reach gas-liquid cycle and dispersion object.
Be connected with anode fluidizing gas in anode fluidized bed plant, anode fluidizing gas adopts the CO of doping carbon fuel 2, N 2, H 2one or more in O and inert gas, wherein inert gas is one or more in helium, neon, argon, krypton and xenon.Be connected with negative electrode fluidizing gas in negative electrode fluidized bed plant, negative electrode fluidizing gas is the mist of oxygen and steam, or the mist of air and steam.
Microporosity separator adopts nickel or nichrome.
Carbon fuel adopt in graphite, carbon black, coke and coal one or more.
The utility model carries out realizing Conversion of Energy based on following principle:
Using molten caustic soda electrolyte as electrolyte, as anode, there is oxidation reaction in solid carbon fuel, release electronics; Oxygen, in negative electrode generation reduction reaction, obtains electronics; The transfer of electronics from anode to negative electrode provides electric energy for the external world, and carbon dioxide discharges as unique product.Chemical equation is as follows:
Anode reaction: C+4OH -=CO 2+ 2H 2o+4e -
Cathode reaction: O 2+ 2H 2o+4e-=4OH -
Net reaction: C+O 2=CO 2
Fluidized bed plant is the circulating device that have employed fluidizing gas, operationally, the mode of external heat is adopted to keep the electrolytical working temperature of molten caustic soda between 500 DEG C ~ 800 DEG C, anode fluidizing gas is passed into from anode inlet by fluid bed anode pipe, the carbon fuel in positive plate storehouse is made to be in fluidized state, anode fluidizing gas is discharged by anode gas outlet, after Anodic Recirculation System device, re-inject anode inlet; Pass into negative electrode fluidizing gas to cathode inlet mouth, negative electrode fluidizing gas is discharged by anode gas outlet, re-injects cathode inlet mouth by fluid bed cathode pipe after cathode gas circulating device.
Of the present utility model by adding fluidized bed plant on traditional carbon fuel cell device, adopt Self-Priming Gas-Liquid Reactor, make the Direct Electrochemistry reaction interface of carbon fuel from 2 D extension to three-dimensional, and the gasification reaction of carbon can be promoted, thus raising battery performance, the setting of negative electrode fluidized bed plant can promote the abundant mixing of oxygen, molten caustic soda electrolyte and cathode composite, increase reaction interface and the reaction frequency of gas, liquid, solid three-phase, improve the power density in unit interval and space.Meanwhile, negative electrode can also heat transfer further in intensifier electrode and mass transfer, improves the combination property of Direct Carbon Fuel Cells.
Advantage of the present utility model:
1, fluidized bed plant increases the electrochemical reaction interface of anode and negative electrode, improves the reaction frequency of gas-liquid-solid three-phase, enhances heat transfer and the mass transfer of electrode, improves the combination property of carbon consuming cell;
2, negative electrode adopts nickel lanthanide composite material, and is processed into multi-C stereo shape, effectively can improve the electrochemical reaction in unit space;
3, molten caustic soda electrolyte adopts the mixing match solution of LiOH, KOH and NaOH, can from strengthening the speed and efficiency that improve electrochemical reaction to a greater extent, and reduce the reaction temperature of carbon consuming cell, suppress or avoid the generation that Bu Duaer Boudouard reacts.
Accompanying drawing explanation
Fig. 1 is the schematic diagram of fluid-bed electrode carbon fuel cell device of the present utility model;
Fig. 2 is the schematic diagram of the section curve of the negative electrode of fluid-bed electrode carbon fuel cell device of the present utility model, wherein, (a) is triangular waveform, and (b) is sawtooth waveform, c () is sinusoidal wave pattern, (d) is square waveform;
Fig. 3 is the flow chart of the control method of fluid-bed electrode carbon fuel cell device of the present utility model.
Embodiment
Below in conjunction with accompanying drawing, by specific embodiment, set forth the utility model further.
As shown in Figure 1, the fluid-bed electrode carbon fuel cell device of the present embodiment comprises: reaction unit 1, positive plate storehouse 2, minus plate storehouse 3, anode 7, negative electrode 8, anode current collector plate 4, cathode collector plate 5, microporosity separator 6, fluid bed anode pipe 9, fluid bed cathode pipe 10, Anodic Recirculation System device 11, cathode gas circulating device 12, molten caustic soda electrolyte 13 and carbon fuel 14; Wherein, in reaction unit 1, molten caustic soda electrolyte 13 is full of; The positive plate storehouse 2 of tubular and minus plate storehouse 3 are separately positioned on the bottom of reaction unit 1; Anode 7 and negative electrode 8 are placed in positive plate storehouse 2 and minus plate storehouse 3 respectively; Positive plate storehouse and minus plate storehouse arrange the pertusate anode current collector plate 4 of tool and cathode collector plate 5 respectively; Microporosity separator 6 is set between positive plate storehouse and minus plate storehouse; Be positioned at positive plate storehouse in the bottom of reaction unit anode inlet is set, at the top of reaction unit and the position relative with anode inlet arranges anode gas outlet, jointed anode air inlet and the anode gas outlet respectively, two ends of fluid bed anode pipe 9; Fluid bed anode pipe arranges Anodic Recirculation System device 11; Anode inlet, anode gas outlet, fluid bed anode pipe and Anodic Recirculation System device form anode fluidized bed plant, are connected with anode fluidizing gas in anode fluidized bed plant; Be positioned at minus plate storehouse arrange cathode inlet mouth in the bottom of reaction unit, at the top of reaction unit and the position relative with cathode inlet mouth arranges negative electrode gas outlet, the two ends of fluid bed cathode pipe 10 connect cathode inlet mouth and negative electrode gas outlet respectively; Fluid bed cathode pipe arranges cathode gas circulating device 12; Cathode inlet mouth, negative electrode gas outlet, fluid bed cathode pipe and cathode gas circulating device form negative electrode fluidized bed plant, are connected with negative electrode fluidizing gas in negative electrode fluidized bed plant; Carbon fuel 14 is placed in positive plate storehouse 2.Anode current collector plate 4 is connected ammeter A respectively with cathode collector plate 5.
In the present embodiment, negative electrode adopts nickel lanthanide composite material, and wherein, the molar content of nickel accounts for 90%, the molar content 10% of lanthanum.Molten caustic soda electrolyte adopts the mixing match solution of LiOH, KOH and NaOH tri-kinds, and wherein, LiOH is 10%, KOH is 50%, NaOH is 40%.Anode fluidizing gas is the CO of doping carbon fuel 2; Negative electrode fluidizing gas is the mist of oxygen and steam.
As shown in Figure 2, negative electrode is non-planar multi-C stereo shape, and the section curve of negative electrode is the one in triangular waveform, sawtooth waveform, sinusoidal wave pattern, square waveform and corrugated.
As shown in Figure 3, the control method of the fluid-bed electrode carbon fuel cell device of the present embodiment, comprises the following steps:
1) two ends of fluid bed anode pipe are connected respectively the top anode gas outlet being positioned at anode inlet bottom reaction unit and being positioned at reaction unit, fluid bed anode pipe arranges Anodic Recirculation System device, form anode fluidized bed plant, and be connected with anode fluidizing gas; The two ends of fluid bed cathode pipe connected respectively the cathode inlet mouth of the bottom being positioned at reaction unit and be positioned at the top cathode gas outlet of reaction unit, fluid bed cathode pipe arranges cathode gas circulating device, form negative electrode fluidized bed plant, and be connected with negative electrode fluidizing gas;
2) reaction unit is heated, make the molten caustic soda electrolyte in reaction unit remain on working temperature between 500 DEG C ~ 800 DEG C;
3) control by Anodic Recirculation System device the flow velocity that anode fluidizing gas enters positive plate storehouse, coutroi velocity scope is between 3.5m/s ~ 6.8m/s, make anode fluidizing gas turbulent flow in positive plate storehouse, entered the speed in minus plate storehouse simultaneously by cathode gas circulating device control cathode fluidizing gas, make negative electrode fluidizing gas turbulent flow in minus plate storehouse;
4) turbulent flow of the anode fluidizing gas in positive plate storehouse, fluid particle moves brokenly and collides with each other, fluid particle disturbance and produce vortex tempestuously, thus realize anode fluidizing gas, fully contacting between molten caustic soda electrolyte with carbon fuel gas-liquid-solid three-phase, greatly increase reaction interface, improve mass transfer velocity; In minus plate storehouse, the turbulent flow of negative electrode fluidizing gas, produces whirlpool, thus realizes negative electrode, O 2and the gas-liquid-solid reaction of molten caustic soda electrolyte three, to improve conductivity;
5) in minus plate storehouse, the reaction under the effect of molten caustic soda electrolyte and cathode catalysis of oxygen and water generates OH-ion, accept electronics from cathode collector plate simultaneously, OH-ion is diffused in the molten caustic soda electrolyte of reaction unit by minus plate storehouse, then enter into positive plate storehouse, OH-ion and carbon react and generate CO 2and water, discharge electronics to anode current collector plate, electronics passes through anode current collector plate to external circuit, then completes current loop through cathode collector plate simultaneously, thus generating.
It is finally noted that, the object publicizing and implementing example is to help to understand the utility model further, but it will be appreciated by those skilled in the art that: in the spirit and scope not departing from the utility model and appended claim, various substitutions and modifications are all possible.Therefore, the utility model should not be limited to the content disclosed in embodiment, and the scope that the claimed scope of the utility model defines with claims is as the criterion.

Claims (4)

1. a fluid-bed electrode carbon fuel cell device, it is characterized in that, described cell apparatus comprises: reaction unit, positive plate storehouse, minus plate storehouse, anode, negative electrode, anode current collector plate, cathode collector plate, microporosity separator, fluid bed anode pipe, fluid bed cathode pipe, Anodic Recirculation System device, cathode gas circulating device, molten caustic soda electrolyte and carbon fuel; Wherein, in reaction unit, molten caustic soda electrolyte is held; The positive plate storehouse of tubular and minus plate storehouse are separately positioned on the bottom of reaction unit; Anode and negative electrode are placed in positive plate storehouse and minus plate storehouse respectively; The pertusate anode current collector plate of tool and cathode collector plate penetrate from the top of reaction unit respectively and extend into positive plate storehouse and minus plate storehouse; Between positive plate storehouse and minus plate storehouse, microporosity separator is set; Be positioned at positive plate storehouse in the bottom of reaction unit anode inlet is set, at the top of reaction unit and the position relative with anode inlet arranges anode gas outlet, jointed anode air inlet and the anode gas outlet respectively, two ends of fluid bed anode pipe; Fluid bed anode pipe arranges Anodic Recirculation System device; Anode inlet, anode gas outlet, fluid bed anode pipe and Anodic Recirculation System device form anode fluidized bed plant, are connected with anode fluidizing gas in anode fluidized bed plant; Be positioned at minus plate storehouse arrange cathode inlet mouth in the bottom of reaction unit, at the top of reaction unit and the position relative with cathode inlet mouth arranges negative electrode gas outlet, the two ends of fluid bed cathode pipe connect cathode inlet mouth and negative electrode gas outlet respectively; Fluid bed cathode pipe arranges cathode gas circulating device; Cathode inlet mouth, negative electrode gas outlet, fluid bed cathode pipe and cathode gas circulating device form negative electrode fluidized bed plant, are connected with negative electrode fluidizing gas in negative electrode fluidized bed plant; Carbon fuel is placed in positive plate storehouse.
2. cell apparatus as claimed in claim 1, is characterized in that, described negative electrode adopts nickel lanthanide composite material.
3. cell apparatus as claimed in claim 1, it is characterized in that, described negative electrode is non-planar multi-C stereo shape, and the section curve of negative electrode is the one in triangular waveform, sawtooth waveform, sinusoidal wave pattern, square waveform and corrugated.
4. cell apparatus as claimed in claim 1, is characterized in that, described Anodic Recirculation System device or cathode gas circulating device adopt Self-Priming Gas-Liquid Reactor.
CN201520710589.4U 2015-09-14 2015-09-14 Fluidization bed electrode carbon fuel cell device Withdrawn - After Issue CN204966602U (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105206858A (en) * 2015-09-14 2015-12-30 山西宇翔信息技术有限公司 Fluidized bed electrode carbon fuel cell device and control method thereof
CN108963309A (en) * 2018-08-09 2018-12-07 中南大学 Fluidized bed type semisolid liquid stream reaction system
CN113346092A (en) * 2021-04-28 2021-09-03 东南大学 Fluidized bed electrode solid oxide fuel cell device

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105206858A (en) * 2015-09-14 2015-12-30 山西宇翔信息技术有限公司 Fluidized bed electrode carbon fuel cell device and control method thereof
CN105206858B (en) * 2015-09-14 2016-10-26 山西宇翔信息技术有限公司 A kind of fluid-bed electrode carbon fuel cell device and control method thereof
CN108963309A (en) * 2018-08-09 2018-12-07 中南大学 Fluidized bed type semisolid liquid stream reaction system
CN113346092A (en) * 2021-04-28 2021-09-03 东南大学 Fluidized bed electrode solid oxide fuel cell device
CN113346092B (en) * 2021-04-28 2023-12-08 东南大学 Fluidized bed electrode solid oxide fuel cell device

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