CN204908027U - Knee pad - Google Patents
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- CN204908027U CN204908027U CN201520365065.6U CN201520365065U CN204908027U CN 204908027 U CN204908027 U CN 204908027U CN 201520365065 U CN201520365065 U CN 201520365065U CN 204908027 U CN204908027 U CN 204908027U
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Abstract
本实用新型涉及一种护膝。一种护膝,包括护膝本体及设置于所述护膝本体上的加热膜,所述加热膜包括:包括第一绝缘层;导电层,形成于所述第一绝缘层的表面;电极层,形成于所述导电层的表面且与所述导电层电连接,所述电极层包括正电极及负电极,所述正电极包括正极汇流条及自所述正极汇流条延伸而出的多个正极内电极,所述负电极包括负极汇流条及自所述负极汇流条延伸而出的多个负极内电极,所述正极内电极与所述负极内电极交替设置且相互间隔;及第二绝缘层,形成于所述电极层的表面;所述护膝还包括与所述加热膜的电极层电连接的连接线。上述护膝具有加热功能且可以采用较低电压供电。
The utility model relates to a knee protector. A knee pad, comprising a knee pad body and a heating film arranged on the knee pad body, the heating film includes: a first insulating layer; a conductive layer formed on the surface of the first insulating layer; an electrode layer formed on the The surface of the conductive layer is electrically connected to the conductive layer, the electrode layer includes a positive electrode and a negative electrode, and the positive electrode includes a positive bus bar and a plurality of positive inner electrodes extending from the positive bus bar , the negative electrode includes a negative bus bar and a plurality of negative internal electrodes extending from the negative bus bar, the positive internal electrodes and the negative internal electrodes are alternately arranged and spaced from each other; and a second insulating layer is formed on the surface of the electrode layer; the knee pad also includes a connection wire electrically connected to the electrode layer of the heating film. The above-mentioned knee pad has a heating function and can be powered by a lower voltage.
Description
技术领域technical field
本实用新型涉及一种护膝。The utility model relates to a knee protector.
背景技术Background technique
目前,护膝大多采用棉、绒或者皮毛等阻热性好的材料制备以对膝盖进行保暖。在使用的时候,这些护膝自身不能释放热量,而是靠蓄积人体散发的热量来达到保暖的目的,在寒冷的环境中使用时,这些护膝对膝部的保暖作用非常有限,难以抵抗外来寒气的侵袭。At present, knee pads are mostly made of materials with good heat resistance such as cotton, velvet or fur to keep the knees warm. When in use, these knee pads cannot release heat by themselves, but rely on accumulating the heat emitted by the human body to keep warm. When used in a cold environment, these knee pads have very limited heat preservation effect on the knees, and it is difficult to resist the external cold. invasion.
发热护膝一般在护膝本体上设置电阻丝进行发热,然而,金属电热丝作为电阻丝需要的供电电压较高,一旦发生漏电,会危及生命,危险性较大。Heating knee pads generally have resistance wires installed on the body of the knee pads to generate heat. However, metal heating wires require a higher power supply voltage as resistance wires. Once leakage occurs, it will be life-threatening and dangerous.
实用新型内容Utility model content
基于此,有必要提供一种可以采用较低电压供电的具有加热功能的护膝。Based on this, it is necessary to provide a knee pad with a heating function that can be powered by a lower voltage.
一种护膝,包括护膝本体及设置于所述护膝本体上的加热膜,所述加热膜包括:A knee pad, comprising a knee pad body and a heating film arranged on the knee pad body, the heating film includes:
第一绝缘层;first insulating layer;
导电层,形成于所述第一绝缘层的表面;a conductive layer formed on the surface of the first insulating layer;
电极层,形成于所述导电层的表面且与所述导电层电连接,所述电极层包括正电极及负电极,所述正电极包括正极汇流条及自所述正极汇流条延伸而出的多个正极内电极,所述负电极包括负极汇流条及自所述负极汇流条延伸而出的多个负极内电极,所述正极内电极与所述负极内电极交替设置且相互间隔;及An electrode layer, formed on the surface of the conductive layer and electrically connected to the conductive layer, the electrode layer includes a positive electrode and a negative electrode, and the positive electrode includes a positive bus bar and a bus bar extending from the positive bus bar a plurality of positive internal electrodes, the negative electrode includes a negative bus bar and a plurality of negative internal electrodes extending from the negative bus bar, the positive internal electrodes and the negative internal electrodes are alternately arranged and spaced from each other; and
第二绝缘层,形成于所述电极层的表面。The second insulating layer is formed on the surface of the electrode layer.
在其中一个实施例中,所述正极汇流条及所述负极汇流条均为直线形且平行设置,多个所述正极内电极自所述正极汇流条靠近所述负极汇流条的一侧向所述负极汇流条延伸,多个所述负极内电极自所述负极汇流条靠近所述正极汇流条的一侧向所述正极汇流条延伸。In one of the embodiments, the positive bus bar and the negative bus bar are linear and arranged in parallel, and a plurality of the positive inner electrodes extend from the side of the positive bus bar close to the negative bus bar to all The negative bus bar extends, and a plurality of the negative inner electrodes extend from a side of the negative bus bar close to the positive bus bar to the positive bus bar.
在其中一个实施例中,所述正极汇流条及所述负极汇流条均为弧形且间隔设置,所述正极内电极自所述正极汇流条的内侧向所述负极汇流条的内侧延伸,所述负极内电极自所述负极汇流条的内侧向所述正极汇流条的内侧延伸。In one of the embodiments, both the positive bus bar and the negative bus bar are arc-shaped and arranged at intervals, and the positive inner electrodes extend from the inner side of the positive bus bar to the inner side of the negative bus bar, so The negative inner electrode extends from the inner side of the negative bus bar to the inner side of the positive bus bar.
在其中一个实施例中,所述加热膜还包括设置于所述第一绝缘层及所述导电层之间的辅助电极层,所述辅助电极层与所述导电层电连接,所述辅助电极层包括辅助正电极及辅助负电极,所述辅助正电极包括辅助正极汇流条及自所述辅助正极汇流条延伸而出的多个辅助正极内电极,所述辅助负电极包括辅助负极汇流条及自所述辅助负极汇流条延伸而出的多个辅助负极内电极,所述辅助正极内电极与所述辅助负极内电极交替设置且相互间隔。In one of the embodiments, the heating film further includes an auxiliary electrode layer disposed between the first insulating layer and the conductive layer, the auxiliary electrode layer is electrically connected to the conductive layer, and the auxiliary electrode layer The layer includes an auxiliary positive electrode and an auxiliary negative electrode, the auxiliary positive electrode includes an auxiliary positive bus bar and a plurality of auxiliary positive internal electrodes extending from the auxiliary positive bus bar, and the auxiliary negative electrode includes an auxiliary negative bus bar and A plurality of auxiliary negative internal electrodes extending from the auxiliary negative bus bar, the auxiliary positive internal electrodes and the auxiliary negative internal electrodes are alternately arranged and spaced apart from each other.
在其中一个实施例中,所述辅助电极层的辅助正极内电极及所述辅助负极内电极在所述导电层的投影与所述电极层的正极内电极及所述负极内电极在所述导电层的投影相互错开。In one of the embodiments, the projection of the auxiliary positive internal electrode and the auxiliary negative internal electrode of the auxiliary electrode layer on the conductive layer is the same as that of the positive internal electrode and the negative internal electrode of the electrode layer on the conductive layer. The projections of the layers are offset from each other.
在其中一个实施例中,所述加热膜还包括第一胶层及第二胶层,所述第一胶层设置于所述第一绝缘层及所述导电层之间,所述第二胶层设置于所述电极层及所述第二绝缘层之间。In one of the embodiments, the heating film further includes a first adhesive layer and a second adhesive layer, the first adhesive layer is disposed between the first insulating layer and the conductive layer, and the second adhesive layer A layer is disposed between the electrode layer and the second insulating layer.
在其中一个实施例中,所述正电极有多个,多个所述正电极串联;In one of the embodiments, there are multiple positive electrodes, and multiple positive electrodes are connected in series;
及/或,所述负电极有多个,多个所述负电极串联。And/or, there are multiple negative electrodes, and multiple negative electrodes are connected in series.
在其中一个实施例中,所述加热件还包括控制器及无线通信器,所述控制器与所述电极层电连接,所述无线通信器可接收控制指令,并将所述控制指令传送给所述控制器,所述控制器根据所述控制指令控制所述加热膜的加热。In one of the embodiments, the heating element further includes a controller and a wireless communicator, the controller is electrically connected to the electrode layer, and the wireless communicator can receive control instructions and transmit the control instructions to The controller, the controller controls the heating of the heating film according to the control instruction.
另一种护膝,another knee pad,
包括护膝本体及设置于所述护膝本体上的加热膜,所述加热膜包括:It includes a knee pad body and a heating film arranged on the knee pad body, and the heating film includes:
第一绝缘层;first insulating layer;
第一电极层,形成于所述第一绝缘层的表面,所述第一电极层包括正电极,所述正电极包括正极汇流条及自所述正极汇流条延伸而出的多个正极内电极,The first electrode layer is formed on the surface of the first insulating layer, the first electrode layer includes a positive electrode, and the positive electrode includes a positive electrode bus bar and a plurality of positive electrode internal electrodes extending from the positive electrode bus bar ,
导电层,形成于所述第一电极层的表面,所述导电层与所述第一电极层电连接;a conductive layer formed on the surface of the first electrode layer, the conductive layer is electrically connected to the first electrode layer;
第二电极层,形成于所述导电层的表面且与所述导电层电连接,所述第二电极层包括负电极,所述负电极包括负极汇流条及自所述负极汇流条延伸而出的多个负极内电极,所述正极内电极与所述负极内电极在所述导电层的投影交替设置且相互间隔;及The second electrode layer is formed on the surface of the conductive layer and is electrically connected to the conductive layer. The second electrode layer includes a negative electrode, and the negative electrode includes a negative bus bar and extends from the negative bus bar. A plurality of negative internal electrodes, the positive internal electrodes and the projections of the negative internal electrodes on the conductive layer are alternately arranged and spaced from each other; and
第二绝缘层,形成于所述第二电极层的表面。The second insulating layer is formed on the surface of the second electrode layer.
上述护膝,由于加热膜的电极层的正电极包括多个正极内电极,负电极包括多个负极内电极,正极内电极与负极内电极交替设置,降低了相邻的内电极之间的间距,从而使得位于正极内电极及负极内电极之间的导电层的电阻较小,从而可以采用较低的电压供电,即使采用普通的锂电池供电,即可达到迅速加热的目的,从而可以使用较低的电压供电。In the aforementioned knee pads, since the positive electrode of the electrode layer of the heating film includes a plurality of positive inner electrodes, the negative electrode includes a plurality of negative inner electrodes, and the positive inner electrodes and the negative inner electrodes are arranged alternately, reducing the distance between adjacent inner electrodes, Therefore, the resistance of the conductive layer located between the positive inner electrode and the negative inner electrode is small, so that a lower voltage can be used for power supply, even if a common lithium battery is used for power supply, the purpose of rapid heating can be achieved, so that a lower voltage can be used. voltage supply.
附图说明Description of drawings
图1为一实施方式的护膝的结构示意图;Fig. 1 is a schematic structural view of a knee pad according to an embodiment;
图2为图1中的护膝的加热件的结构示意图;Fig. 2 is a structural schematic diagram of the heating element of the knee pad in Fig. 1;
图3为图2中的加热件的加热膜的结构示意图;Fig. 3 is a structural schematic diagram of the heating film of the heating element in Fig. 2;
图4为图3中加热膜的电极层的结构示意图;Fig. 4 is a schematic structural view of the electrode layer of the heating film in Fig. 3;
图5为另一实施方式的护膝的加热膜的结构示意图;Fig. 5 is a structural schematic diagram of a heating film of a knee pad in another embodiment;
图6为另一实施方式的护膝的加热膜的结构示意图;Fig. 6 is a structural schematic diagram of a heating film of a knee pad in another embodiment;
图7为另一实施方式的护膝的加热膜的结构示意图;Fig. 7 is a structural schematic diagram of a heating film of a knee pad in another embodiment;
图8为另一实施方式的护膝的加热膜的电极层的结构示意图;8 is a schematic structural view of the electrode layer of the heating film of the knee pad in another embodiment;
图9为另一实施方式的护膝的加热膜的电极层的结构示意图;9 is a schematic structural view of the electrode layer of the heating film of the knee pad in another embodiment;
图10为另一实施方式的护膝的加热膜的电极层的结构示意图;Fig. 10 is a schematic structural view of the electrode layer of the heating film of the knee pad in another embodiment;
图11为红外热像仪拍摄的实施例1的加热膜温度分布照片;Fig. 11 is the temperature distribution photo of the heating film of embodiment 1 taken by the infrared thermal imager;
图12为红外热像仪拍摄的实施例2的加热膜温度分布照片。Fig. 12 is a photograph of the temperature distribution of the heating film in Example 2 taken by an infrared thermal imager.
具体实施方式Detailed ways
为使本实用新型的上述目的、特征和优点能够更加明显易懂,下面结合附图对本实用新型的具体实施方式做详细的说明。在下面的描述中阐述了很多具体细节以便于充分理解本实用新型。但是本实用新型能够以很多不同于在此描述的其它方式来实施,本领域技术人员可以在不违背本实用新型内涵的情况下做类似改进,因此本实用新型不受下面公开的具体实施的限制。In order to make the above purpose, features and advantages of the present utility model more obvious and understandable, the specific implementation of the present utility model will be described in detail below in conjunction with the accompanying drawings. In the following description, numerous specific details are set forth in order to provide a full understanding of the present invention. However, the utility model can be implemented in many other ways different from those described here, and those skilled in the art can make similar improvements without violating the connotation of the utility model, so the utility model is not limited by the specific implementation disclosed below .
请同时参阅图1及图2,一实施方式的护膝1,包括加热件10及护膝本体90。Please refer to FIG. 1 and FIG. 2 at the same time. A knee pad 1 according to an embodiment includes a heating element 10 and a knee pad body 90 .
加热件10包括加热膜110、外罩130、供电装置150、电源开关170、控温装置180。The heating element 10 includes a heating film 110 , an outer cover 130 , a power supply device 150 , a power switch 170 , and a temperature control device 180 .
外罩130套设于加热膜110,加热膜110收容于外罩130中。The outer cover 130 is sleeved on the heating film 110 , and the heating film 110 is accommodated in the outer cover 130 .
供电装置150、电源开关170及控温装置180通过连接线(图未视)与加热膜110电连接。外罩130的材料可以为布料,当然也可以采用其他业内常用的材料,如远红外材料。The power supply device 150 , the power switch 170 and the temperature control device 180 are electrically connected to the heating film 110 through connecting wires (not shown in the figure). The material of the outer cover 130 can be cloth, and of course other commonly used materials in the industry, such as far-infrared materials, can also be used.
在图示的实施方式中,护膝本体90大致为长条形,加热膜110为带状,加热膜110及外罩130固设于护膝本体90上。当然,在其他实施方式中,护膝本体90也可以为由弹性材料制成的套筒。需要说明的是,护膝本体90还可以进一步包括内层及外层,将加热膜110直接夹设于护膝本体90的外层和内层之间即可,此时外罩130可以省略。当然,护膝1还可以包括用于固定的绑带或者粘扣等其他部件,在此不做赘述。In the illustrated embodiment, the knee pad body 90 is roughly strip-shaped, the heating film 110 is strip-shaped, and the heating film 110 and the outer cover 130 are fixed on the knee pad body 90 . Certainly, in other embodiments, the knee pad body 90 may also be a sleeve made of elastic material. It should be noted that the knee pad body 90 may further include an inner layer and an outer layer, and the heating film 110 may be directly sandwiched between the outer layer and the inner layer of the knee pad body 90 , and the outer cover 130 may be omitted at this time. Of course, the knee pad 1 may also include other components such as straps or velcro for fixing, which will not be described in detail here.
请参阅图3,在图示的实施方式中,加热膜110包括依次层叠的第一绝缘层112、导电层114、电极层116及第二绝缘层118。Referring to FIG. 3 , in the illustrated embodiment, the heating film 110 includes a first insulating layer 112 , a conductive layer 114 , an electrode layer 116 and a second insulating layer 118 stacked in sequence.
第一绝缘层112为基底。第一绝缘层112的材料为玻璃或者聚合物。优选的,聚合物为PET、PVC、PE、PMMA、PVDF、PANI或PC。优选的,第一绝缘层112的厚度为10μm~125μm。The first insulating layer 112 is a base. The material of the first insulating layer 112 is glass or polymer. Preferably, the polymer is PET, PVC, PE, PMMA, PVDF, PANI or PC. Preferably, the thickness of the first insulating layer 112 is 10 μm˜125 μm.
导电层114形成于第一绝缘层112的一侧表面。导电层114由导电材料形成。优选的,导电层114的材料为银、铜、铝、石墨烯、碳纳米管、ITO、FTO或AZO。进一步优选的,导电层114的材料为单层石墨烯或多层石墨烯。当导电层的材料为石墨烯时,导电层114还可以含有掺杂剂,掺杂剂为有机掺杂剂或无机掺杂剂。优选的,导电层的厚度为10nm~100nm。The conductive layer 114 is formed on one side surface of the first insulating layer 112 . The conductive layer 114 is formed of a conductive material. Preferably, the material of the conductive layer 114 is silver, copper, aluminum, graphene, carbon nanotubes, ITO, FTO or AZO. Further preferably, the material of the conductive layer 114 is single-layer graphene or multi-layer graphene. When the material of the conductive layer is graphene, the conductive layer 114 may further contain a dopant, and the dopant is an organic dopant or an inorganic dopant. Preferably, the conductive layer has a thickness of 10 nm to 100 nm.
电极层116形成于导电层114的表面,且与导电层114电连接。The electrode layer 116 is formed on the surface of the conductive layer 114 and is electrically connected to the conductive layer 114 .
请参阅图4,在图示的实施方式中,电极层116包括正电极1162及负电极1164。电极层116的厚度为10nm~35μm。Referring to FIG. 4 , in the illustrated embodiment, the electrode layer 116 includes a positive electrode 1162 and a negative electrode 1164 . The thickness of the electrode layer 116 is 10 nm to 35 μm.
正电极1162包括正极汇流条1162a及自正极汇流条1162a延伸而出的多个正极内电极1162b。The positive electrode 1162 includes a positive bus bar 1162 a and a plurality of positive inner electrodes 1162 b extending from the positive bus bar 1162 a.
在图示的实施方式中,正极汇流条1162a大致为条状,包括主体(图未标)、连接部(图未标)及与连接部连接的延伸部(图未标)。主体、连接部及延伸部为均为直线条状。连接部的一端与主体的一端垂直连接,连接部的另一端与延伸部的一端垂直连接,且主体与延伸部分别位于连接部的两侧。In the illustrated embodiment, the positive electrode bus bar 1162a is roughly strip-shaped, including a main body (not shown), a connecting portion (not shown), and an extension portion (not shown) connected to the connecting portion. The main body, the connection part and the extension part are all in the shape of a straight line. One end of the connection part is vertically connected to one end of the main body, the other end of the connection part is vertically connected to one end of the extension part, and the main body and the extension part are respectively located on two sides of the connection part.
正极内电极1162b有多个,多个正极内电极1162b均自主体的一侧延伸而出。在图示的实施方式中,正极内电极1162b为直线型且均垂直于正极汇流条1162a的主体。正极内电极1162b与正极汇流条1162a的连接部位于正极汇流条1162a的主体的同侧。正极内电极1162b的宽度为0.5mm~4mm。正极汇流条1162a的宽度远大于正极内电极1162b的宽度。正极汇流条1162a的宽度为6mm~10mm。There are multiple positive internal electrodes 1162b, and the multiple positive internal electrodes 1162b extend from one side of the main body. In the illustrated embodiment, the positive internal electrodes 1162b are straight and perpendicular to the main body of the positive bus bar 1162a. The connection portion between the positive internal electrode 1162b and the positive bus bar 1162a is located on the same side as the main body of the positive bus bar 1162a. The positive inner electrode 1162b has a width of 0.5 mm to 4 mm. The width of the positive bus bar 1162a is much larger than the width of the positive inner electrode 1162b. The width of the positive electrode bus bar 1162a is 6mm˜10mm.
负电极1164包括负极汇流条1164a及自负极汇流条1164a延伸而出的多个负极内电极1164b。The negative electrode 1164 includes a negative bus bar 1164 a and a plurality of negative inner electrodes 1164 b extending from the negative bus bar 1164 a.
在图示的实施方式中,负极汇流条1164a大致为条状,包括主体(图未标)、连接部(图未标)及与连接部连接的延伸部(图未标)。主体、连接部及延伸部为均为直线条状。连接部的一端与主体的一端垂直连接,连接部的另一端与延伸部的一端垂直连接,且主体与延伸部分别位于连接部的两侧。负极汇流条1164a的主体与正极汇流条1162a的主体相互平行且间隔设置,正极内电极1162b位于负极汇流条1164a的主体与正极汇流条1162a的主体之间,且正极内电极1162b远离正极汇流条1162a的一端与负极汇流条1164a的主体相间隔。负极汇流条1164a的连接部自负极汇流条1164a的主体的一端向靠近正极汇流条1162a的连接部的方向延伸,且负极汇流条1164a的连接部与正极汇流条1162a的连接部大致平齐。In the illustrated embodiment, the negative electrode bus bar 1164a is roughly strip-shaped, including a main body (not shown), a connecting portion (not shown), and an extension portion (not shown) connected to the connecting portion. The main body, the connection part and the extension part are all in the shape of a straight line. One end of the connection part is vertically connected to one end of the main body, the other end of the connection part is vertically connected to one end of the extension part, and the main body and the extension part are respectively located on two sides of the connection part. The main body of the negative bus bar 1164a and the main body of the positive bus bar 1162a are arranged parallel to each other and at intervals, the positive inner electrode 1162b is located between the main body of the negative bus bar 1164a and the main body of the positive bus bar 1162a, and the positive inner electrode 1162b is far away from the positive bus bar 1162a One end of is spaced from the main body of the negative bus bar 1164a. The connecting portion of the negative bus bar 1164a extends from one end of the main body of the negative bus bar 1164a toward the direction close to the connecting portion of the positive bus bar 1162a, and the connecting portion of the negative bus bar 1164a is substantially flush with the connecting portion of the positive bus bar 1162a.
负极内电极1164b有多个,负极内电极1164b均自负极汇流条1164a的主体靠近正极汇流条1162a的主体的一侧延伸而出,朝向正极汇流条1162a的主体延伸,且负极内电极1164b的末端与正极汇流条1162a的主体相间隔。在图示的实施方式中,负极内电极1164b为直线型且均垂直负极汇流条1164a的主体。负极内电极1164b与正极内电极1162b交替设置且相互间隔,即,与正极内电极1162b相邻的均为负极内电极1164b,与负极内电极1164b相邻的均为正极内电极1162b。相邻的内电极来自不同的汇流条。优选的,电极层116中,正极内电极1162b与负极内电极1164b均匀分布,即相邻的正极内电极1162b及负极内电极1164b之间的间距相同,为2mm~8mm。负极内电极1164b与负极汇流条1164a的连接部位于负极汇流条1164a的主体的同侧。负极内电极1164b的宽度为0.5mm~4mm。负极汇流条1164a的宽度远大于负极内电极1164b的宽度。负极汇流条1164a的宽度为6mm~10mm。There are a plurality of negative internal electrodes 1164b, and the negative internal electrodes 1164b all extend from the side of the main body of the negative bus bar 1164a close to the main body of the positive bus bar 1162a, and extend toward the main body of the positive bus bar 1162a, and the ends of the negative internal electrodes 1164b It is spaced apart from the main body of the positive bus bar 1162a. In the illustrated embodiment, the negative inner electrodes 1164b are straight and perpendicular to the main body of the negative bus bar 1164a. Negative internal electrodes 1164b and positive internal electrodes 1162b are arranged alternately and spaced from each other, that is, those adjacent to positive internal electrodes 1162b are all negative internal electrodes 1164b, and those adjacent to negative internal electrodes 1164b are all positive internal electrodes 1162b. Adjacent internal electrodes come from different bus bars. Preferably, in the electrode layer 116, the positive internal electrodes 1162b and the negative internal electrodes 1164b are evenly distributed, that is, the distance between adjacent positive internal electrodes 1162b and negative internal electrodes 1164b is the same, which is 2mm-8mm. The connection portion between the negative inner electrode 1164b and the negative bus bar 1164a is located on the same side of the main body of the negative bus bar 1164a. The negative inner electrode 1164b has a width of 0.5 mm to 4 mm. The width of the negative bus bar 1164a is much larger than the width of the negative inner electrode 1164b. The width of the negative electrode bus bar 1164a is 6mm˜10mm.
电极层116的材料为银、铜、铝、铂、石墨烯、碳纳米管、ITO、FTO或AZO。当然,电极层116也可以由银浆或铜浆涂布后固化形成,此时电极层116不可避免的含有浆料中的其他材料。优选的,电极层116与导电层114一体成型。优选的,当导电层114的材料为石墨烯时,电极层116的材料也为石墨烯,且电极层116与导电层114一体成型。通过设置电极层116,将电极层116应用于材料为单层石墨烯制成的导电层114上,可以使得加热膜110在≤12V的电压下工作,如果导电层114的材料为多层石墨烯,可以进一步降低工作电压。The material of the electrode layer 116 is silver, copper, aluminum, platinum, graphene, carbon nanotube, ITO, FTO or AZO. Of course, the electrode layer 116 can also be formed by coating silver paste or copper paste and then solidified. In this case, the electrode layer 116 inevitably contains other materials in the paste. Preferably, the electrode layer 116 and the conductive layer 114 are integrally formed. Preferably, when the material of the conductive layer 114 is graphene, the material of the electrode layer 116 is also graphene, and the electrode layer 116 and the conductive layer 114 are integrally formed. By arranging the electrode layer 116, applying the electrode layer 116 to the conductive layer 114 made of single-layer graphene can make the heating film 110 work at a voltage of ≤ 12V, if the material of the conductive layer 114 is multi-layer graphene , can further reduce the operating voltage.
进一步的,电极层116的正极汇流条1162a、正极内电极1162b、负极汇流条1164a及负极内电极1164b可以为同种材料,也可以为不同种材料。Further, the positive bus bar 1162a, the positive inner electrode 1162b, the negative bus bar 1164a and the negative inner electrode 1164b of the electrode layer 116 may be made of the same material or different materials.
第二绝缘层118形成于电极层116的表面。第二绝缘层118的材料为玻璃或者聚合物。优选的,聚合物为PET、PVC、PE、PMMA、PVDF、PANI或PC。优选的,第二绝缘层118的厚度为10μm~125μm。The second insulating layer 118 is formed on the surface of the electrode layer 116 . The material of the second insulating layer 118 is glass or polymer. Preferably, the polymer is PET, PVC, PE, PMMA, PVDF, PANI or PC. Preferably, the thickness of the second insulating layer 118 is 10 μm˜125 μm.
请同时参阅图1至图3,供电装置150通过连接线与加热膜110的电极层116电连接。供电装置150用于对加热膜110进行供电,具体在本实施方式中,供电装置150为可移动式电源,比如锂电池。Please refer to FIG. 1 to FIG. 3 at the same time, the power supply device 150 is electrically connected to the electrode layer 116 of the heating film 110 through a connection wire. The power supply device 150 is used to supply power to the heating film 110 . Specifically, in this embodiment, the power supply device 150 is a portable power source, such as a lithium battery.
进一步的,供电装置150上还设置有充电接口152以进行充电。Further, the power supply device 150 is also provided with a charging interface 152 for charging.
电源开关170同时与供电装置150及电极层116电连接,用于控制供电装置150对电极层116的供电与否。The power switch 170 is electrically connected to the power supply device 150 and the electrode layer 116 at the same time, and is used to control whether the power supply device 150 supplies power to the electrode layer 116 or not.
控温装置180与供电装置150及电极层116电连接,用于控制供电装置150对电极层116输出的电压高低,从而控制导电层114的发热温度。The temperature control device 180 is electrically connected to the power supply device 150 and the electrode layer 116 , and is used to control the output voltage of the power supply device 150 to the electrode layer 116 , thereby controlling the heating temperature of the conductive layer 114 .
请同时参阅图1及图2,供电装置150、电源开关170及控温装置180固定于护膝本体90的表面,连接线140设于护膝1的内部,对外不可见。在其他实施方式中,护膝1还包括控制件,供电装置150、电源开关170及控温装置180均集成于控制件以方便操作。Please refer to Fig. 1 and Fig. 2 at the same time, the power supply device 150, the power switch 170 and the temperature control device 180 are fixed on the surface of the knee pad body 90, and the connecting wire 140 is arranged inside the knee pad 1 and is invisible to the outside. In other embodiments, the knee pad 1 further includes a control part, and the power supply device 150, the power switch 170 and the temperature control device 180 are all integrated into the control part for easy operation.
护膝1还包括控制器及无线通信器,控制器与电极层116电连接。无线通信器可接收控制指令,并将控制指令传送给控制器,控制器根据控制指令控制加热膜110的加热。控制指令由控制端发送。控制端包括遥控器、手机、平板电脑、台式电脑和笔记本电脑的至少一种。控制端设置有红外收发模块、WIFI模块或ZIGBEE模块,控制端通过红外收发模块、WIFI模块或ZIGBEE模块与控制器进行通信。进一步的,护膝1还设置有与控制器电连接的温度传感器,从而控制器可以根据接收到的温度传感器收集的温度信息对加热膜的加热温度进行调节。进一步的,也可以在手机上安装相应的APP以方便控制加热膜的加热与否及加热温度。The knee pad 1 also includes a controller and a wireless communicator, and the controller is electrically connected to the electrode layer 116 . The wireless communicator can receive the control instruction, and transmit the control instruction to the controller, and the controller controls the heating of the heating film 110 according to the control instruction. Control commands are sent by the control terminal. The control terminal includes at least one of a remote controller, a mobile phone, a tablet computer, a desktop computer and a notebook computer. The control terminal is provided with an infrared transceiver module, a WIFI module or a ZIGBEE module, and the control terminal communicates with the controller through the infrared transceiver module, the WIFI module or the ZIGBEE module. Further, the knee pad 1 is also provided with a temperature sensor electrically connected to the controller, so that the controller can adjust the heating temperature of the heating film according to the received temperature information collected by the temperature sensor. Further, it is also possible to install a corresponding APP on the mobile phone to conveniently control whether the heating film is heated or not and the heating temperature.
优选的,为了为在低电压下获得良好的温度均匀性,针对电极层116的特殊结构,温差、起始温度、供电电压、相邻的正极内电极1162b与负极内电极1164b之间的间距和导电层114的方块电阻符合如下公式:Preferably, in order to obtain good temperature uniformity at low voltage, for the special structure of the electrode layer 116, the temperature difference, initial temperature, supply voltage, the distance between the adjacent positive internal electrode 1162b and the negative internal electrode 1164b and The sheet resistance of the conductive layer 114 conforms to the following formula:
T=kU2/d2R+t(1)T=kU 2 /d 2 R+t(1)
式(1)中:In formula (1):
t——起始温度,单位为℃;t - initial temperature, in °C;
T——加热膜最终温差,单位为℃;T——The final temperature difference of the heating film, in °C;
U——供电电压,单位为V,U≤12V;U——supply voltage, the unit is V, U≤12V;
d——相邻的正极内电极1162b与负极内电极1164b之间的间距,单位为cm,相邻的正极内电极1162b与负极内电极1164b之间的间距按照导电层一面上的间距计算;d——the distance between adjacent positive internal electrodes 1162b and negative internal electrodes 1164b, in cm, and the distance between adjacent positive internal electrodes 1162b and negative internal electrodes 1164b is calculated according to the distance on one side of the conductive layer;
R——导电层方块电阻,单位为Ω/□;R——The square resistance of the conductive layer, the unit is Ω/□;
k——常数,取值范围为10-200,k取值范围根据加热膜与空气之间的传导系数会有不同,与加热膜与空气之间的传导系数成反比。k—constant, the value range is 10-200, the value range of k will be different according to the conduction coefficient between the heating film and the air, and it is inversely proportional to the conduction coefficient between the heating film and the air.
进一步的,为了保证护膝1加热温度的均匀性,正极汇流条1162a及负极汇流条1162b的宽度和厚度需考虑所用材料的电流承载能力和电阻率,电阻率要足够小,以减小正极汇流条1162a及负极汇流条1162b上的电压降,保证正极内电极1162b及负极内电极1164b设置在正极汇流条1162a或负极汇流条1162b的不同位置最高电压和最低电压相差不超过10%,而且电流承载能力决定了正极汇流条1162a及负极汇流条1162b截面积必须大于某一数值才能保证正极汇流条1162a及负极汇流条1162b不被烧毁,存在如下公式(2):Further, in order to ensure the uniformity of the heating temperature of the knee pad 1, the width and thickness of the positive bus bar 1162a and the negative bus bar 1162b need to consider the current carrying capacity and resistivity of the materials used, and the resistivity should be small enough to reduce the size of the positive bus bar. 1162a and the voltage drop on the negative bus bar 1162b, to ensure that the positive inner electrode 1162b and the negative inner electrode 1164b are arranged at different positions of the positive bus bar 1162a or the negative bus bar 1162b, the difference between the highest voltage and the lowest voltage is not more than 10%, and the current carrying capacity It is determined that the cross-sectional area of the positive bus bar 1162a and the negative bus bar 1162b must be greater than a certain value to ensure that the positive bus bar 1162a and the negative bus bar 1162b will not be burned, and the following formula (2) exists:
n(n+1)lρl/WHR<1/5(2)n(n+1)lρ l /WHR<1/5(2)
其中:in:
n——正极内电极1162b及负极内电极1164b产生的间隔数;n——the interval number generated by the positive inner electrode 1162b and the negative inner electrode 1164b;
ρ1——正极汇流条1162a及负极汇流条1162b材料电阻率,单位为Ω·m;ρ 1 ——Material resistivity of positive bus bar 1162a and negative bus bar 1162b, unit is Ω·m;
l——正极内电极1162b和负极内电极1164b的长度,单位为m;l - the length of the positive inner electrode 1162b and the negative inner electrode 1164b, in m;
W——正极汇流条1162a及负极汇流条1162b宽度,单位为m;W——the width of the positive bus bar 1162a and the negative bus bar 1162b, in m;
H——正极汇流条1162a及负极汇流条1162b厚度,单位为m;H——the thickness of the positive bus bar 1162a and the negative bus bar 1162b, in m;
R——导电层114的方块电阻,单位为Ω/□。R——the sheet resistance of the conductive layer 114 , the unit is Ω/□.
上述公式中,假定正极汇流条1162a及负极汇流条1162b材料相同,宽度及厚度均相同,正极内电极1162b和负极内电极1164b的长度相同。In the above formula, it is assumed that the positive bus bar 1162a and the negative bus bar 1162b are made of the same material, have the same width and thickness, and the positive inner electrode 1162b and the negative inner electrode 1164b have the same length.
同样,内电极也需保证电流承载能力和考虑同一内电极上最大电压差不超过10%。存在如下公式(3):Similarly, the internal electrodes also need to ensure the current carrying capacity and consider that the maximum voltage difference on the same internal electrode does not exceed 10%. There is the following formula (3):
nl2ρ2/whLR<1/5(3)nl 2 ρ 2 /whLR<1/5(3)
其中:in:
n——正极内电极1162b及负极内电极1164b产生的间隔数;n——the interval number generated by the positive inner electrode 1162b and the negative inner electrode 1164b;
l——正极内电极1162b和负极内电极1164b的长度,单位为m;l - the length of the positive inner electrode 1162b and the negative inner electrode 1164b, in m;
ρ2——正极内电极1162b和负极内电极1164b的材料的电阻率,单位为Ω·m;ρ 2 ——the resistivity of the material of the positive inner electrode 1162b and the negative inner electrode 1164b, the unit is Ω·m;
w——正极内电极1162b和负极内电极1164b的宽度,单位为m;w—the width of the positive inner electrode 1162b and the negative inner electrode 1164b, in m;
h——正极内电极1162b和负极内电极1164b的厚度,单位为m;h——the thickness of the positive inner electrode 1162b and the negative inner electrode 1164b, in m;
L——正极汇流条1162a及负极汇流条1162b的长度,单位m;L——the length of the positive bus bar 1162a and the negative bus bar 1162b, in m;
R——导电层114的方块电阻,单位为Ω/□。R——the sheet resistance of the conductive layer 114 , the unit is Ω/□.
上述公式中,假定正极汇流条1162a及负极汇流条1162b尺寸相同,正极内电极1162b和负极内电极1164b的材料、长度、宽度及厚度均相同。In the above formula, it is assumed that the size of the positive bus bar 1162a and the negative bus bar 1162b are the same, and the material, length, width and thickness of the positive inner electrode 1162b and the negative inner electrode 1164b are the same.
上述护膝,通过采用特殊结构的电极层,通过设置正极内电极及负极内电极,降低了相邻的内电极之间的间距,从而使得位于正极内电极及负极内电极之间的导电层的电阻较小,从而可以采用较低的电压供电,即使采用普通的锂电池供电,即可达到迅速加热的目的;当导电层114的材料为单层石墨烯时,采用不高于1.5V的电压供电即可获得与传统的加热膜相同的加热效果;通过改变电极层的正极汇流条1162a及负极汇流条1164a的面积、正极内电极1162b与负极内电极1164b之间的间距,从而可以实现不同的加热功率,满足不同的加热温度需求。采用较低的电压供电,即使出现漏电,也完全不会威胁到人身安全,加热时间短,重量轻,体感平滑,不存在加热丝断裂等问题,无电磁辐射。The aforementioned knee pads, by adopting an electrode layer with a special structure, and by arranging the positive internal electrode and the negative internal electrode, reduce the distance between adjacent internal electrodes, thereby making the resistance of the conductive layer between the positive internal electrode and the negative internal electrode Smaller, so that a lower voltage can be used for power supply, even if an ordinary lithium battery is used for power supply, the purpose of rapid heating can be achieved; when the material of the conductive layer 114 is single-layer graphene, a voltage not higher than 1.5V is used for power supply The same heating effect as the traditional heating film can be obtained; by changing the area of the positive bus bar 1162a and the negative bus bar 1164a of the electrode layer, and the distance between the positive inner electrode 1162b and the negative inner electrode 1164b, different heating can be realized power to meet different heating temperature requirements. Using a lower voltage power supply, even if there is a leakage, it will not threaten personal safety at all, the heating time is short, the weight is light, the body feels smooth, there is no problem such as heating wire breakage, and there is no electromagnetic radiation.
当护膝的导电层的材料为石墨烯时,可以采用不超过7V的电压供电,同时通过控温装置调整温度,加热膜会发出与人体自然发出的远红外射线极其一致的远红外线,达到治疗的目的。When the material of the conductive layer of the knee pad is graphene, the voltage of no more than 7V can be used for power supply, and the temperature can be adjusted through the temperature control device at the same time, and the heating film will emit far-infrared rays that are very consistent with the far-infrared rays naturally emitted by the human body to achieve the therapeutic effect. Purpose.
请参阅图5,另一实施方式的护膝与护膝1的结构大致相同,其不同在于:在图示的实施方式中,护膝的加热膜210包括依次层叠的第一绝缘层212、第一胶层213、导电层214、电极层216、第二胶层217及第二绝缘层218。导电层214与第一绝缘层212通过第一胶层213粘合,第二绝缘层218与电极层216通过第二绝缘层218粘合。优选的,第一胶层213的材料为紫外光固化胶、热熔胶或硅胶,第二胶层217的材料为紫外光固化胶、热熔胶或硅胶。Please refer to Fig. 5, the structure of the knee pad of another embodiment is substantially the same as that of the knee pad 1, the difference is that in the illustrated embodiment, the heating film 210 of the knee pad includes a first insulating layer 212, a first adhesive layer stacked in sequence 213 , a conductive layer 214 , an electrode layer 216 , a second adhesive layer 217 and a second insulating layer 218 . The conductive layer 214 is bonded to the first insulating layer 212 through the first adhesive layer 213 , and the second insulating layer 218 is bonded to the electrode layer 216 through the second insulating layer 218 . Preferably, the material of the first adhesive layer 213 is ultraviolet curable adhesive, hot melt adhesive or silica gel, and the material of the second adhesive layer 217 is ultraviolet curable adhesive, hot melt adhesive or silica gel.
上述护膝中,加热膜210由以下步骤制备:In the above knee pads, the heating film 210 is prepared by the following steps:
步骤S310、提供预制板,预制板包括用于制备电极层的基层及形成于基层表面的导电层214。Step S310 , providing a prefabricated board, the prefabricated board includes a base layer for preparing an electrode layer and a conductive layer 214 formed on the surface of the base layer.
优选的,基层为金属箔。金属箔为铜箔、镍箔或其他金属箔,在此不做限制。Preferably, the base layer is metal foil. The metal foil is copper foil, nickel foil or other metal foil, which is not limited here.
该步骤中,所提供的预制板,导电层(比如石墨烯)直接生长于基层上。In this step, the conductive layer (such as graphene) is directly grown on the base layer of the provided prefabricated board.
步骤S320、通过第一胶层213将第一绝缘层212粘合至预制板的导电层214。Step S320 , bonding the first insulating layer 212 to the conductive layer 214 of the prefabricated board through the first adhesive layer 213 .
步骤S330、在基层的表面制备掩膜,并对基层进行蚀刻处理,除去掩膜后得到电极层。Step S330 , preparing a mask on the surface of the base layer, and etching the base layer, and removing the mask to obtain an electrode layer.
该步骤中,掩膜的图案根据需要的电极层的图案设计。蚀刻处理时,将制作好掩膜的预制板置于蚀刻液中,蚀刻除去未被掩膜保护的基层。In this step, the pattern of the mask is designed according to the desired pattern of the electrode layer. During the etching process, the prefabricated plate with the mask prepared is placed in the etching solution, and the base layer not protected by the mask is etched away.
优选的,蚀刻液中含有可以改善导电层214的导电性的物质。Preferably, the etching solution contains substances that can improve the conductivity of the conductive layer 214 .
步骤S340、通过第二胶层217将第二绝缘层218粘合至电极层216的表面。Step S340 , bonding the second insulating layer 218 to the surface of the electrode layer 216 through the second adhesive layer 217 .
优选的,第二胶层217及第二绝缘层218开设有对应于电极层216的正电极及负电极的通孔以制作引线。Preferably, the second glue layer 217 and the second insulating layer 218 are provided with through holes corresponding to the positive electrode and the negative electrode of the electrode layer 216 to make lead wires.
上述加热膜210的制备方法较为简单,节省时间和材料成本,同时,采用金属箔制备电极层,导电性好,有利于加热膜温度的均匀性的控制。The preparation method of the above-mentioned heating film 210 is relatively simple, saving time and material cost. At the same time, the electrode layer is prepared by using metal foil, which has good conductivity and is beneficial to control the uniformity of the temperature of the heating film.
优选的,第一胶层213及第二胶层217的厚度为25~75μm。Preferably, the thickness of the first adhesive layer 213 and the second adhesive layer 217 is 25-75 μm.
请参阅图6,另一实施方式的护膝与护膝1的结构大致相同,其不同在于:在图示的实施方式中,护膝的加热膜410包括依次层叠的第一绝缘层412、导电层414、电极层416、第二胶层417及第二绝缘层418。第二绝缘层418与电极层416通过第二绝缘层418粘合。优选的,第二胶层417的材料为紫外光固化胶、热熔胶或硅胶。Please refer to Fig. 6, the structure of the knee pad of another embodiment is substantially the same as that of the knee pad 1, the difference is that in the illustrated embodiment, the heating film 410 of the knee pad includes a first insulating layer 412, a conductive layer 414, The electrode layer 416 , the second adhesive layer 417 and the second insulating layer 418 . The second insulating layer 418 is bonded to the electrode layer 416 through the second insulating layer 418 . Preferably, the material of the second adhesive layer 417 is ultraviolet curing adhesive, hot melt adhesive or silica gel.
上述护膝中,加热膜410由以下步骤制备:In the above knee pads, the heating film 410 is prepared by the following steps:
步骤S510、在形成于第一绝缘层412表面的导电层144表面印刷或蒸镀制备电极层416。Step S510 , printing or evaporating on the surface of the conductive layer 144 formed on the surface of the first insulating layer 412 to prepare the electrode layer 416 .
步骤S520、通过第二胶层417将第二绝缘层418粘合至电极层416的表面。Step S520 , bonding the second insulating layer 418 to the surface of the electrode layer 416 through the second adhesive layer 417 .
优选的,第二胶层417及第二绝缘层418开设有对应于电极层416的正电极及负电极的通孔以制作引线。Preferably, the second adhesive layer 417 and the second insulating layer 418 are provided with through holes corresponding to the positive electrode and the negative electrode of the electrode layer 416 to make lead wires.
上述加热膜410的制备方法较为简单。The preparation method of the above-mentioned heating film 410 is relatively simple.
请参阅图7,另一实施方式的护膝与护膝1的结构大致相同,其不同在于:在图示的实施方式中,护膝的加热膜510包括依次层叠的第一绝缘层512、辅助电极层513、导电层514、电极层516及第二绝缘层518。辅助电极层513与导电层514电连接。辅助电极层513的结构与电极层516的结构相同。辅助电极层513包括辅助正电极(图未视)及辅助负电极(图未视)。辅助正电极包括辅助正极汇流条及自辅助正极汇流条延伸而出的多个辅助正极内电极。辅助负电极包括辅助负极汇流条及自辅助负极汇流条延伸而出的多个辅助负极内电极。辅助正极内电极与辅助负极内电极交替设置且相互间隔。进一步优选的,辅助电极层513的辅助正极内电极及辅助负极内电极在导电层514的投影与电极层516的正极内电极及所述负极内电极在导电层的投影相互错开。Please refer to FIG. 7 , the structure of the knee pad in another embodiment is substantially the same as that of the knee pad 1 , the difference is that in the illustrated embodiment, the heating film 510 of the knee pad includes a first insulating layer 512 and an auxiliary electrode layer 513 stacked in sequence. , a conductive layer 514 , an electrode layer 516 and a second insulating layer 518 . The auxiliary electrode layer 513 is electrically connected to the conductive layer 514 . The structure of the auxiliary electrode layer 513 is the same as that of the electrode layer 516 . The auxiliary electrode layer 513 includes an auxiliary positive electrode (not shown) and an auxiliary negative electrode (not shown). The auxiliary positive electrode includes an auxiliary positive bus bar and a plurality of auxiliary positive inner electrodes extending from the auxiliary positive bus bar. The auxiliary negative electrode includes an auxiliary negative electrode bus bar and a plurality of auxiliary negative electrode inner electrodes extending from the auxiliary negative electrode bus bar. The auxiliary positive inner electrodes and the auxiliary negative inner electrodes are arranged alternately and spaced apart from each other. Further preferably, the projections of the auxiliary positive internal electrode and the auxiliary negative internal electrode of the auxiliary electrode layer 513 on the conductive layer 514 are staggered from the projections of the positive internal electrode and the negative internal electrode of the electrode layer 516 on the conductive layer.
请参阅图8,另一实施方式的护膝与护膝1的结构大致相同,其不同在于:在图示的实施方式中,电极层616包括正电极6162、第一负电极6164及第二负电极6166。第一负电极6164与第二负电极6166串联。正电极6162包括正极汇流条6162a及自正极汇流条6162a延伸而出的多个正极内电极6162b。正极内电极6162b有多个,多个正极内电极6162b均自正极汇流条6162a的一侧延伸而出。在图示的实施方式中,正极内电极6162b为直线型且均垂直正极汇流条6162a。Please refer to FIG. 8 , the structure of the knee pad in another embodiment is substantially the same as that of the knee pad 1 , the difference is that in the illustrated embodiment, the electrode layer 616 includes a positive electrode 6162 , a first negative electrode 6164 and a second negative electrode 6166 . The first negative electrode 6164 is connected in series with the second negative electrode 6166 . The positive electrode 6162 includes a positive bus bar 6162a and a plurality of positive inner electrodes 6162b extending from the positive bus bar 6162a. There are multiple positive internal electrodes 6162b, and the multiple positive internal electrodes 6162b extend from one side of the positive bus bar 6162a. In the illustrated embodiment, the positive inner electrodes 6162b are straight and perpendicular to the positive bus bar 6162a.
第一负电极6164包括第一负极汇流条6164a及自第一负极汇流条6164a延伸而出的多个第一负极内电极6164b。第二负电极包括第二负极汇流条6166a及自第二负极汇流条6166a延伸而出的多个第二负极内电极6166b。第一负极汇流条6164a及第二负极汇流条6166a均为直线型,第一负极汇流条6164a及第二负极汇流条6166a均与正极汇流条6162a平行设置,第一负极汇流条6164a与第二负极汇流条6166a位于同一条直线上且相互间隔,且第一负极汇流条6164a远离第二负极汇流条6166a的一端与正极汇流条6162a的一端大致平齐,第二负极汇流条6166a远离第一负极汇流条6164a的一端与正极汇流条6162a的另一端大致平齐。The first negative electrode 6164 includes a first negative bus bar 6164a and a plurality of first negative inner electrodes 6164b extending from the first negative bus bar 6164a. The second negative electrode includes a second negative bus bar 6166a and a plurality of second negative inner electrodes 6166b extending from the second negative bus bar 6166a. Both the first negative bus bar 6164a and the second negative bus bar 6166a are linear, the first negative bus bar 6164a and the second negative bus bar 6166a are all arranged in parallel with the positive bus bar 6162a, and the first negative bus bar 6164a is connected to the second negative bus bar. The bus bars 6166a are located on the same straight line and are spaced apart from each other, and the end of the first negative bus bar 6164a away from the second negative bus bar 6166a is substantially flush with the end of the positive bus bar 6162a, and the second negative bus bar 6166a is far away from the first negative bus bar. One end of the bar 6164a is approximately flush with the other end of the positive bus bar 6162a.
正极内电极6162b远离正极汇流条6162a的一端靠近第一负极汇流条6164a或第二负极汇流条6166a,且与第一负极汇流条6164a或第二负极汇流条6166a相间隔。第一负极内电极6164b从第一负极汇流条6164a靠近正极内电极6162a的一侧向正极内电极6162a延伸且与正极内电极6162a相间隔,且第一负极内电极6164b与对应于第一负极汇流条6164a的正极内电极6162b交替设置。第二负极内电极6166b从第二负极汇流条6166a靠近正极内电极6162a的一侧向正极内电极6162a延伸且与正极内电极6162a相间隔,且第二负极内电极6166b与对应于第二负极汇流条6166a的正极内电极6162b交替设置。The end of the positive inner electrode 6162b away from the positive bus bar 6162a is close to the first negative bus bar 6164a or the second negative bus bar 6166a, and is spaced apart from the first negative bus bar 6164a or the second negative bus bar 6166a. The first negative internal electrode 6164b extends from the side of the first negative bus bar 6164a close to the positive internal electrode 6162a to the positive internal electrode 6162a and is spaced from the positive internal electrode 6162a, and the first negative internal electrode 6164b is connected to the first negative bus bar The positive inner electrodes 6162b of the strips 6164a alternate. The second negative internal electrode 6166b extends from the side of the second negative electrode bus bar 6166a close to the positive internal electrode 6162a to the positive internal electrode 6162a and is spaced from the positive internal electrode 6162a, and the second negative internal electrode 6166b is connected to the second negative internal electrode 6166b corresponding to the second negative electrode bus bar. The positive inner electrodes 6162b of the strips 6166a alternate.
需要说明的是,第一负电极6164与第二负电极6166不限于为串联,也可以并联设置。正电极也可为多个,多个正电极串联或并联。负电极不限于为两个,也可以为一个或大于2个。It should be noted that the first negative electrode 6164 and the second negative electrode 6166 are not limited to be connected in series, and can also be arranged in parallel. There may be multiple positive electrodes, and multiple positive electrodes are connected in series or in parallel. The number of negative electrodes is not limited to two, and may be one or more than two.
请参阅图9,另一实施方式的护膝与护膝1的结构大致相同,其不同在于:在图示的实施方式中,电极层716的正极汇流条7162a与负极汇流条7164a均为直线形。负极汇流条7162a与正极汇流条7164a间隔设置且负极汇流条7164a沿正极汇流条7162a的延伸方向延伸。正极内电极7162b自正极汇流条7162a向负极汇流条7164a弯折延伸,正极内电极7162b的末端靠近负极汇流条7164a且与负极汇流条7164a相间隔。负极内电极7164b自负极汇流条7164a向正极汇流条7162a弯折延伸,负极内电极7164b的末端靠近正极汇流条7162a且与正极汇流条相间隔。Please refer to FIG. 9 , the structure of the knee pad in another embodiment is substantially the same as that of the knee pad 1 , the difference is that in the illustrated embodiment, the positive bus bar 7162 a and the negative bus bar 7164 a of the electrode layer 716 are both linear. The negative bus bar 7162a is spaced apart from the positive bus bar 7164a, and the negative bus bar 7164a extends along the extending direction of the positive bus bar 7162a. The positive inner electrode 7162b bends and extends from the positive bus bar 7162a to the negative bus bar 7164a, and the end of the positive inner electrode 7162b is close to the negative bus bar 7164a and spaced from the negative bus bar 7164a. The negative inner electrode 7164b bends and extends from the negative bus bar 7164a to the positive bus bar 7162a, and the end of the negative inner electrode 7164b is close to the positive bus bar 7162a and spaced from the positive bus bar.
请参阅图10,另一实施方式的护膝与护膝1的结构大致相同,其不同在于:在图示的实施方式中,正极汇流条8162a及负极汇流条8164a均为弧形且间隔设置,正极汇流条8162a及负极汇流条8164a围设成圆环形。正极内电极8162a自正极汇流条8162a的内侧向负极汇流条8162b的内侧延伸,正极内电极8162b的末端靠近负极汇流条8164a且与负极汇流条8164a相间隔。负极内电极8164b自负极汇流条8164a的内侧向正极汇流条8162a的内侧延伸,负极内电极8164b的末端靠近正极汇流条8162a且与正极汇流条相间隔。在图示的实施方式中,正极内电极8162b及负极内电极8164b均为直线型。Please refer to FIG. 10 , the structure of the knee pad in another embodiment is substantially the same as that of the knee pad 1, the difference is that in the illustrated embodiment, the positive bus bar 8162a and the negative bus bar 8164a are both arc-shaped and arranged at intervals, and the positive bus bar The bar 8162a and the negative bus bar 8164a are arranged in a circular shape. The positive inner electrode 8162a extends from the inner side of the positive bus bar 8162a to the inner side of the negative bus bar 8162b, and the end of the positive inner electrode 8162b is close to the negative bus bar 8164a and spaced from the negative bus bar 8164a. The negative inner electrode 8164b extends from the inner side of the negative bus bar 8164a to the inner side of the positive bus bar 8162a, and the end of the negative inner electrode 8164b is close to the positive bus bar 8162a and spaced from the positive bus bar. In the illustrated embodiment, both the positive electrode internal electrode 8162b and the negative electrode internal electrode 8164b are linear.
需要说明的是,正极汇流条及负极汇流条不限于为上述几个实施例列举的形状,也可以为其他形状;正极内电极及负极内电极也不限于为上述几个实施例列举的形状,也可以为其他形状,如曲线形或波浪形等,只要使得正极内电极与负极内电极交替设置,降低正极内电极及负极内电极之间的间距即可。It should be noted that the positive bus bar and the negative bus bar are not limited to the shapes listed in the above-mentioned several embodiments, and may also be in other shapes; the positive inner electrode and the negative inner electrode are not limited to the shapes listed in the above-mentioned several embodiments, It can also be in other shapes, such as curved or wavy, as long as the positive inner electrodes and the negative inner electrodes are arranged alternately, and the distance between the positive inner electrodes and the negative inner electrodes is reduced.
可以理解,还可以在导电层的两侧分别设置正电极及负电极,正电极及负电极在导电层的投影与上述实施例中导电层的结构相同。It can be understood that a positive electrode and a negative electrode can also be respectively arranged on both sides of the conductive layer, and the projection of the positive electrode and the negative electrode on the conductive layer is the same as the structure of the conductive layer in the above-mentioned embodiment.
以下结合具体实施例进一步说明。Further description below in conjunction with specific examples.
实施例1:Example 1:
请同时参阅图4和图5,单层石墨烯作为加热膜的导电层,电极层采用银浆印刷。Please refer to Figure 4 and Figure 5 at the same time, the single-layer graphene is used as the conductive layer of the heating film, and the electrode layer is printed with silver paste.
1、在面积150mm×150mm厚度125μm的PET(第一绝缘层)上转移一层石墨烯,石墨烯已经过掺杂,方阻为250Ω/□;1. Transfer a layer of graphene on the PET (first insulating layer) with an area of 150mm×150mm and a thickness of 125μm. The graphene has been doped and the square resistance is 250Ω/□;
2、使用丝网印刷设备在转移好的石墨烯上印刷银浆电极图案,图案形状如图4所示,正极内电极和负极内电极间距为6mm,正极内电极和负极内电极长108mm,宽1mm,共15条,正极汇流条和负极汇流条宽8mm,银浆厚度25μm;2. Use screen printing equipment to print the silver paste electrode pattern on the transferred graphene. The shape of the pattern is shown in Figure 4. The distance between the positive inner electrode and the negative inner electrode is 6mm, and the length of the positive inner electrode and the negative inner electrode is 108mm. 1mm, a total of 15 pieces, the width of the positive and negative bus bars is 8mm, and the thickness of the silver paste is 25μm;
3、将印刷好的电极层置于烘箱中烘烤,使银浆固化,烘烤温度为130℃,时间为40min。3. Bake the printed electrode layer in an oven to solidify the silver paste. The baking temperature is 130°C for 40 minutes.
初始温度为室温(22℃),此种情况下,将引线分别将电极层的正电极及负电极连接5V电源的正负极,经测试,60秒即可达到稳定状态,此时加热膜的平均温度可达77.5℃左右(室温为22℃)。The initial temperature is room temperature (22°C). In this case, connect the lead wires to the positive and negative electrodes of the electrode layer to the positive and negative electrodes of the 5V power supply. After testing, it can reach a stable state in 60 seconds. At this time, the temperature of the heating film The average temperature can reach about 77.5°C (room temperature is 22°C).
使用3.7V电压供电时加热膜的平均加热功率为1500w/m2左右。When using 3.7V voltage for power supply, the average heating power of the heating film is about 1500w/m 2 .
优选地,进一步进行以下步骤:Preferably, the following steps are further carried out:
4、将面积150mm×150mm厚度50μm的OCA胶与相同面积的PET贴合在一起;4. Lay OCA glue with an area of 150mm×150mm and a thickness of 50μm with PET of the same area;
5、使用激光切割设备在贴合好的PET/OCA开方形孔,孔大小为5mm×5mm,开孔的位置要保证该PET/OCA与电极层案贴合后,汇流条末端露出5mm×5mm的电极;5. Use laser cutting equipment to open a square hole in the bonded PET/OCA. The size of the hole is 5mm×5mm. The position of the hole should ensure that after the PET/OCA is bonded to the electrode layer, the end of the bus bar is exposed 5mm×5mm the electrode;
6、对好位后将PET/OCA与电极层贴合;6. After aligning the position, attach the PET/OCA to the electrode layer;
7、在小孔露出的电极出制作引线;7. Make lead wires from the electrodes exposed in the small holes;
此种情况下,测得加热膜电阻为2.7Ω,将引线分别连接5V电源的正负极,经测试,60秒即可达到稳定状态,图11所示为使用红外热像仪拍摄的加热膜温度分布照片,此时加热膜的平均温度可达66℃左右(室温为22℃)。In this case, the measured resistance of the heating film is 2.7Ω. Connect the lead wires to the positive and negative electrodes of the 5V power supply respectively. After testing, it can reach a stable state in 60 seconds. Figure 11 shows the heating film taken by an infrared thermal imager The temperature distribution photo shows that the average temperature of the heating film can reach about 66°C (room temperature is 22°C).
测试结果显示,使用3.7V电压供电时加热膜的平均加热功率为1300w/m2左右,而电压为3.7V时使用传统的无内电极的加热膜平均加热功率为5w/m2左右,要达到与我们新设计的加热膜相同的加热效果使用电压需提高至60V左右,这已经远远超过了人体安全电压。The test results show that the average heating power of the heating film is about 1300w /m2 when the voltage is 3.7V, and the average heating power of the traditional heating film without internal electrodes is about 5w/ m2 when the voltage is 3.7V. With the same heating effect as our newly designed heating film, the voltage needs to be increased to about 60V, which has far exceeded the safe voltage of the human body.
实施例2:Example 2:
本实施例采用两层石墨烯作为加热膜的导电层,电极层采用银浆印刷。In this embodiment, two layers of graphene are used as the conductive layer of the heating film, and the electrode layer is printed with silver paste.
1、在面积120mm×120mm厚度125μm的PET(第一绝缘层)上转移两层石墨烯作为导电层,石墨烯已经过掺杂,方阻为120Ω/□;1. Transfer two layers of graphene as the conductive layer on the PET (first insulating layer) with an area of 120mm×120mm and a thickness of 125μm. The graphene has been doped and the square resistance is 120Ω/□;
2、使用丝网印刷设备在转移好的导电层上印刷银浆电极层,图案形状如图10所示,汇流条外圆直径96mm,内电极间距为6mm,宽1mm,汇流条宽8mm,银浆厚度25μm;2. Use screen printing equipment to print the silver paste electrode layer on the transferred conductive layer. The pattern shape is shown in Figure 10. The outer diameter of the bus bar is 96mm, the inner electrode spacing is 6mm, and the width is 1mm. The bus bar width is 8mm, silver Slurry thickness 25μm;
3、将印刷好的电极图案置于烘箱中烘烤,使银浆固化,烘烤温度为130℃,时间为40min。3. Bake the printed electrode pattern in an oven to solidify the silver paste. The baking temperature is 130°C for 40 minutes.
此种情况下,将引线分别连接5V电源的正负极,经测试,60S即可达到稳定状态,此时加热膜的平均温度可达137.7℃左右(初始温度为室温22℃)。In this case, connect the lead wires to the positive and negative poles of the 5V power supply respectively. After testing, it can reach a stable state in 60 seconds. At this time, the average temperature of the heating film can reach about 137.7°C (initial temperature is room temperature 22°C).
测试结果显示,使用我们实用新型的电极设计方案,使用3.7V电压供电时加热膜的平均加热功率为3168w/m2左右。The test results show that using our utility model electrode design scheme, the average heating power of the heating film is about 3168w /m2 when the power supply is powered by 3.7V.
优选地,进一步进行以下步骤:Preferably, the following steps are further carried out:
4、将面积120mm×120mm厚度50μm的OCA胶与相同面积的PET贴合在一起;4. Lay OCA glue with an area of 120mm×120mm and a thickness of 50μm with PET of the same area;
5、使用激光切割设备在贴合好的PET/OCA开方形孔,孔大小为5mm×5mm,开孔的位置要保证该PET/OCA与电极层贴合后,汇流条末端露出5mm×5mm的电极;5. Use laser cutting equipment to open a square hole in the bonded PET/OCA. The size of the hole is 5mm×5mm. The position of the hole should ensure that after the PET/OCA is bonded to the electrode layer, a 5mm×5mm hole is exposed at the end of the bus bar. electrode;
6、对好位后将PET/OCA与电极层贴合;6. After aligning the position, attach the PET/OCA to the electrode layer;
7、在小孔露出的电极出制作引线;7. Make lead wires from the electrodes exposed in the small holes;
此种情况下,测得加热膜电阻为2Ω,将引线分别连接5V电源的正负极,经测试,40S钟即可达到稳定状态,图12所示为使用红外热像仪拍摄的加热膜温度分布照片,此时加热膜的平均温度可达90.9℃左右(室温为22℃)。In this case, the measured resistance of the heating film is 2Ω. Connect the lead wires to the positive and negative poles of the 5V power supply respectively. After testing, it takes 40 seconds to reach a stable state. Figure 12 shows the temperature of the heating film taken by an infrared thermal imager. Distribution photos, at this time the average temperature of the heating film can reach about 90.9°C (room temperature is 22°C).
测试结果显示,使用3.7V电压供电时加热膜的平均加热功率为1300w/m2左右,而电压为3.7V时使用传统的无内电极的加热膜平均加热功率为5w/m2左右,要达到与我们新设计的加热膜相同的加热效果使用电压需提高至60V左右,这已经远远超过了人体安全电压。The test results show that the average heating power of the heating film is about 1300w /m2 when the voltage is 3.7V, and the average heating power of the traditional heating film without internal electrodes is about 5w/ m2 when the voltage is 3.7V. With the same heating effect as our newly designed heating film, the voltage needs to be increased to about 60V, which has far exceeded the safe voltage of the human body.
实施例3:Example 3:
请参阅图8,单层石墨烯作为加热膜的导电层,制备工艺如下:Please refer to Figure 8, the single-layer graphene is used as the conductive layer of the heating film, and the preparation process is as follows:
1、将生长好石墨烯(石墨烯经过掺杂,方阻为250Ω/□)的铜箔与大小为150mm×300mm厚度为125μm的PET通过UV胶贴合在一起,铜箔大小为140mm×280mm,厚度为25μm;1. Lay the copper foil with the grown graphene (graphene is doped, the square resistance is 250Ω/□) and the PET with the size of 150mm×300mm and the thickness of 125μm through UV glue, and the size of the copper foil is 140mm×280mm , with a thickness of 25 μm;
2、将UV胶固化,波长为365nm,能量为1000mJ/cm2;2. Curing the UV glue with a wavelength of 365nm and an energy of 1000mJ/cm 2 ;
3、使用丝网印刷设备在贴合好的铜箔上印刷可剥胶掩膜,图案形状如图8所示,此时,相当于加热膜被一分为二,形成左右两块加热膜串联的效应,实际的利用电压减半,内电极间距为3mm,长108mm,宽1mm,共32条,汇流条宽8mm,铜箔厚度25μm;3. Use screen printing equipment to print a peelable mask on the bonded copper foil. The pattern shape is shown in Figure 8. At this time, it is equivalent to dividing the heating film into two, forming two left and right heating films connected in series effect, the actual utilization voltage is halved, the internal electrode spacing is 3mm, the length is 108mm, and the width is 1mm, a total of 32, the bus bar width is 8mm, and the copper foil thickness is 25μm;
4、将印刷好的电极图案置于烘箱中烘烤,使可剥胶固化,烘烤温度为135℃,时间为40min;4. Bake the printed electrode pattern in an oven to cure the peelable glue. The baking temperature is 135°C for 40 minutes;
5、烘烤后的样品置于30%的FeCl3刻蚀液中刻蚀,刻蚀结束后水洗吹干,揭下电极表面的可剥胶。5. The baked sample is etched in 30% FeCl 3 etching solution. After the etching is completed, it is washed with water and dried, and the peelable glue on the electrode surface is peeled off.
此种情况下,测得加热膜电阻为1.7Ω,将引线分别连接3.7V锂离子电池的正负极(相对于一半的加热膜是1.85V),经测试,30S稳定后加热膜的温度可达46℃左右(室温为22℃)。In this case, the measured resistance of the heating film is 1.7Ω, and the lead wires are respectively connected to the positive and negative electrodes of the 3.7V lithium-ion battery (1.85V compared to half of the heating film). After testing, the temperature of the heating film can be stabilized after 30S. It reaches about 46°C (room temperature is 22°C).
测试结果显示,使用本实用新型的电极设计方案,使用3.7V电压(实际应用于两电极的电压为1.85V)供电时加热膜的平均加热功率为1521w/m2左右。The test results show that the average heating power of the heating film is about 1521w/m 2 when using the electrode design scheme of the utility model and using 3.7V voltage (the voltage actually applied to the two electrodes is 1.85V) for power supply.
优选地,进一步进行以下步骤:Preferably, the following steps are further carried out:
6、将面积150mm×300mm厚度50μm的OCA胶与相同面积的PET贴合在一起;6. Lay OCA glue with an area of 150mm×300mm and a thickness of 50μm with PET of the same area;
7、使用激光切割设备在贴合好的PET/OCA开方形孔,孔大小为5mm×5mm,开孔的位置要保证该PET/OCA与电极层贴合后,汇流条末端露出5mm×5mm的电极;7. Use laser cutting equipment to open a square hole in the bonded PET/OCA. The size of the hole is 5mm×5mm. The position of the hole should ensure that after the PET/OCA is bonded to the electrode layer, a 5mm×5mm hole is exposed at the end of the bus bar. electrode;
8、对好位后将PET/OCA与电极图案贴合;8. After aligning the position, attach the PET/OCA to the electrode pattern;
9、在小孔露出的电极出制作引线;9. Make lead wires from the electrodes exposed in the small holes;
测得加热膜电阻为2.5Ω,将引线分别连接3.7V(实际利用电压相当于1.85V)锂离子电池的正负极,经测试,70S稳定后加热膜的温度可达45℃左右(室温为22℃),符合公式T=kU2/d2R+t(K=151)。The measured resistance of the heating film is 2.5Ω, and the lead wires are respectively connected to the positive and negative electrodes of the 3.7V (actually used voltage is equivalent to 1.85V) lithium-ion battery. After testing, the temperature of the heating film can reach about 45°C after 70S stabilization (room temperature is 22°C), conforming to the formula T=kU 2 /d 2 R+t (K=151).
实施例4:Example 4:
本实施例采用ITO薄膜作为加热膜的导电层,银浆作为电极,图案设计参照图4,制备工艺如下:In this embodiment, the ITO film is used as the conductive layer of the heating film, and the silver paste is used as the electrode. The pattern design refers to Figure 4. The preparation process is as follows:
1、使用丝网印刷设备在方阻为尺寸为150mm×150mm,方阻为150Ω的ITO薄膜(方阻为400Ω/□)上印刷银浆电极图案,图案形状如图4所示,内电极间距为6mm,长108mm,宽1mm,共15条,汇流条宽8mm,银浆厚度25μm;1. Use screen printing equipment to print the silver paste electrode pattern on the ITO film with a square resistance of 150mm x 150mm and a square resistance of 150Ω (square resistance 400Ω/□). The shape of the pattern is shown in Figure 4. The distance between the internal electrodes 6mm, length 108mm, width 1mm, a total of 15, bus bar width 8mm, silver paste thickness 25μm;
2、将印刷好的电极图案置于烘箱中烘烤,使银浆固化,烘烤温度为130℃,时间为40min。2. Bake the printed electrode pattern in an oven to solidify the silver paste. The baking temperature is 130°C for 40 minutes.
3、将面积150mm×150mm厚度50μm的OCA胶与相同面积的PET贴合在一起;3. Lay OCA glue with an area of 150mm×150mm and a thickness of 50μm with PET of the same area;
4、使用激光切割设备在贴合好的PET/OCA开方形孔,孔大小为5mm×5mm,开孔的位置要保证该PET/OCA与电极层贴合后,汇流条末端露出5mm×5mm的电极;4. Use laser cutting equipment to open a square hole in the bonded PET/OCA. The size of the hole is 5mm×5mm. The position of the hole should ensure that after the PET/OCA is bonded to the electrode layer, a 5mm×5mm hole is exposed at the end of the bus bar. electrode;
5、对好位后将PET/OCA与电极图案贴合;5. After aligning the position, attach the PET/OCA to the electrode pattern;
6、在小孔露出的电极出制作引线;6. Make lead wires from the electrodes exposed in the small holes;
此种情况下,测得加热膜电阻为5Ω,将引线分别连接12V电源的正负极,经测试,55S即可达到稳定状态,此时加热膜的平均温度可达92℃左右(室温为22℃),符合公式T=kU2/d2R+t(K=70)。In this case, the measured resistance of the heating film is 5Ω. Connect the lead wires to the positive and negative poles of the 12V power supply respectively. After testing, it can reach a stable state in 55 seconds. At this time, the average temperature of the heating film can reach about 92°C (room temperature is 22°C). °C), conforming to the formula T=kU 2 /d 2 R+t (K=70).
实施例5:Example 5:
本实施例透明导电层采用单层石墨烯(250Ω/□),电极层采用10层石墨烯,制备方法与实施例1大致相同,不同之处在于:采用向石墨烯膜上继续转移石墨烯的方式,转移至第11层,停止转移,然后将上面的10层石墨烯刻蚀成图案化的电极层,或者采用直接生长多层石墨烯,再制成图案化的电极层,本实施例电极层的图案如图4所示,内电极间距为3mm,长108mm,宽1mm,共15条,汇流条宽8mm,电极(10层石墨烯)厚35nm。In this embodiment, the transparent conductive layer adopts single-layer graphene (250Ω/□), and the electrode layer adopts 10 layers of graphene. method, transfer to the 11th layer, stop the transfer, and then etch the top 10 layers of graphene into a patterned electrode layer, or directly grow multi-layer graphene, and then make a patterned electrode layer, the electrode of this embodiment The pattern of the layer is shown in Figure 4, the internal electrode spacing is 3mm, the length is 108mm, and the width is 1mm, a total of 15, the bus bar width is 8mm, and the electrode (10 layers of graphene) is 35nm thick.
此种情况下,测得加热膜电阻为2Ω,将引线分别连接1.5V电源的正负极,经测试,85S即可达到稳定状态,此时加热膜的平均温度可达34℃左右(室温为22℃),符合公式T=kU2/d2R+t(K=120)。In this case, the measured resistance of the heating film is 2Ω. Connect the lead wires to the positive and negative poles of the 1.5V power supply respectively. After testing, it can reach a stable state in 85 seconds. At this time, the average temperature of the heating film can reach about 34°C (room temperature is 22°C), conforming to the formula T=kU 2 /d 2 R+t (K=120).
实施例6:Embodiment 6:
本实施例采用4层石墨烯(62.5Ω/□)作为导电层,电极层的材料为ITO,制备方法与实施例1大致相同,不同之处在于:采用将ITO印刷于透时导电层上,电极图案化设计参见图10,内电极间距为4mm,宽1mm,共16条,汇流条宽8mm,银浆厚度25μm。In this embodiment, 4 layers of graphene (62.5Ω/□) are used as the conductive layer, and the material of the electrode layer is ITO. The electrode pattern design is shown in Figure 10. The internal electrode spacing is 4mm, the width is 1mm, and there are 16 electrodes in total. The width of the bus bar is 8mm, and the thickness of the silver paste is 25μm.
此种情况下,测得加热膜电阻为1.6Ω,将引线分别连接7.5V电源的正负极,经测试,100S即可达到稳定状态,此时加热膜的平均温度可达103℃左右(室温为22℃),符合公式T=kU2/d2R+t(K=90)。In this case, the measured resistance of the heating film is 1.6Ω. Connect the lead wires to the positive and negative poles of the 7.5V power supply respectively. After testing, it can reach a stable state in 100 seconds. At this time, the average temperature of the heating film can reach about 103°C (room temperature is 22°C), which conforms to the formula T=kU 2 /d 2 R+t (K=90).
实施例7:Embodiment 7:
实施例7与实施例3大致相同,不同在于:电极层的结构如图4所示,内电极间距为3mm,长108mm,宽1mm,共115条,汇流条宽8mm,铜铂厚度25μm。Example 7 is roughly the same as Example 3, except that the structure of the electrode layer is as shown in Figure 4, the internal electrode spacing is 3mm, the length is 108mm, and the width is 1mm, a total of 115, the bus bar width is 8mm, and the thickness of copper and platinum is 25μm.
此种情况下,测得加热膜电阻为1.7Ω,将引线分别连接12V电源的正负极,经测试,100S即可达到稳定状态,此时加热膜的平均温度可达226℃左右(室温为22℃),符合公式T=kU2/d2R+t(K=32)。In this case, the measured resistance of the heating film is 1.7Ω. Connect the lead wires to the positive and negative poles of the 12V power supply respectively. After testing, it can reach a stable state in 100 seconds. At this time, the average temperature of the heating film can reach about 226°C (room temperature is 22°C), conforming to the formula T=kU 2 /d 2 R+t (K=32).
实施例8:Embodiment 8:
实施例8与实施例1大致相同,不同在于:电极层由铜箔制成,电极层结构如图10所示,内电极间距为2mm,长108mm,宽1mm,共16条,汇流条宽8mm,铜箔厚度25μm。以单层石墨烯作为材料的导电层的方阻为250Ω/□。Embodiment 8 is roughly the same as Embodiment 1, except that the electrode layer is made of copper foil. The structure of the electrode layer is shown in Figure 10. The internal electrode spacing is 2 mm, the length is 108 mm, and the width is 1 mm. There are 16 bars in total, and the bus bar is 8 mm wide. , copper foil thickness 25μm. The square resistance of the conductive layer made of single-layer graphene is 250Ω/□.
此种情况下,测得加热膜电阻为2Ω,将引线分别连接3.7V电源的正负极,经测试,30S即可达到稳定状态,此时加热膜的平均温度可达143.8℃左右(室温为22℃),符合公式T=kU2/d2R+t(K=89)。In this case, the measured resistance of the heating film is 2Ω. Connect the lead wires to the positive and negative poles of the 3.7V power supply respectively. After testing, it can reach a stable state in 30 seconds. At this time, the average temperature of the heating film can reach about 143.8°C (room temperature is 22°C), conforming to the formula T=kU 2 /d 2 R+t (K=89).
实施例9:Embodiment 9:
本实施例采用将正电极和负电极分开设置于导电层的两面,正电极和负电极在导电层的投影如图4所示,导电层的材料采用单层石墨烯(方阻为250Ω/□),电极采用5-10层的石墨烯或者厚度为10-30μm的铜箔,其中,正负相邻内电极间距为4mm,长108mm,宽1mm,共15条,汇流条宽8mm。In this embodiment, the positive electrode and the negative electrode are separately arranged on both sides of the conductive layer, and the projection of the positive electrode and the negative electrode on the conductive layer is as shown in Figure 4, and the material of the conductive layer adopts single-layer graphene (the square resistance is 250 Ω/□ ), the electrode uses 5-10 layers of graphene or copper foil with a thickness of 10-30 μm, wherein the positive and negative adjacent internal electrode spacing is 4mm, the length is 108mm, and the width is 1mm, a total of 15, and the width of the bus bar is 8mm.
此种情况下,测得加热膜电阻为2.1Ω,将引线分别连接7.5V电源的正负极,经测试,30S即可达到稳定状态,此时加热膜的平均温度可达210℃左右(室温为22℃),符合公式T=kU2/d2R+t(K=134)。In this case, the measured resistance of the heating film is 2.1Ω. Connect the lead wires to the positive and negative electrodes of the 7.5V power supply respectively. After testing, it can reach a stable state in 30 seconds. At this time, the average temperature of the heating film can reach about 210°C (room temperature is 22°C), which conforms to the formula T=kU 2 /d 2 R+t (K=134).
实施例10:Example 10:
实施例10与实施例3大致相同,不同在于:电极层的结构如图8所示,导电层采用6层石墨烯(方阻为41.6Ω/□),电极层由铜箔制成。内电极间距为3mm,宽1mm,共9条,汇流条宽8mm,铜箔厚度25μm。Embodiment 10 is roughly the same as Embodiment 3, except that the structure of the electrode layer is shown in Figure 8, the conductive layer is made of 6 layers of graphene (square resistance is 41.6Ω/□), and the electrode layer is made of copper foil. The internal electrode spacing is 3mm, the width is 1mm, and there are 9 electrodes in total, the width of the bus bar is 8mm, and the thickness of the copper foil is 25μm.
此种情况下,测得加热膜电阻为1.9Ω,将引线分别连接1.5V电源的正负极,经测试,30S即可达到稳定状态,此时加热膜的平均温度可达86.3℃左右(室温为22℃),符合公式T=kU2/d2R+t(K=107)。In this case, the measured resistance of the heating film is 1.9Ω. Connect the lead wires to the positive and negative poles of the 1.5V power supply respectively. After testing, it can reach a stable state in 30 seconds. At this time, the average temperature of the heating film can reach about 86.3°C (room temperature is 22°C), which conforms to the formula T=kU 2 /d 2 R+t (K=107).
实施例11:Example 11:
实施例11与实施例1大致相同,不同在于:内电极和汇流条采用不同的材料,金属铂作为汇流条的材料和10层的石墨烯作为内电极的材料。单层石墨烯作为透明导电层的材料(方阻为250Ω/□)。电极层的结构如图4所示,石墨烯内电极间距为5mm,长108mm,宽1mm,共32条,汇流条宽8mm,厚度25μm。Embodiment 11 is substantially the same as Embodiment 1, except that different materials are used for the internal electrodes and bus bars, and metal platinum is used as the material for the bus bars and 10-layer graphene is used as the material for the internal electrodes. Single-layer graphene is used as the material of the transparent conductive layer (square resistance is 250Ω/□). The structure of the electrode layer is shown in Figure 4. The electrode spacing in the graphene is 5 mm, the length is 108 mm, and the width is 1 mm. There are 32 bars in total. The bus bar is 8 mm wide and 25 μm thick.
此种情况下,测得加热膜电阻为1.9Ω,将引线分别连接12V电源的正负极,经测试,30S即可达到稳定状态,此时加热膜的平均温度可达243℃左右(室温为22℃),符合公式T=kU2/d2R+t(K=96)。In this case, the measured resistance of the heating film is 1.9Ω. Connect the lead wires to the positive and negative poles of the 12V power supply respectively. After testing, it can reach a stable state in 30 seconds. At this time, the average temperature of the heating film can reach about 243°C (room temperature is 22°C), conforming to the formula T=kU 2 /d 2 R+t (K=96).
以上所述实施例的各技术特征可以进行任意的组合,为使描述简洁,未对上述实施例中的各个技术特征所有可能的组合都进行描述,然而,只要这些技术特征的组合不存在矛盾,都应当认为是本说明书记载的范围。The technical features of the above-mentioned embodiments can be combined arbitrarily. To make the description concise, all possible combinations of the technical features in the above-mentioned embodiments are not described. However, as long as there is no contradiction in the combination of these technical features, should be considered as within the scope of this specification.
以上所述实施例仅表达了本实用新型的几种实施方式,其描述较为具体和详细,但并不能因此而理解为对实用新型专利范围的限制。应当指出的是,对于本领域的普通技术人员来说,在不脱离本实用新型构思的前提下,还可以做出若干变形和改进,这些都属于本实用新型的保护范围。因此,本实用新型专利的保护范围应以所附权利要求为准。The above-mentioned embodiments only express several implementation modes of the utility model, and the description thereof is relatively specific and detailed, but it should not be understood as limiting the scope of the utility model patent. It should be noted that those skilled in the art can make several modifications and improvements without departing from the concept of the utility model, and these all belong to the protection scope of the utility model. Therefore, the scope of protection of the utility model patent should be based on the appended claims.
Claims (10)
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105433466A (en) * | 2015-05-29 | 2016-03-30 | 冯欣悦 | Kneecap |
| CN105919719A (en) * | 2016-05-31 | 2016-09-07 | 上海烯旺信息科技有限公司 | Graphene-based intelligent infrared hot compress bag system |
| CN105935326A (en) * | 2016-05-31 | 2016-09-14 | 上海烯旺信息科技有限公司 | Intelligent graphene temperature control leg guard system |
| CN105943237A (en) * | 2016-05-31 | 2016-09-21 | 上海烯旺信息科技有限公司 | Intelligent infrared protective unit system based on graphene |
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2015
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105433466A (en) * | 2015-05-29 | 2016-03-30 | 冯欣悦 | Kneecap |
| CN105919719A (en) * | 2016-05-31 | 2016-09-07 | 上海烯旺信息科技有限公司 | Graphene-based intelligent infrared hot compress bag system |
| CN105935326A (en) * | 2016-05-31 | 2016-09-14 | 上海烯旺信息科技有限公司 | Intelligent graphene temperature control leg guard system |
| CN105943237A (en) * | 2016-05-31 | 2016-09-21 | 上海烯旺信息科技有限公司 | Intelligent infrared protective unit system based on graphene |
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