CN204211695U - There is the slag bank fluid on thermo-lag drippage edge - Google Patents

There is the slag bank fluid on thermo-lag drippage edge Download PDF

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Publication number
CN204211695U
CN204211695U CN201420277527.4U CN201420277527U CN204211695U CN 204211695 U CN204211695 U CN 204211695U CN 201420277527 U CN201420277527 U CN 201420277527U CN 204211695 U CN204211695 U CN 204211695U
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CN
China
Prior art keywords
drippage
slag
cooling tube
bank fluid
edge
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
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CN201420277527.4U
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Chinese (zh)
Inventor
N.菲舍尔
H.霍佩
T.尤斯特
M.兴尼茨
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Siemens AG
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Siemens AG
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46Gasification of granular or pulverulent flues in suspension
    • C10J3/48Apparatus; Plants
    • C10J3/485Entrained flow gasifiers
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72Other features
    • C10J3/74Construction of shells or jackets
    • C10J3/76Water jackets; Steam boiler-jackets

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Industrial Gases (AREA)
  • Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)
  • Furnace Details (AREA)

Abstract

The utility model relate to a kind of there is thermo-lag drippage edge slag bank fluid, namely for original for the gasification of heat gas and molten slag are transferred to slag bank fluid for directly carrying out the quench chamber that cools, wherein in order to the drippage of described molten slag constructs thermo-lag drippage edge from the vaporizer of entrained flow gasifiers.Described drippage along preventing molten slag because backflow, the quenched water of cold air that water vapor is saturated and spray and just harden before entering into quench chamber and cause blocking.

Description

There is the slag bank fluid on thermo-lag drippage edge
Technical field
The present invention relates to a kind of for when to when carrying out partial oxidation containing the liquid fuel of ash or the solid fuel of dirt shape preferably in supercharging the gasification gas of the slag of liquid state and heat transferred to device the quench chamber of entrained flow gasification reactor from vaporizer.
Background technology
The present invention is not only suitable for reactor that vaporizer surrounds by cooling cowl but also is suitable for the reactor that those vaporizers are limited by fire-resistant furnace lining, shown in patent documentation DE4446803 and EP0677567.
At this, according to the different system introduced in this art, the slag of original gas and melting is discharged from the vaporizer of equipment for gasification dividually or jointly, as shown in DE14718131.At J.Carl, " Noell-Konversationsverfahren (Noel's transformation approach) " of P. Fritz, EF press, " Die Veredelung und Umwandlung von Kohle (refining of coal and conversion) " DGMK of 1996 and M.Schingnitz, can find the detailed description to whole technology in " GSP-Verfahren(GSP method) " this chapter in December, 2008.From vaporizer, discharge the original gas of gasification and molten slag be uninterruptedly not only prerequisite that continuously carrying out gasifies runs but also the output determining granular slag, thin slag and thin dirt, wherein the latter needs to expend a lot of time and efforts and cleans.
Document DD299893 show a kind of for by original for the gasification of heat gas and molten slag from the vaporizer of entrained flow gasifiers be discharged to subsequently, be used for cooling gas and be used for the device the fast cooling device of granulated slag.This device is made up of the cover of water cooling tube, and the bottom of described water cooling tube is surrounded by drowning pipe, and described drowning pipe is damaged by the protected medium be not heated of moisture film on inner side.Described drowning pipe passes into the pond for the original gas of cooling heat and slag and its granulation.The interference caused by the slag deposition thing in drowning pipe is shown as disadvantageous, and these slag deposition things do not allow the moisture film of homogeneous to enter.The water carried by spray has prevented slag constantly to drip along on limit at the lower of dropping body, can form obstruct thus.
Document DD288614 shows a kind of device, and wherein the vaporizer of entrained flow gasifiers and outdoor fast cooling device (Freiraumquenchung) couple together by slag bank fluid.This outdoor fast cooling device is not by the quenched water accessory that sprayed into by single-stage or multistage nozzle ring of water coolant in other words.Here also exist following dangerous, i.e. bank fluid lower is sprayed water moistening along limit, this equally also causes forming the slag deposition thing solidified.Even if when selecting resistant to elevated temperatures material, the change programme had without the thermal protection system of cooling also only demonstrates insufficient stability because temperature is very high.
Summary of the invention
From prior art, task of the present invention realizes a kind of device, its allow heat the original gas of gasification and molten slag from the vaporizer of entrained flow gasifiers reliably transfer to subsequently, for the quench chamber by spraying into the direct cooling heat medium of moisture.The temperature up to 1900 DEG C and the pressure up to 10MPa can be there is at this.
This task is solved by the device with feature described in Section 1 claim, and wherein dependent claims specifies the favourable embodiment for solving proposed task.
By arranging that thermo-lag drippage is along preventing in slag excretion body, even if still arrive drippage edge from the quenched water spraying into nozzle under the interference of uniform atomizing and therefore may cause slag deposition, described slag deposition can hinder slag to discharge equably.Namely prevent molten slag because adverse current, the quenched water of cold air that water vapor is saturated and spray and just harden before entering into quench chamber and cause blocking.
Accompanying drawing explanation
In the scope of necessity in order to understand, the present invention is set forth with reference to three accompanying drawings below by two embodiments.In figure:
Fig. 1 shows the schematic diagram of the gasifying reactor with cooling cowl and slag bank fluid,
Fig. 2 shows the first change programme according to slag bank fluid of the present invention, and
Fig. 3 shows the second change programme according to slag bank fluid of the present invention.
Reference numerals list:
The cooling cowl of 1 water percolation
2 slag bank fluid
The lower part of 2a slag bank fluid
3 quench chamber
4 chilling nozzles
5 carry the water-carriage system of water to slag bank fluid
6 discharge the water exhaust system of water from slag bank fluid
7 slag drippage edges
The slag of 8 drippages
9 vaporizers
The ramming mix of 10 heat conduction
11 slag films
The structure on 12 slag drippage edges
13 cooling tubes
14 cooling tube diameters
The minor diameter of the expansion section of 15 slag bank fluid
The major diameter of the expansion section of 16 slag bank fluid.
In these figures, identical Reference numeral represents identical element.
Embodiment
Embodiment 1:
This embodiment sees figures.1.and.2 and illustrates.That be 500MW according to the total power shown in Fig. 1, that its vaporizer is surrounded by the cooling cowl 1 of water percolation entrained flow gasifiers utilizes carbonic acid gas for the vector gas conveying Ash content fuel that is 8Ma% with the speed of 80Mg/h according to the principle of flowing conveying and together with 45000m 3the oxygen of i.N./h is converted to Raw syngas when temperature is 1650 DEG C and pressure is 4.5MPa.Amount is 11500m 3the Raw syngas of i.N./h and 5.9Mg/h, the slag amount that formed by coal ash to flow in quench chamber 3 and by spraying into water cooling to about 220 DEG C by chilling nozzle 4 through slag bank fluid 2 with the gasification temperature of mentioned 1650 DEG C.Original gas is saturated at this water vapor.Be discharged (not shown at this) from quench chamber 3 dividually by the slag of the original gas of chilling and granulation.Slag bank fluid has water-carriage system 5 and water exhaust system 6, and wherein set temperature like this and pressure, make to there will not be boiling state.Hydraulic pressure in slag bank fluid 2 is also selected higher than the hydraulic pressure in quench chamber 3, thus prevents from slag bank fluid, occur have the gasification air infiltration of heat to enter when leaking.
Described slag bank fluid is formation that is rotational symmetric, tubulose substantially, and this formation utilizes its upper part 2 to be connected on vaporizer 9 and its underpart 2a extend in quench chamber 3.Slag bank fluid is made up of the cooling tube 13 being coiled into shroud (Rohrschirm).In slag bank fluid along limit outwards and be bent downwardly.Heat-eliminating medium, particularly water coolant can be fed to cooling tube and be discharged in slag bank fluid lower part in slag bank fluid upper part.Sleeve pipe for carrying and discharge cooling fluid is arranged in quench chamber 3.Slag bank fluid has the increase portion of its diameter leap formula downwards, and wherein form drippage at minor diameter place along 7, described drippage is along being subject to thermal protection by the lower part 2a of slag bank fluid.So can select geometrical shape, thus prevent the direct-path from the tip of nozzle 4 to drippage along the whole periphery of 7 by the lower part 2a of slag bank fluid.So can select geometrical shape, thus prevent the direct-path from the tip of nozzle 4 to drippage along the ring section towards described nozzle of 7 by the lower part 2a of slag bank fluid.The cooling tube pin being configured to the slag bank fluid of shroud is fixed on drippage along scribbling ramming mix (Stampfmasse) 10, the such as SiC of heat conduction above 7.Identical ramming mix can be coated equally in the below dripped along 7 at slag.The slag flowed out from vaporizer 9 flows out with the form of slag film 11 usually via the ramming mix 10 of heat conduction.At slag drippage along on 7, the slag of outflow splits into single drop and to fall in pond through quench chamber 3 to cool and to be discharged (not shown at this).The cooling tube of slag bank fluid has the diameter of 25 to 75mm, and the ramming mix 10 of described heat conduction is coated with the thickness between 8 to 25mm.Can reliably drip in order to ensure slag, slag drippage is along separating at least one cooling tube diameter with the lower part 2a of slag bank fluid.The length of the lower part 2a of slag bank fluid is at least three cooling tube diameters, and the diameter of lower part 2a goes out greatly at least four cooling tube diameters than the diameter of upper part 2.Drippage is formed in the following manner along 7, namely between the upper part 2 and lower part 2a of slag bank fluid, so selects make 12, thus makes the central point of cooling tube 13 form triangular apex isosceles triangle down.
Embodiment 2:
This embodiment illustrates with reference to Fig. 1 and Fig. 3.The slag bank fluid 2 according to change programme 2 is used, just as shown in Figure 3 like that under condition in the same manner as in Example 1.The circle (Windung) of cooling tube 13 is flatly arranged between the top and the bottom 2 and 2a of slag bank fluid.Drip and be made up of the ramming mix 10 of coated heat conduction and the slag of solidification along 7.
The present invention is also by for transferring to for the device by spraying into quench chamber (3) that water directly carries out cooling given by original for the gasification of heat gas and the molten slag that formed by fuel ash from the vaporizer (9) of entrained flow gasifiers, wherein can there is up to 1900 DEG C, to gasify original gas and slag temperature and the pressure up to 10MPa, wherein be called as device its diameter expanded, particularly sudden enlargement of slag bank fluid, and construct thermo-lag drippage edge at this expansion section place.
Described slag drippage is along on the cooling tube that can be arranged in flatly or design with staggering.

Claims (13)

1. for original for the gasification of heat gas and the molten slag that formed by fuel ash are transferred to for the device by spraying into by multiple nozzle (4) quench chamber (3) that water directly carries out cooling from the vaporizer (9) of entrained flow gasifiers, wherein there is up to 1900 DEG C, to gasify original gas and slag temperature and the pressure up to 10MPa, wherein
-substantially the formation of tubulose form slag bank fluid (2,2a),
-described slag bank fluid is configured with the cooling tube (13) of coiling, described cooling tube by heat-eliminating medium percolation,
-described slag bank fluid has the expansion section of its diameter leap formula thereon downwards between part (2) and its underpart (2a),
-form the drippage of annular substantially along (7) at minor diameter (15) place of described expansion section,
The lower part (2a) of the described slag bank fluid of-structure like this, thus avoid the direct-path of the ring section towards described nozzle from described nozzle to described drippage edge.
2. according to device according to claim 1, it is characterized in that, so the lower part (2a) of the described slag bank fluid of structure, thus avoid the direct-path from described nozzle to the semi-ring towards described nozzle on described drippage edge.
3. according to the device according to any one of the claims, it is characterized in that, so the lower part (2a) of the described slag bank fluid of structure, thus avoid the direct-path from described nozzle to the whole ring on described drippage edge.
4. according to the device according to any one of claim 1 or 2, it is characterized in that, the cooling tube of described coiling is welded into shroud airtightly.
5. according to the device according to any one of claim 1 or 2, it is characterized in that, described cooling tube diameter (14) is between 25mm to 75mm.
6. according to the device according to any one of claim 1 or 2, it is characterized in that, described lower part (2a) expands at least two cooling tube diameters (14) relative to described upper part (2) on diameter (16).
7. according to the device according to any one of claim 1 or 2, it is characterized in that, the length in the upper lower part (2a) expanded of diameter (16) with at least three cooling tube diameters (14) of described slag bank fluid.
8. according to the device according to any one of claim 1 or 2, it is characterized in that, so the described drippage edge of structure, thus the described cooling tube of at least one circle is arranged along between (7) and described lower part (2a) at described drippage with upwards staggering.
9. according to the device according to any one of claim 1 or 2, it is characterized in that, so structure drippage edge, thus make the central point of described cooling tube (13) form triangular apex trilateral down.
10. according to the device according to any one of claim 1 or 2, it is characterized in that, the upper part (2) of described slag bank fluid is provided with ramming mix within it.
11. according to device according to claim 10, it is characterized in that, the described drippage of structure like this along (7), thus makes described ramming mix form described drippage edge, and wherein the described cooling tube of at least one circle is upwards arranged relative to described drippage edge between drippage edge and lower part (2a) with staggering.
12., according to the device according to any one of claim 1 or 2, is characterized in that, the pressure of the inner pressure ratio of described heat-eliminating medium in cooling tube in the vaporizer (9) of entrained flow gasifiers is higher.
13., according to the device according to any one of claim 1 or 2, is characterized in that, described cooling tube has the temperature and pressure avoiding described heat-eliminating medium to evaporate.
CN201420277527.4U 2013-05-28 2014-05-28 There is the slag bank fluid on thermo-lag drippage edge Expired - Fee Related CN204211695U (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102013209912.6 2013-05-28
DE102013209912.6A DE102013209912B4 (en) 2013-05-28 2013-05-28 Slag drain body with thermally protected drip edge

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CN204211695U true CN204211695U (en) 2015-03-18

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Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102016218855A1 (en) * 2016-09-29 2018-03-29 Siemens Aktiengesellschaft Freiraumquench with self-cooling, mehrmanteligem central tube

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE147181C (en)
DD237319A1 (en) * 1985-05-14 1986-07-09 Freiberg Brennstoffinst DEVICE FOR REMOVING LIQUID SLUDGE AND GAS FROM A GAS GENERATOR
DD299893A7 (en) 1989-10-18 1992-05-14 Freiberg Brennstoffinst DEVICE FOR DISPENSING HOT GAS AND SLAG
DD288614B3 (en) 1989-10-18 1993-03-25 Noell Dbi Energie Entsorgung REACTOR FOR FLOW CURING
US5324336A (en) 1991-09-19 1994-06-28 Texaco Inc. Partial oxidation of low rank coal
DE4446803C2 (en) 1994-12-24 1998-05-28 Krc Umwelttechnik Gmbh Process and device for thermal and material recycling of residual and waste materials
DE102010033323A1 (en) * 2010-08-04 2012-02-09 Siemens Aktiengesellschaft Device for quenching raw gas of entrained flow gasifier, has quencher that is arranged under reaction room, where rings of quench nozzles are arranged for injecting quench water in direction in raw gas around guide pipe

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CF01 Termination of patent right due to non-payment of annual fee
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Granted publication date: 20150318

Termination date: 20210528