CN204198666U - A kind of biomass cracking carbonizing and gasifying device - Google Patents
A kind of biomass cracking carbonizing and gasifying device Download PDFInfo
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- CN204198666U CN204198666U CN201420566738.XU CN201420566738U CN204198666U CN 204198666 U CN204198666 U CN 204198666U CN 201420566738 U CN201420566738 U CN 201420566738U CN 204198666 U CN204198666 U CN 204198666U
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
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Abstract
The utility model provides a kind of biomass cracking carbonizing and gasifying device, comprise the pulverizer sequentially passing through pipeline and connect, moisture eliminator, forming machine, cracker, first water-sealed tank, thick cleaner, pickling tank, refrigerated separation device, gas-liquid separation device, caustic treater, blower fan, decoking device, first gas phase purifying device, devulcanizer, denitrator, gas filter, the second gas phase purifying device, the second water-sealed tank, gas-holder, also comprises coke activator, oil-liquid separator, wood vinegar withdrawer, wood tar oil withdrawer, wood tar oil water distilling apparatus, water circulation tank.The utility model adopts coke activator to activate the coke that cracking produces, improve quality of activated carbon, and the various impurity eliminated in combustion gas, ensure that the seed output and quality of combustion gas, whole production process is discharged without waste gas, waste residue, waste liquid, can not pollute, be the biomass cracking carbonizing and gasifying device of a kind of combustion gas, gac and liquid fuel coproduction.
Description
Technical field
The utility model relates to a kind of biomass cracking technical field, particularly relates to a kind of biomass cracking carbonizing and gasifying device.
Background technology
Biomass are organism that plant is generated by photosynthesis, and biomass energy is the one of sun power, and biomass are more clean compared with the mineral substance energy, plant biomass comprises according to wood, firewood, weeds, pine needle leaf, crop material, cattle and sheep animal manure, edible fungi residues etc.
Biomass energy is the energy contained in biomass, is that green plants converts solar energy into chemical energy by chlorophyll and is stored in the energy of biomass inside.Biomass energy is the important energy source that human society is depended on for existence always, and it has renewable and eco-friendly dual characteristics, is subject to the attention that the whole world is general, and one of prior development direction becoming new forms of energy.
Biomass energy has recyclability, and Resources Reserve enriches, and according to estimates, the energy that plant stores every year is about equivalent to 10 times of world's main fuel consumption, and is less than 1% of its total amount as the utilization of the energy.Biomass volatile matter is high, be easy to burning, and most of low molecular hydrocarbon polymer in biomass fuel, runs into certain temperature thermal decomposition and distillation is easily ignited.
The important directions that biomass energy is shaping, cracking technique is biomass utilization, but be also faced with following defect and difficulty: 1, scale production is difficult to realize, and it is longer to be crushed to formed product consumes time from biomass material, make production be difficult to mass-producing, the use limiting system process is promoted; 2, biomass moulding, cracking product are single, be only about 25%, can not accomplish the comprehensive utilization of biomass resource, cause the waste of the energy the utilization ratio of biomass resource is lower; 3, water seal arrangement back-fire relief poor effect, safety coefficient is not high; 4, not thorough to gas sweetening, do not fully take into account the filtration of gaseous impurities, may have aqueous vapor, impurity etc., therefore the purity of its gas produced is lower; 5, gac mainly contains powdery, particle dress and formation type three types, and according to the development trend of absorbent charcoal material, absorbent charcoal material is gradually from powdery to the transformation of particulate state and moulding product; At present; the high-quality granulated active carbon that China uses needs a large amount of import; gac is produced with agricultural wastes; not only make agricultural wastes resource utilization; also solve straw pollution problem, China's existing production granulated active carbon technology and equipment utilizes biomass in the pyrolysis of fixed-bed reactor discontinuous mostly, and then carries out interval activation act; continuous seepage cannot be carried out, the difficult quality guarantee of granulated active carbon.
Summary of the invention
The purpose of this utility model is: the biomass cracking carbonizing and gasifying device of coproduction of provide a kind of for above-mentioned deficiency and can expand the scale of production, make full use of biomass cracking product, improve water seal security, gas-purification degree is high, the improve combustion gas of quality of activated carbon, gac and liquid fuel.
For achieving the above object, the technical solution of the utility model is:
A kind of biomass cracking carbonizing and gasifying device, comprises the pulverizer sequentially passing through pipeline and connect, moisture eliminator, forming machine, pyrolyzer, the first water-sealed tank, thick cleaner, pickling tank, refrigerated separation device, gas-liquid separation device, caustic treater, blower fan, decoking device, the first gas phase purifying device, devulcanizer, denitrator, gas filter, second gas phase purifying device, the second water-sealed tank, gas-holder; Also comprise coke activator, oil-liquid separator, wood vinegar withdrawer, wood tar oil withdrawer, wood tar oil water distilling apparatus, water circulation tank, coke activator is connected with bottom pyrolyzer, pickling tank, refrigerated separation device, gas-liquid separator, decoking device is connected with retrieving arrangement, and retrieving arrangement comprises oil-liquid separator, water circulation tank, oil-liquid separator is connected with wood tar oil withdrawer, wood vinegar withdrawer, and wood tar oil withdrawer is connected with wood tar oil water distilling apparatus; Pyrolyzer is cylindrical, is provided with whipping appts in pyrolyzer, and the aspect ratio of pyrolyzer is 25:1; Coke activator is cylindrical structure, the aspect ratio of coke activator is 20:1, steam entry is provided with bottom coke activator, coke activator top is provided with steam outlet, coke activator low inside is put and is welded with out foraminate leveling board, this leveling board percentage of open area is 11%-14%, and opening diameter is 0.8-1.8mm; Equidistantly four pieces of vertical plates are provided with side by side above this leveling board, this vertical plate has aperture, percentage of open area is 30%-50%, opening diameter is 0.4-0.7mm, be 0.2-0.4 apart from the distance of this leveling board and leveling board diameter ratio below vertical plate, plate washer is 0.8-1 apart from the distance at coke activator top and leveling board diameter ratio; Refrigerated separation device comprises three cooling separators side by side, be followed successively by the first cooling separator, the second cooling separator and the 3rd cooling separator, and the temperature of three cooling separators reduces gradually; Gas-liquid separation device comprises three gas-liquid separators side by side, and be followed successively by the first gas-liquid separator, the second gas-liquid separator and the 3rd gas-liquid separator, three gas-liquid separators all adopt drop type separator; First water-sealed tank is identical with the second water-sealed tank structure, sealing water is had in water-sealed tank tank body, water-sealed tank is provided with evacuated tube, inlet pipe, escape pipe, water-in, water port, inlet pipe extend into below sealing water liquid level, escape pipe extend into more than sealing water liquid level, polylith fire-proof plate is horizontally set between inlet pipe and escape pipe, and fire-proof plate is located at water-sealed tank sidewall by web member, does not all contact at the bottom of the tank deck of fire-proof plate and water-sealed tank and tank.
Preferably, fire-proof plate is 5 pieces, is evenly spacedly up and down arranged in water-sealed tank, and topmost one piece of fire-proof plate is positioned at the above 30cm of sealing water, and bottom one piece of fire-proof plate and the height distance at the bottom of water-sealed tank tank are 25cm.
Preferably, described thick cleaner is cyclonic separator.
The advantage of biomass cracking carbonizing and gasifying device of the present utility model has: the discharge 1, not having flue dust in cracking process, and wood tar oil, wood vinegar are carried out Separation and Recovery, whole production process is discharged without waste gas, waste residue, waste liquid, not only can not pollute air and soil, and ensure that the seed output and quality of carbonized gas, facilitate environment protection and harmonious economy; 2, multiple cracking still is placed in the airtight heating pyrolyze of pyrolyzer together, improves industrial scale; 3, the biomass charcoal, gasoline, diesel oil, wood pitch, pyroligneous liquor, the biological fuel gas that go out of this device fabrication, all have very high utility value, combustion gas is for resident's cooking gas, generating, industrial heat resources gas; Biomass charcoal can be used for non-ferrous metal metallurgy and oxidation inhibitor, and powdered carbon makes the sorbent material of gac for sewage and foul odour, of many uses in industry and environmental protection; Wood vinegar, as plant growth agent and fodder additives, can improve peanut, corn, vegetable crop 10-15%, and is good wormer, bio-preservative; Wood tar oil: be better than coal tar is a kind of valuable industrial chemicals, at present for paint and fuel industry, rubber industry, utilizes the method for distillation wood tar oil can also be changed into biological gasoline, diesel oil and wood pitch, of many uses; 4, adopt multiple stage, continuous purification equipment, eliminate the various impurity in combustion gas, obtain meeting the high-quality combustion gas that combustion gas specifies; 5, produce gac with biomass material, the gac quality better of preparation, save energy, reduce costs and decrease the waste of biomass material.
Accompanying drawing explanation
Fig. 1 is the structural representation of biomass cracking carbonizing and gasifying device of the present utility model;
Accompanying drawing is detailed as follows: 1, pulverizer; 2, moisture eliminator; 3, forming machine; 4, pyrolyzer; 5, the first water-sealed tank; 6, thick cleaner; 7, pickling tank; 8, the first cooling separator; 9, the second cooling separator; 10, the 3rd cooling separator; 11, the first gas-liquid separator; 12, the second gas-liquid separator; 13, the 3rd gas-liquid separator; 14, caustic treater; 15, blower fan; 16, decoking device; 17, the first gas phase purifying device; 18, devulcanizer; 19, denitrator; 20, gas filter; 21, the second gas phase purifying device; 22, the second water-sealed tank; 23, gas-holder; 24, oil-liquid separator; 25, wood vinegar withdrawer; 26, wood tar oil withdrawer; 27, wood tar oil water distilling apparatus; 28, vertical plate; 29, coke activator; 30, leveling board; 31, steam entry; 32, steam outlet.
Embodiment
Below in conjunction with drawings and Examples, the utility model is further illustrated.
The structure of biomass cracking carbonizing and gasifying device of the present utility model as shown in Figure 1, comprises the pulverizer 1 sequentially passing through pipeline and connect, moisture eliminator 2, forming machine 3, pyrolyzer 4, the first water-sealed tank 5, thick cleaner 6, pickling tank 7, refrigerated separation device, gas-liquid separation device, caustic treater 14, blower fan 15, decoking device 16, first gas phase purifying device 17, devulcanizer 18, denitrator 19, gas filter 20, the second gas phase purifying device 21, second water-sealed tank 22, gas-holder 23, also comprises coke activator 29, oil-liquid separator 24, wood vinegar withdrawer 25, wood tar oil withdrawer 26, wood tar oil water distilling apparatus 27, water circulation tank, coke activator 29 is connected with bottom pyrolyzer 4, pickling tank 7, refrigerated separation device, gas-liquid separator, decoking device 16 is connected with retrieving arrangement, and retrieving arrangement comprises oil-liquid separator 24, water circulation tank, oil-liquid separator 24 and wood tar oil withdrawer 26, wood vinegar withdrawer 25 connects, and wood tar oil withdrawer 26 is connected with wood tar oil water distilling apparatus 27.Pyrolyzer 4 is cylindrical, is provided with whipping appts in pyrolyzer 4, and the aspect ratio of pyrolyzer 4 is 25:1.
Coke activator 29 is cylindrical structure, the aspect ratio of coke activator 29 is 20:1, steam entry 31 is provided with bottom coke activator 29, coke activator 29 top is provided with steam outlet 32, coke activator 29 low inside is put and is welded with out foraminate leveling board 30, this leveling board 30 percentage of open area is 11%-14%, and opening diameter is 0.8-1.8mm; Equidistantly four pieces of vertical plates 28 are provided with side by side above this leveling board 30, this vertical plate 28 has aperture, percentage of open area is 30%-50%, opening diameter is 0.4-0.7mm, be 0.2-0.4 apart from the distance of this leveling board 30 and leveling board 30 diameter ratio below vertical plate 28, vertical plate 28 is 0.8-1 apart from the distance at coke activator 29 top and leveling board 30 diameter ratio.
Tripping device comprises three cooling separators side by side, be followed successively by the first cooling separator 8, second cooling separator 9 and the 3rd cooling separator 10, and the temperature of three cooling separators reduces gradually; Gas-liquid separation device comprises three gas-liquid separators side by side, is followed successively by the first gas-liquid separator 11, second gas-liquid separator 12 and the 3rd gas-liquid separator 13, three gas-liquid separators all adopt drop type separator; First water-sealed tank 5 is identical with the second water-sealed tank 22 structure, sealing water is had in water-sealed tank tank body, water-sealed tank is provided with evacuated tube, inlet pipe, escape pipe, water-in, water port, inlet pipe extend into below sealing water liquid level, and escape pipe extend into more than sealing water liquid level, and polylith fire-proof plate is horizontally set between inlet pipe and escape pipe, fire-proof plate is located at water-sealed tank sidewall by web member, does not all contact at the bottom of the tank deck of fire-proof plate and water-sealed tank and tank.
Fire-proof plate is 5 pieces, is evenly spacedly up and down arranged in water-sealed tank, and topmost one piece of fire-proof plate is positioned at the above 30cm of sealing water, and bottom one piece of fire-proof plate and the height distance at the bottom of water-sealed tank tank are 25cm.The stirring velocity of whipping appts is 8 rpms, can shorten the production time, enhancing productivity by stirring.Thick cleaner can adopt cyclonic separator, and product market is on sale.First water-sealed tank enters in pyrolyzer for the air when device quits work and causes return-air accident, the effect of the second water-sealed tank prevents gas backstreaming in gas-holder and can clean gas, fire-proof plate prevents air inlet splashing from gushing out, sealing water liquid fluctuating between fire-proof plate is little, can also improve the situation band of gas water excess.
The principle of work of this device is: 1. pulverized by pulverizer 1 pair of material, makes material reach particle size required by system cloud gray model; If but the size of material own is less and even, then without the need to pulverizing again, such as rice husk, sawdust etc.2. being dried by moisture eliminator 2 makes material water ratio remain between 3 ~ 12%.3. utilize forming machine 3 that material is made into desired shape after drying, these shapes both can be bar-shaped, spherical, and also can be block and particulate state, shape be chosen and determined according to the purposes of final gained biomass charcoal.Generally for and enable forming machine continuously shaped, choose bar-shaped this shape, the charcoal of such gained is carbon rod.The mold temperature of forming machine is 200-400 DEG C, is obtained by electrically heated, and forming pressure is about 8 tons.4. sent in pyrolyzer 4 by shaping material and carry out cracking, be provided with whipping appts in pyrolyzer 4, molding materials adds in pyrolyzer 4, carries out heating pyrolyze by pyrolyzer 4 pairs of materials.In cracking process, stirred by whipping appts, when stirring, be with the speed of per minute 8 turns, turning over materials lentamente, makes the even cracking of material.Cracking is undertaken by the mode progressively heated up and is finally made temperature remain between 700 ~ 1000 DEG C, and pyrolysis time is 80-200 minute.Gaseous state and solid-state resultant is obtained by thermo-cracking.After cracking completes, the solid-state resultant (coke) of cracking gained is sent in coke activator 29, passes into the water vapour being preheated to 250 ~ 6500 DEG C, in coke activator 29, activate 50-180 minute at 400 ~ 800 DEG C of temperature in coke activator 29; Meanwhile gaseous product carries out corresponding subsequent disposal.5. the gas produced during cracking enters thick cleaner 6 by preventing return-air first water-sealed tank 5, to remove solid particulate in gas, gas is purified further.6. the gas purified through thick cleaner 6 enters in pickling tank 7 and carries out pickling, cools simultaneously, to remove wood tar oil and wood vinegar, prevents wood tar oil and wood vinegar occluding device.Pickle solution be acetic acid, pickle solution in acetic acid pond is pumped into spray washing in pickling tank through acid, after washing liq is separated in pickling tank, acetic acid returns in vinegar liquid pool and carries out recycle, wood tar oil and wood vinegar enter in oil-liquid separator 24 and are separated, wood tar oil enters wood tar oil withdrawer 26, and wood vinegar enters wood vinegar withdrawer 25.7. the gas temperature through overpickling is also higher, must cool it, to reduce gas temperature and to be separated wood tar oil and wood vinegar further, gas enters successively in the first cooling separator 8, second cooling separator 9 and the 3rd cooling separator 10 and carries out three grades of coolings, first cooling separator 8, second cooling separator 9, the 3rd cooling separator 10 are cooled to high-temperature gas by cooling circulating water, and a large amount of tar, the pyroligneous liquor mixture input oil-liquid separator 24 that will produce in temperature-fall period, thus obtain gas of lowering the temperature; The wood tar oil cooled down and wood vinegar enter fluid and are separated in 24 devices and are separated, and wood tar oil enters wood tar oil withdrawer 26, and wood vinegar enters vinegar liquid withdrawer 25.8. cooled gas enters the first gas-liquid separator 11, second gas-liquid separator 12, the 3rd gas-liquid separator 13 carries out gas-liquid separation, wood tar oil through separating and wood vinegar enter in oil-liquid separator 24 and are separated, wood tar oil enters wood tar oil withdrawer 26, and wood vinegar enters wood vinegar withdrawer 25.9. gas enters in caustic treater 14 and carries out alkali liquid washing, the acidic substance contained in removing gas, prevent it to the corrosion of equipment, alkaline wash adopt be 3% NaOH solution, alkali lye in alkali lye pond is sent in caustic treater through lye pump and carries out spray washing to gas, alkaline wash after spray returns alkali lye pond internal recycle and uses, and regular replenishment alkali, keep alkali lye pH value to be greater than 8.10. gas is sent in decoking device 16 through blower fan 15, the wood tar oil further in removing gas, then purifies gas through the first gas phase purifying device, is then removed sulphur, the nitrogen in gas successively by devulcanizer 18, denitrator 19.11. gases remove other impurity in gas through gas filter 20.12. gases enter the second gas phase purifying device 21 pairs of gases and purify.13. gases enter gas-holder 23 finally by the second water-sealed tank 22.Gas in gas-holder 23 can generate electricity for generating set, also can for resident's cooking and heating gas.14. wood tar oil withdrawers 26 are connected with wood tar oil water distilling apparatus 27, utilize the method for distillation that wood tar oil is changed into biological gasoline, diesel oil and wood pitch.
The utility model is airtight heating pyrolyze in cracker, does not have the discharge of flue dust; Material is placed in the airtight heating pyrolyze of pyrolyzer, utilizes whipping appts to stir and accelerate cracking, thus expand industrial scale; Utilize coke activator activate the coke that cracking produces and obtain gac, improve quality of activated carbon; Utilize biomass to produce biomass charcoal, wood tar oil, pyroligneous liquor, biological fuel gas, wood tar oil, wood vinegar are carried out Separation and Recovery, and distillation process is carried out to wood tar oil, obtain gasoline, diesel oil, wood pitch, thus biomass resource is made full use of; Adopt multiple stage, continuous purification equipment, eliminate the various impurity in combustion gas, obtain meeting the high-quality combustion gas that combustion gas specifies.Whole production process is discharged without waste gas, waste residue, waste liquid, not only can not pollute, and ensure that the seed output and quality of combustion gas, utilize biomass material to produce gac, improving quality of activated carbon, is the biomass cracking carbonizing and gasifying device of a kind of combustion gas, gac and liquid fuel coproduction.
Claims (3)
1. a biomass cracking carbonizing and gasifying device, comprises the pulverizer sequentially passing through pipeline and connect, moisture eliminator, forming machine, pyrolyzer, the first water-sealed tank, thick cleaner, pickling tank, refrigerated separation device, gas-liquid separation device, caustic treater, blower fan, decoking device, first gas phase purifying device, devulcanizer, denitrator, gas filter, the second gas phase purifying device, second water-sealed tank, gas-holder, is characterized in that:
Also comprise coke activator, oil-liquid separator, wood vinegar withdrawer, wood tar oil withdrawer, wood tar oil water distilling apparatus, water circulation tank, coke activator is connected with bottom pyrolyzer, pickling tank, refrigerated separation device, gas-liquid separator, decoking device is connected with retrieving arrangement, and retrieving arrangement comprises oil-liquid separator, water circulation tank, oil-liquid separator is connected with wood tar oil withdrawer, wood vinegar withdrawer, and wood tar oil withdrawer is connected with wood tar oil water distilling apparatus;
Pyrolyzer is cylindrical, is provided with whipping appts in pyrolyzer, and the aspect ratio of pyrolyzer is 25:1;
Coke activator is cylindrical structure, the aspect ratio of coke activator is 20:1, steam entry is provided with bottom coke activator, coke activator top is provided with steam outlet, coke activator low inside is put and is welded with out foraminate leveling board, this leveling board percentage of open area is 11%-14%, and opening diameter is 0.8-1.8mm; Equidistantly four pieces of vertical plates are provided with side by side above this leveling board, this vertical plate has aperture, percentage of open area is 30%-50%, opening diameter is 0.4-0.7mm, be 0.2-0.4 apart from the distance of this leveling board and leveling board diameter ratio below vertical plate, plate washer is 0.8-1 apart from the distance at coke activator top and leveling board diameter ratio;
Refrigerated separation device comprises three cooling separators side by side, be followed successively by the first cooling separator, the second cooling separator and the 3rd cooling separator, and the temperature of three cooling separators reduces gradually; Gas-liquid separation device comprises three gas-liquid separators side by side, and be followed successively by the first gas-liquid separator, the second gas-liquid separator and the 3rd gas-liquid separator, three gas-liquid separators all adopt drop type separator; First water-sealed tank is identical with the second water-sealed tank structure, sealing water is had in water-sealed tank tank body, water-sealed tank is provided with evacuated tube, inlet pipe, escape pipe, water-in, water port, inlet pipe extend into below sealing water liquid level, escape pipe extend into more than sealing water liquid level, polylith fire-proof plate is horizontally set between inlet pipe and escape pipe, and fire-proof plate is located at water-sealed tank sidewall by web member, does not all contact at the bottom of the tank deck of fire-proof plate and water-sealed tank and tank.
2. biomass cracking carbonizing and gasifying device according to claim 1, it is characterized in that: fire-proof plate is 5 pieces, evenly spacedly up and down be arranged in water-sealed tank, topmost one piece of fire-proof plate is positioned at the above 30cm of sealing water, and bottom one piece of fire-proof plate and the height distance at the bottom of water-sealed tank tank are 25cm.
3. biomass cracking carbonizing and gasifying device according to claim 1, is characterized in that: described thick cleaner is cyclonic separator.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201420566738.XU CN204198666U (en) | 2014-09-23 | 2014-09-23 | A kind of biomass cracking carbonizing and gasifying device |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201420566738.XU CN204198666U (en) | 2014-09-23 | 2014-09-23 | A kind of biomass cracking carbonizing and gasifying device |
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| CN204198666U true CN204198666U (en) | 2015-03-11 |
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| CN201420566738.XU Withdrawn - After Issue CN204198666U (en) | 2014-09-23 | 2014-09-23 | A kind of biomass cracking carbonizing and gasifying device |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104232124A (en) * | 2014-09-23 | 2014-12-24 | 济南联星石油化工有限公司 | Biomass pyrolysis carbonization gasification device |
| CN108314039A (en) * | 2017-01-17 | 2018-07-24 | 郭伟生 | The continuously carbonizing activation equipment and technique of grain biomass material based on fluid bed |
| CN111804272A (en) * | 2020-06-23 | 2020-10-23 | 生态环境部南京环境科学研究所 | Preparation and activation integrated device of charcoal adsorbent for organic sewage treatment |
-
2014
- 2014-09-23 CN CN201420566738.XU patent/CN204198666U/en not_active Withdrawn - After Issue
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104232124A (en) * | 2014-09-23 | 2014-12-24 | 济南联星石油化工有限公司 | Biomass pyrolysis carbonization gasification device |
| CN108314039A (en) * | 2017-01-17 | 2018-07-24 | 郭伟生 | The continuously carbonizing activation equipment and technique of grain biomass material based on fluid bed |
| CN111804272A (en) * | 2020-06-23 | 2020-10-23 | 生态环境部南京环境科学研究所 | Preparation and activation integrated device of charcoal adsorbent for organic sewage treatment |
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| C14 | Grant of patent or utility model | ||
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| AV01 | Patent right actively abandoned |
Granted publication date: 20150311 Effective date of abandoning: 20160427 |
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